CN108559278A - A kind of environment-friendly plasticizer - Google Patents
A kind of environment-friendly plasticizer Download PDFInfo
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- CN108559278A CN108559278A CN201810242078.2A CN201810242078A CN108559278A CN 108559278 A CN108559278 A CN 108559278A CN 201810242078 A CN201810242078 A CN 201810242078A CN 108559278 A CN108559278 A CN 108559278A
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- acid methyl
- ester
- methyl ester
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to chemical industry additive technology fields, more particularly to a kind of environment-friendly plasticizer；It is composed of the following components in parts by weight：3 7~8 parts of phthalic acid two (4 chlorphenyl) esters, 22~30 parts of phthalic anhydride, 2 15~20 parts of propyl enanthols, 15~18 parts of phytosterol, 17~19 parts of organic solvent, 12~15 parts of oxide, 13~14 parts of flexible PVC, 0.2~0.3 part of roseolic acid, 12 parts~18 parts of polyvinyl alcohol of acetalization, 35 45 parts of glycerine, 25 35 parts of vegetable oil, 0.5 1 parts of sodium alkoxide, 10 20 parts of fatty acid methyl ester, 16 18 parts of butyl acrylate, 12 14 parts of glycidyl methacrylate, 12 15 parts of epoxy aliphatic acid methyl ester, 6~8 parts of flight graphite, 68 parts of rosin and 10~12 parts of appropriate palm oil and adhesive；The present invention solves existing plasticizer, and there are noxious materials, the problem of being easy to damage human body.
Description
Technical field
The present invention relates to chemical industry additive technology fields, more particularly to a kind of environment-friendly plasticizer.
Background technology
Plasticizer, generally also referred to as plasticiser.Plasticizer is the high molecular material auxiliary agent being industrially widely used, in plastics
This substance is added in processing, its flexibility can be made to enhance, be easily worked, and legal can be used for industrial use, but some are plasticized
Agent is because ingredient difference may have toxicity, and some people start to add such toxicity plasticizer wantonly in food at present, if
The danger that may cause breeding unsoundness, even cause monster, cancer is eaten for a long time.Artificial leather, insulation wire body, sheet body,
It is used in plank, improves flexibility, used as softening agent, be harmful to containing more in the raw material of existing plasticizer
Substance, for a long time using be easy to causeing actual bodily harm.
Invention content
The present invention provides a kind of environment-friendly plasticizer, solves existing plasticising to solve above-mentioned existing technical disadvantages
There are noxious materials for agent, the problem of being easy to damage human body.
To achieve the above object, the present invention provides a kind of environment-friendly plasticizer, is composed of the following components in parts by weight：
7~8 parts of 3- phthalic acids two (4- chlorphenyls) ester, 22~30 parts of phthalic anhydride, 2- propyl enanthols 15~20
Part, 15~18 parts of phytosterol, 17~19 parts of organic solvent, 12~15 parts of oxide, 13~14 parts of flexible PVC, roseolic acid
0.2~0.3 part, 12 parts~18 parts of polyvinyl alcohol of acetalization, 35-45 parts of glycerine, 25-35 parts of vegetable oil, 0.5-1 parts of sodium alkoxide, fat
10-20 parts of fatty acid methyl esters, 16-18 parts of butyl acrylate, 12-14 parts of glycidyl methacrylate, epoxy aliphatic acid methyl ester
12-15 parts, 6~8 parts of flight graphite, 6-8 parts of rosin and appropriate palm oil and 10~12 parts of adhesive.
Preferably, a kind of environment-friendly plasticizer, is composed of the following components in parts by weight：3- phthalic acids two (4- chlorphenyls) ester
7 parts, it is 28 parts of phthalic anhydride, 18 parts of 2- propyl enanthols, 17 parts of phytosterol, 18 parts of organic solvent, 14 parts of oxide, soft poly-
13 parts of vinyl chloride, 0.2 part of roseolic acid, 15 parts of polyvinyl alcohol of acetalization, 40 parts of glycerine, 30 parts of vegetable oil, 0.8 part of sodium alkoxide, fat
18 parts of sour methyl esters, 17 parts of butyl acrylate, 13 parts of glycidyl methacrylate, 13 parts of epoxy aliphatic acid methyl ester, flight stone
7 parts of ink, 7 parts of rosin and appropriate palm oil and 11 parts of adhesive.
