CN107758061A - Communication intelligence optical maintenance tool box - Google Patents

Communication intelligence optical maintenance tool box Download PDF

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Publication number
CN107758061A
CN107758061A CN201711238683.4A CN201711238683A CN107758061A CN 107758061 A CN107758061 A CN 107758061A CN 201711238683 A CN201711238683 A CN 201711238683A CN 107758061 A CN107758061 A CN 107758061A
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China
Prior art keywords
weight
parts
upper shell
tool box
maintenance tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201711238683.4A
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Chinese (zh)
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CN107758061B (en
Inventor
王艺旋
付静
石国松
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Nanyang Power Supply Co of State Grid Henan Electric Power Co Ltd
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Nanyang Power Supply Co of State Grid Henan Electric Power Co Ltd
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Priority to CN201711238683.4A priority Critical patent/CN107758061B/en
Publication of CN107758061A publication Critical patent/CN107758061A/en
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Publication of CN107758061B publication Critical patent/CN107758061B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D25/00Details of other kinds or types of rigid or semi-rigid containers
    • B65D25/02Internal fittings
    • B65D25/04Partitions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B21/00Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
    • G08B21/02Alarms for ensuring the safety of persons
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B25/00Alarm systems in which the location of the alarm condition is signalled to a central station, e.g. fire or police telegraphic systems
    • G08B25/01Alarm systems in which the location of the alarm condition is signalled to a central station, e.g. fire or police telegraphic systems characterised by the transmission medium
    • G08B25/10Alarm systems in which the location of the alarm condition is signalled to a central station, e.g. fire or police telegraphic systems characterised by the transmission medium using wireless transmission systems
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Mechanical Engineering (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of communication intelligence optical maintenance tool box,Including outer container,The outer container includes upper shell,The upper shell bottom is provided with lower house,The upper shell is flexibly connected with lower house by hinge,Solar panel is provided with the top of the upper shell,Battery is provided with inside the upper shell,The battery side is provided with converter,The converter side is provided with GPS locator and bottom is provided with programmable controller,The programmable controller is provided with operating switch and cancel switch,The cancel switch is at the top of operating switch,The programmable controller side is provided with alarm,The present invention is by provided with GPS locator and signal conveyer,User can be deployed to search and rescue by the position signalling that GPS locator sends in order to the staff of server internal,So as to improve the security of user,Make the present invention that there is higher practicality.

Description

Communication intelligence optical maintenance tool box
Technical field
The present invention relates to technical field of electric power, more particularly to a kind of communication intelligence optical maintenance tool box.
Background technology
Electric power overhaul is a job with higher risk, due to undermanned, many electric power overhaul persons Need to carry out service work alone, be also exactly which results in electric power because some electric power overhaul regions are more remote When if maintenance person occurs surprisingly to cause stupor when carrying out service work, can not effectively be rescued.
Therefore, it is necessary to solve the above problems to invent a kind of communication intelligence optical maintenance tool box.
The content of the invention
It is an object of the invention to provide a kind of communication intelligence optical maintenance tool box, to solve to carry in above-mentioned background technology The problem of going out, while the casing satisfactory mechanical property of the present invention, water-fast, high temperature resistant, corrosion-resistant, adhesive force is strong.
To achieve the above object, the present invention provides following technical scheme:A kind of communication intelligence optical maintenance tool box, including Outer container, the outer container include upper shell, and the upper shell bottom is provided with lower house, and the upper shell is lived with lower house by hinge Dynamic connection, the upper shell top are provided with solar panel, battery, the battery side are provided with inside the upper shell Provided with converter, the converter side is provided with GPS locator and bottom is provided with programmable controller, the PLC technology Device is provided with operating switch and cancel switch, and the cancel switch is at the top of operating switch, the programmable controller side Provided with alarm, the alarm side is provided with signal conveyer, and communicator, the lower casing are provided with the top of the signal conveyer Internal portion is provided with baffler, and the baffler both sides are equipped with well, are provided with piston in the well, the piston enters Gas port is provided with check valve, the electric expansion bar for pulling piston rod is provided with the well, the electric expansion bar is with may be programmed Controller connects.
Preferably, the signal conveyer connection end is provided with signal receiver, and the signal receiver is in server Portion.
Preferably, the first overcoat is provided with the inside of the upper shell, the second overcoat is provided with the inside of the lower house.
Preferably, first overcoat, the second overcoat and baffler are made by sponge material.
Preferably, the battery, GPS locator, alarm, signal conveyer and communicator be and programmable controller It is electrically connected with.
Preferably, the outer container side is provided with lock, and handle is provided between the lock.
Preferably, the solar panel is electrically connected with by converter and battery.
The outer surface of the upper shell and lower house is coated with abrasion-proof insulating layer, is made up of following components and its content: Epoxy resin 30-44 parts by weight, PMA 2-5 parts, chloroform 5-10 parts, coupling agent 3.8-5.5 parts by weight, nanometer Oxide 12-17 parts by weight, polydiene base the third alkyl dimethyl ammonium chloride 4.5-5.6 parts by weight, tributyl phosphate 2.8-3.3 weight Part, waterproofing agent 6.7-7.2 parts by weight, heat-resistant agent 5.8-6.3 parts by weight, corrosion-resistant agent 8.9-9.6 parts by weight, corrosion inhibiter 7.3- 8.8 parts by weight, acetone 20-26 parts by weight, water 46-55 parts by weight.
