CN107718804A - A kind of resin coated steel sheet - Google Patents
A kind of resin coated steel sheet Download PDFInfo
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- CN107718804A CN107718804A CN201711173371.XA CN201711173371A CN107718804A CN 107718804 A CN107718804 A CN 107718804A CN 201711173371 A CN201711173371 A CN 201711173371A CN 107718804 A CN107718804 A CN 107718804A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/28—Multiple coating on one surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/718—Weight, e.g. weight per square meter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of resin coated steel sheet, including substrate, the lower surface of the substrate is followed successively by the first zinc coat and back of the body enamelled coating from top to bottom, and the upper surface of the substrate is from lower to being sequentially provided with the second zinc coat, chemical composition coating, organosilicon membrane and resinous coat.A kind of resin coated steel sheet of the present invention, organosilicon membrane and resinous coat are coated with the surface of substrate, and silicone layer has good isolation effect, plays water repellent, the effect of heatproof, can stop erosion, damage of the extraneous undesirable element to steel plate;Using epoxy resin and thermosetting acrylic resin as main film forming matter in resinous coat, cellulose plays good dispersive property in resin, also added glass microballoon in addition, and glass microsphere can improve the toughness of coating, steel plate is had good mechanical property;The hollow-core construction of glass microsphere can mitigate the weight of coating, reduce product cost.
Description
Technical field
The present invention relates to field of material technology, more particularly to a kind of resin coated steel sheet.
Background technology
Steel plate with organic coating refers to coated natural or the resin of synthesis on substrate.Steel plate with organic coating has corrosion resistance
The advantages that good, bright in luster, appearance looks elegant, machine-shaping is convenient, intensity height, and cost is relatively low, is widely used in building household electrical appliances and friendship
The industries such as logical transport.
Conventional color coated steel sheet be using zinc-plated or aluminum-zinc alloy substrate as base material, preprocessed degreasing, apply chemical composition coating,
Secondary baking forms after base coat back coating, painting finishing coat.Common steel plate with organic coating is with epoxy or polyester or polyurethane tree
Main film forming substance of the fat as priming coat, the main film forming matter of finishing coat is used as using polyester or Si modification resin or other resins
Matter.Different according to product purpose are accordingly arranged in pairs or groups to meet property of the different use occasions to film to priming coat, finishing coat composition
It can require.
By the developing history of more than 20 years, steel plate with organic coating industry obtained tremendous expansion in China, and its yield is with every
The speed of annual 40% increases, but the quality of product also has also in low side, its durability, feature and same kind of products at abroad
A certain distance.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of resin coated steel sheet, and the steel plate is in substrate
On be coated with organosilicon membrane and resinous coat, possess excellent persistence and mechanical property.
A kind of resin coated steel sheet, including substrate, the lower surface of the substrate be followed successively by from top to bottom the first zinc coat and
Carry on the back enamelled coating, the upper surface of the substrate is applied to being sequentially provided with the second zinc coat, chemical composition coating, organosilicon membrane and resin from lower
Layer.
Preferably, the back of the body enamelled coating is fluorine carbon anticorrosive paint, and the thickness of the back of the body enamelled coating is 10-15 μm.
Preferably, the chemical composition coating is complex acid salt film.
Preferably, the organosilicon membrane is epoxy-modified polysiloxane, and the thickness of the organosilicon membrane is 5-12 μm.
Preferably, the chemical composition coating is complex acid salt film.
Preferably, the organosilicon membrane is epoxy-modified polysiloxane, and the thickness of the organosilicon membrane is 5-12 μm.
The thickness of the resinous coat is 20-30 μm, and the resinous coat includes following component ring in parts by weight
Oxygen tree fat 50-60 parts, acrylic resin 20-30 parts, cellulose 10-15 parts, glass microballoon 5-10 parts, pigment 10-15 parts, solvent
15-20 parts, toughener 2-7 parts.Acrylic resin selects thermosetting acrylic resin;Butyl glycol or isopropyl may be selected in solvent
Alcohol;Diethyl phthalate or triphenyl phosphate can be selected in toughener.
Further, the cellulose is in methylcellulose, hydroxypropyl methyl cellulose, hydroxyethylmethylcellulose
It is a kind of.
