CN107721462A - The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove - Google Patents

The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove Download PDF

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Publication number
CN107721462A
CN107721462A CN201711245611.2A CN201711245611A CN107721462A CN 107721462 A CN107721462 A CN 107721462A CN 201711245611 A CN201711245611 A CN 201711245611A CN 107721462 A CN107721462 A CN 107721462A
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CN
China
Prior art keywords
coating
acrylonitrile butadiene
fingerprint
ceramic hand
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711245611.2A
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Chinese (zh)
Inventor
耿宪兵
石昌利
王丙志
刘新玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zibo Hao Xiang Mold Technology Co Ltd
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Zibo Hao Xiang Mold Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zibo Hao Xiang Mold Technology Co Ltd filed Critical Zibo Hao Xiang Mold Technology Co Ltd
Priority to CN201711245611.2A priority Critical patent/CN107721462A/en
Publication of CN107721462A publication Critical patent/CN107721462A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/87Ceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5037Clay, Kaolin

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Present invention relates particularly to a kind of ceramic hand-mold coating and its production, application method, coating used suitable for acrylonitrile butadiene glove to be characterised by that the weight content of each raw material is:Aluminum oxide 4% 10%;Datong District's soil 20% 30%;Feldspar 34% 39%;Stalactite 5% 9%;Ripe talcum 5% 10%;Suzhou soil 2% 6%;Camwood knag 8% 12%;Electrolyte 0.2% 0.3%.Production method is characterised by that ball mill, ball milling 46 50 hours will be sent into after each feed proportioning, and 10 μm of fineness accounts for 76% 82%, mud is made, and through 325 mesh sieve net filtrations, permanent-magnetic iron expeller iron removaling, is tuned into Baume degrees as 38 ° 42 °.Application method is characterised by that coating uniform is sprayed onto into fingerprint surface through spray gun behind ceramic hand-mold repaired biscuit, scutching face, and the fingerprint sprayed enters tunnel cave and burnt till.Coating of the present invention has the advantages of acidproof, alkaline resistance properties is good, good thermal shock stability.Using coating of the present invention, fingerprint is easier to clean.