Further, the coupling agent is APTES or 3- glycydoxy front threes TMOS.
Further, the nano-oxide is the mixing of nano magnesia, nano silicon, nano titanium oxide Thing, weight compare nano magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
Further, the waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Firmly Resin acid calcium is 7:3.
Further, the corrosion-resistant agent is the one or more in hexa, cinnamic acid, poly-aspartate.
Further, the corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, and weight compares hexa-methylene Tetramine:Cinnamic acid:Poly-aspartate is 2:3:5.
Further, the corrosion inhibiter is sodium chromate or natrium nitrosum.
Further, the heat-resistant agent is one kind in N-phenylmaleimide or Dacthal Or two kinds.
Further, the heat-resistant agent is the mixing of N-phenylmaleimide and Dacthal Thing, weight compare N-phenylmaleimide:Dacthal is 4:6.
Further, the preparation method of described abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 12-17 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 13-14h, with 20-26 parts by weight Acetone mixing, add 3.8-5.5 parts by weight coupling agent, be placed in magnetic stirring apparatus and stir, in 20 DEG C -25 DEG C of condition Under, rotating speed 300-400r/min, mixing time 2-4h, filter, 6-8h is dried in 75-80 DEG C of baking oven, grind, obtain table The nano-oxide powder that face is modified;
2)The PMA of 2-5 parts by weight is added in the chloroform of 5-10 parts by weight and mixed, is placed in magnetic agitation In device, under conditions of 20 DEG C -25 DEG C, rotating speed 200-300r/min, mixing time 40-45min, mixed liquor one is obtained;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds The water of 46-55 parts by weight and the tributyl phosphate of 2.8-3.3 parts by weight are placed in ball milling in ball mill, rotating speed 150-180r/ Min, time 10-12h, obtain mixed liquor two;
4)To step 3)Epoxy resin, the polydiene of 4.5-5.6 parts by weight of 30-44 parts by weight are added in obtained mixed liquor two The alkyl dimethyl ammonium chloride of base third, is placed in high-speed mixer, and regulation rotating speed is 700-900r/min, mixing time 15-30min, Then add the waterproofing agent of 6.7-7.2 parts by weight, the heat-resistant agent of 5.8-6.3 parts by weight, 8.9-9.6 parts by weight corrosion-resistant agent, The corrosion inhibiter of 7.3-8.8 parts by weight, regulation rotating speed are 400-500r/min, mixing time 5-8h, produce target product;
5)By step 4)Obtained target product shakes 10-12h, amplitude 50mm, rotating speed 100-200r/ in bottle swingging machine Min, filter, produce final product.
The beneficial effects of the invention are as follows:Epoxy resin is as etch-proof material, and not only water resistant, leakage resistance are good, intensity It is higher, while adhesive force is strong, dielectric properties are good, and deformation retract rate is small, can improve the stability and pliability of material.The present invention The epoxy resin used has a good mechanical performance for novolac epoxy resin, and heat resistance is more preferable.
Using coupling agent modified nano-oxide, the lipophile of nano-particle is improved, is made it easier in organic solvent It is scattered, strengthen the compatibility between molecule, show good interfacial phenomenon, improve the mechanical property of material.Polydiene base third Alkyl dimethyl ammonium chloride and nanometer oxide particle organically combine, improve the corrosion resistance of material, while reinforced epoxy is consolidated Change effect.
Chloroform dissolves PMA as solvent.PMA has anti-microbial property and ultraviolet screener Performance, combined with epoxy resin, improve the adhesive force of coating, acted synergistically with nano-oxide, extend the weatherability of material.Phosphorus Sour tributyl reduces surface tension, suppresses foam and produce, improve chemical stability as defoamer.
Waterproofing agent strengthens hydrophobicity, improves the impervious moisture protection of material, and corrosion-resistant agent improves material acid-proof alkaline, increases Extensive chemical stability, extend the service life of material.Heat-resistant agent can be acceleratedCrystalline rate, increase crystal density and promote crystal grain chi Very little miniaturization, significantly improve the heat distortion temperature of coating.Molecular orientation in corrosion inhibiter is arranged in metal surface, forms one layer and dredges Moisture film, isolation hydrone contact with metal surface, and so as to play inhibition, anti-rust action, acetone is organic solvent.
The present invention is modified to nano-oxide, and nano-oxide has a significant cooperative effect, and various materials are organic With reference to playing the cooperative effect of each component, obtained abrasion-proof insulating layer, mechanical performance and excellent insulating property, water-fast, resistance to height Warm, resistant to chemical etching, adhesive force is strong, can keep stability for a long time in acid or alkali environment, can be in -50 DEG C to 100 DEG C of ring Used for a long time in border, excellent combination property.The coating can form one layer of fine and close diaphragm on an iron rake with three to six teeth surface, etch-proof same When, the effect of antirust is played, extends the service life of electric power tower.
