CN107735071A - Solid-like foaminess baths - Google Patents
Solid-like foaminess baths Download PDFInfo
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- CN107735071A CN107735071A CN201680039661.2A CN201680039661A CN107735071A CN 107735071 A CN107735071 A CN 107735071A CN 201680039661 A CN201680039661 A CN 201680039661A CN 107735071 A CN107735071 A CN 107735071A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- Animal Behavior & Ethology (AREA)
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Abstract
The present invention relates to a kind of solid-like foaminess baths, and it effectively suppresses the attachment to tableting die during fabrication, and when in use, the directly contact of pin or palm is made in bath water and sufficiently warms effect in use, can actually experience.That is, the present invention relates to a kind of solid-like foaminess baths, it contains：(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and below 50 mass %；(B) organic acid；Caloric value when 1.0g is dissolved in the water by (C) is more than 150cal/g and below 500cal/g inorganic compound, and composition (C) is more than 0.6 and less than 7.0 relative to the mass ratio ((C)/sodium acid carbonate) of sodium acid carbonate.
Description
Technical field
The present invention relates to solid-like foaminess baths.
Background technology
Since so far, the baths for being combined with carbonate and organic acid produces the bubble of carbon dioxide in bath water, leads to
Blood circulation facilitation effect or heat insulation effect can be obtained by crossing the carbon dioxide, or enjoy foaming sense, therefore be used as excellent bath
Agent and be widely known by the people, and then develop and have the preparation that assigns various performances.
For example, have disclosed in patent document 1 it is a kind of with carbonate and organic acid and with the silver-colored bath agent of hydroxycarboxylic acid, its
Carbon dioxide is produced when in use, and can suppress the breeding of miscellaneous bacteria.Also, there is one kind disclosed in patent document 2 with specified quantitative
Come and use the carbonate and/or bicarbonate of specified quantitative；With the foot-bath agent of the hygroscopic agent such as organic acid and sodium sulphate, according to the lavipeditum
It agent, can prevent from disengaging carbon dioxide in preservation, mitigate carbon dioxide being vaporized in shower water surface, it is ensured that two in bath water
The concentration of carbonoxide.
And then having a kind of warm composition disclosed in patent document 3, it contains generates heat as by hydration reaction
The standard dissolution enthalpy to water of pyrogen there is the inorganic salts that are specifically worth or zeolite and carbonate and fumaric acid, it can
Applied to creams shape or the extensive formulation such as bag-like, powdered, by the part in body such as being coated with or being adhered to, can obtain
Warm effect.
On the other hand, there is a kind of tablet form with the three-decker containing acid and carbonate disclosed in patent document 4
Foaminess bath agent, its mixed acid and carbonate, easy caused tabletting obstacle (sticking) when trial prevents tabletting.
(patent document 1) Japanese Patent Laid-Open 2010-37264 publications
(patent document 2) Japanese Patent Laid-Open 2005-200350 publications
(patent document 3) Japanese Patent Laid-Open 11-318967 publications
(patent document 4) Japanese Patent Laid-Open 03-74321 publications
The content of the invention
The present invention relates to a kind of solid-like foaminess baths, wherein, contain following component (A)~(C)：
(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and 50
Below quality %；
(B) organic acid；With
(C) caloric value when 1.0g is dissolved in the water is more than 150cal/g and below 500cal/g inorganic chemical
Thing,
Composition (C) is more than 0.6 and less than 7 relative to the mass ratio ((C)/sodium acid carbonate) of sodium acid carbonate.
Also, the present invention relates to a kind of solid-like foaminess baths, wherein, contain following component (A)~(C)：
(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and 50
Below quality %；
(B) organic acid；With
(C) caloric value when 1.0g is dissolved in the water is more than 150cal/g and below 500cal/g inorganic chemical
Thing,
Also, composition (C) is more than 0.6 and less than 7.0 relative to the mass ratio ((C)/sodium acid carbonate) of sodium acid carbonate, and
And the solid-like foaminess baths is at least to be used in bath water with the skin contact of a part for body.
Such as in bath water, make the surface of baths with the direct skin contact of pin or hand and in use, patent document 1
Preparation described in~2 fully can not actually experience warm effect, even if also, the composition described in patent document 3 will
Solid-like is configured to, is also had because release property is insufficient therefore can not prevent the worry of the attachment to tableting die or mould.Enter
And even preparation described in patent document 4, not only need that the peculiar process of the preparation of three-decker is made, and
As the preparation for directly sufficiently to warm effect to skin tape in bath water, still there is room for improvement.
Therefore, the present invention relates to a kind of solid-like foaminess baths, when it effectively suppresses manufacture to tableting die or
The attachment of mould, and when in use, with the direct skin contact such as pin or hand and in use, can actually experience in bath water
Sufficiently warm effect.
