CN107739155A - A kind of coloured glaze material and preparation method thereof - Google Patents
A kind of coloured glaze material and preparation method thereof Download PDFInfo
- Publication number
- CN107739155A CN107739155A CN201711088606.5A CN201711088606A CN107739155A CN 107739155 A CN107739155 A CN 107739155A CN 201711088606 A CN201711088606 A CN 201711088606A CN 107739155 A CN107739155 A CN 107739155A
- Authority
- CN
- China
- Prior art keywords
- coloured glaze
- glaze material
- parts
- agent
- preheated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of coloured glaze material, and in parts by weight, coloured glaze material includes following components：60 70 parts of quartz sand, 20 35 parts of fining agent, 5 10 parts of oxidant, 5 15 parts of fluxing agent, 15 25 parts of colouring agent, 15 parts of organobentonite, 25 parts of sodium silicate.The present invention uses environment-friendly type fining agent, it is ensured that health, and reduce environmental pollution, the colored glaze product prepared by above-mentioned process, color is beautiful, pure color.
Description
Technical field
The present invention relates to silicate product, especially a kind of coloured glaze material and preparation method.
Background technology
Coloured glaze is a kind of common ornament materials, and coloured glaze has the good characteristics such as low, the material property length of softening point, generally in coloured glaze
Basic ingredient in add fining agent so that coloured glaze melt temperature reduce, fusing quality be improved, avoid produce gas
The defects of bubble, striped.But currently used fining agent has ceria, white arsenic, white arsenic is extremely toxic substance, and harmful to human is good for
Health, and environment is polluted, and because the performance of each component limits in material, also there is some defects in coloured glaze material：
Softening point is high, material property is short, clarifying effect is poor, settling time is long, product integrated quality is poor.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of coloured glaze material and preparation method, the present invention are clear using environment-friendly type
Clear agent, it is ensured that health, and reduce environmental pollution, the colored glaze product prepared by above-mentioned process, color is beautiful, face
Colour purity is just.
In order to solve the above-mentioned technical problem, the invention provides a kind of coloured glaze material, in parts by weight, coloured glaze material
Including following components：
In the preferred embodiment of the present invention, further comprise, in parts by weight, coloured glaze material includes following
Component：
In the preferred embodiment of the present invention, further comprise, the fining agent is antimony oxide.
In the preferred embodiment of the present invention, further comprise, the particle diameter of the quartz sand is 1-5mm.
In the preferred embodiment of the present invention, further comprise, the oxidant is ammonium nitrate or potassium nitrate.
In the preferred embodiment of the present invention, further comprise, the fluxing agent is aluminum oxide.
The present invention a preferred embodiment in, further comprise, the colouring agent include it is following in one kind or several
Kind：Manganese dioxide, cupric oxide, nickel sesquioxide.
In the preferred embodiment of the present invention, further comprise, a kind of coloured glaze material preparation method, including following step
Suddenly：
S 101 weighs each component in material, standby；
Quartz sand, fining agent, oxidant are well mixed by S 102, are preheated, and are preheated to 220-260 DEG C；
After S 103 is preheated, 0.5-1h is incubated under preheating temperature；
S 104 adds fluxing agent, colouring agent in the material into S103, is melted inside kiln, and fusion temperature is
1480-1500 DEG C, fusing time 14-16h；
S 105 is clarified after melting, and clarifying temp clarifies 10h at 1680 DEG C, obtains liquid coloured glaze；
S 106 adds liquid coloured glaze into mould, is molded, and subsequently into being annealed in annealing furnace, annealing temperature is
350-400 DEG C, 4 hours are incubated, is cooled to room temperature, obtains product.
The technique effect of the present invention：
The coloured glaze material fining agent of the present invention uses antimony oxide, solves traditional coloured glaze and uses white arsenic conduct
Fining agent, antimony oxide have a safety feature, environmentally friendly, and settling time is shorter.
