CN107747069A - A kind of aluminum matrix composite and its manufacture method - Google Patents

A kind of aluminum matrix composite and its manufacture method Download PDF

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Publication number
CN107747069A
CN107747069A CN201711051950.7A CN201711051950A CN107747069A CN 107747069 A CN107747069 A CN 107747069A CN 201711051950 A CN201711051950 A CN 201711051950A CN 107747069 A CN107747069 A CN 107747069A
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CN
China
Prior art keywords
weight
parts
matrix composite
aluminum matrix
manufacture method
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CN201711051950.7A
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Chinese (zh)
Inventor
曾加红
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Guilin Plus Macro Auto Repair Co Ltd
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Guilin Plus Macro Auto Repair Co Ltd
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Publication date
Application filed by Guilin Plus Macro Auto Repair Co Ltd filed Critical Guilin Plus Macro Auto Repair Co Ltd
Priority to CN201711051950.7A priority Critical patent/CN107747069A/en
Publication of CN107747069A publication Critical patent/CN107747069A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/08Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • C22C49/04Light metals
    • C22C49/06Aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/14Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)

Abstract

The present invention relates to a kind of aluminum matrix composite and its manufacture method.A kind of aluminum matrix composite, include the component of following parts by weight:The parts by weight of carbon fiber 8 20, the parts by weight of polyvinyl chloride 3 12, the parts by weight of Zinc oxide particles 10 20, the parts by weight of graphite powder 10 30, the parts by weight of nano silicon 8 15.Aluminum matrix composite of the present invention and its manufacture method, have the advantages that manufacture method is simple, heat resistance is good.Inventor has carried out the screening experiment of substantial amounts of component and dosage early stage, is found surprisingly that, technical scheme is by reasonably matching and the combination tool of each component increases significantly the effect of intensity.The heat resistance of aluminum matrix composite material is improved, largely increases its modulus of elasticity and low-expansion coefficient, cost is low, easy to utilize.