Further, the glass microballoon is hollow-core construction, 15-100 μm of particle diameter.
Further, the pigment is rust resisting pigment, and the rust resisting pigment is red red, lead monoxide, barium acid zinc, metaboric acid
One kind in barium.
A kind of resin coated steel sheet of the present invention, chemical composition coating can reduce the chemism of metal in itself, make metal
Heat endurance improve, while also increase the adhesion of surface protecting layer and base metal;Complex acid salt film and organic coating
Binding ability is strong, can be as good bottom.Organosilicon membrane has high temperature resistant using epoxy-modified polysiloxane, while also has concurrently
There is good mechanical performance.
In resinous coat, adhesion of epoxy resin is strong, chemical-resistant, anti-corrosive properties, water resistance, heat endurance, thermosetting
Acrylic resin has excellent richness, gloss, hardness, solvent resistance, weather resisteant, non-discolouring, the not brightness reversion in high-temperature baking;
Certain functional group is carried in thermosetting acrylic resin structure, netted knot can be formed with the functional group reactionses in epoxy resin
Structure, improve the performance of coating.Effect of the cellulose in resinous coat be with it is good thicken, disperse, emulsifying, bonding,
Film forming etc..
The density of hollow glass micropearl is approximately ten parts of traditional inserts density of particle, can be mitigated significantly after filling
The base weight of product, more production resins are substituted and saved, reduce product cost.Hollow glass micropearl wetting and dispersing is easy,
It can be filled in most of thermosetting thermoplastic resins, increase the processing characteristics of plastics, while improve the surface levelling of engineering plastics,
The toughness of reinforced plastics, the rigidity of itself is not reduced.
Beneficial effect in the present invention:
A kind of resin coated steel sheet of the present invention, organosilicon membrane and resinous coat, organosilicon are coated with the surface of substrate
Layer has good isolation effect, plays water repellent, the effect of heatproof, can stop erosion of the extraneous undesirable element to steel plate, damage
Wound;Played in resinous coat using epoxy resin and thermosetting acrylic resin as main film forming matter, cellulose in resin
Good dispersive property, glass microballoon is also added in addition, glass microsphere can improve the toughness of coating, steel plate is had well
Mechanical property;The hollow-core construction of glass microsphere can mitigate the weight of coating, reduce product cost.A kind of resin of the present invention applies
Layer steel plate has excellent durability and mechanical property.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, and a part for constitution instruction, the reality with the present invention
Apply example to be used to explain the present invention together, be not construed as limiting the invention.In the accompanying drawings:
Fig. 1 is a kind of structural representation of resin coated steel sheet proposed by the present invention.
In figure:1- substrates, the zinc coats of 2- first, 3- back ofs the body enamelled coating, the zinc coats of 4- second, 5- chemical composition coatings, 6- organosilicons
Film, 7- resinous coats.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment 1
A kind of resin coated steel sheet, including substrate 1, the lower surface of substrate 1 are followed successively by the first zinc coat 2 and the back of the body from top to bottom
Enamelled coating 3, the upper surface of substrate 1 is from lower to being sequentially provided with the second zinc coat 4, chemical composition coating 5, organosilicon membrane 6 and resinous coat
7。
Back of the body enamelled coating is fluorine carbon anticorrosive paint, and the thickness for carrying on the back enamelled coating is 10 μm;Chemical composition coating is complex acid salt film;Organosilicon membrane
For epoxy-modified polysiloxane, the thickness of organosilicon membrane is 5 μm.
The thickness of resinous coat is 20 μm, resinous coat include 50 parts of following component epoxide resin in parts by weight,
20 parts of acrylic resin, 10 parts of cellulose, 5 parts of glass microballoon, 10 parts of pigment, 15 parts of solvent, 2 parts of toughener.
Acrylic resin selects thermosetting acrylic resin;Cellulose is methylcellulose;Glass microballoon is hollow-core construction,
15 μm of particle diameter;Pigment is red red;Solvent is butyl glycol;Toughener is diethyl phthalate.
Embodiment 2
A kind of resin coated steel sheet, structure is the same as embodiment 1.
