CN107722504A - A kind of esters environment-friendly plasticizer - Google Patents
A kind of esters environment-friendly plasticizer Download PDFInfo
- Publication number
- CN107722504A CN107722504A CN201711068224.6A CN201711068224A CN107722504A CN 107722504 A CN107722504 A CN 107722504A CN 201711068224 A CN201711068224 A CN 201711068224A CN 107722504 A CN107722504 A CN 107722504A
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- China
- Prior art keywords
- parts
- acid methyl
- methyl ester
- friendly plasticizer
- esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of esters environment-friendly plasticizer, it is characterised in that is made up of according to parts by weight following raw material：10 20 parts of fatty acid methyl ester, 10 12 parts of glyceryl tribenzoate, 10 20 parts of polyvinyl alcohol of acetalization, 13 14 parts of flexible PVC, 15 20 parts of butyl acrylate, 10 15 parts of GMA, 10 15 parts of epoxy aliphatic acid methyl ester, 5~10 parts of flight graphite, 58 parts of rosin and appropriate palm oil.Increase flight graphite component in the feed so that the object surface after addition plasticizer becomes bright gloss, has carbon black effect, and all additives do not have toxicant, and human body will not be damaged, and meet existing environmental protection concept.
Description
Technical field
The present invention relates to chemical industry additive agent field, and in particular to a kind of esters environment-friendly plasticizer.
Background technology
Plasticizer, typically also referred to as plasticiser.Plasticizer is the high polymer material auxiliary agent being industrially widely used, in plastics
This material is added in processing, can strengthen its pliability, be easily worked, legal can be used for industrial use, but some are plastified
Agent is because composition difference may have toxicity, and some people start to add such toxicity plasticizer wantonly in food at present, if long
Phase, which eats, may cause breeding unsoundness, even cause the danger of monster, cancer.In artificial leather, insulation wire body, lamellar body, plate
Used in material, improve flexibility, used as softening agent, be harmful in the raw material of existing plasticizer containing more
Material, it is applicable easily causes actual bodily harm for a long time.
The content of the invention
For the deficiency in the presence of prior art, the invention provides a kind of esters environment-friendly plasticizer, solve existing
Plasticizer the problem of noxious material, easily damaged to human body be present.
To achieve the above object, present invention employs following technical scheme：
A kind of esters environment-friendly plasticizer, it is characterised in that be made up of according to parts by weight following raw material：Fatty acid methyl ester 10-
20 parts, glyceryl tribenzoate 10-12 parts, polyvinyl alcohol of acetalization 10-20 parts, flexible PVC 13-14 parts, acrylic acid
Butyl ester 15-20 parts, GMA 10-15 parts, epoxy aliphatic acid methyl ester 10-15 parts, flight graphite 5~10
Part, rosin 5-8 parts and appropriate palm oil.
Above-mentioned a kind of esters environment-friendly plasticizer, it is characterised in that be made up of according to parts by weight following raw material：Fatty acid methyl
Ester 10-18 parts, glyceryl tribenzoate 10-11 parts, polyvinyl alcohol of acetalization 10-18 parts, flexible PVC 13-13.5 parts,
Butyl acrylate 15-18 parts, GMA 10-14 parts, epoxy aliphatic acid methyl ester 10-13 parts, flight graphite
6~8 parts, rosin 5-7 parts and appropriate palm oil.
Above-mentioned a kind of esters environment-friendly plasticizer, it is characterised in that be made up of according to parts by weight following raw material：Fatty acid methyl
16 parts of ester, 11 parts of glyceryl tribenzoate, 15 parts of polyvinyl alcohol of acetalization, 13.5 parts of flexible PVC, butyl acrylate
18 parts, 14 parts of GMA, 15 parts of epoxy aliphatic acid methyl ester, 6 parts of flight graphite, 6 parts of rosin and appropriate palm fibre
Palmitic acid oil.
A kind of above-mentioned esters environment-friendly plasticizer, it is characterised in that：The rosin passes through difference using pine resin as raw material
The obtained non-volatile natural resin of processing mode, be widely used in the industries such as soap, papermaking, paint, rubber.
A kind of above-mentioned esters environment-friendly plasticizer, it is characterised in that：The palm oil is a kind of tropical xylophyta oil, by
Palm fruit squeezing on oil palm tree forms.
Compared to prior art, the present invention has the advantages that：Increase flight graphite component in the feed so that add
Add the object surface after plasticizer to become bright gloss, there is carbon black effect, and all additives do not have toxic substance
Matter, human body will not be damaged, meet existing environmental protection concept.
Embodiment
The present invention is described further below.
Embodiment 1
A kind of esters environment-friendly plasticizer, it is made up of according to parts by weight following raw material：10 parts of fatty acid methyl ester, glycerine triphen
10 parts of formic acid esters, 10 parts of polyvinyl alcohol of acetalization, 13 parts of flexible PVC, 15 parts of butyl acrylate, Glycidyl methacrylate are sweet
10 parts of grease, 10 parts of epoxy aliphatic acid methyl ester, 5 parts of flight graphite, 5 parts of rosin and appropriate palm oil.