Description

A kind of aluminum matrix composite and its manufacture method
Technical field
The invention belongs to aluminum matrix composite manufacturing technology field, more particularly to a kind of aluminum matrix composite and its manufacturer Method.
Background technology
Obtain enough different particle enhanced aluminum-based composite materials, due to density is low, casting character is excellent, wearability, High specific strength, good heat conduction, electric conductivity, thermal coefficient of expansion be small, etc. a series of excellent properties, there is potential application prospect With wide market, the metal-base composites of particle enhancing, the fiber-reinforced metal matrix composite that compares has cost low Honest and clean, anisotropy is small, is readily synthesized.
When preparing containing carbon fiber, alumina particle enhancing composite, because carbon fiber, alumina particle and aluminium close Wetability between gold is very poor, and the technological requirement of preparation is higher, mainly there is powder metallurgic method, spray deposition, stirring casting at present Make method and squeeze casting method.Although existing process preparation method has successfully manufactured composite, it is difficult to industrialize Production, to further perfect and new technology the main task for being developed into next step research work of existing process, therefore There is an urgent need to invent a kind of carbon fiber of improvement to a certain extent, alumina particle and Al wetability effective ways in production, this Invention carries out chemical reaction with villiaumite method salt and silicon-carbide particle and prepares aluminum matrix composite, promotes carbon fiber, alumina particle Infiltration, improve wellability difference problem of the Al melts to carbon fiber, alumina particle, energy consumption is low, the simple and convenient operation of technique Cost is low, can be with industrialized production.
The content of the invention
The technical problems to be solved by the invention are in view of the shortcomings of the prior art, there is provided a kind of aluminum matrix composite and its Manufacture method, to solve at least one of above-mentioned technical problem.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:A kind of aluminum matrix composite, including following parts by weight Component:Carbon fiber 8-20 parts by weight, polyvinyl chloride 3-12 parts by weight, Zinc oxide particles 10-20 parts by weight, graphite powder 10-30 Parts by weight, nano silicon 8-15 parts by weight.
The beneficial effects of the invention are as follows:Aluminum matrix composite of the present invention, has that manufacture method is simple, heat resistance is good The advantages that.Inventor has carried out the screening experiment of substantial amounts of component and dosage early stage, is found surprisingly that, technical side of the invention Case is by reasonably matching and the combination tool of each component increases significantly the effect of intensity.Improve aluminum matrix composite material The heat resistance of material, its modulus of elasticity and low-expansion coefficient are largely increased, cost is low, easy to utilize.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the component of following parts by weight is included:The parts by weight of carbon fiber 14, the parts by weight of polyvinyl chloride 8, Zinc oxide particles 12 parts by weight, the parts by weight of graphite powder 25, the parts by weight of nano silicon 10.
Further, the particle diameter of the nanometer silicon dioxide particle is 1.0 nanometers to 50 nanometers.
The present invention also provides a kind of manufacture method of above-mentioned aluminum matrix composite, comprises the following steps:
Step 1, prepare material by mass percentage first, by carbon fiber 8-20 parts by weight, polyvinyl chloride 3-12 parts by weight, Zinc oxide particles 10-20 parts by weight, graphite powder 10-30 parts by weight, nano silicon 8-15 parts by weight are well mixed;
Step 2, in melting furnace by fine aluminium or aluminum alloy melting, by above-mentioned mixed powder after being warming up to 660 DEG C~1500 DEG C Shape raw material accounts for two kinds of powdery mixed materials of aluminum melt weight 1%-100% or several mixed materials are added fully to stir in stove and melted After liquid insulation 5-100min, then liquation is skimmed;
Step 3, the liquation agitation after above-mentioned remove slag is cast into various products.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the warming temperature is 700 DEG C, 900 DEG C or 1100 DEG C.
Further, the soaking time is 5min, 15min, 40min or 60min.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
A kind of aluminum matrix composite, include the component of following parts by weight:Carbon fiber 8-20 parts by weight, polyvinyl chloride 3-12 weights Measure part, Zinc oxide particles 10-20 parts by weight, graphite powder 10-30 parts by weight, nano silicon 8-15 parts by weight.The nanometer The particle diameter of silica dioxide granule is 1.0 nanometers to 50 nanometers.During manufacture, comprise the following steps:Step 1, first by quality percentage Than preparing material, by carbon fiber 8-20 parts by weight, polyvinyl chloride 3-12 parts by weight, Zinc oxide particles 10-20 parts by weight, graphite powder 10-30 parts by weight, nano silicon 8-15 parts by weight are well mixed;Step 2, pure aluminum or aluminum alloy is melted in melting furnace Change, above-mentioned mixing powder raw material is accounted for into two kinds of powderies of aluminum melt weight 1%-100% after being warming up to 660 DEG C~1500 DEG C mixes original In material or several mixed materials addition stove after fully agitation liquation insulation 5-100min, then liquation is skimmed;Step 3, the liquation agitation after above-mentioned remove slag is cast into various products.The warming temperature is 700 DEG C, 900 DEG C or 1100 DEG C.It is described Soaking time is 5min, 15min, 40min or 60min..
Relative to prior art, aluminum matrix composite of the present invention, it is excellent to have that manufacture method is simple, heat resistance is good etc. Point.Inventor has carried out the screening experiment of substantial amounts of component and dosage early stage, is found surprisingly that, technical scheme is led to The combination tool for crossing rational proportioning and each component increases significantly the effect of intensity.Improve aluminum matrix composite material Heat resistance, its modulus of elasticity and low-expansion coefficient are largely increased, cost is low, easy to utilize.
It is introduced below by specific embodiment.
Embodiment 1
A kind of aluminum matrix composite, including following components by weight percent:Carbon fiber 1.5kg, polyvinyl chloride 0.6kg, zinc oxide Grain 1kg, graphite powder 2.0kg, nano silicon 1.2kg.During manufacture, each component is weighed by proportioning, is mixed together, the heating Temperature is 700 DEG C, and the soaking time is 15min.Aluminum matrix composite material is made.
Embodiment 2
A kind of aluminum matrix composite, including following components by weight percent:Carbon fiber 1.4kg, polyvinyl chloride 0.7kg, zinc oxide Grain 1.2kg, graphite powder 2.1kg, nano silicon 1.0kg.During manufacture, each component is weighed by proportioning, is mixed together, the liter Temperature is 700 DEG C, and the soaking time is 15min.Aluminum matrix composite material is made.
Embodiment 3
A kind of aluminum matrix composite, including following components by weight percent:Carbon fiber 1.6kg, polyvinyl chloride 1.0kg, zinc oxide Grain 1kg, graphite powder 1.8kg, nano silicon 0.8kg.During manufacture, each component is weighed by proportioning, is mixed together, the heating Temperature is 700 DEG C, and the soaking time is 15min.Aluminum matrix composite material is made.
Comparative example 1
The carbon fiber 3kg, polyvinyl chloride 0.1kg, remaining is same as Example 1.
Comparative example 2
The carbon fiber 0.1kg, polyvinyl chloride 5kg, remaining is same as Example 1.
Comparative example 3
The carbon fiber 3kg, polyvinyl chloride 5kg, remaining is same as Example 1.
Comparative example 4
The carbon fiber 0.1kg, polyvinyl chloride 0.1kg, remaining is same as Example 1.
Measure of merit
By embodiment 1-3 and comparative example 1-4,7 groups of aluminum matrix composite materials are fabricated to using identical technique.Every group with The aluminum matrix composite material that machine extracts 0.5kg is tested.Aluminum matrix composite material is put into modulus of elasticity test Among instrument, its modulus of elasticity at 20 DEG C is tested.
Test result is as shown in table 1.
Table 1
Modulus of elasticity (GPa)
Embodiment 1 202.3
Embodiment 2 192.5
Embodiment 3 205.8
Comparative example 1 150.2
Comparative example 2 131.4
Comparative example 3 122.8
Comparative example 4 145.6
Data in table 1, which can be seen that technical scheme, can improve the bullet of aluminum matrix composite material Property modulus.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (6)