In the present invention, environment-friendly plasticizer is made by following steps：
1), by 3- phthalic acids two (4- chlorphenyls) ester, phthalic anhydride, 2- propyl enanthols, phytosterol, be added to
It stirs and heats up in reactor；
2) it, waits for that temperature reaches 120-140 DEG C, organic solvent is added, heat preservation is continuously heating to 210 DEG C of stirrings after 1-2 hours
And it adds oxide and carries out reaction 5 hours；
3) flexible PVC, roseolic acid, polyvinyl alcohol of acetalization, glycerine, vegetable oil, sodium alkoxide, fat, are added into reactor
Fatty acid methyl esters, butyl acrylate, glycidyl methacrylate, epoxy aliphatic acid methyl ester, flight graphite, rosin, palm oil
And adhesive, control temperature are stirred, mixing speed 300r/min to 85 DEG C, pressure 10-15MPa, keep 9
Hour；
4), vacuum dehydration, filtering.
The invention has the advantages that：：
1. increasing flight graphite component in the feed so that the object surface after addition plasticizer becomes bright gloss, tool
There is carbon black effect, and all additives will not damage human body without toxicant, meets existing environmental protection reason
It reads.
2. tensile strength of the present invention is high, bond properties is good, can also give out certain fragrance in formula, and have and kill
Bacterium, function for expelling pests enhancing effect are stablized.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained without creative efforts all belongs to
In the scope of protection of the invention.
Embodiment one：
A kind of environment-friendly plasticizer, is composed of the following components in parts by weight：7 parts of 3- phthalic acids two (4- chlorphenyls) ester, neighbour
28 parts of phthalate anhydride, 18 parts of 2- propyl enanthols, 17 parts of phytosterol, 18 parts of organic solvent, 14 parts of oxide, flexible PVC
13 parts, 0.2 part of roseolic acid, 15 parts of polyvinyl alcohol of acetalization, 40 parts of glycerine, 30 parts of vegetable oil, 0.8 part of sodium alkoxide, fatty acid methyl ester
18 parts, 17 parts of butyl acrylate, 13 parts of glycidyl methacrylate, 13 parts of epoxy aliphatic acid methyl ester, 7 parts of flight graphite,
7 parts of rosin and 11 parts of appropriate palm oil and adhesive.
Embodiment two：
7 parts of 3- phthalic acids two (4- chlorphenyls) ester, 22 parts of phthalic anhydride, 15 parts of 2- propyl enanthols, phytosterol
15 parts, it is 17 parts of organic solvent, 12 parts of oxide, 13 parts of flexible PVC, 0.2 part of roseolic acid, 12 parts of polyvinyl alcohol of acetalization, sweet
35 parts of oil, vegetable oil 25,0.5 part of sodium alkoxide, 10 parts of fatty acid methyl ester, 16 parts of butyl acrylate, glycidyl methacrylate
12 parts, 12 parts of epoxy aliphatic acid methyl ester, 6 parts of flight graphite, 6 parts of rosin and appropriate palm oil and 10 parts of adhesive.
Embodiment three：
8 parts of 3- phthalic acids two (4- chlorphenyls) ester, 30 parts of phthalic anhydride, 20 parts of 2- propyl enanthols, phytosterol
18 parts, it is 19 parts of organic solvent, 15 parts of oxide, 14 parts of flexible PVC, 0.3 part of roseolic acid, 18 parts of polyvinyl alcohol of acetalization, sweet
45 parts of oil, 35 parts of vegetable oil, 1 part of sodium alkoxide, 20 parts of fatty acid methyl ester, 18 parts of butyl acrylate, glycidyl methacrylate
14 parts, 15 parts of epoxy aliphatic acid methyl ester, 8 parts of flight graphite, 8 parts of rosin and appropriate palm oil and 12 parts of adhesive.