The technique effect and advantage of the present invention:The present invention is by provided with GPS locator and signal conveyer, in order to service Staff inside device can deploy to search and rescue by the position signalling that GPS locator sends over to user, so as to improve The security of user, make the present invention that there is higher practicality, by provided with the first overcoat, the made of sponge material Two overcoats and baffler, in order to effectively protect the instrument inside well, the present invention is prevented in carrying or transportation, Instrument in well collides with outer container, causes instrument or situation about damaging of the invention, so as to improve the use of the present invention In the life-span, avoid the unnecessary economic loss of user.
Brief description of the drawings
Fig. 1 is the overall structure diagram of the present invention.
Fig. 2 is the upper shell structural representation of the present invention.
Fig. 3 is the lower house structural representation of the present invention.
Fig. 4 is the programmable controller structural representation of the present invention.
In figure:1 outer container, 2 upper shells, 3 lower houses, 4 solar panels, 5 batteries, 6 converters, 7 GPS locators, 8 programmable controllers, 9 operating switches, 10 cancel switches, 11 alarms, 12 signal conveyers, 13 communicators, 14 bafflers, 15 Well, 16 first overcoats, 17 second overcoats, 18 locks, 19 handles.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made Embodiment, belong to the scope of protection of the invention.
It is described outer the invention provides a kind of communication intelligence optical maintenance tool box as Figure 1-4, including outer container 1 Case 1 includes upper shell 2, and the bottom of upper shell 2 is provided with lower house 3, and the upper shell 2 is connected with lower house 3 by hinge activity Connect, the top of upper shell 2 is provided with solar panel 4, and the inside of upper shell 2 is provided with battery 5, the battery 5 one Side is provided with converter 6, and the side of converter 6 is provided with GPS locator 7 and bottom is provided with programmable controller 8, described to compile Range controller 8 is provided with operating switch 9 and cancel switch 10, and the cancel switch 10 is described to compile located at the top of operating switch 9 The side of range controller 8 is provided with alarm 11, and the side of alarm 11 is provided with signal conveyer 12, and the signal conveyer 12 pushes up Portion is provided with communicator 13, and the inside of lower house 3 is provided with baffler 14, and the both sides of baffler 14 are equipped with well 15, use In being provided with piston 22 in storage service kit, the well, the air inlet of the piston is provided with check valve 23, the well Interior to be provided with the electric expansion bar 21 for pulling piston rod, the electric expansion bar is connected with programmable controller.After casing is closed, The sealing ring set between casing plays sealing function, and the vertical section position taper of sealing ring, is controlled, can compiled by Digiplex Range controller control electric expansion bar pulls piston rod, and the air sucker in casing, the interior formation negative pressure of casing is annular Height on the outside of sealing ring is higher than inner side, and O-ring seal is inwardly squeezed between upper shell and lower house, suction function sealing Effect is good, while the air in casing is absorbed piston by piston, less air is contacted with valuable equipment, and equipment preserves good It is good.
The connection end of signal conveyer 12 is provided with signal receiver, and the signal receiver is located at server internal, institute State the inner side of upper shell 2 and be provided with the first overcoat 16, the inner side of lower house 3 is provided with the second overcoat 17, first overcoat 16th, the second overcoat 17 and baffler 14 are made by sponge material, in order to effectively protect the instrument inside well 15, prevent Only in carrying or transportation, the instrument in well 15 collides the present invention with outer container 1, causes instrument or present invention damage Situation, so as to improve the service life of the present invention, avoid the unnecessary economic loss of user, the battery 5, GPS locator 7, alarm 11, signal conveyer 12 and communicator 13 are electrically connected with programmable controller 8, the outer container 1 Side is provided with lock 18, is provided with handle 19 between the lock 18, the solar panel 4 passes through converter 6 and battery 5 It is electrically connected with, storage is stored in order to which solar panel 4 absorbs solar energy and converted solar energy into electrical energy by converter 6 In battery 5.
This practical operation principle:When user carries out service work, outer container 1 is opened, presses operating switch 9, GPS locator 7 start working, and the instrument that user takes out needs from well 15 proceeds by service work, when GPS locator 7 in real time to Programmable controller 8 sends signal, and programmable controller 8 is sent out by signal conveyer 12 to the signal receiver of server internal Position signalling is sent, when programmable controller 8 detects that GPS locator 7 does not move in setting time, programmable controller 8 Alarm 11 is controlled to carry out sound and light alarm, now user can press cancel switch 10, and programmable controller 8 controls alarm 11 stop being alarmed, and when not pressing cancel switch 10 in user's setting time, programmable controller 8 is conveyed by signal Device 12 sends position signalling to the signal receiver of server internal, so as to remind at the staff user of server internal In abnormality, the staff of server contacts user, when can not contact, the work of server internal by communicator 13 The position signalling that personnel are sended over by GPS locator 7 deploys to search and rescue.
The abrasion-proof insulating layer is made up of following components and its content:The parts by weight of epoxy resin 30, PMA 2 Part, 5 parts of chloroform, the parts by weight of APTES 3.8, the parts by weight of nano-oxide 12, polydiene base third The parts by weight of alkyl dimethyl ammonium chloride 4.5, the parts by weight of tributyl phosphate 2.8, the parts by weight of waterproofing agent 6.7, N-phenylmaleimide 5.8 Parts by weight, the parts by weight of hexa 8.9, the parts by weight of sodium chromate 7.3, the parts by weight of acetone 20, the parts by weight of water 46.
