CN107313129A - Aluminum bronze zirconium reinforcing fiber and preparation method thereof and aluminum bronze zirconium super plastic alloy base clad aluminum - Google Patents
Aluminum bronze zirconium reinforcing fiber and preparation method thereof and aluminum bronze zirconium super plastic alloy base clad aluminum Download PDFInfo
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- CN107313129A CN107313129A CN201710707637.8A CN201710707637A CN107313129A CN 107313129 A CN107313129 A CN 107313129A CN 201710707637 A CN201710707637 A CN 201710707637A CN 107313129 A CN107313129 A CN 107313129A
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/08—Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/02—Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
- C22C49/04—Light metals
- C22C49/06—Aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
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Abstract
The present invention discloses aluminum bronze zirconium reinforcing fiber and preparation method thereof and aluminum bronze zirconium super plastic alloy base clad aluminum.By weight percentage, it is made up of 89% 99% igneous rock, 0 9% cupric oxide, 0 1% zirconium oxide and 1% carbon dust；Wherein, 0 value is taken when the cupric oxide is different from the content of the zirconium oxide.The present invention, by introducing cupric oxide, zirconia components, generates a kind of high sial copper zirconium reinforcing fiber of amorphous on the basis of natural high sial igneous rock ore.The high sial copper zirconium reinforcing fiber of amorphous and the super modeling aluminium alloy compound of aluminum bronze zirconium, silicon, aluminium, copper in reinforcing material, zirconium component, molecule fusion can occur with metal belt, so as to improve the binding strength of compound interface, that is, the intensity of aluminum bronze zirconium super plastic alloy base clad aluminum is improved.
Description
Technical field
The present invention relates to aluminum matrix composite preparation field, more particularly to a kind of high sial copper zirconium reinforcing fiber of amorphous and its
Preparation method, and use the fibre-reinforced aluminum bronze zirconium super plastic alloy base clad aluminum.
Background technology
The aluminium first generation is fine aluminium（, Denmark's oersted in 1825）, the second generation is alloy aluminum（1903, Alcoa was public
Department）, the aluminium third generation is the chimeric aluminium of ceramics（1950s）, forth generation is amorphous inorganic materials enhancing clad aluminum（2007, Nanjing day
Gan new materials Science and Technology Ltd.）.
Clad aluminum is lighter than steel, stronger, more, more resistant, more anti-corrosion, can reduce motorized vehicles and vessels for substituting steel
Energy consumption.In the steel housing for substituting automobiles/ships, clad aluminum ductility should try one's best and steel are close.
It is a kind of amorphous inorganic materials of high rigidity due to clad aluminum reinforcing material.The matrix obtained using melt-blown shaping
Material is 7050 aviation clad aluminum, in order to ensure fracture elongation falls into 4-5.5% scope, the addition of its reinforcing material
Only 3% or so.
Therefore, prior art needs to improve, while clad aluminum reinforcing material addition is improved so that clad aluminum
Still possess higher fracture elongation.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of high sial copper zirconium reinforcing fiber of amorphous
And preparation method, and be combined using the aluminum bronze zirconium super plastic alloy of the fiber and high fracture elongation.It is intended to improve compound interface parent
And power（That is tensile strength）While, also assure that clad aluminum has higher fracture elongation.
Technical scheme is as follows：
A kind of high sial copper zirconium reinforcing fiber of amorphous, wherein, by weight percentage, by 89%-99% igneous rock, 0-9% oxygen
Change copper, 0-1% zirconium oxide and 1% carbon dust composition；Wherein, 0 value is taken when the cupric oxide is different from the content of the zirconium oxide.
The high sial copper zirconium reinforcing fiber of described amorphous, wherein, by weight percentage, by 90%-93% igneous rock, 5-
8% cupric oxide, 0.5-1% zirconium oxide and 1% carbon dust composition.
