CN107715703A - A kind of process units and method of MULTILAYER COMPOSITE Flat Membrane - Google Patents

A kind of process units and method of MULTILAYER COMPOSITE Flat Membrane Download PDF

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Publication number
CN107715703A
CN107715703A CN201711092756.3A CN201711092756A CN107715703A CN 107715703 A CN107715703 A CN 107715703A CN 201711092756 A CN201711092756 A CN 201711092756A CN 107715703 A CN107715703 A CN 107715703A
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CN
China
Prior art keywords
fixed slot
flat membrane
multilayer composite
composite flat
coating
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Granted
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CN201711092756.3A
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Chinese (zh)
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CN107715703B (en
Inventor
陈忠杰
郑世发
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Xiamen Zhanghua Environmental Protection Technology Co ltd
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Xiamen Pulse Technology Co Ltd
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Priority to CN201711092756.3A priority Critical patent/CN107715703B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/06Flat membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • B01D71/34Polyvinylidene fluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/26Spraying processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/42Details of membrane preparation apparatus

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of process units and method of MULTILAYER COMPOSITE Flat Membrane, the present apparatus includes uncoiling frame, swings coating head, spray coating head, surface modification apparatus for coating;The non-woven fabrics base material of web-like is placed with uncoiling frame, the lower end of non-woven fabrics base material is laid on traction conveyer belt;Flattening device is provided with traction conveyer belt on rear side of uncoiling frame;The first fixed slot, the second fixed slot are disposed with rear side of flattening device;Surface is disposed with rear side of second fixed slot and is modified apparatus for coating, heat setting device, automatic rolling device;Swing coating head is provided between flattening device and the first fixed slot;Spray coating head is provided between first fixed slot and the second fixed slot, air knife puts down device.The present invention can be used for the higher MULTILAYER COMPOSITE Flat Membrane of production membrane aperture precision, and the membranous wall thickness of Flat Membrane is uniform, and process units is adaptable, all has extensive adaptability to wet method phase inversion, thermally induced phase separation, composite thermotropic phase method technique.