Present invention employs fluxing agent, it is possible to increase the burn-off rate in process of coloured glaze material, reduces technique
Requirement to temperature.
Embodiment
The invention will be further described for following specific embodiment, so that those skilled in the art can be more preferably geographical
The solution present invention can be simultaneously practiced, but illustrated embodiment is not as a limitation of the invention.
Embodiment 1
The formula of coloured glaze material is as shown in table 1 in embodiment 1.
Coloured glaze material prescription table in the embodiment 1 of table 1
| Component | Content (part) |
| Quartz sand | 60 |
| Fining agent | 20 |
| Oxidant | 5 |
| Fluxing agent | 5 |
| Colouring agent | 15 |
| Organobentonite | 1 |
| Sodium silicate | 2 |
Embodiment 2
The formula of coloured glaze material is as shown in table 2 in embodiment 2.
The formula table of coloured glaze material in the embodiment 2 of table 2
| Component | Content (part) |
| Quartz sand | 65 |
| Fining agent | 36 |
| Oxidant | 7 |
| Fluxing agent | 10 |
| Colouring agent | 20 |
| Organobentonite | 3 |
| Sodium silicate | 3 |
Embodiment 3
The formula of coloured glaze material is as shown in table 3 in embodiment 3.
The formula table of coloured glaze material in the embodiment 3 of table 3
| Component | Content (part) |
| Quartz sand | 70 |
| Fining agent | 35 |
| Oxidant | 10 |
| Fluxing agent | 15 |
| Colouring agent | 25 |
| Organobentonite | 5 |
| Sodium silicate | 5 |
The fining agent in embodiment 1-3 is antimony oxide.
The particle diameter of the quartz sand is 1-5mm.
The oxidant is ammonium nitrate or potassium nitrate.
The fluxing agent is aluminum oxide.
The colouring agent include it is following in one or more：Manganese dioxide, cupric oxide, nickel sesquioxide.
Formula in embodiment 1-3 is prepared using this method, is comprised the following steps：
S 101 weighs each component in material, standby；
Quartz sand, fining agent, oxidant are well mixed by S 102, are preheated, and are preheated to 220-260 DEG C；
After S 103 is preheated, 0.5-1h is incubated under preheating temperature；
S 104 adds fluxing agent, colouring agent in the material into S103, is melted inside kiln, and fusion temperature is
1480-1500 DEG C, fusing time 14-16h；
S 105 is clarified after melting, and clarifying temp clarifies 10h at 1680 DEG C, obtains liquid coloured glaze；
S 106 adds liquid coloured glaze into mould, is molded, and subsequently into being annealed in annealing furnace, annealing temperature is
350-400 DEG C, 4 hours are incubated, is cooled to room temperature, obtains product.
Comparative example 1
In material prescription in comparative example 1, fining agent is substituted for white arsenic, other components unchangeds, in preparation process, in vain
After arsenic is slightly soluble in cold water, hot water, white crystalline powder or amorphous glass shape material are soluble in.White arsenic dosage can excessively increase
Add volatile quantity, and pollute environment, to human health, 0.06 gram of white arsenic can make one lethal, need in use
Strict monitoring.And by contrasting, the settling time in embodiment 1-3 is unlike the length in embodiment 1, therefore, using three oxidations
Two antimony can either be harmful to human health as fining agent, will not also cause environmental pollution, and settling time is suitable.
Comparative example 2
Preparation method in comparative example is as follows：
S 101 weighs each component in material, standby；
Quartz sand, fining agent, oxidant are well mixed by S 102, are preheated, and are preheated to 220-260 °C；
S 103 adds fluxing agent, colouring agent in the material into S102, is melted inside kiln, and fusion temperature is
1480-1500 DEG C, fusing time 14-16h；
S 104 is clarified after melting, and clarifying temp clarifies 10h at 1680 DEG C, obtains liquid coloured glaze；
S 105 adds liquid coloured glaze into mould, is molded, and subsequently into being annealed in annealing furnace, annealing temperature is
350-400 DEG C, 4 hours are incubated, is cooled to room temperature, obtains product.