The high sial copper zirconium reinforcing fiber of described amorphous, wherein, by weight percentage, by 90.8% igneous rock, 7.5%
Cupric oxide, 0.7% zirconium oxide and 1% carbon dust composition.
The high sial copper zirconium reinforcing fiber of described amorphous, wherein, by weight percentage, by 98.3% igneous rock, 0.7%
Zirconium oxide and 1% carbon dust composition.
Described amorphous high sial copper zirconium reinforcing fiber, wherein, by weight percentage, by 90.3% igneous rock, 8%
Cupric oxide, 0.7% zirconium oxide and 1% carbon dust composition.
The high sial copper zirconium reinforcing fiber of described amorphous, wherein, on the basis of igneous rock, the igneous rock is contained to be aoxidized
The gross weight of iron, ferrous oxide<3%, igneous rock institute silicon oxide-containing, the gross weight of aluminum oxide>68%.
A kind of preparation method of the high sial copper zirconium reinforcing fiber of amorphous as described above, wherein, including step：
Above-mentioned formula is first according to be well mixed igneous rock, cupric oxide, zirconium oxide and carbon dust, and the fire that will be well mixed
Diagenesis, cupric oxide, zirconium oxide and carbon dust carry out melting, obtain melt；
Then melt is subjected to wire drawing, obtains the high sial copper zirconium reinforcing fiber of amorphous.
The preparation method of the high sial copper zirconium reinforcing fiber of described amorphous, wherein, specifically include step：
Above-mentioned formula is first according to be well mixed igneous rock, cupric oxide, zirconium oxide and carbon dust, and the fire that will be well mixed
Diagenesis, cupric oxide, zirconium oxide and carbon dust are put into vertical-insert electrode all-electric melting furnace and carry out melting, obtain melt；
Then solution is subjected to wire drawing by bushing, obtains the high sial copper zirconium reinforcing fiber of amorphous.
A kind of aluminum bronze zirconium super plastic alloy base clad aluminum, wherein, by the high sial copper zirconium reinforcing fiber of amorphous as described above and
The super modeling aluminium alloy of aluminum bronze zirconium is mixed.
Described aluminum bronze zirconium super plastic alloy base clad aluminum, wherein, the preparation side of the aluminum bronze zirconium super plastic alloy base clad aluminum
Method includes step：The high sial copper zirconium reinforcing fiber of the amorphous being chopped is put into the super modeling aluminum alloy melt of aluminum bronze zirconium, then cooled,
It is stirred for homogenizing, finally heating is poured, and obtains aluminum bronze zirconium super plastic alloy base clad aluminum；Wherein, the high sial copper zirconium of the amorphous increases
The weight ratio of strong fiber and the super modeling aluminum alloy melt of aluminum bronze zirconium is 3:97.
Beneficial effect：The present invention is on the basis of natural high sial igneous rock ore, by introducing cupric oxide, zirconium oxide, raw
Into a kind of high sial copper zirconium reinforcing fiber of amorphous.The high sial copper zirconium reinforcing fiber of amorphous and the super modeling aluminium alloy of aluminum bronze zirconium copper zirconium
Compound, molecule fusion can occur with metal belt for silicon, aluminium, copper in reinforcing material, zirconium component, so as to strengthen compound interface
Binding strength, that is, strengthen the mechanical strength of aluminum bronze zirconium super plastic alloy base clad aluminum.
Embodiment
The present invention provides a kind of high sial copper zirconium reinforcing fiber of amorphous and preparation method and is combined with aluminum bronze zirconium super plastic alloy base
Aluminium, to make the purpose of the present invention, technical scheme and effect clearer, clear and definite, the present invention is described in more detail below.Should
Work as understanding, the specific embodiments described herein are merely illustrative of the present invention, be not intended to limit the present invention.
The present invention provides a kind of high sial copper zirconium reinforcing fiber of amorphous, wherein, by weight percentage, by 89%-99%'s
Igneous rock, 0-9% cupric oxide, 0-1% zirconium oxide and 1% carbon dust composition；Wherein, the cupric oxide and the zirconium oxide
Content takes 0 value when different.
