CN107721265A - A kind of diatom ooze - Google Patents

A kind of diatom ooze Download PDF

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Publication number
CN107721265A
CN107721265A CN201711117639.8A CN201711117639A CN107721265A CN 107721265 A CN107721265 A CN 107721265A CN 201711117639 A CN201711117639 A CN 201711117639A CN 107721265 A CN107721265 A CN 107721265A
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CN
China
Prior art keywords
diatom ooze
parts
diatomite
present
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711117639.8A
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Chinese (zh)
Inventor
李绍龙
唐世家
吴沁
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Dongguan Environmental Protection Technology Co Ltd
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Dongguan Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201711117639.8A priority Critical patent/CN107721265A/en
Publication of CN107721265A publication Critical patent/CN107721265A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/28Polysaccharides or derivatives thereof
    • C04B26/285Cellulose or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of diatom ooze, and it belongs to paint field, and in particular to a kind of coating composition.The diatom ooze of the present invention includes the raw material of following mass fraction:120 180 parts of diatomite, 50 60 parts of polyanion celluloses, 20 40 parts of bamboo charcoals and 20 40 parts of sea cowry mud.The diatom ooze of the present invention is used as coating for wall surface, the semi-transparent membrane structure and selective absorption performance of its uniqueness, can effectively remove the harmful substances such as free formaldehyde in air, ammonia and because of peculiar smell caused by pet, smoking, rubbish, purify the air of a room.The diatom ooze of the present invention does not burn, even if fire occurs, will not also emerge any harmful smog.When temperature rises to 1200 DEG C Celsius, simply there is molten condition, pernicious gas Deng field mists will not be produced.