Description

A kind of process units and method of MULTILAYER COMPOSITE Flat Membrane
Technical field
The present invention relates to a kind of process units and method, more particularly to a kind of process units of MULTILAYER COMPOSITE Flat Membrane and side Method.
Background technology
Flat Membrane is a kind of film of the selective penetrated property with micropore, and it can be widely used for the place of industry and municipal wastewater The filtering or separation in the various fields such as reason, drink water purifying, Treated sewage reusing, seawater desalinization pretreatment, pharmacy and food.It is flat at present The spinning production of plate film mainly uses scraper type one-shot forming apparatus and technique, is primarily present following defect:1) membrane aperture essence Degree is not high;2) membranous wall became uneven;3) process units bad adaptability, wet method phase inversion or hot method phase inversion can only such as be adapted to Technique.
The content of the invention
In order to solve the weak point present in above-mentioned technology, the invention provides a kind of production of MULTILAYER COMPOSITE Flat Membrane Apparatus and method.
In order to solve the above technical problems, the technical solution adopted by the present invention is:A kind of production of MULTILAYER COMPOSITE Flat Membrane Device, including uncoiling frame, it also includes swinging coating head, spray coating head, surface modification apparatus for coating;It is placed with uncoiling frame The non-woven fabrics base material of web-like, the lower end of non-woven fabrics base material are laid on traction conveyer belt;On traction conveyer belt on rear side of uncoiling frame It is provided with flattening device;The first fixed slot, the second fixed slot are disposed with rear side of flattening device;
Automatic rolling device is provided with rear side of second fixed slot;Traction between second fixed slot and automatic rolling device Heat setting device is provided with conveyer belt;Surface is provided with front side of heat setting device and is modified apparatus for coating;
The upper end of traction conveyer belt between flattening device and the first fixed slot is provided with swing coating head;First fixed slot The upper end of traction conveyer belt between the second fixed slot is disposed with spray coating head from front to back, air knife puts down device.
First fixed slot, the second fixed slot are constant temperature, the fixed slot of permanent concentration, and the style keeping liquid in fixed slot is water-soluble Liquid.
Flattening device is made up of nip rolls and deviation correction mechanism, and nip rolls and deviation correction mechanism are respectively used to flat substrates and automatic Correction.
Be provided with the aperture of row's spray in spray coating head, hole diameter be 0.2~2mm, pitch of holes for 3~ 10mm。
The gap that air knife puts down air knife on device is 0.1~2mm, and operating air pressure is 0.1~0.5MPa.
It is multitube aerosol spray equipment that surface, which is modified apparatus for coating, and tube pitch is 10~200mm.
Heater on heat setting device is quartz ampoule.
A kind of production method of MULTILAYER COMPOSITE Flat Membrane, it is comprised the following steps that:
A, the non-woven fabrics base material of Flat Membrane is placed on uncoiling frame;
B, non-woven fabrics base material passes through from flattening device first in the presence of conveyer belt is drawn, by nip rolls and correction Mechanism effect become it is more smooth with it is neat;
C, swing coating head is swung in the range of 5~50mm according to operating mode, and it is equably coated in casting solution On non-woven fabrics base material;
D, the non-woven fabrics base material for scribbling casting solution is shaped in the first fixed slot, forms the counterdie of MULTILAYER COMPOSITE Flat Membrane;
E, coating medium is further uniformly coated on the counterdie of MULTILAYER COMPOSITE Flat Membrane by spray coating head, then in gas Knife puts down the lower rapid draing of purging effect of device;
F, dried coating counterdie, which is resent in the second fixed slot, carries out secondary sizing, forms MULTILAYER COMPOSITE Flat Membrane Semi-finished product film;
G, after the semi-finished product film of MULTILAYER COMPOSITE Flat Membrane comes out from the second fixed slot, then by surface modification apparatus for coating Effect spray coating liquor is uniformly coated on the extexine of MULTILAYER COMPOSITE Flat Membrane semi-finished product;
H, the MULTILAYER COMPOSITE Flat Membrane finished product finally hot briquetting in heat setting device of spray coating liquor is scribbled, and by automatic The winding of wrap-up acts on forming web-like, completes to prepare.
The present invention can be used for the higher MULTILAYER COMPOSITE Flat Membrane of production membrane aperture precision, and the membranous wall thickness of Flat Membrane is equal Even, process units is adaptable, all has to wet method phase inversion, thermally induced phase separation, composite thermotropic phase method technique extensive Adaptability.
Brief description of the drawings
Fig. 1 is the system structure diagram of the present invention.
In figure:1st, uncoiling frame;2nd, flattening device;3rd, coating head is swung;4th, the first fixed slot;5th, coating head is sprayed;6th, gas Knife puts down device;7th, the second fixed slot;8th, surface is modified apparatus for coating;9th, heat setting device;10th, automatic rolling device.
Embodiment
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
A kind of process units of MULTILAYER COMPOSITE Flat Membrane shown in Fig. 1 includes uncoiling frame 1, it also include swing coating head 3, Spray coating head 5, surface is modified apparatus for coating 8;The non-woven fabrics base material of web-like is placed with uncoiling frame 1, under non-woven fabrics base material Hold level with both hands and be laid on traction conveyer belt;Flattening device 2 is provided with the traction conveyer belt of the rear side of uncoiling frame 1;Flattening device 2 is by flattening Roller and deviation correction mechanism composition, nip rolls and deviation correction mechanism are respectively used to flat substrates and automatic deviation correction.
The rear side of flattening device 2 is disposed with the first fixed slot 4, the second fixed slot 7;First fixed slot 4, second is shaped Groove 7 is constant temperature, the fixed slot of permanent concentration, and the style keeping liquid in fixed slot is the aqueous solution.
The rear side of second fixed slot 7 is provided with automatic rolling device 10, and automatic rolling device is the stepless speed regulation of air-expanding shaft Wrap-up, it is 0~50 m/min that it, which produces hauling speed,;Traction transmission between second fixed slot 7 and automatic rolling device 10 Take and be provided with heat setting device 9, the heater on heat setting device 9 is quartz ampoule.
The front side of heat setting device 9 is provided with surface and is modified apparatus for coating 8;It is multitube gas that surface, which is modified apparatus for coating 8, Spray painting automatic doubler surface glouer, spray coating liquor very unfertile land can be evenly coated on the extexine of MULTILAYER COMPOSITE Flat Membrane semi-finished product, tube pitch 10 ~200mm.
The upper end of traction conveyer belt between the fixed slot 4 of flattening device 2 and first, which is provided with, swings coating head 3, swings and applies The hunting range of the leftover of bolt of cloth 3 is 5~50mm;The upper end of traction conveyer belt between first fixed slot 4 and the second fixed slot 7 is from forward direction After be disposed with spray coating head 5, air knife and put down device 6.The aperture of row's spray is provided with spray coating head 5, it is small Bore dia is 0.2~2mm, and pitch of holes is 3~10mm.The gap that air knife puts down air knife on device 6 is 0.1~2mm, operating air pressure For 0.1~0.5MPa.