Therefore the present inventors carry out various researchs, although being as a result judged as, if being used as carbonate using sodium acid carbonate
The attachment to tableting die or mould then can be effectively prevented, but is difficult to also have higher warm effect concurrently.Therefore, according to entering one
The research of step finds, by and to specified quantitative contain sodium acid carbonate specified quantitative carbonate and organic acid, and relative to
Sodium acid carbonate uses specific inorganic compound with specific mass ratio, and can obtain can effectively suppress to tableting die or mould
Tool adheres to and plays the solid-like foaminess baths of higher warm effect.
According to the solid-like foaminess baths of the present invention, when can not assign special layer and forming and effectively suppress manufacture
Attachment to tableting die or mould, the simplification of process and the raising of productivity ratio can be sought.Also, in bath water when in use,
Sufficiently warm effect, therefore good foaming sense can be enjoyed can be played, and such as a part for the body with pin or hand
Direct skin contact and in use, comfortable warm effect can be experienced actually.
Embodiment
Hereinafter, the present invention is described in detail.
The solid-like foaminess baths of the present invention contains more than 20 mass % and below 50 mass % carbonate conduct
Composition (A), the carbonate contains more than 15 mass % and below 100 mass % sodium acid carbonate.In this way, by with 20 mass %
Above and below 50 mass % amount contains carbonate, when in bath water using the solid-like foaminess baths of the present invention,
The amount of carbon dioxide, brings good foaming sense caused by can together ensuring with the organic acid of following compositions (B), also, logical
Cross and play excellent blood circulation facilitation effect, additionally it is possible to assign skin good warming sense.Moreover, by the carbonate
Containing more than 15 mass % and below 100 mass % as suppressing baths to tableting die or the composition of the tack of mould
And the sodium acid carbonate that serviceability is higher, in the solid-like foaminess baths of the manufacture present invention, baths and tabletting can be improved
The release property of drift or mould, effectively suppress the unwanted attachment to tableting die or mould.
Baths is to for the viewpoint of tableting die or the tack of mould when effectively suppressing manufacture, at composition (A)
Carbonate in, the content of sodium acid carbonate is more than 15 mass %, preferably more than 25 mass %, more preferably 35 mass % with
On.Also, for the viewpoint of higher warm effect when ensuring use in bath water, in composition (A) carbonate, carbon
The content of sour hydrogen sodium is below 100 mass %, preferably below 85 mass %, more preferably below 70 mass %.Then, into
Divide in the carbonate of (A), the content of sodium acid carbonate is more than 15 mass % and below 100 mass %, preferably 25~85 matter
Measure %, more preferably 35~70 mass %.
And then baths is to for the viewpoint of tableting die or the tack of mould when effectively suppressing manufacture, solid
In body shape foaminess baths, the content of sodium acid carbonate is preferably more than 3 mass %, more preferably more than 8 mass %, Jin Eryou
Elect as more than 13 mass %.Also, for the viewpoint of higher warm effect when ensuring use in bath water, in solid-like
In foaminess baths, the content of sodium acid carbonate is preferably below 50 mass %, more preferably below 40 mass %, and then preferably
For below 30 mass %.Then, in solid-like foaminess baths, the content of sodium acid carbonate be preferably 3~50 mass % with
Under, more preferably 8~40 mass %, and then preferably 13~30 mass %.
The carbonate of composition (A) can contain selected from sodium carbonate, magnesium carbonate, potassium carbonate in addition to containing above-mentioned sodium acid carbonate
It is and one kind or two or more in calcium carbonate.Wherein, thus it is ensured that the viewpoint of higher warm effect during use in bath water and
Speech, more preferably a kind or 2 kinds be preferably selected from sodium carbonate and calcium carbonate, sodium carbonate.
Furthermore such as composition (dissolution enthalpy with sodium carbonate for heat generation：- 60.0cal/g) compare, it is contained in composition (A)
Above-mentioned sodium acid carbonate be the higher composition (dissolution enthalpy of heat absorptivity：+ 54.2cal/g), thus while when typically having reduction use
The tendency of warm effect in bath water, but the present invention solid-like foaminess baths in, also with following compositions or
Its content and specific mass ratio complement each other, and can play excellent warm effect.