The nano-oxide is nano magnesia, nano silicon, the mixture of nano titanium oxide, and weight ratio is received Rice magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Calcium stearate is 7:3。
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 12 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 13h, mixed with the acetone of 20 parts by weight Close, add the coupling agent of 3.8 parts by weight, be placed in magnetic stirring apparatus and stir, under conditions of 20 DEG C -25 DEG C, rotating speed 300r/ Min, mixing time 2h, filter, 6h is dried in 75 DEG C of baking ovens, grind, obtain the nano-oxide powder of surface modification;
2)The PMA of 2 parts by weight is added in the chloroform of 5 parts by weight and mixed, is placed in magnetic stirring apparatus, Under conditions of 20 DEG C -25 DEG C, rotating speed 200r/min, mixing time 40min, mixed liquor one is obtained;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 46 The water of parts by weight and the tributyl phosphate of 2.8 parts by weight are placed in ball milling in ball mill, rotating speed 150r/min, time 10h, obtain To mixed liquor two;
4)To step 3)The epoxy resin of 30 parts by weight, the polydiene base the third two of 4.5 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 700r/min, mixing time 15min, then adds 6.7 weights The waterproofing agent of part, the heat-resistant agent of 5.8 parts by weight, corrosion-resistant agent, the corrosion inhibiter of 7.3 parts by weight of 8.9 parts by weight are measured, adjusts rotating speed For 400r/min, mixing time 5h, target product is produced;
5)By step 4)Obtained target product shakes 10h, amplitude 50mm, rotating speed 100r/min in bottle swingging machine, filters, Produce final product.
Embodiment two
A kind of abrasion-proof insulating layer, is made up of following components and its content:2.5 parts of the parts by weight of epoxy resin 32, PMA, 6 parts of chloroform, the parts by weight of APTES 4, the parts by weight of nano-oxide 13, the dimethyl of polydiene base third The parts by weight of ammonium chloride 4.7, the parts by weight of tributyl phosphate 2.9, the parts by weight of waterproofing agent 6.8, Dacthal 5.9 Parts by weight, the parts by weight of cinnamic acid 9, the parts by weight of natrium nitrosum 7.5, the parts by weight of acetone 21, the parts by weight of water 48.
The nano-oxide is nano magnesia, nano silicon, the mixture of nano titanium oxide, and weight ratio is received Rice magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Calcium stearate is 7:3。
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 13 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 13.5h, the acetone with 21 parts by weight Mixing, the APTES of 4 parts by weight is added, is placed in magnetic stirring apparatus and stirs, in 20 DEG C -25 DEG C of bar Under part, rotating speed 300r/min, mixing time 2.5h, filter, 6.5h is dried in 75 DEG C of baking ovens, grind, obtain to surface and change The nano-oxide powder of property;
2)The PMA of 2.5 parts by weight is added in the chloroform of 6 parts by weight and mixed, is placed in magnetic stirring apparatus In, under conditions of 20 DEG C -25 DEG C, rotating speed 200r/min, mixing time 42min, obtain mixed liquor one;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 48 The water of parts by weight and the tributyl phosphate of 2.9 parts by weight are placed in ball milling in ball mill, rotating speed 160r/min, time 10.5h, Obtain mixed liquor two;
4)To step 3)The epoxy resin of 32 parts by weight, the polydiene base the third two of 4.7 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 750r/min, mixing time 18min, then adds 6.8 weights Measure the waterproofing agent of part, the Dacthal of 5.9 parts by weight, the cinnamic acid of 9 parts by weight, the Asia of 7.8 parts by weight Sodium nitrate, regulation rotating speed are 450r/min, mixing time 5.5h, produce target product;
5)By step 4)Obtained target product shakes 10.5h in bottle swingging machine, amplitude 50mm, rotating speed 120r/min, takes out Filter, produces final product.
Embodiment three
A kind of abrasion-proof insulating layer, is made up of following components and its content:3 parts of the parts by weight of epoxy resin 35, PMA, three 7 parts of chloromethanes, the parts by weight of 3- glycydoxies trimethoxy silane 4.4, the parts by weight of nano-oxide 14, polydiene The parts by weight of the third alkyl dimethyl ammonium chloride of base 4.8, the parts by weight of tributyl phosphate 3, the parts by weight of waterproofing agent 6.9, N-phenylmaleimide 6 Parts by weight, the parts by weight of poly-aspartate 9.2, the parts by weight of sodium chromate 7.6, the parts by weight of acetone 22, the parts by weight of water 49.
