CN107740975A - A kind of corrosion-resistant Crystal lamp suspension member - Google Patents
A kind of corrosion-resistant Crystal lamp suspension member Download PDFInfo
- Publication number
- CN107740975A CN107740975A CN201711019182.7A CN201711019182A CN107740975A CN 107740975 A CN107740975 A CN 107740975A CN 201711019182 A CN201711019182 A CN 201711019182A CN 107740975 A CN107740975 A CN 107740975A
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- Prior art keywords
- suspension member
- layer
- crystal lamp
- corrosion
- lamp suspension
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21S—NON-PORTABLE LIGHTING DEVICES; SYSTEMS THEREOF; VEHICLE LIGHTING DEVICES SPECIALLY ADAPTED FOR VEHICLE EXTERIORS
- F21S8/00—Lighting devices intended for fixed installation
- F21S8/04—Lighting devices intended for fixed installation intended only for mounting on a ceiling or the like overhead structures
- F21S8/06—Lighting devices intended for fixed installation intended only for mounting on a ceiling or the like overhead structures by suspension
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0641—Nitrides
- C23C14/0652—Silicon nitride
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
- C23C14/165—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
- C23C14/185—Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V13/00—Producing particular characteristics or distribution of the light emitted by means of a combination of elements specified in two or more of main groups F21V1/00 - F21V11/00
Abstract
The invention discloses a kind of corrosion-resistant Crystal lamp suspension member, including Crystal lamp suspension member, it is adjacent to successively from inside to outside on the Crystal lamp suspension member surface and is compounded with six film layers, wherein it is B that the first film layer, which is most theca interna,2O3Layer, the second film layer is zinc-tin layer, and third membrane layer is layers of copper, and the 4th film layer is titanium dioxide layer, and the 5th film layer is SSTOx layers, and the 6th film layer is Si3N4.Corrosion-resistant Crystal lamp suspension member provided by the invention is not easy to be worn in use, scratched, and in atmosphere, surface is less prone to the phenomenon being corroded.
Description
Technical field
The present invention relates to a kind of Crystal lamp suspension member, especially corrosion-resistant Crystal lamp suspension member.
Background technology
Crystal lamp suspension member be current people like for the ornament that uses of lamp collocation, but crystal in the market
Lamp suspension member in use, is easily worn, scratched, and most of Crystal lamp suspension members reveal in atmosphere put a period of time after go out
The phenomenon now corroded, it is especially even more serious in the adverse circumstances such as kitchen, toilet, and then the attractive in appearance of Crystal lamp suspension member is influenceed,
For Crystal lamp suspension member after corrosion, dust dirt is gradually accumulated on surface simultaneously, visual effect caused by Crystal lamp suspension member is deteriorated, band
Carry out bad influence.
The content of the invention
The present invention seeks to overcome the deficiencies in the prior art, there is provided and one kind is not easy to be worn in use, scratched,
In atmosphere, surface is not easy the corrosion-resistant Crystal lamp suspension member being etched.
In order to achieve the above object, the present invention uses following scheme：
A kind of corrosion-resistant Crystal lamp suspension member, including Crystal lamp suspension member, on the Crystal lamp suspension member surface from inside to outside successively
It is adjacent to and is compounded with six film layers, wherein it is B that the first film layer, which is most theca interna,2O3Layer, the second film layer are zinc-tin layer, third membrane layer
For layers of copper, the 4th film layer is titanium dioxide layer, and the 5th film layer is SSTOx layers, and the 6th film layer is Si3N4。
Corrosion-resistant Crystal lamp suspension member as described above, the first film layer are most theca interna B2O3The thickness of layer is 20~30nm.
Corrosion-resistant Crystal lamp suspension member as described above, the thickness of the second film layer zinc-tin layer is 30~40nm.
Corrosion-resistant Crystal lamp suspension member as described above, the thickness of the third membrane layer layers of copper is 5~10nm.
Corrosion-resistant Crystal lamp suspension member as described above, the thickness of the 4th film layer titanium dioxide layer is 50~60nm.
Corrosion-resistant Crystal lamp suspension member as described above, the thickness of the 5th film layer SSTOx layers is 50~60nm.