On composition (A) content, just complemented each other with the organic acid of following compositions (B) to ensure that carbon dioxide produces
Amount, it is 20 matter in the solid-like foaminess baths of the present invention for assigning the viewpoint that good foaming is felt when in use
More than % is measured, preferably more than 25 mass %, more preferably more than 30 mass %.Also, it is maintained for good storage stability
For viewpoint, in the solid-like foaminess baths of the present invention, the content of composition (A) is below 50 mass %, preferably 45
Below quality %, more preferably below 40 mass %.Then, in the solid-like foaminess baths of the present invention, composition contains
Measure as more than 20 mass % and below 50 mass %, preferably 25~45 mass %, more preferably 30~40 mass %.
The solid-like foaminess baths of the present invention contains organic acid as composition (B).As the composition (B), can enumerate：
Selected from fumaric acid, citric acid, malic acid, tartaric acid, butanedioic acid, maleic acid, phthalic acid, glutaric acid, adipic acid, benzene first
It is one kind or two or more in acid, salicylic acid and oxalic acid.Wherein, thus it is ensured that higher warm effect during use in bath water
For viewpoint, be preferably selected from it is one kind or two or more in fumaric acid, citric acid, malic acid, tartaric acid and butanedioic acid, more preferably
To be one kind or two or more in fumaric acid, citric acid, malic acid and tartaric acid.
Furthermore substantially all organic acids are the composition for showing heat absorptivity, in the solid-like foaminess of the selection present invention
, can also be organic by these for playing the viewpoint of excellent warm effect when in use during composition (B) used in baths
The value of the dissolution enthalpy of acid is set to index, preferably selects value smaller.When obtaining the value of specific dissolution enthalpy, will can also survey
The value obtained by thermal balance when making each organic acid be dissolved in the water under the same conditions surely is as index.
Carbon dioxide yield is ensured, and in bath water when in use for the viewpoint of raising warm effect,
In the solid-like foaminess baths of the present invention, the content of composition (B) is preferably more than 20 mass % more preferably 25 mass %
More than, and then preferably more than 30 mass %.Also, it is maintained for for the viewpoint of good storage stability, in consolidating for the present invention
In body shape foaminess baths, the content of composition (B) is preferably below 50 mass %, more preferably below 45 mass %, and then
Preferably below 40 mass %.Then, in the solid-like foaminess baths of the present invention, the content of composition (B) is preferably 20
~50 mass %, more preferably 25~45 mass %, and then preferably 30~40 mass %.
Carbon dioxide yield is just effectively ensured that, when seeking the raising of the sense of foaming during use, and can make to using
Sufficient amount of carbon dioxide is dissolved in bath water for enjoying the blood circulation facilitation effect as caused by carbon dioxide
For viewpoint, in the solid-like foaminess baths of the present invention, the alkali molar equivalent X of mentioned component (A) relative to it is above-mentioned into
The ratio (X/Y) for dividing the sour molar equivalent Y of (B) is preferably more than 0.7, and more preferably more than 0.75, and then preferably more than 0.8.
Also, for same viewpoint, the alkali molar equivalent X of mentioned component (A) relative to the sour molar equivalent Y of composition (B) ratio (X/
Y it is preferably) less than 1, more preferably less than 0.97, and then preferably less than 0.95.Then, the alkali mole of mentioned component (A) is worked as
It is preferably 0.7~1 that X, which is measured, relative to the sour molar equivalent Y of composition (B) ratio (X/Y), more preferably 0.75~0.97, Jin Eryou
Elect 0.8~0.95 as.
Furthermore the alkali molar equivalent X of composition (A) be according to { the alkali valence mumber of content × composition (A) of composition (A)) }/into
The molecular weight of point (A) } calculate, when composition (A) contains the situation of a variety of carbonate, alkali mole that will be obtained respectively by each composition
The sum of equivalent is set to X.Similarly, the sour molar equivalent Y of composition (B) is also according to { content × composition (B) of composition (B)
Acid value number) }/{ molecular weight of composition (B) } calculate.
The solid-like foaminess baths of the present invention contain caloric value when 1.0g is dissolved in the water for 150cal/g with
Upper and below 500cal/g inorganic compound as composition (C), composition (C) relative to sodium acid carbonate mass ratio ((C)/carbon
Sour hydrogen sodium) it is more than 0.6 and less than 7.Although as described above, the present invention solid-like foaminess baths in composition (A) with
Specified quantitative contains as suppressing that baths is to tableting die or the composition of the tack of mould and sodium acid carbonate that serviceability is higher,
But the dissolution enthalpy of the sodium acid carbonate is+54.2cal/g, the as higher composition of heat absorptivity, therefore it is to be unsuitable for when in use
Bath water in improve warm effect composition.However, in the present invention, distinguish：Due to the inorganic compound 1.0g of composition (C)
Caloric value when being dissolved in the water is more than 150cal/g and below 500cal/g, i.e., it is the higher composition of heat generation, therefore
By using the composition relative to sodium acid carbonate with above-mentioned mass ratio, the manufacture for realizing that existing baths can not be realized can be had concurrently
When warm effect excellent to the tachment inhibiting effect of tableting die or mould and when using.
