CN1077172A - The explosion-suppressing material that is used for combustible and explosive articles - Google Patents

The explosion-suppressing material that is used for combustible and explosive articles Download PDF

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Publication number
CN1077172A
CN1077172A CN 92102437 CN92102437A CN1077172A CN 1077172 A CN1077172 A CN 1077172A CN 92102437 CN92102437 CN 92102437 CN 92102437 A CN92102437 A CN 92102437A CN 1077172 A CN1077172 A CN 1077172A
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Prior art keywords
explosion
suppressing material
combustible
suppressing
netted
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CN 92102437
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CN1029105C (en
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汪之清
南子江
李怀德
贺发达
赵淑兰
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Shanghai Hua Bang Explosion Protection Technology Co., Ltd.
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No 52 Institute of China North Industries Group Corp
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Abstract

A kind of explosion-suppressing material that is used for combustible and explosive articles, its alloying component percentage by weight is: Mn0.8~1.8, Fe0.3~0.7, Si0.3~0.6, Cu0.1~0.2, Zn0.1, Mg0.03~0.1, the Al surplus, the extraordinary alloy foil net after it is also expanded by joint-cutting is made, and has cellular open texture.Be divided into netted and spherical two kinds of explosion-suppressing materials, the holder that is used for storing inflammable and explosive fluid is avoided the accident of blasting, and to storing holders such as band oil, gas, can directly weld mending-leakage, and the density of Web materials is 30kg/m 3, the volume ratio that accounts for holder is 1%.The density 63kg/m of spheroidal material 3, account for the volume ratio 3.9% of holder.