Corrosion-resistant Crystal lamp suspension member as described above, the 6th film layer Si3N4The thickness of layer is 60~100nm.
Corrosion-resistant Crystal lamp suspension member as described above, first film layer are most theca interna B2O3The thickness of layer 21 is 25nm.
Corrosion-resistant Crystal lamp suspension member as described above, the thickness of the third membrane layer layers of copper 23 is 8nm.
Corrosion-resistant Crystal lamp suspension member as described above, the 6th film layer Si3N426 layers of thickness is 80nm.
Compared with prior art, the present invention has the following advantages：
1st, the corrosion-resistant Crystal lamp suspension member that the present invention makes, utilizes B2O3Chemical property is stable at normal temperatures, has corrosion-resistant
The characteristics of, magnetron sputtering B2O3As most theca interna, the corrosion-resistant Crystal lamp suspension member is protected to be less prone to the phenomenon being corroded,
Enter without influenceing the attractive in appearance of Crystal lamp suspension member.
2nd, the corrosion-resistant Crystal lamp suspension member that the present invention makes also utilizes Si3N4With good physical property and corrosion resistance
Can, with Si3N4As outermost film plating layer, protect the Crystal lamp suspension member not oxidizable, prevent that the Crystal lamp suspension member surface is rotten
Erosion, while the high Crystal lamp suspension member mechanical endurance energy of energy, prevent the phenomenon for being scratched, wearing.
Brief description of the drawings
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
Fig. 1 is the corrosion-resistant Crystal lamp suspension member stereogram of the present invention.
Fig. 2 is the corrosion-resistant Crystal lamp suspension member surface of the present invention and the thickness structure schematic diagram of each film plating layer.
Embodiment
Fig. 1, Fig. 2 are referred to, in this specific embodiment, a kind of corrosion-resistant Crystal lamp suspension member, including Crystal lamp suspension member 1,
It is adjacent to successively from inside to outside on the surface of Crystal lamp suspension member 1 and is compounded with six film layers, wherein the first film layer is most theca interna
For B2O3Layer 21, the second film layer are zinc-tin layer 22, and third membrane layer is layers of copper 23, and the 4th film layer is titanium dioxide layer 24, the 5th film layer
For SSTOx layers 25, the 6th film layer is Si3N426.In this specific embodiment, the shape of the corrosion-resistant Crystal lamp suspension member can be with
It is circular to be square, taper, ellipse, hexa-prism etc., the corrosion-resistant Crystal lamp suspension member one of which shape as described in being used as Fig. 1
Shape.
First film layer is that most theca interna is B2O3Layer 21, i.e. boron oxide layer 21.B2O3Chemical property is steady at normal temperatures
It is fixed, there is corrosion resistant feature, therefore, magnetron sputtering B2O3As most theca interna, the corrosion-resistant Crystal lamp suspension member is protected to be not easy
There is the phenomenon being corroded in such as adverse circumstances such as kitchen, toilet, enter without influenceing the attractive in appearance of Crystal lamp suspension member.Described
Magnetron sputtering B on Crystal lamp suspension member surface2O321 thickness of layer are 20~30nm, preferably 25nm.
Second film layer is zinc-tin layer, has protective effect to corrosion-resistant Crystal lamp suspension member.In the B2O3Magnetic on layer 21
The thickness for controlling sputtering zinc oxide tin layers 22 is 30~40nm, preferably 40nm.
The third membrane layer is layers of copper 23, is functional layer, provides layer as glassy yelloe, makes corrosion-resistant Crystal lamp suspension member
The transparent yellow of outward appearance.Magnetron sputtering layers of copper 23 is 5~10nm, preferably 8nm in the zinc oxide tin layers 22.
4th film layer is titanium dioxide layer 24, and titanium dioxide is smooth as Coating Materials, and has to light
Extremely strong refraction, reflex, therefore the refractivity between composite film can be improved, and by the effect of reflection to adjust
The color of Crystal lamp suspension member is stated, the Crystal lamp suspension member is showed the third membrane layer layers of copper in appearance and is carried as glassy yelloe
For the visual effect of layer.The thickness of magnetron sputtering titanium dioxide layer 24 is 50~60nm, preferably 55nm in the layers of copper 23.