Compared with prior art, the present invention is mainly theed improvement is that, on the basis of natural high sial igneous rock ore, is drawn
Enter cupric oxide, zirconia components, generate a kind of high sial copper zirconium reinforcing fiber of amorphous.The high sial copper zirconium of the amorphous of generation increases
When strong fiber surpasses modeling aluminium alloy compound with aluminum bronze zirconium, the matrix and fiber corresponding element of compound interface can produce molecule fusion, from
And increase the composite reactive and binding strength at interface, so as to strengthen the mechanical strength of aluminum bronze zirconium super plastic alloy base clad aluminum；Secondly,
Reinforcing fiber introduces cupric oxide, zirconia components, can effectively improve fibre strength.Find after tested, it is of the present invention non-
The tensile strength of brilliant high sial calcium reinforcing fiber can reach 4000-6000MPa, and the stable tensile strength of existing domestic carbon fibre
Only 3500MPa.Preferably, the high sial copper zirconium reinforcing fiber of described amorphous, wherein, by weight percentage, by 90%-93%
Igneous rock, 5-8% cupric oxide, 0.5-1% zirconium oxide and 1% carbon dust composition.Under the formula, the high sial copper zirconium of amorphous
Reinforcing fiber and aluminum bronze zirconium surpass the compound interface blending of modeling aluminium alloy more preferably, so as to further enhance aluminum bronze zirconium super plastic alloy base
The mechanical strength of clad aluminum.
In the present invention, on the basis of igneous rock, the gross weight of iron oxide, ferrous oxide contained by the igneous rock<3%, it is described
Igneous rock institute silicon oxide-containing, the gross weight of aluminum oxide>68%.The igneous rock is selected, meets the high sial copper zirconium of the low iron amorphous of production and increases
The adequate condition of strong fibrous material.
The present invention also provides a kind of preparation method of the high sial copper zirconium reinforcing fiber of amorphous as described above, wherein, including
Step：
Above-mentioned formula is first according to be well mixed igneous rock, cupric oxide, zirconium oxide and carbon dust, and the fire that will be well mixed
Diagenesis, cupric oxide, zirconium oxide and carbon dust carry out melting, obtain melt；
Then melt is subjected to wire drawing, obtains the high sial copper zirconium reinforcing fiber of amorphous.
Preferably, the preparation method of the high sial copper zirconium reinforcing fiber of the amorphous, specifically includes step：
Above-mentioned formula is first according to be well mixed igneous rock, cupric oxide, zirconium oxide and carbon dust, and the fire that will be well mixed
Diagenesis, cupric oxide, zirconium oxide and carbon dust are put into vertical-insert electrode all-electric melting furnace and carry out melting, obtain melt；
Then solution is subjected to wire drawing by bushing, obtains the high sial copper zirconium reinforcing fiber of amorphous.
Preferably, the temperature of melting of the present invention is 1600 ~ 1800 DEG C, and more preferably temperature is 1700 DEG C.
The fibre length for the high sial copper zirconium reinforcing fiber of the amorphous that the present invention is prepared is 5 ~ 9 millimeters.
The present invention also provides a kind of aluminum bronze zirconium super plastic alloy base clad aluminum, wherein, by the high sial copper of amorphous as described above
Zirconium reinforcing fiber and the super modeling aluminium alloy of aluminum bronze zirconium are mixed.By the high sial copper zirconium reinforcing fiber of the amorphous and the super modeling of aluminum bronze zirconium
Aluminium alloy compound, can obtain the aluminum bronze zirconium super plastic alloy base clad aluminum of the high intensity of interface fusion excellent performance.