Description

A kind of diatom ooze
Technical field
The invention belongs to paint field, and in particular to a kind of coating composition.
Background technology
The main raw material(s) of diatom ooze is that diatom was a kind of life after 1 years diatom mineral --- the diatomite formed Algae in ocean, lake.The aquatic class biology that swims that diatom ooze is taken before living in millions of years --- diatom deposit and Into natural materials, main component is opal, and rich in multiple beneficial mineral matter, quality is light and soft, and electron microscope shows its grain Sublist face has countless small holes, and for porosity up to more than 90%, specific surface area is up to 65m2/g.Point of exactly this protrusion Sub- sieve structure, determine its unique function --- there is extremely strong physical absorption performance and ion-exchange performance, it is big in metope Area is sprayed water, and can be absorbed a large amount of water, be illustrated that adsorptivity is extremely strong, and slowly sustained release negative oxygen ion, energy effectively decomposing formaldehyde, Harmful carcinogen such as benzene, radon gas.
Diatom ooze as indoor coating process, its construction, smearing, pattern-making etc. all can any moulding, and can inhale The temperature in formaldehyde and regulation room in attached air, receives the favor of people.But diatom ooze of the prior art, cost compared with Height, the shelf-life is short, and certain financial burden is caused to people, can not popularize application.
The content of the invention
It is an object of the invention to provide a kind of cost is low, service life is long, the diatom ooze of safe fire resisting.
To achieve the above object, the technical scheme is that a kind of diatom ooze, the diatom ooze include following mass parts Several raw materials:120-180 parts diatomite, 50-60 parts polyanion cellulose, 20-40 parts bamboo charcoal and 20-40 part sea cowry mud.
Preferably, the raw material of the diatom ooze according to mass fraction include 130-170 parts diatomite, 52-58 parts it is poly- cloudy from Subbundle element, 23-37 parts bamboo charcoal and 23-37 part sea cowry mud.
Preferably, the raw material of the diatom ooze according to mass fraction include 140-160 parts diatomite, 54-56 parts it is poly- cloudy from Subbundle element, 27-33 parts bamboo charcoal and 27-33 part sea cowry mud.
Preferably, the raw material of the diatom ooze includes 150 parts of diatomite, 55 parts of polyanion fibers according to mass fraction Element, 30 parts of bamboo charcoals and 30 parts of sea cowry mud.
Preferably, the diatomite is the diatomite of 300-500 mesh.
Preferably, the diatomite is Yixing City Jun Lian diatomite Co., Ltd product.
Preferably, the bamboo charcoal is 400-500 mesh.
Preferably, the sea cowry mud is 400-500 mesh.
The occupation mode of the diatom ooze of the present invention is that stirring turns into fine and smooth paste after being mixed with water.
Diatomite is a kind of biogenic siliceous sedimentary rock in the present invention, and it is mainly by the remains institute group of ancient times diatom Into being mainly distributed on the states such as China, the U.S., Japan, Denmark, France, Romania.Diatomaceous mineral composition is mainly albumen Stone and its mutation, next to that clay mineral-hydromica, kaolinite and mineral chip.Mineral chip has quartz, feldspar, biotite And organic matter etc.;Content of organics is from micro to more than 30%;Diatomaceous color is white, canescence, grey and putty Color etc., there are fine and smooth, loose, light, porous, water imbibition and the strong property of permeability.Diatomaceous silica majority be it is noncrystal, Soluble silicon acid content is 50-80% in alkali.Armorphous SiO2It is heated to be changed into crystal formation at 800~1000 DEG C, it is soluble in alkali Silicic acid may decrease to 20-30%.Diatomite is used for coating additive product, with porosity is big, absorbability is strong, chemical property is steady The features such as fixed, wear-resisting, heat-resisting, excellent surface property, increase-volume, thickening and raising adhesive force can be provided for coating;Due to it With larger pore volume, film can be made to shorten drying time;The dosage of resin can be also reduced, reduces cost.Therefore diatomite It is considered as a kind of efficient coating flatting silica product with good cost performance, by large-scale coating material productions numerous in the world Business is widely used in water-based diatom ooze as articles for use are specified.
In the present invention polyanion cellulose be by native cellulose it is chemically modified prepared by water-soluble cellulose ether Analog derivative, it is a kind of important water-soluble cellulose ether, its commonly used sodium salt, is widely used in oil drilling, particularly Saline wells and offshore oil drilling.Polyanion cellulose has many uses, and can be applied to the usable institute of carboxymethyl cellulose (CMC) There is industry, there is provided more stable application performance.Such as:1. can be as the fine gauze sizing agent that starch is substituted in textile industry;2. make Paper pulp is added in paper, the longitudinal strength and smoothness of paper can be improved, improves the oil resistivity and absorbency of paper;3. used in daily chemical industry In with soap system and synthetic detergent;4. it is used as latex stabilizer in rubber industry;5. in coating, food, cosmetics, ceramic powder In the processing of the fine chemistry industries such as material, leather, as adjusting thick agent, emulsion stabilizer, crystallization generation preventing agent, thickener, binding agent, outstanding Floating agent, water-loss reducer, dispersant etc..
Bamboo charcoal is a kind of charcoal for being formed through nearly thousand degree of high-temperature firings using high mountain mao bamboon as raw material in the present invention.Bamboo charcoal has Loose porous structure, its molecule is fine and closely woven porous, and quality is hard.Have very strong adsorption capacity, can purify air, eliminate peculiar smell, Moisture absorption is mould proof, antibacterial expelling parasite.It can be dried absorbing sweat with human contact, promote blood circulation of human body and metabolism, fatigue-relieving.Through After science refines processing, it is widely used in daily life.