Back of the body enamelled coating is fluorine carbon anticorrosive paint, and the thickness for carrying on the back enamelled coating is 15 μm;Chemical composition coating is complex acid salt film;Organosilicon membrane
For epoxy-modified polysiloxane, the thickness of organosilicon membrane is 12 μm.
The thickness of resinous coat is 30 μm, resinous coat include 60 parts of following component epoxide resin in parts by weight,
30 parts of acrylic resin, 15 parts of cellulose, 10 parts of glass microballoon, 15 parts of pigment, 20 parts of solvent, 7 parts of toughener.
Acrylic resin selects thermosetting acrylic resin;Cellulose is hydroxypropyl methyl cellulose;Glass microballoon is sky
Core structure, 100 μm of particle diameter;Pigment is lead monoxide;Solvent is isopropanol;Toughener is triphenyl phosphate.
Embodiment 3
A kind of resin coated steel sheet, structure is the same as embodiment 1.
Back of the body enamelled coating is fluorine carbon anticorrosive paint, and the thickness for carrying on the back enamelled coating is 13 μm;Chemical composition coating is complex acid salt film;Organosilicon membrane
For epoxy-modified polysiloxane, the thickness of organosilicon membrane is 8 μm.
The thickness of resinous coat is 25 μm, resinous coat include 55 parts of following component epoxide resin in parts by weight,
25 parts of acrylic resin, 13 parts of cellulose, 7 parts of glass microballoon, 12 parts of pigment, 18 parts of solvent, 5 parts of toughener.
Acrylic resin selects thermosetting acrylic resin;Cellulose is hydroxyethylmethylcellulose;Glass microballoon is sky
Core structure, 20 μm of particle diameter;Pigment is barium acid zinc;Solvent is isopropanol;Toughener is triphenyl phosphate.
Embodiment 4
A kind of resin coated steel sheet, structure is the same as embodiment 1.
Back of the body enamelled coating is fluorine carbon anticorrosive paint, and the thickness for carrying on the back enamelled coating is 12 μm;Chemical composition coating is complex acid salt film;Organosilicon membrane
For epoxy-modified polysiloxane, the thickness of organosilicon membrane is 9 μm.
The thickness of resinous coat is 23 μm, resinous coat include 59 parts of following component epoxide resin in parts by weight,
27 parts of acrylic resin, 11 parts of cellulose, 8 parts of glass microballoon, 13 parts of pigment, 16 parts of solvent, 4 parts of toughener.
Acrylic resin selects thermosetting acrylic resin;Cellulose is methylcellulose;Glass microballoon is hollow-core construction,
50 μm of particle diameter;Pigment is barium metaborate;Solvent is butyl glycol;Toughener is diethyl phthalate.
Embodiment 5
A kind of resin coated steel sheet, structure is the same as embodiment 1.
Back of the body enamelled coating is fluorine carbon anticorrosive paint, and the thickness for carrying on the back enamelled coating is 11 μm;Chemical composition coating is complex acid salt film;Organosilicon membrane
For epoxy-modified polysiloxane, the thickness of organosilicon membrane is 7 μm.
The thickness of resinous coat is 28 μm, resinous coat include 51 parts of following component epoxide resin in parts by weight,
22 parts of acrylic resin, 14 parts of cellulose, 9 parts of glass microballoon, 11 parts of pigment, 17 parts of solvent, 6 parts of toughener.
Acrylic resin selects thermosetting acrylic resin;Cellulose is methylcellulose;Glass microballoon is hollow-core construction,
70 μm of particle diameter;Pigment is red red;Solvent is butyl glycol;Toughener is diethyl phthalate.
Performance test
1st, durability experiment
Experimental method:National standard GB/T 12754-2006 carry out resistance to neutral salt spray test and uviol lamp accelerated aging tests.It is right
Steel plate according to group is to make the organosilicon membrane in steel plate of the present invention and resinous coat into epoxy coating.
Experimental result:It is shown in Table 1.
The durability experiment result of table 1
Test result indicates that:In resistance to neutral salt spray test, resin coated steel sheet made from embodiment 1-5 has started
The time of bubble phenomenon is much larger than control group;In uviol lamp accelerated aging tests, resin coated steel sheet made from embodiment 1-5 goes out
The time now bubble, ftractureed is much larger than control group.As can be seen here, a kind of resin coated steel sheet proposed by the present invention possesses excellent
Durability.