To in preparation technology, directly melting after preheating, not being incubated in comparative example 2, the color of the coloured glaze product prepared
Color stability, because after preheating, then is incubated than slightly worse in embodiment 1-3, is really that various components are steady in insulating process
A fixed process, it is possible to increase the quality of coloured glaze product, it is ensured that the stability of product.
Embodiment described above is only to absolutely prove preferred embodiment that is of the invention and being lifted, protection model of the invention
Enclose not limited to this.The equivalent substitute or conversion that those skilled in the art are made on the basis of the present invention, in the present invention
Protection domain within.Protection scope of the present invention is defined by claims.
Claims (8)
1. a kind of coloured glaze material, it is characterised in that in parts by weight, coloured glaze material includes following components：
A kind of 2. coloured glaze material as claimed in claim 1, it is characterised in that in parts by weight, coloured glaze material include with
Lower component：
3. a kind of coloured glaze material as claimed in claim 1, it is characterised in that the fining agent is antimony oxide.
4. a kind of coloured glaze material as claimed in claim 1, it is characterised in that the particle diameter of the quartz sand is 1-5mm.
5. a kind of coloured glaze material as claimed in claim 1, it is characterised in that the oxidant is ammonium nitrate or potassium nitrate.
6. a kind of coloured glaze material as claimed in claim 1, it is characterised in that the fluxing agent is aluminum oxide.
A kind of 7. coloured glaze material as claimed in claim 1, it is characterised in that the colouring agent include it is following in one kind or several
Kind：Manganese dioxide, cupric oxide, nickel sesquioxide.
8. a kind of coloured glaze material preparation method, it is characterised in that comprise the following steps：
S 101 weighs each component in material, standby；
Quartz sand, fining agent, oxidant are well mixed by S 102, are preheated, and are preheated to 220-260 DEG C；
After S 103 is preheated, 0.5-1h is incubated under preheating temperature；
S 104 adds fluxing agent, colouring agent in the material into S103, is melted inside kiln, fusion temperature 1480-
1500 DEG C, fusing time 14-16h；
S 105 is clarified after melting, and clarifying temp clarifies 10h at 1680 DEG C, obtains liquid coloured glaze；
S 106 adds liquid coloured glaze into mould, is molded, subsequently into being annealed in annealing furnace, annealing temperature 350-
400 DEG C, 4 hours are incubated, is cooled to room temperature, obtains product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711088606.5A CN107739155A (en) | 2017-11-08 | 2017-11-08 | A kind of coloured glaze material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711088606.5A CN107739155A (en) | 2017-11-08 | 2017-11-08 | A kind of coloured glaze material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107739155A true CN107739155A (en) | 2018-02-27 |
Family
ID=61233444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711088606.5A Pending CN107739155A (en) | 2017-11-08 | 2017-11-08 | A kind of coloured glaze material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107739155A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445940A (en) * | 2014-10-31 | 2015-03-25 | 太仓市科教新城琉璃艺术策划中心 | Production process of high-clarity colored glaze |
| CN105152529A (en) * | 2015-09-30 | 2015-12-16 | 太仓市双凤镇薄彩工艺品厂 | Colored glaze |
| CN106219974A (en) * | 2016-08-08 | 2016-12-14 | 太仓市科教新城琉璃艺术策划中心 | High-cleanness, high coloured glaze |
| CN106277772A (en) * | 2016-08-16 | 2017-01-04 | 太仓市科教新城琉璃艺术策划中心 | A kind of preparation technology of positive red coloured glaze |
| CN106277779A (en) * | 2016-08-23 | 2017-01-04 | 太仓市双凤镇薄彩工艺品厂 | A kind of transparent coloured glaze of abrasionproof and manufacture method thereof |