The characteristics of bamboo charcoal:Bamboo charcoal molecular structure is in hexagon, and quality is hard, fine and closely woven porous, and absorption power is strong, has absorption work( Energy;Bamboo charcoal voidage is high, is highly suitable as the carrier of edaphon and organic nutrition composition, can strengthen soil vitality, It is a kind of good soil improvement material;Bamboo charcoal has weak inductive, plays a part of antistatic and shielding electromagnetic radiation;
The effect of bamboo charcoal:1. absorption:Because carbonaceous has countless holes in itself, this carbonaceous stomata can be adsorbed effectively A part of suspended solid in air, the harmful chemicals such as sulfide, hydride, methanol, benzene, phenol are played absorption, decompose it is different Taste and smelly eliminating effect;2. automatic humidifying:Bamboo charcoal is fine and closely woven porous, and specific surface area is big, if ambient humidity is big, can absorb water Point, if surrounding environment is dried, releasable moisture.
Sea cowry mud is one kind of diatom ooze in the present invention, and its main component is diatomite, and it, which has, eliminates formaldehyde, purification sky The functions such as gas, regulation humidity, releasing negative oxygen ion, fire protection flame retarding, the self-cleaning, deodorization and sterilization of metope.Due to diatom ooze health environment-friendly, It is only not ornamental very well, it is the house decorative material of new generation for substituting wallpaper and emulsion paint also with feature.Sea cowry mud is It will be combined with modern high technology technology with professional equipment after the marine spray-dried purification of live body sea cowry with other mineral matters, By sea cowry successful conversion into " mud ".Sea cowry mud shows that there are numerous small holes on surface under an electron microscope, has extremely strong energy of adsorption Power and disinfection function.
The diatom ooze of the present invention has the following advantages that:
1st, diatom ooze of the invention is used as coating for wall surface, the semi-transparent membrane structure and selective absorption performance of its uniqueness, can be with Free formaldehyde in air, the harmful substance such as ammonia are effectively removed and because of peculiar smell caused by pet, smoking, rubbish, in clean room Air.
2nd, for diatom ooze of the invention as coating for wall surface, metope reflection light is naturally soft, and people does not allow to be also easy to produce vision tired Labor, the eyesight of occupant is effectively protected, especially to protecting children's vision significant effect;Diatom ooze wall color is lasting simultaneously, no Fugitive color, metope as newly, add the life-span of metope for a long time, reduce wall decoration number, saved room cost.
3rd, diatom ooze of the invention does not burn, even if fire occurs, will not also emerge any harmful smog.When When temperature rises to 1200 DEG C Celsius, simply there is molten condition, pernicious gas Deng field mists will not be produced.
4th, diatom ooze of the invention can absorb or discharge water with the change of Various Seasonal Dinner ambient air temperatures early Point, indoor air humidity is automatically adjusted, makes up to relative equilibrium.
5th, diatom ooze of the invention is not likely to produce electrostatic, and metope surface is not easy dust fall, application easy to spread.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
Embodiment 1
The diatom ooze of the present embodiment is by 120kg diatomite, 55kg polyanion celluloses, 33kg bamboo charcoals and 37kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Embodiment 2
The diatom ooze of the present embodiment is by 170kg diatomite, 58kg polyanion celluloses, 37kg bamboo charcoals and 40kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Embodiment 3
The diatom ooze of the present embodiment is by 140kg diatomite, 52kg polyanion celluloses, 23kg bamboo charcoals and 27kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Embodiment 4
The diatom ooze of the present embodiment is by 160kg diatomite, 54kg polyanion celluloses, 30kg bamboo charcoals and 30kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Embodiment 5
The diatom ooze of the present embodiment is by 130kg diatomite, 50kg polyanion celluloses, 20kg bamboo charcoals and 33kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Embodiment 6
The diatom ooze of the present embodiment is by 180kg diatomite, 56kg polyanion celluloses, 27kg bamboo charcoals and 20kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Embodiment 7
The diatom ooze of the present embodiment is by 150kg diatomite, 60kg polyanion celluloses, 40kg bamboo charcoals and 23kg sea cowries Made of being well mixed after mud milling.
Diatomite is Yixing City Jun Lian diatomite Co., Ltd product in the present embodiment.
Checking test
Stirring is tested as fine and smooth paste as coating for wall surface after obtained product in embodiment 1-7 is mixed with water The fundamental property of obtained product in embodiment 1-7 is demonstrate,proved, it is as a result as follows:
Fire resistance:Coating coating in embodiment 1-7 uses 1200 DEG C of flame tests after completing 1 month, and coating is not Burn and non smoke produces, molten condition only occur
It is water-fast, hold color, life-span:Respectively after coating completes 6 months and 12 months, with giant to scribbling embodiment 1- The wall of diatom ooze coating continuously sprays 1000L water in 7, does not occur wall and fades, ftractures, peeling phenomenon.
Purify air performance:(space is 20m in the closing space of obtained coating in inwall coating embodiment 1-73), It is 0.2mg/m to adjust initial concentration of formaldehyde3, tested again after 24h, concentration of formaldehyde point in the closing space of 7 embodiments 0.06mg/m is not down to it3、0.08mg/m3、0.06mg/m3、0.07mg/m3、0.06mg/m3、0.07mg/m3、0.07mg/m3, say Bright product of the invention can effectively adsorb the harmful substance formaldehyde in air.
After measured, product of the invention can effectively adjust indoor humidity, and overcome electrostatic interaction, so as to avoid to ash Metope caused by the absorption of dirt pollutes.
Although above with general explanation and specific embodiment, the present invention is described in detail, at this On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore, These modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to the scope of protection of present invention.