Moreover, the inorganic compound of the composition (C) is because heat generation is higher than the inorganic salts such as sodium sulphate, therefore can be effective
The raising of warm effect when using is realized on ground, also, without having to worry about distinctive smelly compared with the inorganic salts such as calcium chloride or magnesium chloride
The generation of taste or the precipitation of insoluble matter, it is thus ensured that good use feeling.
As composition (C) inorganic compound, specifically, can enumerate：Selected from anhydrous magnesium sulfate (MgSO4, dissolution enthalpy：-
180.4cal/g), anhydrous slufuric acid aluminium (Al2(SO4)3), dead plaster (CaSO4) etc. sulfate；Anhydrous calcium chloride (CaCl2)、
Anhydrous magnesium chloride (MgCl2), anhydrous Aluminum chloride (AlCl3) etc. chloride；It is and one kind or two or more in calcium oxide.
Wherein, with regard to heat generation is higher or the viewpoint of security and for suppressing the smelly viewpoint of base, it is preferably selected from anhydrous
1 kind in calcium chloride and anhydrous magnesium sulfate or 2 kinds, also, for preventing viewpoint that dissolving remains, more preferably anhydrous slufuric acid
Magnesium.
For the viewpoint of excellent warm effect when ensuring to use well, composition (C) is relative to mentioned component (A)
In contained sodium acid carbonate mass ratio ((C)/sodium acid carbonate) for more than 0.6, preferably more than 1.0, more preferably 1.1 with
On.Also, to for the viewpoint of tableting die or the tachment inhibiting effect of mould, composition (C) is relative when ensuring manufacture well
In sodium acid carbonate mass ratio ((C)/sodium acid carbonate) be less than 7.0, preferably less than 2.5, more preferably less than 1.7.Then,
Composition (C) is more than 0.6 and less than 7.0, preferably 1.0~2.5 relative to the mass ratio ((C)/sodium acid carbonate) of sodium acid carbonate,
More preferably 1.1~1.7.
For the viewpoint of excellent warm effect when ensuring to use well, bathed in the solid-like foaminess of the present invention
With in agent, the content of composition (C) is preferably more than 10 mass %, more preferably more than 15 mass %, and then preferably 18 matter
Measure more than %.Also, to tableting die or the viewpoint of the tachment inhibiting effect of mould when just ensuring manufacture well, and it is true well
Protect for the viewpoint of excellent warm effect when using, the content of composition (C) is preferably below 40 mass % more preferably 30
Below quality %, and then preferably below 25 mass %.Then, the content of composition (C) is preferably 10~40 mass %, more preferably
For 15~30 mass %, and then preferably 18~25 mass %.
The solid-like foaminess baths of the present invention is being had concurrently to the tachment inhibiting effect of tableting die or mould with using
When higher warm effect, and the lossless effect for substantially ensuring that blown with carbon dioxide amount and the generation or insoluble for preventing stink
The precipitation of thing and in the range of ensuring the effect of good use feeling, contain the inorganic salts beyond composition (A) and composition (C).
As the inorganic salts, such as can enumerate：It is one kind or two or more in sodium sulphate, calcium chloride and magnesium chloride.
In the solid-like foaminess baths of the present invention, the content of the inorganic salts beyond the composition (A) and composition (C) is excellent
Elect as below 30 mass %, more preferably below 15 mass %, or preferably in addition to inevitably mixed situation not
Containing the inorganic salts beyond composition (A) and composition (C).
Also, for keeping the viewpoint of the tachment inhibiting effect to tableting die or mould well, solid of the invention
Shape foaminess baths is preferably the content for limiting sorbierite.In the solid-like foaminess baths of the present invention, the sorbierite
Content be preferably below 7.5 mass %, more preferably below 5 mass %, and then preferably below 3.0 mass %, Huo Zheben
The solid-like foaminess baths of invention is preferably to be free of sorbierite.
As the composition beyond other mentioned components, solid-like foaminess baths of the invention can also be suitably containing usual
For the composition of baths, for example, nonionic surfactant；Water soluble polymer；Carbohydrate；Powdered quartz, nothing are fixed
The water-insoluble excipient (D)s such as type silica, unformed aluminosilicate；Fatty acid ester or glyceride, higher fatty acids or higher alcohol
Deng oil components；The CGRP responsiveness accelerator such as ginseng, Thujopsis dolabrata, cucumber, white birch and these extract；Vitamins；Egg
White catabolic enzyme；Sterilization antiseptic；Spices；Pigment etc..