The preparation method of aluminum bronze zirconium super plastic alloy base clad aluminum of the present invention includes step：By the high silicon of the amorphous being chopped
Aluminum bronze zirconium reinforcing fiber is put into the super modeling aluminium alloy solution of aluminum bronze zirconium（About 700 DEG C of temperature in mixed liquor）, then cool（Reduction is about
5~50℃）To increase viscosity, then homogenized with 300 ~ 30000 revs/min of agitator stirring, a length of 3 ~ 10 minutes during stirring；Most
After heat up（It is warming up to initial temperature, i.e., 700 DEG C）Casting, obtains aluminum bronze zirconium super plastic alloy base clad aluminum.
On the basis of aluminum bronze zirconium super plastic alloy base clad aluminum, the weight accounting of the high sial copper zirconium reinforcing fiber of amorphous is
1% ~ 30%, such as 3%, i.e., the described high sial copper zirconium reinforcing fiber of amorphous and the weight ratio of the super modeling aluminum alloy melt of aluminum bronze zirconium are 3:97.
The high sial copper zirconium reinforcing fiber of amorphous of the present invention surpasses with aluminum bronze zirconium before modeling aluminium alloy compound, including step：
Sial copper zirconium reinforcing fiber high to the amorphous carries out the processing that is chopped.Specifically, being 5 ~ 9 millimeters of the high silicon of amorphous by fibre length
Aluminum bronze zirconium reinforcing fiber cuts into the high sial copper zirconium reinforcing fiber of amorphous that fibre length is 1 ~ 3 millimeter by chopping machine.This is
Because in the fiber length ranges, the high sial copper zirconium reinforcing fiber of amorphous can inject aluminium better by high pressure duster
The super modeling aluminium alloy solution of copper zirconium.
The present invention selects the super modeling aluminium alloy of high ductibility as matrix, on the premise of ductility is ensured, passes through addition
More reinforcing fibers, so as to improve the intensity of aluminum bronze zirconium super plastic alloy base clad aluminum.
Below by embodiment, the present invention is described in detail.
Embodiment 1
A kind of high sial copper zirconium reinforcing fiber of amorphous, by weight percentage by 90.8% igneous rock, 7.5% cupric oxide,
0.7% zirconium oxide, 1% carbon dust composition, the gross weight 2.87% of iron oxide and ferrous oxide contained by the igneous rock, and fire into
Rock institute silicon oxide-containing 63.93%, aluminum oxide 17.51% and magnesia 1.32%, meet the abundant bar for producing low iron amorphous reinforcing material
Part.
By the ratio between Cu and CuO molecular weight=63.55:79.545 it is approximately equal to 64:80, it is known that when cupric oxide is 7.5%, copper content
For 6%.Similarly, when zirconia content is 0.7%, zirconium content is 0.5%.Test shows that the zirconium of the copper of aluminium -6% -0.5% is that aluminum bronze zirconium surpasses
Alloy optimal proportion is moulded, the optimal deformation temperature of its alloy is 430 DEG C, and maximum elongation rate is 3000%.
Igneous rock stone is derived from Hebei, and component of its percentage by weight more than 1% is as follows:Silica 63.93%, oxidation
Aluminium 17.51%, magnesia 1.32%, potassium oxide 4.80%, cupric oxide 1.74%, sodium oxide molybdena 6.04%, iron oxide/ferrous oxide
2.87%。
Embodiment 2
A kind of high sial copper zirconium reinforcing fiber of amorphous, by weight percentage by 98.3% igneous rock, 0.7% zirconium oxide, 1%
Carbon dust composition, the gross weight 2.87% of iron oxide and ferrous oxide contained by the igneous rock, and igneous rock institute silicon oxide-containing
63.93%th, aluminum oxide 17.51% and magnesia 1.32%, meet the adequate condition for producing low iron amorphous reinforcing material.