Description

The explosion-suppressing material that is used for combustible and explosive articles
The present invention relates to the datonation-inhibition packing material in flammable and combustible liquids or the gas reservoir, belong to functional metallic material.
At present, in liquid, gas fuel and inflammable and explosive fluid reservoirs such as gasoline, propane, acetylene, ether, behind the installation hole gap material, utilize the heat absorption of this material and inhibitory action can increase the safety of this container in accident effectively.
Known US Patent 3356256 " explosive safe fluid container " is a kind of packing material that is used for explosive fluid container.This material is to be combined by coarse mesh and two kinds of expanded metal of fine mesh, and used expanded metal is the aluminum alloy that contains beryllium and titanium.The pack density of this packing material in container is 52.4Kg/M 3, the volume ratio that accounts for container is 1.937%, is full of with this material basically in the container.Another packing material that US Patent 4149649 " datonation-inhibition thing " proposes, similar to above-mentioned 3356256 proprietary materials, in order to reduce density of material and to increase material stiffness, only done improvement on the method stacking of web material compartment, this effect of improving one's methods is in use not remarkable, and particularly the density of material there is no significantly and reduces.In use also need be full of container, and the manufacture craft of this material is complicated.US Patent 4613054 " is used for flammable fluid weighting material and manufacture method ".It is a kind of ball packing, solved preferably and be difficult for the problem of packing into and taking out when existing container uses this material, but the maximum deficiency of this material is the volume ratio big (generally being not less than 5%) that occupies container, thereby has limited practicality greatly, and service efficiency is low.
The objective of the invention is, a kind of suppress flammable fluid burning and the netted and spherical explosion-suppressing material that explodes in the container are provided.This density of material is low, and it is little to occupy volume, and manufacture craft is simple, and cost is low, and good combination property is convenient to pack in container and take out, and is easy to use, safe and reliable.
The present invention is used for the explosion-suppressing material of combustible and explosive articles, and its chemical analysis percentage by weight is: Mn is 0.8~1.8, and Fe is 0.3~0.7, and Si is 0.3~0.6, and Cu is 0.1~0.2, and Zn is 0.1, and Mg is 0.03~0.1, the Al surplus.Make aluminium foil according to technological requirement, its manufacturing process flow is as follows:
Aluminium alloy ingots → rolling → alloy foil → netted the explosion-suppressing material of grooving machine joint-cutting → joint-cutting aluminium foil → shaping → coiling shaping → cylinder of mesh scroll → net puller expansion → aluminum foil web → folded make the netted blank of the netted explosion-suppressing material of shape → rectangle lamination shape → cutting shaping → make → → marble forming machine system ball → spherical explosion-suppressing material
The explosion-suppressing material of netted combustible and explosive articles of the present invention is to be made through technologies such as superimposed or coilings by the aluminium foil after joint-cutting and the expansion, and whole material all has similar cellular pore configuration from inside to outside.
The explosion-suppressing material of spherical combustible and explosive articles of the present invention is to be made through operations such as punching presses by the aluminium foil after joint-cutting and the expansion, and it is roughly level and smooth that it has an outside face, and inside is the spheroid of similar cellular pore configuration.
Below in conjunction with accompanying drawing the present invention is further described:
Fig. 1 is the explosion-suppressing material joint-cutting scheme drawing of combustible and explosive articles;
Fig. 2 is the single grid scheme drawing of the explosion-suppressing material of combustible and explosive articles;
Fig. 3 is the explosion-suppressing material rhythmo structure scheme drawing of combustible and explosive articles;
Fig. 4 is the running condition scheme drawing of netted explosion-suppressing material;
Fig. 5 is the structural representation of spherical explosion-suppressing material;
Fig. 6 is the embodiment scheme drawing of spherical explosion-suppressing material;
As shown in Figure 1: 1 is material of aluminum foil, makes the explosion-suppressing material of netted combustible and explosive articles, and its thickness is selected 0.02~0.2mm.Make the explosion-suppressing material of spherical combustible and explosive articles, its thickness is selected 0.04~0.2mm, and its width is 50~800mm.2 is the joint-cutting that cuts on aluminium foil through grooving machine, the length A of cutting, and being used for netted explosion-suppressing material is 8~25mm.Being used for spherical explosion-suppressing material is 10~25mm.Joint-cutting vertically is being discontinuous, laterally is being staggered symmetric offset spread, and the fore-and-aft distance B(between joint-cutting is the length of connecting portion) be 2~6mm at netted explosion-suppressing material.At spherical explosion-suppressing material is 2~8mm.Transverse distance C(between joint-cutting is that muscle is wide) be 1~2.5mm at netted inhibition material.At spherical explosion-suppressing material is 1~3mm.
As shown in Figure 2: 3 is the connecting portion between grid, and its width D is 2~5mm at netted explosion-suppressing material, is 2~6mm at spherical explosion-suppressing material.4 for forming the muscle of grid with connecting portion, its width is 1~2.5mm at Web materials, is 1~3mm at spherical explosion-suppressing material.The length E of the prism mesh that single grid is formed is 6~22mm at netted explosion-suppressing material, is 8~22mm at spheroidal material.
As shown in Figure 3: 5 and 6 is adjacent two layers of mesh compartment, the muscle 7 of levels and 8 interlocks superimposed, every layer of grid and adjacent grid have been formed with the interlaced structure of same direction, when the several layers grid is superimposed, muscle between lamination and connecting portion are asymmetric state substantially, but the superimposed direction of each layer grid all is basically identicals, and promptly the length of prismatic grid such as the E among Fig. 2 all are parastate and arrange, and has formed the unordered staggered cellular pore configuration that is similar between multi-layer net.
As shown in Figure 4: 9 is the outer layer net compartment of netted explosion-suppressing material, 10 is the mid-level net compartment, net volume is the single layer mesh of making by the selection size of Fig. 1 Fig. 2, adopts the described method of Fig. 3 through coiling or foldedly make shape, and whole net volume all goes out similar cellular pore configuration from inside to outside and forms.The netted explosion-suppressing material of cylinder scroll can be as requested, both can be superimposed or turn to rectangle or other shape, but also sawing is other needed shape.
As shown in Figure 5: 11 is the shape of single spherical explosion-suppressing material, it is to be made through operations such as system balls by netted blank, its external diameter is 12~80mm, the aluminium foil band 12 that constitutes spherical explosion-suppressing material is made up of muscle in the netted blank and connecting portion, ball 11 is to be made of bonded assembly band 12, and the inside of ball is similar cellular pore configuration, and the outside face of ball is level and smooth basically, so can guarantee the usage safety performance of material, be convenient to again in holder, spheroidal material be packed into or take out.
As shown in Figure 6: the weighting material of being installed in the portable holder 13 14 is netted explosion-suppressing material, 15 is the oil drum handle, and 16 is the holder geat, because of holder 13 is cylindrical, so installed the netted explosion-suppressing material of cylinder scroll, the load mode of this material is to pack into simultaneously at the making holder.Spherical explosion-suppressing material then can be directly packed into or is taken out from the holder perfusing hole of making, and the running condition of spherical explosion-suppressing material is that a plurality of balls stack in holder naturally.
The common ground that is used for the netted and spherical explosion-suppressing material of combustible and explosive articles of the present invention is, its alloy composition does not all have rare precious metal, when guaranteeing shop characteristic and operating needs, reduced cost, corrosion stability is strong, can use for permanent in container, the size of mesh opening and the shaped design of this material are reasonable, have both guaranteed datonation-inhibition function and rigidity, reduced the density of material again significantly, the datonation-inhibition function of this material is reliable.Use proof by experiment: netted and spherical explosion-suppressing material, all can suppress to fire pressure significantly, the holder (as gasoline drum) of installing these two kinds of materials is when lighting with naked light, and gasoline wherein only is little flare shape burning, the accident of will not blasting.This holder also can directly be with oil, band gas to carry out safe mending-leakage without emptying electricity consumption, gas welding, this loading netted and spherical explosion-suppressing material all can be selected (being 100% when filling container fully) by the requirement of withstand voltage of holder between 60%~100%, both guarantee the vessel safety use, reduced the volume of the shared container of material again.
Netted explosion-suppressing material of the present invention is characterized in: the mesh between the grid lamination is with the interlaced arrangement of same direction, multi-layer net has formed unordered cross structure each other, this structure efficient in retardance flame and blast propagation is higher, thereby having improved the datonation-inhibition function of material effectively, the rigidity of structure of this material is better.Density of material can be according to operating needs at 20~40Kg/M 3Select in the scope, the volume ratio that accounts for holder is 0.7%~1.5%, and its datonation-inhibition function is suppressed to the explosion pressure of propane air Mixture and is not more than 0.05MPa under standard test conditions, (not using the explosion pressure of this material to be 0.814MPa), density of material is 30Kg/M 3, the volume ratio that accounts for holder is 1%, loadings is 95%.
The characteristics of spherical explosion-suppressing material of the present invention are: the inside of globoid has guaranteed similar cellular high pore configuration, has datonation-inhibition function preferably, its density according to operating needs at 50~70Kg/M 3Select in the scope, the volume ratio that accounts for holder is 3.0~4.5%, and its datonation-inhibition function is suppressed to the explosion pressure of propane air Mixture and is not more than 0.07MPa under standard test conditions, (not using the explosion pressure of this material to be 0.814MPa), this moment, density of material was 63Kg/M 3, the volume ratio that accounts for container is 3.9%, loadings is 90%.