The present invention solid-like foaminess baths be by the way that mentioned component is mixed after, be configured to according to conventional methods
Solid-like and obtain, without other special process, can effectively suppress the attachment to tableting die or mould.As specific shape
State, sheet (tablet-like) tablet or lumps (briquette-like) tablet can be enumerated, not including powder shaped or particle
The tablet of shape.In the situation of flake tablets, it is made by rotary tablet machine, hydraulic type tablet press machine, centering type tablet press machine etc.
Shaping, in the situation of lumps tablet, makes its shaping by cuber, compacting machine etc..Especially preferably be made Formulation,
Compress granulated formulation (such as agglomerate piece).Herein, so-called " agglomerate piece " refers to that the major diameter of tablet is 3~25mm size.
The quality (g/1) of every 1 solid-like foaminess baths of the invention can also change according to the mode of shower,
Preferably 30~60 (g/1), more preferably 35~55 (g/1).Also, the sight of comfortable warm effect is just brought when in use
For point, per 100g, the caloric value (cal/100g) of the solid-like foaminess baths of the present invention is preferably 1000~5000cal/
100g, more preferably 1300~4000cal/100g, and then preferably 2000~3200cal/100g.
Furthermore the value of the quality ratio of each composition that can be in baths and the dissolution enthalpy per the above-mentioned each compositions of 100g is calculated
Go out the caloric value of the solid-like foaminess baths of every 100g present invention.
With regard to conveying when tablet do not rupture or the viewpoint of defect for, the tablet of solid-like foaminess baths of the invention
Intensity (kgf) is preferably more than 5kgf, more preferably more than 7kgf, and then preferably more than 9kgf.Also, just improve solid-like hair
Bubble property baths is for the viewpoint of the dissolution velocity of bath water, preferably below 21kgf, more preferably below 18kgf, and then
Preferably below 15kgf.Furthermore, will be hard when tablet is the situation that rectangle etc. has angular shape when determining tablet strength
The center for spending the pressing of meter is pressed against the point of the central 5mm from the summit at arbitrary angle towards tablet, in the shape without angle
Situation when, the maximum piece across length that the center of scleroscopic pressing is pressed against on the horizontal plane equivalent to tablet
On on the line of agent and from end towards central 5mm point, apply load and determine.
The solid-like foaminess baths of the present invention is put into bath water, impregnates body at least in the bath water
A part and use.As the mode of shower, there is no particular restriction, can be the overall full bath of dipping body, or only soak
The part bath of a part for the bodies such as stain pin, hand, arm, head or shoulder.Wherein, excellent warm when using just fully is enjoyed
Effect, the viewpoint for carrying out directly to skin tape comfortable warm-heat effect, and for actually experiencing the viewpoint of comfortable foaming sense, it is excellent
Elect as make in bath water the solid-like foaminess baths of the present invention at least with the skin contact of a part for body and use,
When in this respect, specifically, a more preferably part for body is pin, arm or hand, and then preferably sole.It is more specific and
Speech, such as the solid-like foaminess baths of the present invention is configured in the bottom for being fed with the bathing pool of bath water, make one of body
Divide and contacted with the surface of the baths, such as a part for the body such as upper surface placement pin of the baths of self-configuring, make
The skin of a part for the body directly contacts with baths.
For fully enjoying the viewpoint of warm effect, the bath water of the solid-like foaminess baths of the present invention is put into
Temperature be preferably 30~45 DEG C, more preferably 35~43 DEG C, and then preferably 38~43 DEG C.In 30~45 DEG C of bath water
In, the time of dipping is preferably more than 1 minute, more preferably more than 3 minutes, and then preferably more than 5 minutes, at 35~43 DEG C
Bath water in be preferably more than 1 minute, more preferably more than 3 minutes, and then preferably more than 5 minutes, or 38~43
DEG C bath water in be more than 1 minute, preferably more than 3 minutes, and then preferably more than 5 minutes.
Wherein, in the situation for making the solid-like foaminess baths of the present invention and the skin contact of sole and using, i.e.,
When the solid-like foaminess baths of the present invention to be used as to the situation of foot-bath agent, just it is dissolved in sufficient amount of carbon dioxide and washes one's hair
In bath water and for bringing the viewpoint of good warmth sensation, the solid-like foaminess baths of the present invention is put into bath water
Amount relative to bath water 1L be preferably more than 3g, preferably more than 4.5g, and then preferably more than 6g.Also, by the present invention
Solid-like foaminess baths be used as foot-bath agent situation when, just effectively using carbon dioxide and suppress hot water temperature is increased
When scald viewpoint for, by the amount that puts into bath water of solid-like foaminess baths of the present invention relative to bath water
1L is preferably below 140g, more preferably below 70g, and then preferably below 50g, and then more preferably below 25g.