| CN106277774A (en) * | 2016-08-23 | 2017-01-04 | 太仓市双凤镇薄彩工艺品厂 | A kind of environmental protection coloured glaze and processing technology thereof |
| CN106316110A (en) * | 2016-08-23 | 2017-01-11 | 太仓市双凤镇薄彩工艺品厂 | Easily-formed colored glaze and manufacturing method thereof |
-
2017
- 2017-11-08 CN CN201711088606.5A patent/CN107739155A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445940A (en) * | 2014-10-31 | 2015-03-25 | 太仓市科教新城琉璃艺术策划中心 | Production process of high-clarity colored glaze |
| CN105152529A (en) * | 2015-09-30 | 2015-12-16 | 太仓市双凤镇薄彩工艺品厂 | Colored glaze |
| CN106219974A (en) * | 2016-08-08 | 2016-12-14 | 太仓市科教新城琉璃艺术策划中心 | High-cleanness, high coloured glaze |
| CN106277772A (en) * | 2016-08-16 | 2017-01-04 | 太仓市科教新城琉璃艺术策划中心 | A kind of preparation technology of positive red coloured glaze |
| CN106277779A (en) * | 2016-08-23 | 2017-01-04 | 太仓市双凤镇薄彩工艺品厂 | A kind of transparent coloured glaze of abrasionproof and manufacture method thereof |
| CN106277774A (en) * | 2016-08-23 | 2017-01-04 | 太仓市双凤镇薄彩工艺品厂 | A kind of environmental protection coloured glaze and processing technology thereof |
| CN106316110A (en) * | 2016-08-23 | 2017-01-11 | 太仓市双凤镇薄彩工艺品厂 | Easily-formed colored glaze and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102503122B (en) | Leadless, cadmium-free and strontium-free glass and manufacture process thereof | |
| CN101723589B (en) | Lead-free glass powder with low melting point for sealing PDP and preparation method thereof | |
| CN102659314A (en) | Barium oxide based crystal lead-free glass and preparation method thereof | |
| CN103058524B (en) | Arsenic-free low-expansion black and transparent microcrystalline glass | |
| CN103626398B (en) | A kind of crystallization type lead-free low-temperature seal glass and preparation thereof and using method | |
| CN106430988A (en) | Low-temperature lead-free glass powder for automobile front windshield laminated glass ink and preparation method thereof | |
| CN104609733A (en) | Vanadium-free arsenic-free low-expansion black transparent glass ceramic and preparation method thereof | |
| CN103539351A (en) | Production method of brown glass and brown glass beer bottles | |
| CN102757182A (en) | Low-temperature low expansion coefficient high-rigidity lead-free electronic glass powder and preparation method thereof | |
| CN1944304B (en) | Sealing micro crystal glass and its sealing method | |
| CN105060718A (en) | Glass door made of devitrified glass | |
| CN103539352A (en) | Method for producing glass bowl | |
| CN103449702A (en) | Production method of dark-green sodium calcium patterned glass | |
| CN107601866A (en) | A kind of gloss coloured glaze material and preparation method thereof | |
| CN104909562A (en) | High-refractivity environment-friendly ruby glass and preparation method thereof | |
| CN107739155A (en) | A kind of coloured glaze material and preparation method thereof | |
| CN101723590A (en) | Crystallization type colored low melting point sealing glass powder and method for preparing same | |
| CN102503151B (en) | Lead-free low-melting-point glass powder for ZnO valve plate and preparation method thereof | |
| CN112592053A (en) | Novel environment-friendly glass suitable for glass bottle and can production and preparation process thereof | |
| CN109824265B (en) | Preparation method of environment-friendly lead-free cadmium red glass and product prepared by preparation method | |
| CN102775061B (en) | A kind of Lead-free fusible environmental protection glass and preparation method thereof | |
| CN107417116A (en) | A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity | |
| CN103896487B (en) | For making the coloured devitrified glass containing neodymium sesquioxide of building wall brick | |
| CN105110638A (en) | Heat-resistant glass and preparation method therefor | |
| CN107601867A (en) | A kind of environment-friendly type coloured glaze material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180227 |