A kind of production method of MULTILAYER COMPOSITE Flat Membrane, it is comprised the following steps that:
A, the non-woven fabrics base material of Flat Membrane is placed on uncoiling frame 1;
B, non-woven fabrics base material passes through from flattening device 2 first in the presence of conveyer belt is drawn, and by nip rolls and entangles The effect of inclined mechanism become it is more smooth with it is neat;
C, swing coating head 3 is swung in the range of 5~50mm according to operating mode, and it is equably coated in casting solution On non-woven fabrics base material;
D, the non-woven fabrics base material for scribbling casting solution is shaped in the first fixed slot 4, forms the counterdie of MULTILAYER COMPOSITE Flat Membrane;
E, coating medium is further uniformly coated on the counterdie of MULTILAYER COMPOSITE Flat Membrane by spray coating head 5, Ran Hou Air knife puts down the lower rapid draing of purging effect of device 6;
F, dried coating counterdie, which is resent in the second fixed slot 7, carries out secondary sizing, forms MULTILAYER COMPOSITE flat board The semi-finished product film of film;
G, after the semi-finished product film of MULTILAYER COMPOSITE Flat Membrane comes out from the second fixed slot 7, then it is modified painting by surface and arranges Put 8 effect spray coating liquor is uniformly coated on the extexine of MULTILAYER COMPOSITE Flat Membrane semi-finished product;
H, the MULTILAYER COMPOSITE Flat Membrane finished product finally hot briquetting in heat setting device 9 of spray coating liquor is scribbled, and by certainly The winding of dynamic wrap-up 10 acts on forming web-like, completes to prepare.
The technique effect of the present invention and its extensive adaptability are explained in detail below by three specific embodiments State:
Embodiment one,
The process units of MULTILAYER COMPOSITE Flat Membrane in the present invention is used for wet production PVDF MULTILAYER COMPOSITE Flat Membranes:Setting It is 16 ms/min to produce hauling speed, swings coating head 3 first and stops not turning, and sprays coating head 5 and surface is modified apparatus for coating 8 are not worked, are produced equivalent in general Flat Membrane, and sample 1 is taken after stabilization within 10 minutes after operation;Then setting swings coating head Amplitude of fluctuation 20mm/min start to swing, spray coating head 5 and surface and be modified apparatus for coating 8 and do not work, treat operation 10 Sample 2 is taken after minute is stable;Then spray coating head 5 is further opened, at this moment air knife puts down device 6 and surface is modified coating Device 8 is not worked, and sample 3 is taken after stabilization within 10 minutes after operation;Then further open air knife and put down device 6, set air knife Crack 0.3mm, the air knife that air pressure is 0.2MPa are purged, and sample 4 is taken after stabilization within 10 minutes after operation;Finally it is then turned on surface modification Apparatus for coating 8 and heat setting device 9, sample 5 is taken after stabilization within 10 minutes after operation.
After 5 samples in embodiment one are post-processed by the usual mode of production, data and analysis are detected, and be shown in Table 1。
Embodiment two,
The process units of MULTILAYER COMPOSITE Flat Membrane in the present invention is used into thermally induced phase separation production PVDF MULTILAYER COMPOSITEs to put down Plate film:Production hauling speed is set as 45 ms/min, coating head 3 is swung first and stops not turning, spray coating head 5 and surface changes Property apparatus for coating 8 do not work, produced equivalent in general Flat Membrane, sample 6 taken after operation 10 minutes is stable;Then set The amplitude of fluctuation 30mm/min of coating head 3 is swung, starts simultaneously at swing, coating head 5 is sprayed and surface modification apparatus for coating 8 is equal Do not work, sample 7 is taken after stabilization within 10 minutes after operation;Then further open spray coating head 5, air knife put down device 6 and Surface is modified apparatus for coating 8 and not worked, and sample 8 is taken after stabilization within 10 minutes after operation;Then further open air knife and put down dress 6 are put, sets air knife crack 0.5mm, the air knife that air pressure is 0.5MPa is purged, and sample 9 is taken after stabilization within 10 minutes after operation;Finally open Open surface and be modified apparatus for coating 8 and heat setting device 9, sample 10 is taken after stabilization within 10 minutes after operation.
After 5 samples in embodiment two are post-processed by the usual mode of production, detection data and analysis such as table 1.
Embodiment three,
The process units of MULTILAYER COMPOSITE Flat Membrane in the present invention is used for composite thermotropic phase method PVDF MULTILAYER COMPOSITE Flat Membranes: Production hauling speed is set as 30 ms/min, coating head 3 is swung first and stops not turning, coating head 5 is sprayed and surface is modified coating Device 8 is not worked, is produced equivalent in general Flat Membrane, and sample 11 is taken after stabilization within 10 minutes after operation;Setting swings coating First 3 amplitude of fluctuation 40mm/min, swing is started simultaneously at, sprays coating head 5 and surface is modified apparatus for coating 8 and do not worked, Sample 12 is taken after operation after stabilization within 10 minutes;Then spray coating head 5 is further opened, at this moment air knife puts down device 6 and table Face is modified apparatus for coating 8 and not worked, and sample 13 is taken after stabilization within 10 minutes after operation;Then open air knife and put down device 6, set Air knife crack 0.6mm, the air knife that air pressure is 0.3MPa are purged, and sample 14 is taken after stabilization within 10 minutes after operation;Finally enable surface Modified apparatus for coating 8 and heat setting device 9, sample 15 is taken after stabilization within 10 minutes after operation.
After in embodiment three 5 individual sample is post-processed by the usual mode of production, detection data and analysis such as table 1.
The MULTILAYER COMPOSITE Flat Membrane of table 1 detects tables of data
The present invention has the advantage that compared with conventional art:
(1) effect of MULTILAYER COMPOSITE, the performance of comprehensive each composite bed are passed through, it is possible to increase the separation essence of flat film product Degree;
(2) using coating head is swung, by the swing of coating head, drive the horizontal levelling of casting solution and further mix equal Even effect, improve the uniformity of the bottom membrane wall thickness of MULTILAYER COMPOSITE Flat Membrane;Material mixing can be further improved simultaneously Uniformity, the homogeneity in aperture is separated so as to improve it.
(3) device is put down using spray coating head, air knife so that in the extexine of spread plate film, be coated with and put down Mechanism will not have with the bottom membrane of MULTILAYER COMPOSITE Flat Membrane to be contacted firmly, so as to not damage bottom membrane, and improves flat board film layer Uniformity.
(4) multi-tube structure of apparatus for coating is modified by using surface, spray coating liquor very unfertile land is evenly coated in multilayer and answered The extexine of Flat Membrane semi-finished product is closed, further increases the adaptability of this process units.
Above-mentioned embodiment is not limitation of the present invention, and the present invention is also not limited to the example above, this technology neck The variations, modifications, additions or substitutions that the technical staff in domain is made in the range of technical scheme, also belong to this hair Bright protection domain.