The nano-oxide is nano magnesia, nano silicon, the mixture of nano titanium oxide, and weight ratio is received Rice magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Calcium stearate is 7:3。
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 14 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 14h, mixed with the acetone of 22 parts by weight Close, add the 3- glycydoxy trimethoxy silanes of 4.4 parts by weight, be placed in magnetic stirring apparatus and stir, 20 Under conditions of DEG C -25 DEG C, rotating speed 350r/min, mixing time 3h, filter, 7h is dried in 80 DEG C of baking ovens, grind, obtain The nano-oxide powder that surface is modified;
2)The PMA of 3 parts by weight is added in the chloroform of 7 parts by weight and mixed, is placed in magnetic stirring apparatus, Under conditions of 20 DEG C -25 DEG C, rotating speed 300r/min, mixing time 45min, mixed liquor one is obtained;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 49 The water of parts by weight and the tributyl phosphate of 3 parts by weight are placed in ball milling in ball mill, rotating speed 160r/min, time 11h, obtain Mixed liquor two;
4)To step 3)The epoxy resin of 35 parts by weight, the polydiene base the third two of 4.8 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 800r/min, mixing time 20min, then adds 6.9 weights Measure the waterproofing agent of part, the N-phenylmaleimide of 6 parts by weight, poly-aspartate, the chromic acid of 7.6 parts by weight of 9.2 parts by weight Sodium, regulation rotating speed are 450r/min, mixing time 7h, produce target product;
5)By step 4)Obtained target product shakes 11h, amplitude 50mm, rotating speed 150r/min in bottle swingging machine, filters, Produce final product.
Example IV
A kind of abrasion-proof insulating layer, comprising component and its content with embodiment three.
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 14 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 14h, mixed with the acetone of 22 parts by weight Close, add the 3- glycydoxy trimethoxy silanes of 4.4 parts by weight, be placed in magnetic stirring apparatus and stir, 20 Under conditions of DEG C -25 DEG C, rotating speed 400r/min, mixing time 4h, filter, 8h is dried in 80 DEG C of baking ovens, grind, obtain The nano-oxide powder that surface is modified;
2)The PMA of 3 parts by weight is added in the chloroform of 7 parts by weight and mixed, is placed in magnetic stirring apparatus, Under conditions of 20 DEG C -25 DEG C, rotating speed 300r/min, mixing time 45min, mixed liquor one is obtained;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 49 The water of parts by weight and the tributyl phosphate of 3 parts by weight are placed in ball milling in ball mill, rotating speed 180r/min, time 12h, obtain Mixed liquor two;
4)To step 3)The epoxy resin of 35 parts by weight, the polydiene base the third two of 4.8 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 900r/min, mixing time 30min, then adds 6.9 weights Measure the waterproofing agent of part, the N-phenylmaleimide of 6 parts by weight, poly-aspartate, the chromic acid of 7.6 parts by weight of 9.2 parts by weight Sodium, regulation rotating speed are 500r/min, mixing time 8h, produce target product;
5)By step 4)Obtained target product shakes 12h, amplitude 50mm, rotating speed 200r/min in bottle swingging machine, filters, Produce final product.
Embodiment five
A kind of abrasion-proof insulating layer, is made up of following components and its content:4 parts of the parts by weight of epoxy resin 39, PMA, three 8 parts of chloromethanes, the parts by weight of APTES 5, the parts by weight of nano-oxide 15, the dimethyl chloride of polydiene base third Change the parts by weight of ammonium 5.2, the parts by weight of tributyl phosphate 3.1, the parts by weight of waterproofing agent 7, the parts by weight of heat-resistant agent 6.1, the weight of corrosion-resistant agent 9.3 Measure part, the parts by weight of sodium chromate 8.3, the parts by weight of acetone 24, the parts by weight of water 50.
The nano-oxide is nano magnesia, nano silicon, the mixture of nano titanium oxide, and weight ratio is received Rice magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Calcium stearate is 7:3。
The corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, and weight compares hexa:Chinese cassia tree Aldehyde:Poly-aspartate is 2:3:5.
The heat-resistant agent is the mixture of N-phenylmaleimide and Dacthal, and weight compares N- Phenyl maleimide:Dacthal is 4:6.
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 15 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 14h, mixed with the acetone of 24 parts by weight Close, add the APTES of 5 parts by weight, be placed in magnetic stirring apparatus and stir, in 20 DEG C -25 DEG C of condition Under, rotating speed 350r/min, mixing time 4h, filter, 8h is dried in 80 DEG C of baking ovens, grind, obtain receiving for surface modification Rice oxide powder;
2)The PMA of 4 parts by weight is added in the chloroform of 8 parts by weight and mixed, is placed in magnetic stirring apparatus, Under conditions of 20 DEG C -25 DEG C, rotating speed 300r/min, mixing time 45min, mixed liquor one is obtained;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 50 The water of parts by weight and the tributyl phosphate of 3.1 parts by weight are placed in ball milling in ball mill, rotating speed 170r/min, time 12h, obtain To mixed liquor two;
4)To step 3)The epoxy resin of 39 parts by weight, the polydiene base the third two of 5.2 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 800r/min, mixing time 30min, then adds 7 weight The waterproofing agent, the heat-resistant agent of 6.1 parts by weight, the corrosion-resistant agent of 9.3 parts by weight, the sodium chromate of 8.3 parts by weight of part, regulation rotating speed are 450r/min, mixing time 7h, produces target product;
5)By step 4)Obtained target product shakes 12h, amplitude 50mm, rotating speed 180r/min in bottle swingging machine, filters, Produce final product.
Embodiment six
A kind of abrasion-proof insulating layer, including component and its content be with embodiment five, but unlike embodiment five, this implementation The corrosion-resistant agent that example uses is hexa.