Moreover, when the solid-like foaminess baths of the present invention to be used as to the situation of foot-bath agent, preferably make bath water
Temperature rise, specifically, the temperature rising degree of bath water is preferably more than 0.1 DEG C, just brings good warmth sensation
For viewpoint, preferably more than 0.15 DEG C, and then preferably more than 0.2 DEG C.Also, used the solid-like foaminess of the present invention is bathed
When agent is used as the situation of foot-bath agent, for may refrain from the viewpoint due to being scalded caused by the rising of hot water temperature, bath water
Temperature rising degree is preferably less than 1.5 DEG C, more preferably less than 1.3 DEG C, and then preferably less than 1.0 DEG C.
On the embodiment of the invention described above, and then following tablet form foaminess baths is disclosed.
[1] a kind of solid-like foaminess baths, wherein, contain following component (A)~(C)：
(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and 50
Below quality %；
(B) organic acid；With
(C) caloric value when 1.0g is dissolved in the water is more than 150cal/g and below 500cal/g inorganic chemical
Thing,
Composition (C) is more than 0.6 and less than 7.0 relative to the mass ratio ((C)/sodium acid carbonate) of sodium acid carbonate.
[2] a kind of solid-like foaminess baths, wherein, contain following component (A)~(C)：
(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and 50
Below quality %；
(B) organic acid；With
(C) caloric value when 1.0g is dissolved in the water is more than 150cal/g and below 500cal/g inorganic chemical
Thing,
Composition (C) is more than 0.6 and less than 7.0 relative to the mass ratio ((C)/sodium acid carbonate) of sodium acid carbonate, also, institute
It is at least to be used in bath water with the skin contact of a part for body to state solid-like foaminess baths.
[3] the solid-like foaminess baths of [2] as described above, wherein, a part for body is pin, arm or hand.
[4] the solid-like foaminess baths of any one of [1]~[3] as described above, wherein, in composition (A), bicarbonate
The content of sodium is preferably more than 25 mass %, more preferably more than 35 mass %, preferably below 85 mass %, and more preferably 70
Below quality %.
[5] the solid-like foaminess baths of any one of [1]~[4] as described above, wherein, composition (A) is containing being selected from carbon
It is one kind or two or more in sour sodium, magnesium carbonate, potassium carbonate and calcium carbonate.
[6] the solid-like foaminess baths of any one of [1]~[5] as described above, wherein, the content of composition (A) is preferred
For more than 25 mass %, more preferably more than 30 mass %, preferably below 45 mass %, more preferably below 40 mass %.
[7] the solid-like foaminess baths of any one of [1]~[6] as described above, wherein, composition (B) is selected from rich horse
Acid, citric acid, malic acid, tartaric acid, butanedioic acid, maleic acid, phthalic acid, glutaric acid, adipic acid, benzoic acid, salicylic acid
And it is one kind or two or more in oxalic acid, be preferably selected from fumaric acid, citric acid, malic acid, tartaric acid and butanedioic acid a kind or
Two or more, it is more preferably one kind or two or more in fumaric acid, citric acid, malic acid and tartaric acid.
[8] the solid-like foaminess baths of any one of [1]~[7] as described above, wherein, the content of composition (B) is preferred
For more than 20 mass %, more preferably more than 25 mass %, and then preferably more than 30 mass %, preferably 50 mass % with
Under, more preferably below 45 mass %, and then preferably below 40 mass %.
[9] the solid-like foaminess baths of any one of [1]~[8] as described above, wherein, the alkali mole of composition (A) is worked as
It is preferably more than 0.7 that X, which is measured, relative to the sour molar equivalent Y of composition (B) ratio (X/Y), and more preferably more than 0.75, and then preferably
For more than 0.8, preferably less than 1, more preferably less than 0.97, and then preferably less than 0.95.
[10] the solid-like foaminess baths of any one of [1]~[9] as described above, wherein, composition (C) is relative to composition
(A) mass ratio ((C)/sodium acid carbonate) of contained sodium acid carbonate is preferably more than 1.0 in, and more preferably more than 1.1, be preferably
Less than 2.5, more preferably less than 1.7.
[11] the solid-like foaminess baths of any one of [1]~[10] as described above, wherein, composition (C) is preferably to select
From anhydrous magnesium sulfate, anhydrous slufuric acid aluminium, dead plaster, anhydrous calcium chloride, anhydrous magnesium chloride, anhydrous Aluminum chloride (AlCl3) and
It is one kind or two or more in calcium oxide, a kind more preferably in anhydrous calcium chloride and anhydrous magnesium sulfate or 2 kinds, Jin Eryou
Elect anhydrous magnesium sulfate as.