Description

The ceramic hand-mold coating used suitable for acrylonitrile butadiene glove and its production, use Method
Technical field
Present invention relates particularly to a kind of ceramic hand-mold coating used suitable for acrylonitrile butadiene glove and its production, user Method
Background technology
The application of gloves greatly protects extraneous virus, invasion and attack of the bacterium to people, at present the common feature gloves in market It is divided into PVC, natural rubber and acrylonitrile butadiene glove according to material.PVC glove can produce white garbage, natural rubber gloves price Height, groups of people are welcome by more and more people protein mistake, acrylonitrile butadiene glove.
Fingerprint will be used in the production technology of gloves, chemical etching, the acrylonitrile butadiene gloves such as fingerprint should be acidproof, alkaline-resisting make Ceramic hand-mold is particularly harsh:After each use, after first passing through acid wash liquid cleaning, then clean by alkaline rinse.Tradition Fingerprint coating have that acidproof, alkaline resistance properties is poor, difficult cleaning of defect, be not particularly suited for the ceramics that acrylonitrile butadiene glove uses Fingerprint uses.
The content of the invention
Traditional fingerprint coating is acidproof, alkaline resistance properties is poor it is an object of the invention to solving at present, not easy cleaning, it is impossible to suitable A kind of the defects of ceramic hand-mold used for acrylonitrile butadiene glove, there is provided ceramic hand-mold used suitable for acrylonitrile butadiene glove Coating and its production, application method, it has preferable acidproof, alkali resistance, is more beneficial for the cleaning of ceramic hand-mold.
The present invention is achieved by the following technical solution:
I.e. a kind of ceramic hand-mold coating used suitable for acrylonitrile butadiene glove, it is characterised in that the weight content of each raw material For:
Aluminum oxide 4%-10%;
Datong District soil 20%-30%;
Feldspar 34%-39%;
Stalactite 5%-9%;
Ripe talcum 5%-10%;
Suzhou soil 2%-6%;
Camwood knag 8%-12%;
Electrolyte 0.2%-0.3%.
Andesine of the present invention plays welding facilitation, and Datong District's soil, aluminum oxide play acidproof, alkaline-resisting effect, stalactite, ripe talcum Welding, brightness, alkaline-resisting effect are played, Suzhou soil, camwood knag play combination, and electrolyte plays mobilization.
Present invention introduces aluminum oxide and ripe talcum, and mullite-corundum compound phase, mullite-cordierite are formed through oversintering Phase, the raising of thermal shock resistance is more beneficial for, brings up to 190 DEG C by 170 DEG C of prior art, acid resistance is by prior art 95% brings up to 99%, and alkali resistance brings up to 99% by the 95% of prior art.
The oxidation aluminium supplier that the present invention uses is Zibo Sen Lu Trade Co., Ltd.s, technical indicator:Al2O3>=99%, Na2O≤0.6%.
Huairen County Fu Tang ceramic raw materials sales department, technical indicator is in the soil supplier of Datong District that the present invention uses:SiO2: 50%-55%, Al2O3:41%-48%, Fe2O3≤ 0.8%, MgO≤0.5%, CaO≤1.5%, K2O≤0.25%, Na2O≤ 0.5%.
Zibo Dan Feng Trade Co., Ltd.s, technical indicator is in the feldspar supplier that the present invention uses:SiO2:64%-67%, Al2O3:15%-20%, Fe2O3≤ 0.5%, MgO≤0.5%, CaO≤2%, K2O:9%-13%, Na2O:2%-3.5%.
Boshan White Tower Hong Lu ceramic raw materials business department, technical indicator is in the stalactite supplier that the present invention uses:CaO≥ 50%, igloss≤50%.
Boshan White Tower Hong Lu ceramic raw materials business department, technical indicator is in the ripe talcum supplier that the present invention uses:SiO2: 57%-68%, Al2O3≤ 4%, Fe2O3≤ 0.7%, MgO:28%-35%, CaO≤5.5%, K2O≤0.5%, Na2O≤ 0.5%.
Boshan White Tower Hong Lu ceramic raw materials business department, technical indicator is in the Suzhou soil supplier that the present invention uses:SiO2: 42%-52%, Al2O3:30%-35%, Fe2O3≤ 1%, MgO≤0.5%, CaO≤0.5%, K2O≤1.5%, Na2O≤ 0.5%, igloss:12%-19%.
Boshan White Tower Hong Lu ceramic raw materials business department, technical indicator is in the camwood knag supplier that the present invention uses:SiO2: 35%-40%, Al2O3:38%-45%, Fe2O3≤ 1.5%, MgO≤0.5%, CaO≤2.5%, K2O≤0.8%, Na2O≤ 0.5%, igloss:14%-18%.
Zibo Qi Zhongpao caustic soda Co., Ltd, modulus is in the electrolyte supplier that the present invention uses:2.2-2.5.
A kind of production method of the ceramic hand-mold coating used suitable for acrylonitrile butadiene glove, it is characterised in that by each raw material After dispensing, ball mill is sent into, ball milling 46-50 hours, 10 μm of fineness accounts for 76%-82%, mud is made, through 325 mesh sieve net filtrations, Permanent-magnetic iron expeller iron removaling, Baume degrees is tuned into as 38 ° -42 °.
Each raw material of the present invention is easy to ball milling, the convenient source general Ball-milling Time 55-60 hours of prior art, the present invention Ball milling 46-50 hours are only needed, reduce Ball-milling Time, improve productivity effect, and saved production cost.
A kind of application method of the ceramic hand-mold coating used suitable for acrylonitrile butadiene glove, it is characterised in that ceramic hand-mold Coating uniform is sprayed onto fingerprint surface through spray gun behind repaired biscuit, scutching face, its spray gun pressure is 0.1Mpa-0.4Mpa, the hand sprayed Mould enters tunnel cave and burnt till, and firing temperature is 1260 DEG C -1320.Burn till rear SiO2Less than 50%, Al2O3More than 25%.
After coating of the present invention, the smoothness on fingerprint surface, finish increases, and greatly improves gloves Clout cleaning performance, 99% is brought up to by original 85%.
Coating of the present invention has the advantages of acidproof, alkaline resistance properties is good, good thermal shock stability.Using of the present invention Coating, fingerprint is easier to clean, and the present invention is applied to the special ceramic hand-mold coating of acrylonitrile butadiene glove.
Embodiment:
Embodiment 1:
Composition of raw materials:Aluminum oxide 4%, Datong District's soil 27%, feldspar 36%, stalactite 5%, ripe talcum 8%, Suzhou soil 6%, Camwood knag 14%, electrolyte 0.25%.
After formula dispensing, ball mill, ball milling 46-50 hours are sent into, 10 μm of fineness accounts for 76%-82%, mud is made, and passes through 325 mesh sieve net filtrations, permanent-magnetic iron expeller iron removaling, Baume degrees is tuned into as 38 ° -42 °, workshop use of being allowed for access.
Fingerprint surface is uniformly sprayed onto through spray gun, its spray gun pressure is 0.1Mpa-0.4Mpa, and the fingerprint sprayed is with tunnel klining Into firing temperature is 1270 DEG C, and its chemical composition is SiO2:49.21%, Al2O3:24.81%, CaO:2.91%, MgO: 2.88%, K2O:3.75%, Na2O:1.22%, igloss:15.10%.
The experimental result of embodiment 1:By spraying the coating described in the present embodiment, the acid resistance of fingerprint is improved by original 95% To 97%, alkali resistance brings up to 97.5% by original 95%, and the effect for cleaning clout brings up to 95% by original 85%.
Embodiment 2
Composition of raw materials:Aluminum oxide 7%, Datong District's soil 29%, feldspar 35%, stalactite 5%, ripe talcum 7%, Suzhou soil 5%, Camwood knag 12%.
325 eye mesh screen vibration screenings are used in the coating preparation method of the present embodiment, 10 μm of coating fineness accounts for 76%-82%, its He is the same as embodiment 1.
The firing temperature of the fingerprint sprayed in the present embodiment is 1290 DEG C, its coating chemical composition:SiO2:50.30%, Al2O3:29.28%, CaO:2.75%, MgO:2.42%, K2O:3.62%, Na2O:0.87%, igloss:10.65%, other are same Embodiment 1.
The experimental result of embodiment 2:By spraying the coating described in the present embodiment, the acid resistance of fingerprint is improved by original 95% To 98%, alkali resistance brings up to 98% by original 95%, and the effect for cleaning clout brings up to 97% by original 85%.
Embodiment 3
Composition of raw materials:Aluminum oxide 10%, Datong District's soil 29%, stalactite 5%, ripe talcum 7%, feldspar 34%, Suzhou soil 5%, camwood knag 10%.
325 eye mesh screen vibration screenings are used in the coating preparation method of the present embodiment, 10 μm of coating fineness accounts for 76%-82%, its He is the same as embodiment 1.
The firing temperature of the fingerprint sprayed in the present embodiment is 1320 DEG C, its coating chemical composition:SiO2:48.92%, Al2O3:31.20%, CaO:2.70%, MgO:2.32%, K2O:3.45%, Na2O:0.79%, igloss:10.20%, other With embodiment 1.
The experimental result of embodiment 3:By spraying the coating described in the present embodiment, the acid resistance of fingerprint is improved by original 95% To 99%, alkali resistance brings up to 99% by original 95%, and the effect for cleaning clout brings up to 99% by original 85%.