Igneous rock stone is derived from Hebei, and its component of percentage by weight meter more than 1% is as follows:Silica 63.93%, oxygen
Change aluminium 17.51%, magnesia 1.32%, potassium oxide 4.80%, cupric oxide 1.74%, sodium oxide molybdena 6.04%, iron oxide/ferrous oxide
2.87%。
Embodiment 3
A kind of high sial copper zirconium reinforcing fiber of amorphous, by weight percentage by 90.3% igneous rock, 8% cupric oxide, 0.7%
Zirconium oxide, 1% carbon dust composition, the gross weight 2.87% of iron oxide and ferrous oxide contained by the igneous rock, and igneous rock institute
Silicon oxide-containing 63.93%, aluminum oxide 17.51% and magnesia 1.32%, meet the adequate condition for producing low iron amorphous reinforcing material.
Igneous rock stone is derived from Hebei, and its component of percentage by weight meter more than 1% is as follows:Silica 63.93%, oxygen
Change aluminium 17.51%, magnesia 1.32%, potassium oxide 4.80%, cupric oxide 1.74%, sodium oxide molybdena 6.04%, iron oxide/ferrous iron 2.87%.
Embodiment 4
The well mixed igneous rock, cupric oxide, zirconium oxide and the carbon dust of the percentage by weight of embodiment 1,2,3 is used into bottom respectively
Intercalative electrode all-electric melting furnace carries out melting at a temperature of 1700 DEG C, and obtained melt carries out wire drawing by bushing, produces
Fibre length is 5 ~ 9 millimeters, the high sial copper zirconium reinforcing fiber of amorphous of the tensile strength in the range of 4000-6000MPa, then is cut
Into the high sial copper zirconium reinforcing fiber of 1 ~ 3 millimeter of short amorphous.The high sial copper zirconium reinforcing fiber of 1 ~ 3 millimeter of amorphous is passed through into height
Pressure sprayer is uniformly spurted into aluminium liquid, then cooling thickening, then with 2000 revs/min of agitator stirring 6 minutes to homogenizing.
Initial temperature is finally warming up to, clad aluminum, the wherein super modeling aluminium alloy of the high sial copper zirconium reinforcing fiber of amorphous and aluminum bronze zirconium is cast into
Part by weight be 3:97.
Test shows, after addition percentage by weight high sial copper zirconium reinforcing fiber of amorphous described in 3% embodiment 1, room temperature
Under the conditions of clad aluminum tensile strength lifted from 260MPa to 310MPa；And elongation at break be 8%, and steel elongation at break
Just match.Suitable for high corrosion environment with aluminium for steel target.
Add after percentage by weight high sial copper zirconium reinforcing fiber of amorphous described in 3% embodiment 2, it is multiple under room temperature condition
Aluminium tensile strength is closed to be lifted to 300MPa from 260MPa；And elongation at break is 7%.
Add after percentage by weight high sial copper zirconium reinforcing fiber of amorphous described in 3% embodiment 3, it is multiple under room temperature condition
Aluminium tensile strength is closed to be lifted to 280MPa from 260MPa；And elongation at break is 6%.
In summary, a kind of high sial copper zirconium reinforcing fiber of amorphous and preparation method that the present invention is provided and the super modeling of aluminum bronze zirconium
Alloy-based clad aluminum, igneous rock of the present invention, cupric oxide, zirconium oxide and carbon dust compound it is molten using vertical-insert electrode all-electric melting furnace
Refine, then melt passes through the bushing acquisition high sial copper zirconium reinforcing fiber of amorphous.The high sial copper zirconium reinforcing fiber of the amorphous is short
The super modeling aluminium alloy compound of rear and aluminum bronze zirconium system is cut, so as to obtain the high-strength compound aluminium of interface fusion excellent performance.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (10)
1. a kind of high sial copper zirconium reinforcing fiber of amorphous, it is characterised in that by weight percentage, by 89%-99% igneous rock,
0-9% cupric oxide, 0-1% zirconium oxide and 1% carbon dust composition；Wherein, the cupric oxide is different from the content of the zirconium oxide
When take 0 value.