2nd, mechanical property tests
Experimental method:National standard GB/T 12754-2006 detect the yield strength and tensile strength of steel plate.The steel plate of control group
It is to make the organosilicon membrane in steel plate of the present invention and resinous coat into epoxy coating.
Experimental result:It is shown in Table 2.
The mechanical property experimental results of table 2
Group | Yield strength (MPa) | Tensile strength (MPa) |
Control group | 153 | 242 |
Embodiment 1 | 206 | 336 |
Embodiment 2 | 198 | 321 |
Embodiment 3 | 185 | 309 |
Embodiment 4 | 191 | 317 |
Embodiment 5 | 213 | 325 |
Test result indicates that:The yield strength of resin coated steel sheet made from embodiment 1-5 and tensile strength much larger than pair
According to group.As can be seen here, a kind of resin coated steel sheet proposed by the present invention possesses excellent mechanical property.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (8)
1. a kind of resin coated steel sheet, including substrate, the lower surface of the substrate is followed successively by the first zinc coat and the back of the body from top to bottom
Enamelled coating, it is characterised in that:The upper surface of the substrate is from lower to being sequentially provided with the second zinc coat, chemical composition coating, organosilicon membrane
And resinous coat.
2. a kind of resin coated steel sheet according to claim 1, it is characterised in that the back of the body enamelled coating applies for fluorine carbon anti-corrosion
Material, the thickness of the back of the body enamelled coating is 10-15 μm.
3. a kind of resin coated steel sheet according to claim 1, it is characterised in that the chemical composition coating is complex acid salt
Film.
4. a kind of resin coated steel sheet according to claim 1, it is characterised in that the organosilicon membrane is epoxide modified poly-
Siloxanes, the thickness of the organosilicon membrane is 5-12 μm.
5. a kind of resin coated steel sheet according to claim 1, it is characterised in that the thickness of the resinous coat is 20-
30 μm, the resinous coat include following component epoxide resin 50-60 parts in parts by weight, acrylic resin 20-30 parts,
Cellulose 10-15 parts, glass microballoon 5-10 parts, pigment 10-15 parts, solvent 15-20 parts, toughener 2-7 parts.
A kind of 6. resin coated steel sheet according to claim 5, it is characterised in that the cellulose be methylcellulose,
One kind in hydroxypropyl methyl cellulose, hydroxyethylmethylcellulose.
A kind of 7. resin coated steel sheet according to claim 5, it is characterised in that the glass microballoon is hollow-core construction,
15-100 μm of particle diameter.
8. a kind of resin coated steel sheet according to claim 5, it is characterised in that the pigment is rust resisting pigment, described
Rust resisting pigment is one kind in red red, lead monoxide, barium acid zinc, barium metaborate.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109397798A (en) * | 2018-11-09 | 2019-03-01 | 丹阳市曙光特钢有限公司 | A kind of high-strength light type special steel plate |
CN111554203A (en) * | 2020-06-05 | 2020-08-18 | 筑觉绘(上海)科技有限公司 | Micro-crystal face LED display screen |
CN112961515A (en) * | 2021-02-22 | 2021-06-15 | 苏州兴禾源复合材料有限公司 | Preparation method of heat insulation coating coated on surface of steel plate |
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CN202865157U (en) * | 2012-10-25 | 2013-04-10 | 绍兴万成金属薄板有限公司 | Silicon modified polyester color-coated coil |
CN104416993A (en) * | 2013-08-26 | 2015-03-18 | 湖北航天化学技术研究所 | Metal wire drawing-imitating decoration film |
JP2016147386A (en) * | 2015-02-10 | 2016-08-18 | 凸版印刷株式会社 | Aluminum decorative member |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109397798A (en) * | 2018-11-09 | 2019-03-01 | 丹阳市曙光特钢有限公司 | A kind of high-strength light type special steel plate |
CN111554203A (en) * | 2020-06-05 | 2020-08-18 | 筑觉绘(上海)科技有限公司 | Micro-crystal face LED display screen |
CN112961515A (en) * | 2021-02-22 | 2021-06-15 | 苏州兴禾源复合材料有限公司 | Preparation method of heat insulation coating coated on surface of steel plate |
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