5th film layer is SSTOx layers 25, in reactive sputtering, improves the refractive index of film layer, is integrated again so as to be lifted
The transmitance of membrane system is closed, and then makes adjustments glassy yelloe color layers, makes the transparent yellow effect of corrosion-resistant Crystal lamp suspension member.Institute
The thickness for stating magnetron sputtering SSTOx layers 25 on titanium dioxide layer 24 is 50~60nm, preferably 60nm.
The 6th film layer Si3N426 layers.Si3N4It is a kind of high hardness material, there is good physical property and anti-corruption
Corrosion energy, with Si3N4As outermost film plating layer, on the one hand protect the Crystal lamp suspension member not oxidizable, prevent the Crystal lamp from hanging
Part surface is corroded, and on the other hand enables the whole compound film system of the Crystal lamp suspension member have good mechanical endurance, with
And strengthen the physical property of whole compound film system, prevent occurring the phenomenon for being scratched, wearing in use.Described
Magnetron sputtering Si on SSTOx layers 253N4The thickness of layer 26 is 60~100nm, preferably 80nm.
The invention also discloses a kind of method for preparing corrosion-resistant Crystal lamp suspension member, it comprises the following steps：
The first step clean the Crystal lamp suspension member of shaping first, and its step is：The Crystal lamp suspension member of the shaping is put
After being cleaned by ultrasonic 10 minutes in acetone, then with EtOH Sonicate clean 10 minutes, finally 10 points of ultrasonic cleaning in deionized water
Clock；
Then second step is carried out, after molded Crystal lamp suspension member cleaning, magnetron sputtering pallet is put into, is then fed into plating
Film machine；
Final step carries out plated film, and method is as follows：
(1) the magnetron sputtering B on the Crystal lamp suspension member surface2O3Layer 21, made using oxygen as reacting gas, argon gas
For protective gas, bismuth flat target is sputtered with dc source, the ratio of argon oxygen is 300~500SCCM：500~800SCCM；This step
Quality of the middle argon oxygen than determining film forming, therefore, the ratio of preferential argon oxygen is 300SCCM：500SCCM；
(2) in the B2O3Magnetron sputtering zinc oxide tin layers 22 on layer 21, using argon gas as protective gas, oxygen conduct
Reacting gas, zinc-tin target is sputtered with AC power, the ratio of argon oxygen is 300~500SCCM：500~800SCCM, therefore, preferential argon
The ratio of oxygen is 300SCCM：500SCCM；
(3) the magnetron sputtering layers of copper 23 in the zinc oxide tin layers 22, it is as reacting gas, gas flow using argon gas
300~500SCCM, copper target is sputtered with dc source.
(4) the magnetron sputtering titanium dioxide layer 24 in the layers of copper 23, by the use of argon gas as protective gas, oxygen is as reaction
Gas, titanium target is sputtered with AC power, the ratio of argon oxygen is：300-500SCCM：500-800SCCM；Argon oxygen is than determining in this step
The quality of film forming, therefore, the ratio of preferential argon oxygen is 300SCCM：500SCCM；
(5) the magnetron sputtering SSTOx layers 25 on the titanium dioxide layer 24, made using oxygen as reacting gas, argon gas
For protective gas, stainless steel flat target is sputtered with dc source, argon oxygen ratio is：300~500SCCM：500~800SCCM, this step
Quality of the argon oxygen than determining film forming in rapid, therefore, the ratio of preferential argon oxygen is 300SCCM：500SCCM；
(6) the magnetron sputtering Si on the SSTOx layers 253N4Layer 26, employ nitrogen as and be used as guarantor for reacting gas, argon gas
Air-flow is protected, sputters sial target with AC power, the ratio of argon oxygen is：300~500SCCM：500~800SCCM；Argon oxygen in this step
Than the quality for determining film forming, therefore, the ratio of preferential argon oxygen is 300SCCM：500SCCM.
To sum up presently filed embodiment is explained in detail, but the application is not limited to above-mentioned embodiment.Even if
To the application, various changes can be made for it, then still falls within the protection domain in the application.