[12] the solid-like foaminess baths of any one of [1]~[11] as described above, wherein, the content of composition (C) is excellent
Elect as more than 10 mass %, more preferably more than 15 mass %, and then preferably more than 18 mass %, preferably 40 mass % with
Under, more preferably more than 30 mass %, and then preferably more than 25 mass %.
[13] the solid-like foaminess baths of any one of [1]~[12] as described above, wherein, in the tablet form of the present invention
In foaminess baths, the content of the inorganic salts beyond composition (A) and composition (C) is preferably below 30 mass %, more preferably
Below 15 mass %, or be preferably without the inorganic salts beyond composition (A) and composition (C).
[14] the solid-like foaminess baths of any one of [1]~[13] as described above, wherein, the content of sorbierite is preferred
For below 7.5 mass %, more preferably below 5 mass %, and then preferably below 3.0 mass %, or without sorbierite.
[15] the solid-like foaminess baths of any one of [1]~[14] as described above, wherein, form be flake tablets or
Lumps tablet.
[16] the solid-like foaminess baths of any one of [1]~[15] as described above, wherein, the caloric value per 100g
(cal/100g) it is preferably 1000~5000cal/100g, more preferably 1300~4000cal/100g, and then preferably 2000
~3200cal/100g.
[17] the solid-like foaminess baths of any one of [1]~[16] as described above, wherein, tablet strength is preferably
More than 5kgf, more preferably more than 7kgf, so preferably more than 9kgf, preferably below 21kgf, more preferably 18kgf with
Under, and then preferably below 15kgf.
[18] the solid-like foaminess baths of any one of [1]~[17] as described above, wherein, in bath water at least with
The skin contact of a part for body and use.
[19] the solid-like foaminess baths of [18] as described above, wherein, the part of body is pin, arm or hand, excellent
Elect sole as.
[20] the solid-like foaminess baths of any one of above-mentioned [1]~[19] input into bath water and at least with
The skin contact of a part for body and the purposes used.
[21] purposes of the solid-like foaminess baths of [20] as described above, wherein, it is being fed with the bathing pool of bath water
A part for the bodies such as pin is placed in the tablet form foaminess baths of the bottom configuration present invention, the upper surface of the baths of self-configuring
And use.
[22] purposes of the solid-like foaminess baths of [20] or [21] as described above, wherein, the part of body is pin,
Arm or hand, preferably sole.
[23] a kind of bathing method, wherein, the solid-like foaminess baths of any one of above-mentioned [1]~[19] is put into
Into bath water, and at least a part for body is impregnated in bath water, solid-like foaminess baths is made in bath water
At least with the skin contact of a part for body.
[embodiment]
Hereinafter, the present invention is specifically explained based on embodiment.Furthermore if nothing is particularly shown in table, each composition
Content represent quality %.
[embodiment 1~16, comparative example 1~8]
According to the formula shown in table 1, the polygon-octagonal that 1 45g and diagonal line length are 60mm is made using rotary pelleting machine
Tablet.
After the tablet of gained to be configured to the bottom of the bathing pool of the bath water equipped with 40 DEG C, 6L, placed from the top of tablet
Sole and skin is directly contacted with tablet surface and carry out lavipeditum in 10 minutes.According to following methods, carry out every measure and comment
Valency.
Furthermore as described above, the content of each composition in 100g tablets and the value of dissolution enthalpy of each composition calculate institute
The caloric value (cal/100g) of the tablet obtained.
Show the result in table 1.
《Tablet strength》
The intensity of each tablet be use (strain) log cabin make institute Determination of Hardness machine (model number 02040001) measure.Will
The center of scleroscopic pressing (stainless steel, a diameter of 5mm of front end) is compressed to the summit of the random angle from tablet towards piece
The central 5mm of agent part, apply load, the value of load during tablet rupture is set to tablet strength.2 tablets are determined, will
Its average value is set to evaluation of estimate.Unit is represented with kgf.
Furthermore in the situation for more than the 21kgf that the intensity of tablet is the detectable limit as Determination of Hardness machine, it is set to nothing
Method determines.
《Attachment to tableting die》
During for from manufacturing ingredient in tablets to the concavo-convex and caused tabletting obstacle caused by the attachment of tableting die (to piece
The convex-concave of agent surface transfer) degree, its degree is evaluated by visual observation according to following benchmark.