This is used for the preparation method of the erosion resisting insulation material of buried cable with embodiment five.
Embodiment seven
A kind of abrasion-proof insulating layer, is made up of following components and its content:4.5 parts of the parts by weight of epoxy resin 42, PMA, 9 parts of chloroform, the parts by weight of APTES 5.2, the parts by weight of nano-oxide 16, the diformazan of polydiene base third The parts by weight of ammonium chloride 5.4, the parts by weight of tributyl phosphate 3.2, the parts by weight of waterproofing agent 7.1, Dacthal 6.2 parts by weight, the parts by weight of corrosion-resistant agent 9.5, the parts by weight of sodium chromate 8.5, the parts by weight of acetone 25, the parts by weight of water 52.
The nano-oxide is nano magnesia, nano silicon, the mixture of nano titanium oxide, and weight ratio is received Rice magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Calcium stearate is 7:3。
The corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, and weight compares hexa:Chinese cassia tree Aldehyde:Poly-aspartate is 2:3:5.
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 16 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 13h, mixed with the acetone of 25 parts by weight Close, add the APTES of 5.2 parts by weight, be placed in magnetic stirring apparatus and stir, in 20 DEG C -25 DEG C of bar Under part, rotating speed 300r/min, mixing time 2h, filter, 6h is dried in 75 DEG C of baking ovens, grind, obtain surface modification Nano-oxide powder;
2)The PMA of 4.5 parts by weight is added in the chloroform of 9 parts by weight and mixed, is placed in magnetic stirring apparatus In, under conditions of 20 DEG C -25 DEG C, rotating speed 200r/min, mixing time 40min, obtain mixed liquor one;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 52 The water of parts by weight and the tributyl phosphate of 3.2 parts by weight are placed in ball milling in ball mill, rotating speed 150r/min, time 10h, obtain To mixed liquor two;
4)To step 3)The epoxy resin of 42 parts by weight, the polydiene base the third two of 5.4 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 700r/min, mixing time 25min, then adds 7.1 weights Measure the waterproofing agent of part, the Dacthal of 6.2 parts by weight, the corrosion-resistant agent of 9.5 parts by weight, 8.5 parts by weight Sodium chromate, regulation rotating speed is 400r/min, mixing time 5h, produces target product;
5)By step 4)Obtained target product shakes 10h, amplitude 50mm, rotating speed 100r/min in bottle swingging machine, filters, Produce final product.
Embodiment eight
A kind of abrasion-proof insulating layer, is made up of following components and its content:5 parts of the parts by weight of epoxy resin 44, PMA, three 10 parts of chloromethanes, the parts by weight of 3- glycydoxies trimethoxy silane 5.5, the parts by weight of nano-oxide 17, poly- two The parts by weight of the third alkyl dimethyl ammonium chloride of alkenyl 5.6, the parts by weight of tributyl phosphate 3.3, the parts by weight of waterproofing agent 7.2, the weight of heat-resistant agent 6.3 Part, the parts by weight of corrosion-resistant agent 9.6, the parts by weight of natrium nitrosum 8.8, the parts by weight of acetone 26, the parts by weight of water 55.
The nano-oxide is nano magnesia, nano silicon, the mixture of nano titanium oxide, and weight ratio is received Rice magnesia:Nano silicon:Nano titanium oxide is 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight compares sodium methyl silicate:Calcium stearate is 7:3。
The corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, and weight compares hexa:Chinese cassia tree Aldehyde:Poly-aspartate is 2:3:5.
The heat-resistant agent is the mixture of N-phenylmaleimide and Dacthal, and weight compares N- Phenyl maleimide:Dacthal is 4:6.
The preparation method of the abrasion-proof insulating layer, is comprised the following steps:
1)The nano-oxide of 17 parts by weight is placed in 80 DEG C of vacuum drying chambers after drying 14h, mixed with the acetone of 26 parts by weight Close, add the 3- glycydoxy trimethoxy silanes of 5.5 parts by weight, be placed in magnetic stirring apparatus and stir, 20 Under conditions of DEG C -25 DEG C, rotating speed 400r/min, mixing time 4h, filter, 8h is dried in 80 DEG C of baking ovens, grind, obtain The nano-oxide powder that surface is modified;
2)The PMA of 5 parts by weight is added in the chloroform of 10 parts by weight and mixed, is placed in magnetic stirring apparatus, Under conditions of 20 DEG C -25 DEG C, rotating speed 300r/min, mixing time 45min, mixed liquor one is obtained;
3)By step 1)The nano oxidized powder that obtained surface is modified and step 2)Obtained mixed liquor one mixes, and adds 55 The water of parts by weight and the tributyl phosphate of 3.3 parts by weight are placed in ball milling in ball mill, rotating speed 180r/min, time 12h, obtain To mixed liquor two;
4)To step 3)The epoxy resin of 44 parts by weight, the polydiene base the third two of 5.6 parts by weight are added in obtained mixed liquor two Ammonio methacrylate, it is placed in high-speed mixer, regulation rotating speed is 900r/min, mixing time 30min, then adds 7.2 weights The waterproofing agent of part, the heat-resistant agent of 6.3 parts by weight, corrosion-resistant agent, the natrium nitrosum of 8.8 parts by weight of 9.6 parts by weight are measured, regulation turns Speed is 500r/min, mixing time 8h, produces target product;
5)By step 4)Obtained target product shakes 12h, amplitude 50mm, rotating speed 200r/min in bottle swingging machine, filters, Produce final product.