Claims (7)

  1. A kind of 1. diatom ooze, it is characterised in that:The diatom ooze includes the raw material of following mass fraction:120-180 parts diatomite, 50-60 parts polyanion cellulose, 20-40 parts bamboo charcoal and 20-40 part sea cowry mud.
  2. 2. diatom ooze according to claim 1, it is characterised in that:The raw material of the diatom ooze includes according to mass fraction 130-170 parts diatomite, 52-58 parts polyanion cellulose, 23-37 parts bamboo charcoal and 23-37 part sea cowry mud.
  3. 3. diatom ooze according to claim 2, it is characterised in that:The raw material of the diatom ooze includes according to mass fraction 140-160 parts diatomite, 54-56 parts polyanion cellulose, 27-33 parts bamboo charcoal and 27-33 part sea cowry mud.
  4. 4. diatom ooze according to claim 3, it is characterised in that:The raw material of the diatom ooze includes according to mass fraction 150 parts of diatomite, 55 parts of polyanion celluloses, 30 parts of bamboo charcoals and 30 parts of sea cowry mud.
  5. 5. according to the diatom ooze described in any one claim in claim 1-4, it is characterised in that:The diatomite is The diatomite of 300-500 mesh.
  6. 6. diatom ooze according to claim 1, it is characterised in that:The bamboo charcoal is 400-500 mesh.
  7. 7. diatom ooze according to claim 1, it is characterised in that:The sea cowry mud is 400-500 mesh.
CN201711117639.8A 2017-11-13 2017-11-13 A kind of diatom ooze Pending CN107721265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711117639.8A CN107721265A (en) 2017-11-13 2017-11-13 A kind of diatom ooze

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116739351A (en) * 2023-08-10 2023-09-12 山东凯大新型材料科技有限公司 Diatom ooze management system and method based on artificial intelligence

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086652A (en) * 2011-11-02 2013-05-08 张维民 Diatom mud
CN103483930A (en) * 2013-09-26 2014-01-01 无锡阳工机械制造有限公司 Seashell mud waterproofing paint
CN105236881A (en) * 2015-09-06 2016-01-13 三棵树涂料股份有限公司 Diatom ooze internal wall decorative material and preparation method of same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086652A (en) * 2011-11-02 2013-05-08 张维民 Diatom mud
CN103483930A (en) * 2013-09-26 2014-01-01 无锡阳工机械制造有限公司 Seashell mud waterproofing paint
CN105236881A (en) * 2015-09-06 2016-01-13 三棵树涂料股份有限公司 Diatom ooze internal wall decorative material and preparation method of same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨成德: "《涂料开发与试验》", 28 February 2015 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116739351A (en) * 2023-08-10 2023-09-12 山东凯大新型材料科技有限公司 Diatom ooze management system and method based on artificial intelligence
CN116739351B (en) * 2023-08-10 2023-11-21 山东凯大新型材料科技有限公司 Diatom ooze management system and method based on artificial intelligence

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Application publication date: 20180223