The rosin is using pine resin as raw material, the non-volatile natural resin that is obtained by different processing modes, extensively
It is general to be applied to the industries such as soap, papermaking, paint, rubber.
The palm oil is a kind of tropical xylophyta oil, is formed by the palm fruit squeezing on oil palm tree.
Embodiment 2
A kind of esters environment-friendly plasticizer, it is made up of according to parts by weight following raw material：20 parts of fatty acid methyl ester, glycerine triphen
12 parts of formic acid esters, 20 parts of polyvinyl alcohol of acetalization, 14 parts of flexible PVC, 20 parts of butyl acrylate, Glycidyl methacrylate are sweet
15 parts of grease, 15 parts of epoxy aliphatic acid methyl ester, 10 parts of flight graphite, 8 parts of rosin and appropriate palm oil.
The rosin is using pine resin as raw material, the non-volatile natural resin that is obtained by different processing modes, extensively
It is general to be applied to the industries such as soap, papermaking, paint, rubber.
The palm oil is a kind of tropical xylophyta oil, is formed by the palm fruit squeezing on oil palm tree.
Embodiment 3
A kind of esters environment-friendly plasticizer, it is made up of according to parts by weight following raw material：15 parts of fatty acid methyl ester, glycerine triphen
11 parts of formic acid esters, 15 parts of polyvinyl alcohol of acetalization, 13.5 parts of flexible PVC, 18 parts of butyl acrylate, Glycidyl methacrylate
14 parts of glyceride, 13 parts of epoxy aliphatic acid methyl ester, 6 parts of flight graphite, 6 parts of rosin and appropriate palm oil.
The rosin is using pine resin as raw material, the non-volatile natural resin that is obtained by different processing modes, extensively
It is general to be applied to the industries such as soap, papermaking, paint, rubber.
The palm oil is a kind of tropical xylophyta oil, is formed by the palm fruit squeezing on oil palm tree.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover at this
Among the right of invention.
Claims (5)
1. a kind of esters environment-friendly plasticizer, it is characterised in that be made up of according to parts by weight following raw material：Fatty acid methyl ester 10-20
Part, glyceryl tribenzoate 10-12 parts, polyvinyl alcohol of acetalization 10-20 parts, flexible PVC 13-14 parts, butyl acrylate
15-20 parts, GMA 10-15 parts, epoxy aliphatic acid methyl ester 10-15 parts, 5~10 parts of flight graphite, pine
Fragrant 5-8 parts and appropriate palm oil.
2. a kind of esters environment-friendly plasticizer according to claim 1, it is characterised in that according to parts by weight by following raw material group
Into：Fatty acid methyl ester 10-18 parts, glyceryl tribenzoate 10-11 parts, polyvinyl alcohol of acetalization 10-18 parts, flexible PVC
13-13.5 parts, butyl acrylate 15-18 parts, GMA 10-14 parts, epoxy aliphatic acid methyl ester 10-13
Part, 6~8 parts of flight graphite, rosin 5-7 parts and appropriate palm oil.
3. a kind of esters environment-friendly plasticizer according to claim 1, it is characterised in that according to parts by weight by following raw material group
Into：16 parts of fatty acid methyl ester, 11 parts of glyceryl tribenzoate, 15 parts of polyvinyl alcohol of acetalization, 13.5 parts of flexible PVC, third
18 parts of olefin(e) acid butyl ester, 14 parts of GMA, 15 parts of epoxy aliphatic acid methyl ester, 6 parts of flight graphite, 6 parts of rosin
With appropriate palm oil.
A kind of 4. esters environment-friendly plasticizer according to claim 1, it is characterised in that：The rosin is using pine resin as original
Material, the non-volatile natural resin obtained by different processing modes, it is widely used in the row such as soap, papermaking, paint, rubber
Industry.
A kind of 5. esters environment-friendly plasticizer according to claim 1, it is characterised in that：The palm oil is a kind of torrid zone wood
This vegetable oil, formed by the palm fruit squeezing on oil palm tree.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711068224.6A CN107722504A (en) | 2017-11-03 | 2017-11-03 | A kind of esters environment-friendly plasticizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711068224.6A CN107722504A (en) | 2017-11-03 | 2017-11-03 | A kind of esters environment-friendly plasticizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107722504A true CN107722504A (en) | 2018-02-23 |
Family
ID=61222178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711068224.6A Pending CN107722504A (en) | 2017-11-03 | 2017-11-03 | A kind of esters environment-friendly plasticizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107722504A (en) |
-
2017
- 2017-11-03 CN CN201711068224.6A patent/CN107722504A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180223 |