Comparative example one
A kind of abrasion-proof insulating layer, including component and its content with embodiment two, but unlike embodiment two, the comparative example It is not added with waterproofing agent and heat-resistant agent.
The abrasion-proof insulating layer, comprising the step of with embodiment two.
Comparative example two
A kind of abrasion-proof insulating layer, including component and its content with embodiment three, but unlike embodiment three, the comparative example It is not added with corrosion-resistant agent and corrosion inhibiter.
The abrasion-proof insulating layer, comprising the step of with embodiment three.
Comparative example three
A kind of abrasion-proof insulating layer, including component and its content with embodiment five.
This is used for the erosion resisting insulation material of buried cable, comprising the step of with embodiment five, it is but different from embodiment five , the comparative example lacks step 5), i.e., target product is not shaken in bottle swingging machine.
Comparative example four
A kind of abrasion-proof insulating layer, including component and its content with embodiment seven, but unlike embodiment seven, the comparative example Lack coupling agent.
The abrasion-proof insulating layer, comprising the step of with embodiment seven, but unlike embodiment three, the comparative example lacks step 1), i.e., not by nano-oxide with coupling agent modified.
Performance test:
1)Measuring mechanical property
In actual application, the mechanical performance of coating is to weigh the important performance assessment criteria of its durability.Coating is because of formula group Divide ratio different, its mechanical performance has certain difference.
Deployed mixed liquor is poured into mould, coating sample is obtained after solidifying at room temperature.Its specification is:A length of 30 Mm, wide lO mm, thickness are 100 μm.Stress-strain test is carried out to enamelled coating using U.S.'s Mei Tesi CMT5305 universal testing machines, Strain rate is 10mm/min.
Tensile strength be sample when being pulled off on puller system, the load that is born on unit cross-sectional area uses N/mm2Represent, Calculation formula is as shown in 1-1:
P=F/S (1-1)
In formula:
The tensile strength of the samples of P mono-, N/mm2
Power suffered on rupture cross section, N during F- sample fractures;
The area in S- sample fractures face, mm2
Wherein, 1MPa=1N/mm2
Elongation at break is the ratio of the elongation and raw footage when sample is pulled off, and is expressed as a percentage, calculation formula such as 1-2 institutes Show:
E=(L1-L0)/L0 (1-2)
In formula:
The elongation at breaks of E mono-, %;
L0One sample raw footage, mm;
L1The length of part of the force, mm during-sample fracture.
2)Water resistance test
Coating mixed liquor 30g is taken in glass culture dish, spontaneously dries, film is made.The water-fast of film is characterized using water absorption rate Property, film is cut into 15mm × 15mm square sample, weighs sample mass(It is accurate to 0.001g).Put it into and be equipped with In the culture dish of distilled water, distilled water did not had the upper surface of film, was taken out after soaking 24h at room temperature.Gently wiped with filter paper Fall the moisture of film surface, and weigh immediately.According to formula 2-1, the water absorption rate of film is calculated, each sample testing 3 times, make even Average.
W=(m1-m0)/m0×100% (2-1)
In formula, the water absorption rate of W- films, %;
m0The initial mass of-sample, g;
m1Quality after the water suction of-sample, g.
3)Corrosion-resistant test
Three clean beakers are taken, hydrochloric acid, the NaOH solution of 10% concentration of 10% concentration is prepared respectively, coating sample is soaked respectively Enter in two kinds of solution prepared, keep sealed environment to take out the corrosion condition on coating sample viewing film surface after 45 days.
4)Adhesive force is tested
Adhesive force test utilizes cross-hatching, is to be coated on galvanized sheet iron to ground according to ISO2409 and GB/19286-98 standards Thickness is 121-250 μm of test coating, carries out well stroke lattice to coating sample, surface impurity is gently swept off afterwards, with adhesive tape It is middle to be placed in parallel with line lattice, with hand levelling glue band, then to open adhesive tape close to 60 ° of angles, check cutting part state.
5)Long-term height temperature stability
1000mg/L coating is respectively configured, respectively takes 200mL to be respectively placed in ageing can, constant temperature is placed at -50 DEG C by its elder generation 90 days, then constant temperature was placed 90 days at 100 DEG C, and its interfacial tension is determined with surface tension instrument, and calculated interfacial tension growth Rate, investigate the height temperature stability of coating.