Claims (10)
1. a kind of corrosion-resistant Crystal lamp suspension member, including Crystal lamp suspension member (1), it is characterised in that：Crystal lamp suspension member (1) surface
On be adjacent to successively be compounded with six film layers from inside to outside, wherein it is B that the first film layer, which is most theca interna,2O3Layer (21), the second film layer
For zinc-tin layer (22), third membrane layer is layers of copper (23), and the 4th film layer is titanium dioxide layer (24), and the 5th film layer is SSTOx layers
(25), the 6th film layer is Si3N4(26)。
2. corrosion-resistant Crystal lamp suspension member according to claim 1, it is characterised in that：First film layer is most theca interna B2O3Layer
(21) thickness is 20~30nm.
3. corrosion-resistant Crystal lamp suspension member according to claim 1, it is characterised in that：The second film layer zinc-tin layer (22)
Thickness is 30~40nm.
4. corrosion-resistant Crystal lamp suspension member according to claim 1, it is characterised in that：The thickness of the third membrane layer layers of copper (23)
Spend for 5~10nm.
5. corrosion-resistant Crystal lamp suspension member according to claim 1, it is characterised in that：The 4th film layer titanium dioxide layer
(24) thickness is 50~60nm.
6. corrosion-resistant Crystal lamp suspension member according to claim 1, it is characterised in that：The 5th film layer SSTOx layers (25)
Thickness be 50~60nm.
7. corrosion-resistant Crystal lamp suspension member according to claim 1, it is characterised in that：The 6th film layer Si3N4(26) layer
Thickness is 60~100nm.
8. corrosion-resistant Crystal lamp suspension member according to claim 2, it is characterised in that：First film layer is most theca interna
B2O3The thickness of layer (21) is 25nm.
9. corrosion-resistant Crystal lamp suspension member according to claim 4, it is characterised in that：The thickness of the third membrane layer layers of copper (23)
Spend for 8nm.
10. corrosion-resistant Crystal lamp suspension member according to claim 7, it is characterised in that：The 6th film layer Si3N4(26) layer
Thickness be 80nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711019182.7A CN107740975A (en) | 2017-10-27 | 2017-10-27 | A kind of corrosion-resistant Crystal lamp suspension member |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711019182.7A CN107740975A (en) | 2017-10-27 | 2017-10-27 | A kind of corrosion-resistant Crystal lamp suspension member |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107740975A true CN107740975A (en) | 2018-02-27 |
Family
ID=61238325
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711019182.7A Pending CN107740975A (en) | 2017-10-27 | 2017-10-27 | A kind of corrosion-resistant Crystal lamp suspension member |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614696A (en) * | 2013-11-07 | 2014-03-05 | 中山市创科科研技术服务有限公司 | Preparation method of corrosion-resistant thin film |
| CN103741102A (en) * | 2013-12-21 | 2014-04-23 | 揭阳市宏光镀膜玻璃有限公司 | Fabrication method of glass for crystal light pendant |
| CN104264119A (en) * | 2014-10-18 | 2015-01-07 | 中山市创科科研技术服务有限公司 | Asymmetric-film-series double-silver LOW-E glass and preparation method thereof |
| CN106164003A (en) * | 2013-11-20 | 2016-11-23 | 玻璃与陶瓷研究有限公司卢森堡中心 | Have the zinc stannate layer comprised between infrared reflecting layer low-emissivity coating can heat treatment coated article and preparation method thereof |
-
2017
- 2017-10-27 CN CN201711019182.7A patent/CN107740975A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614696A (en) * | 2013-11-07 | 2014-03-05 | 中山市创科科研技术服务有限公司 | Preparation method of corrosion-resistant thin film |
| CN106164003A (en) * | 2013-11-20 | 2016-11-23 | 玻璃与陶瓷研究有限公司卢森堡中心 | Have the zinc stannate layer comprised between infrared reflecting layer low-emissivity coating can heat treatment coated article and preparation method thereof |
| CN103741102A (en) * | 2013-12-21 | 2014-04-23 | 揭阳市宏光镀膜玻璃有限公司 | Fabrication method of glass for crystal light pendant |
| CN104264119A (en) * | 2014-10-18 | 2015-01-07 | 中山市创科科研技术服务有限公司 | Asymmetric-film-series double-silver LOW-E glass and preparation method thereof |
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Application publication date: 20180227 |
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