0：More to the adhesion amount of tableting die, more than 20% in tablet surface produces transfer (printing)
1：Attachment to tableting die is slightly more, and 10% in tablet surface produces transfer less than 20%
(printing)
2：Attachment unconfirmed to tableting die, the transfer of tablet surface are less than 10%, no problem
《To the warm effect of pin》
When carrying out lavipeditum, the warmth sensation that the skin of sole is felt is evaluated according to following benchmark.The evaluation of " 2 "
Expression can obtain good warm effect, and the evaluation of " 3 " represents that more excellent warm effect can be obtained.
0：Feel cold
1：It is neither cold nor warm
2：Somewhat bask
3：Feel good warm, comfortably
4：Feel slightly hot warm
5：Feel very hot
《Foaming sense》
When carrying out lavipeditum, the foaming sense felt the skin of sole is evaluated according to following benchmark.
0：Foaming sense is weak, or does not experience foaming sense
1：It is moderate to feel foaming sense
2：Strong foaming sense is obtained, comfortably
Claims (12)
1. a kind of solid-like foaminess baths, wherein,
Contain following component (A)~(C)：
(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and 50 matter
Measure below %；
(B) organic acid；With
(C) caloric value when 1.0g is dissolved in the water is more than 150cal/g and below 500cal/g inorganic compound,
Mass ratio as composition (C) relative to sodium acid carbonate, (C)/sodium acid carbonate are more than 0.6 and less than 7.0.
2. a kind of solid-like foaminess baths, wherein,
Contain following component (A)~(C)：
(A) carbonate of the sodium acid carbonate containing more than 15 mass % and below 100 mass %, more than 20 mass % and 50 matter
Measure below %；
(B) organic acid；With
(C) caloric value when 1.0g is dissolved in the water is more than 150cal/g and below 500cal/g inorganic compound,
Mass ratio as composition (C) relative to sodium acid carbonate, (C)/sodium acid carbonate are more than 0.6 and less than 7.0, also,
The solid-like foaminess baths is at least to be used in bath water with the skin contact of a part for body.
3. solid-like foaminess baths as claimed in claim 2, wherein,
A part for body is pin, arm or hand.
4. such as solid-like foaminess baths according to any one of claims 1 to 3, wherein,
The content of sorbierite (D) is below 7.5 mass %.
5. such as solid-like foaminess baths according to any one of claims 1 to 4, wherein,
Composition (B) be selected from fumaric acid, citric acid, malic acid, tartaric acid, butanedioic acid, maleic acid, phthalic acid, glutaric acid,
It is one kind or two or more in adipic acid, benzoic acid, salicylic acid and oxalic acid.
6. such as solid-like foaminess baths according to any one of claims 1 to 5, wherein,
Composition (A) is containing one kind or two or more in sodium carbonate, magnesium carbonate, potassium carbonate and calcium carbonate.
7. such as solid-like foaminess baths according to any one of claims 1 to 6, wherein,
Composition (C) is anhydrous magnesium sulfate.
8. such as solid-like foaminess baths according to any one of claims 1 to 7, wherein, form is flake tablets or group
Block tablet.
9. solid-like foaminess baths according to any one of claims 1 to 8 input into bath water and at least with body
The skin contact of a part for body and the purposes used.
10. purposes as claimed in claim 9, wherein,
A part for body is pin, arm or hand.
11. a kind of bathing method, wherein,
Solid-like foaminess baths according to any one of claims 1 to 8 is put into bath water, and at least by body
A part be impregnated in bath water, skin of the solid-like foaminess baths at least with a part for body is made in bath water
Contact.
12. bathing method as claimed in claim 11, wherein,
A part for body is pin, arm or hand.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-150186 | 2015-07-30 | ||
| JP2015150186A JP6640481B2 (en) | 2015-07-30 | 2015-07-30 | Solid foaming bath agent |
| PCT/JP2016/070490 WO2017018194A1 (en) | 2015-07-30 | 2016-07-12 | Solid effervescent bathing product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107735071A true CN107735071A (en) | 2018-02-23 |
| CN107735071B CN107735071B (en) | 2020-11-03 |
Family
ID=57885217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680039661.2A Active CN107735071B (en) | 2015-07-30 | 2016-07-12 | Solid foaming bath agent |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6640481B2 (en) |
| CN (1) | CN107735071B (en) |
| TW (1) | TWI702054B (en) |
| WO (1) | WO2017018194A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021132783A1 (en) * | 2019-12-27 | 2021-07-01 | 요시모토알앤디가부시키가이샤 | Foamable cosmetic |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2017018194A1 (en) | 2017-02-02 |
| CN107735071B (en) | 2020-11-03 |
| TW201707679A (en) | 2017-03-01 |
| JP6640481B2 (en) | 2020-02-05 |
| JP2017031072A (en) | 2017-02-09 |
| TWI702054B (en) | 2020-08-21 |
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