Claims (3)

1. a kind of ceramic hand-mold coating used suitable for acrylonitrile butadiene glove, it is characterised in that the weight content of each raw material is:
Aluminum oxide 4%-10%;
Datong District soil 20%-30%;
Feldspar 34%-39%;
Stalactite 5%-9%;
Ripe talcum 5%-10%;
Suzhou soil 2%-6%;
Camwood knag 8%-12%;
Electrolyte 0.2%-0.3%.
2. a kind of production method of the ceramic hand-mold coating according to claim 1 used suitable for acrylonitrile butadiene glove, It is characterized in that by after each feed proportioning, ball mill is sent into, ball milling 46-50 hours, 10 μm of fineness accounts for 76%-82%, mud is made Slurry, through 325 mesh sieve net filtrations, permanent-magnetic iron expeller iron removaling, Baume degrees is tuned into as 38 ° -42 °.
3. a kind of application method of the ceramic hand-mold coating according to claim 1 used suitable for acrylonitrile butadiene glove, It is characterized in that coating uniform is sprayed onto into fingerprint surface through spray gun behind ceramic hand-mold repaired biscuit, scutching face, its spray gun pressure is 0.1Mpa-0.4Mpa, the fingerprint sprayed enter tunnel cave and burnt till, and firing temperature is 1260 DEG C -1320.
CN201711245611.2A 2017-11-24 2017-11-24 The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove Pending CN107721462A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711245611.2A CN107721462A (en) 2017-11-24 2017-11-24 The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711245611.2A CN107721462A (en) 2017-11-24 2017-11-24 The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112159206A (en) * 2020-09-29 2021-01-01 姜霁洋 Ceramic hand mold for producing nitrile rubber gloves and PVC gloves and preparation method thereof
CN112341166A (en) * 2020-12-04 2021-02-09 淄博昊祥模具科技有限公司 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof
CN112441823A (en) * 2020-12-04 2021-03-05 淄博昊祥模具科技有限公司 Ceramic hand mold suitable for producing nitrile rubber gloves and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1336346A (en) * 2000-08-08 2002-02-20 淄博泰山瓷业有限公司 Reinforced Ca-Mg ceramic
CN102276292A (en) * 2011-08-16 2011-12-14 淄博隆嘉工贸有限公司 Far-infrared ceramic hand shape die and preparation method thereof
CN104193313A (en) * 2014-08-22 2014-12-10 姜宝 Ceramic hand model for producing nitrile rubber and PVC (polyvinyl chloride) gloves and preparation method of ceramic hand model

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1336346A (en) * 2000-08-08 2002-02-20 淄博泰山瓷业有限公司 Reinforced Ca-Mg ceramic
CN102276292A (en) * 2011-08-16 2011-12-14 淄博隆嘉工贸有限公司 Far-infrared ceramic hand shape die and preparation method thereof
CN104193313A (en) * 2014-08-22 2014-12-10 姜宝 Ceramic hand model for producing nitrile rubber and PVC (polyvinyl chloride) gloves and preparation method of ceramic hand model

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112159206A (en) * 2020-09-29 2021-01-01 姜霁洋 Ceramic hand mold for producing nitrile rubber gloves and PVC gloves and preparation method thereof
CN112341166A (en) * 2020-12-04 2021-02-09 淄博昊祥模具科技有限公司 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof
CN112441823A (en) * 2020-12-04 2021-03-05 淄博昊祥模具科技有限公司 Ceramic hand mold suitable for producing nitrile rubber gloves and preparation method thereof
CN112441823B (en) * 2020-12-04 2022-07-08 淄博昊祥模具科技有限公司 Ceramic hand mold suitable for producing nitrile rubber gloves and preparation method thereof

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Application publication date: 20180223