The Measurement results such as table 1 of embodiment one to eight and comparative example one to four:
The test result of the embodiment of table 1 and comparative example
Stretching is strong Spend MPa Fracture is stretched Long rate % It is water-fast Property Acid resistance Alkali resistance Adhesive force High/low temperature is stable Property(%)
Embodiment one 22.5 120.7 41 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 5.4
Embodiment two 22.1 127.6 40 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 5.2
Embodiment three 23.9 133.6 36 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 4.5
Example IV 23.7 130.8 35 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 4.6
Embodiment five 25.4 141.3 31 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 3.8
Embodiment six 24.4 138.9 35 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 4.5
Embodiment seven 24.2 136.7 35 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 4.4
Embodiment eight 25.0 140.3 33 Without elephant skin, Bubble, stripping Fall phenomenon Without elephant skin, bubble, Peeling phenomenon It is smooth, without de- Fall 4.0
Comparative example one 13.2 106.3 55 A large amount of wrinkles Skin, bubble, Peeling phenomenon A large amount of elephant skin, gas Bubble, peeling phenomenon A little coating Come off 12.6
Comparative example two 13.3 105.5 46 A large amount of wrinkles Skin, bubble, Peeling phenomenon A large amount of elephant skin, gas Bubble, peeling phenomenon A little coating Come off 11
Comparative example three 12.4 102.4 52 A large amount of wrinkles Skin, bubble, Peeling phenomenon A large amount of elephant skin, gas Bubble, peeling phenomenon Large area applies Material comes off 11.8
Comparative example four 11.6 100.3 50 A small amount of wrinkle Skin, bubble, Peeling phenomenon A small amount of elephant skin, gas Bubble, peeling phenomenon Large area applies Material comes off 12.5
As can be seen from Table 1:1)Embodiment one to eight shows good combination property:With excellent mechanical performance, draw Intensity is stretched in more than 22MPa, and elongation at break is more than 120%, and water-fast, resistant to chemical etching, adhesive force is strong, in high and low temperature environment Under, stable performance.2)Embodiment one to four is a kind of single material using heat-resistant agent and corrosion-resistant agent, embodiment five to Eight, use the mixture of heat-resistant agent and corrosion-resistant agent for two or three of material, the combination property ratio of the material of embodiment five to eight Embodiment one to four is good;For example IV compared with embodiment three, material composition is identical with content, and the technical parameter of preparation method is not Together, the performance of embodiment three is better than example IV.3)Comparative example one lacks waterproofing agent and heat-resistant agent compared with embodiment two;It is right Ratio two lacks corrosion-resistant agent and corrosion inhibiter compared with embodiment three;Comparative example three is compared with embodiment five, not by target product Shaken in bottle swingging machine;Nano-oxide is not modified by comparative example four compared with embodiment seven;The material of comparative example one to four The performance of material is poorer than embodiment one to eight.Illustrate between each raw material it is complementary, lack any raw material, the property of material It can will be decreased obviously, therefore use the insulating layer material of the present invention, after ground friction uses equal power and Rubbing number, The service chamber abrasion of the present invention is slight, using the material object serious wear of documents, while falls in transport and equal height Falling behind the casing of the present invention substantially without damage, instrument is normal in casing, is destroyed using the insulating materials body structure of documents, And tool damage in casing.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic, Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's Within protection domain.

Claims (7)

1. a kind of communication intelligence optical maintenance tool box, including outer container(1), it is characterised in that:The outer container(1)Including upper shell (2), the upper shell(2)Bottom is provided with lower house(3), the upper shell(2)With lower house(3)It is flexibly connected by hinge, The upper shell(2)Top is provided with solar panel(4), the upper shell(2)Inside is provided with battery(5), the electric power storage Pond(5)Side is provided with converter(6), the converter(6)Side is provided with GPS locator(7)And bottom is provided with programmable control Device processed(8), the programmable controller(8)It is provided with operating switch(9)With cancel switch(10), the cancel switch(10)If In operating switch(9)Top, the programmable controller(8)Side is provided with alarm(11), the alarm(11)Side is set There is signal conveyer(12), the signal conveyer(12)Top is provided with communicator(13), the lower house(3)Inside is provided with resistance Dividing plate(14), the baffler(14)Both sides are equipped with well(15), the outer surface of the upper shell and lower house is coated with There is abrasion-proof insulating layer, be provided with piston in the well, the air inlet of the piston is provided with check valve, is provided with the well The electric expansion bar of piston rod is pulled, the electric expansion bar is connected with programmable controller.
A kind of 2. communication intelligence optical maintenance tool box according to claim 1, it is characterised in that:The signal conveyer (12)Connection end is provided with signal receiver, and the signal receiver is located at server internal.
A kind of 3. communication intelligence optical maintenance tool box according to claim 1, it is characterised in that:The upper shell(2) Inner side is provided with the first overcoat(16), the lower house(3)Inner side is provided with the second overcoat(17).
A kind of 4. communication intelligence optical maintenance tool box according to claim 1 or 3, it is characterised in that:Described first is anti- Sheath(16), the second overcoat(17)And baffler(14)It is made by sponge material.
A kind of 5. communication intelligence optical maintenance tool box according to claim 1, it is characterised in that:The battery(5)、 GPS locator(7), alarm(11), signal conveyer(12)And communicator(13)And programmable controller(8)Electrically connect Connect.
A kind of 6. communication intelligence optical maintenance tool box according to claim 1, it is characterised in that:The outer container(1)Side Face is provided with lock(18), the lock(18)Between be provided with handle(19).
A kind of 7. communication intelligence optical maintenance tool box according to claim 1, it is characterised in that:The solar cell Plate(4)Pass through converter(6)With battery(5)It is electrically connected with.
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