2. the high sial copper zirconium reinforcing fiber of amorphous according to claim 1, it is characterised in that by weight percentage, by
90%-93% igneous rock, 5-8% cupric oxide, 0.5-1% zirconium oxide and 1% carbon dust composition.
3. the high sial copper zirconium reinforcing fiber of amorphous according to claim 2, it is characterised in that by weight percentage, by
90.8% igneous rock, 7.5% cupric oxide, 0.7% zirconium oxide and 1% carbon dust composition.
4. the high sial copper zirconium reinforcing fiber of amorphous according to claim 1, it is characterised in that by weight percentage, by
98.3% igneous rock, 0.7% zirconium oxide and 1% carbon dust composition.
5. the high sial copper zirconium reinforcing fiber of amorphous according to claim 2, it is characterised in that by weight percentage, by
90.3% igneous rock, 8% cupric oxide, 0.7% zirconium oxide and 1% carbon dust composition.
6. the high sial copper zirconium reinforcing fiber of amorphous according to claim 1, it is characterised in that on the basis of igneous rock, institute
State the gross weight of iron oxide contained by igneous rock, ferrous oxide<3%, igneous rock institute silicon oxide-containing, the gross weight of aluminum oxide>
68%。
7. a kind of preparation method of high sial copper zirconium reinforcing fiber of amorphous as described in claim 1 ~ 6 is any, it is characterised in that
Including step：
Above-mentioned formula is first according to be well mixed igneous rock, cupric oxide, zirconium oxide and carbon dust, and the fire that will be well mixed
Diagenesis, cupric oxide, zirconium oxide and carbon dust carry out melting, obtain melt；
Then melt is subjected to wire drawing, obtains the high sial copper zirconium reinforcing fiber of amorphous.
8. the preparation method of the high sial copper zirconium reinforcing fiber of amorphous according to claim 7, it is characterised in that specifically include
Step：
Above-mentioned formula is first according to be well mixed igneous rock, cupric oxide, zirconium oxide and carbon dust, and the fire that will be well mixed
Diagenesis, cupric oxide, zirconium oxide and carbon dust are put into vertical-insert electrode all-electric melting furnace and carry out melting, obtain melt；
Then solution is subjected to wire drawing by bushing, obtains the high sial copper zirconium reinforcing fiber of amorphous.
9. a kind of aluminum bronze zirconium super plastic alloy base clad aluminum, it is characterised in that by any described high sial of amorphous of claim 1 ~ 6
Copper zirconium reinforcing fiber and the super modeling aluminium alloy of aluminum bronze zirconium are mixed.
10. aluminum bronze zirconium super plastic alloy base clad aluminum according to claim 9, it is characterised in that the super modeling of the aluminum bronze zirconium is closed
The preparation method of auri clad aluminum includes step：The high sial copper zirconium reinforcing fiber of the amorphous being chopped is put into the super modeling aluminium of aluminum bronze zirconium
In aluminium alloy, then cool, be stirred for homogenizing, finally heating is poured, and obtains aluminum bronze zirconium super plastic alloy base clad aluminum；Wherein, institute
It is 3 to state the high sial copper zirconium reinforcing fiber of amorphous and the weight ratio of the super modeling aluminum alloy melt of aluminum bronze zirconium:97.
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| CN201710707637.8A CN107313129B (en) | 2017-08-17 | 2017-08-17 | Aluminum-copper-zirconium reinforced fiber, preparation method thereof and aluminum-copper-zirconium superplastic alloy based composite aluminum |
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|---|---|---|---|---|
| CN108998860A (en) * | 2018-08-23 | 2018-12-14 | 深圳市正佳科建科技有限公司 | Sial calcium zinc reinforcing fiber and preparation method and aluminium calcium zinc super plastic alloy base clad aluminum |
| CN109183195A (en) * | 2018-08-23 | 2019-01-11 | 深圳市正佳科建科技有限公司 | Sial copper magnesium reinforcing fiber and preparation method and aluminum bronze magnesium super plastic alloy base clad aluminum |
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