In above three embodiments, organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, described complete
Vinyl chloride, ethylene glycol ether and triethanolamine press 5：8：12 mass ratio composition.
Use the performance parameter of plasticizer of the present invention (referring to Tables 1 and 2)：
Table 1：
Table 2：
Plasticizer excellent quality of the present invention is can be seen that by above-mentioned two table, performance is strong.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (3)
1. a kind of environment-friendly plasticizer, it is characterised in that：It is composed of the following components in parts by weight：
7~8 parts of 3- phthalic acids two (4- chlorphenyls) ester, 15~20 parts of 2- propyl enanthols, is planted at 22~30 parts of phthalic anhydride
15~18 parts of object sterol, 17~19 parts of organic solvent, 12~15 parts of oxide, 13~14 parts of flexible PVC, roseolic acid 0.2~
0.3 part, 12 parts~18 parts of polyvinyl alcohol of acetalization, 35-45 parts of glycerine, 25-35 parts of vegetable oil, 0.5-1 parts of sodium alkoxide, fatty acid methyl
10-20 parts of ester, 16-18 parts of butyl acrylate, 12-14 parts of glycidyl methacrylate, epoxy aliphatic acid methyl ester 12-15
Part, 6~8 parts of flight graphite, 6-8 parts of rosin and appropriate palm oil and 10~12 parts of adhesive.
2. a kind of environment-friendly plasticizer according to claim 1, it is characterised in that：It is composed of the following components in parts by weight：3-
7 parts of phthalic acid two (4- chlorphenyls) ester, 28 parts of phthalic anhydride, 18 parts of 2- propyl enanthols, 17 parts of phytosterol, You Jirong
18 parts of agent, 14 parts of oxide, 13 parts of flexible PVC, 0.2 part of roseolic acid, 15 parts of polyvinyl alcohol of acetalization, 40 parts of glycerine, plant
30 parts of oil, 0.8 part of sodium alkoxide, 18 parts of fatty acid methyl ester, 17 parts of butyl acrylate, 13 parts of glycidyl methacrylate, epoxy
13 parts of fatty acid methyl ester, 7 parts of flight graphite, 7 parts of rosin and appropriate palm oil and 11 parts of adhesive.
3. according to any one of claim 1 to 2 environment-friendly plasticizer, it is characterised in that：It is made by following steps：
1), by 3- phthalic acids two (4- chlorphenyls) ester, phthalic anhydride, 2- propyl enanthols, phytosterol, be added to reaction
It stirs and heats up in device；
2) it, waits for that temperature reaches 120-140 DEG C, organic solvent is added, heat preservation is continuously heating to 210 DEG C and stirs and add after 1-2 hours
Oxygenates carry out reaction 5 hours；
3) flexible PVC, roseolic acid, polyvinyl alcohol of acetalization, glycerine, vegetable oil, sodium alkoxide, aliphatic acid, are added into reactor
Methyl esters, butyl acrylate, glycidyl methacrylate, epoxy aliphatic acid methyl ester, flight graphite, rosin, palm oil and
Adhesive, control temperature are stirred, mixing speed 300r/min to 85 DEG C, pressure 10-15MPa, are kept for 9 hours；
4), vacuum dehydration, filtering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810242078.2A CN108559278A (en) | 2018-03-22 | 2018-03-22 | A kind of environment-friendly plasticizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810242078.2A CN108559278A (en) | 2018-03-22 | 2018-03-22 | A kind of environment-friendly plasticizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108559278A true CN108559278A (en) | 2018-09-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810242078.2A Pending CN108559278A (en) | 2018-03-22 | 2018-03-22 | A kind of environment-friendly plasticizer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500075A (en) * | 2020-05-27 | 2020-08-07 | 山东华跃新材料科技有限责任公司 | Novel environment-friendly plasticizer |
-
2018
- 2018-03-22 CN CN201810242078.2A patent/CN108559278A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500075A (en) * | 2020-05-27 | 2020-08-07 | 山东华跃新材料科技有限责任公司 | Novel environment-friendly plasticizer |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180921 |
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| WD01 | Invention patent application deemed withdrawn after publication |