Claims (4)

1, a kind of explosion-suppressing material that is used for combustible and explosive articles, it is characterized in that: its chemical analysis percentage by weight of expansion aluminium foil is: Mn is 0.8~1.8, Fe is 0.3~0.7, Si is 0.3~0.6, Cu is 0.1~0.2, Zn is 0.1, Mg is 0.03~0.1, the Al surplus, and this netted explosion-suppressing material is by joint-cutting and system folded by the aluminium foil after expanding or coiling forms, grid between layer and the layer is staggered superimposed with equidirectional, the several layers grid has formed unordered cross structure each other, is the superimposed body of the several layers of honeycomb-like pore structure, and the aluminium foil after this spherical explosion-suppressing material is also expanded by joint-cutting is made, outer surface smoother, inside is the spheroid of honeycomb-like pore structure.
2, the explosion-suppressing material of combustible and explosive articles according to claim 1, it is characterized in that: its aluminum foil thickness of netted explosion-suppressing material is 0.02~0.2mm, width is 50~800mm, slot length on the aluminium foil is 8~25mm, connecting portion length is 2~6mm, muscle is wide to be 1~2.5mm, and the mesh size of expansion back single layer mesh is connecting portion width 2~5mm, and prism mesh length is 6~22mm.
3, the explosion-suppressing material of combustible and explosive articles according to claim 1 is characterized in that: the body that intervolves of the aluminum foil web after spherical explosion-suppressing material is also expanded by joint-cutting is stamped to form, and its profile diameter is 12~80mm.
4, according to the explosion-suppressing material of claim 1 or 3 described combustible and explosive articles, it is characterized in that: spherical explosion-suppressing material aluminum foil thickness is 0.04~0.2mm, width is 50~800mm, slot length on the aluminium foil is 10~25mm, connecting portion length is 2~8mm, muscle is wide to be 1~3mm, and the mesh size of expansion back single layer mesh is connecting portion width 2~6mm, and prism mesh length is 8~22mm.
CN 92102437 1992-04-03 1992-04-03 Knock-suppressing material for combustible and explosive articles Expired - Lifetime CN1029105C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 92102437 CN1029105C (en) 1992-04-03 1992-04-03 Knock-suppressing material for combustible and explosive articles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 92102437 CN1029105C (en) 1992-04-03 1992-04-03 Knock-suppressing material for combustible and explosive articles

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CN1077172A true CN1077172A (en) 1993-10-13
CN1029105C CN1029105C (en) 1995-06-28

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CN1319826C (en) * 2005-02-05 2007-06-06 黄晓东 Explosion isolative oil-gas recovery device for normal pressure oil tank
CN100364822C (en) * 2005-03-31 2008-01-30 黄晓东 Interception antiexplosion type automobile oil filling device
CN100365343C (en) * 2005-05-18 2008-01-30 黄晓东 Obstruct set for anti explosion
WO2008017215A1 (en) * 2006-08-02 2008-02-14 Jizhuang Wang A process for manufacturing an explosion suppression material
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CN101956098A (en) * 2010-06-08 2011-01-26 上海华篷防爆科技有限公司 Titanium alloy explosion-proof material suitable for aerospace field and preparation method thereof
CN101956104A (en) * 2010-06-04 2011-01-26 上海华篷防爆科技有限公司 Novel explosion-suppression material
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