1. a kind of aluminum matrix composite, it is characterised in that include the component of following parts by weight:Carbon fiber 8-20 parts by weight, polychlorostyrene Ethene 3-12 parts by weight, Zinc oxide particles 10-20 parts by weight, graphite powder 10-30 parts by weight, nano silicon 8-15 weight Part.
2. a kind of aluminum matrix composite according to claim 1, it is characterised in that include the component of following parts by weight:Carbon is fine Tie up 14 parts by weight, the parts by weight of polyvinyl chloride 8, the parts by weight of Zinc oxide particles 12, the parts by weight of graphite powder 25, the weight of nano silicon 10 Measure part.
A kind of 3. aluminum matrix composite according to claim 1, it is characterised in that the particle diameter of the nanometer silicon dioxide particle For 1.0 nanometers to 50 nanometers.
4. a kind of manufacture method of the aluminum matrix composite as described in claim any one of 1-3, it is characterised in that including following step Suddenly:
Step 1, material is prepared by mass percentage first, by carbon fiber 8-20 parts by weight, polyvinyl chloride 3-12 parts by weight, oxidation Zinc particle 10-20 parts by weight, graphite powder 10-30 parts by weight, nano silicon 8-15 parts by weight are well mixed;
Step 2, it is after being warming up to 660 DEG C~1500 DEG C that above-mentioned mixing powdery is former by fine aluminium or aluminum alloy melting in melting furnace Material accounts for two kinds of powdery mixed materials of aluminum melt weight 1%-100% or several mixed materials add fully agitation liquation in stove and protected After warm 5-100mi n, then liquation is skimmed;
Step 3, the liquation agitation after above-mentioned remove slag is cast into various products.
5. a kind of manufacture method of aluminum matrix composite according to claim 4, it is characterised in that the warming temperature is 700 DEG C, 900 DEG C or 1100 DEG C.
6. a kind of manufacture method of aluminum matrix composite according to claim 4, it is characterised in that the soaking time is 5mi n, 15mi n, 40mi n or 60mi n.
CN201711051950.7A 2017-10-30 2017-10-30 A kind of aluminum matrix composite and its manufacture method Pending CN107747069A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108559929A (en) * 2018-05-29 2018-09-21 合肥智慧龙图腾知识产权股份有限公司 A kind of body of a motor car aluminium base light material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1924073A (en) * 2006-09-25 2007-03-07 哈尔滨工业大学 Amorphous carbon fiber aluminium based composite material and preparation method thereof
CN105695808A (en) * 2016-04-25 2016-06-22 莒南县美达电力实业有限公司 Aluminum alloy wire

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1924073A (en) * 2006-09-25 2007-03-07 哈尔滨工业大学 Amorphous carbon fiber aluminium based composite material and preparation method thereof
CN105695808A (en) * 2016-04-25 2016-06-22 莒南县美达电力实业有限公司 Aluminum alloy wire

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108559929A (en) * 2018-05-29 2018-09-21 合肥智慧龙图腾知识产权股份有限公司 A kind of body of a motor car aluminium base light material and preparation method thereof

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Application publication date: 20180302