Claims (8)

1. a kind of process units of MULTILAYER COMPOSITE Flat Membrane, including uncoiling frame (1), it is characterised in that:It also includes swinging coating Head (3), spray coating head (5), surface are modified apparatus for coating (8);The nonwoven fabric base of web-like is placed with the uncoiling frame (1) Material, the lower end of non-woven fabrics base material are laid on traction conveyer belt;Exhibition is provided with traction conveyer belt on rear side of the uncoiling frame (1) Leveling device (2);The first fixed slot (4), the second fixed slot (7) are disposed with rear side of the flattening device (2);
Automatic rolling device (10) is provided with rear side of second fixed slot (7);Second fixed slot (7) and automatic rolling device (10) heat setting device (9) is provided with the traction conveyer belt between;Surface is provided with front side of the heat setting device (9) to change Property apparatus for coating (8);
The upper end of traction conveyer belt between the flattening device (2) and the first fixed slot (4), which is provided with, swings coating head (3); The upper end of traction conveyer belt between first fixed slot (4) and the second fixed slot (7) is disposed with spray from front to back Coating head (5), air knife put down device (6).
2. the process units of MULTILAYER COMPOSITE Flat Membrane according to claim 1, it is characterised in that:First fixed slot (4), the second fixed slot (7) is constant temperature, the fixed slot of permanent concentration, and the style keeping liquid in fixed slot is the aqueous solution.
3. the process units of MULTILAYER COMPOSITE Flat Membrane according to claim 1, it is characterised in that:The flattening device (2) It is made up of nip rolls and deviation correction mechanism, nip rolls and deviation correction mechanism are respectively used to flat substrates and automatic deviation correction.
4. the process units of MULTILAYER COMPOSITE Flat Membrane according to claim 1, it is characterised in that:The spray coating head (5) aperture of row's spray is provided with, hole diameter is 0.2~2mm, and pitch of holes is 3~10mm.
5. the process units of MULTILAYER COMPOSITE Flat Membrane according to claim 1, it is characterised in that:The air knife puts down device (6) gap of air knife is 0.1~2mm on, and operating air pressure is 0.1~0.5MPa.
6. the process units of MULTILAYER COMPOSITE Flat Membrane according to claim 1, it is characterised in that:The surface is modified coating Device (8) is multitube aerosol spray equipment, and tube pitch is 10~200mm.
7. the process units of MULTILAYER COMPOSITE Flat Membrane according to claim 1, it is characterised in that:The heat setting device (9) heater on is quartz ampoule.
A kind of 8. production method of MULTILAYER COMPOSITE Flat Membrane, it is characterised in that:Methods described comprises the following steps that:
A, the non-woven fabrics base material of Flat Membrane is placed on uncoiling frame (1);
B, non-woven fabrics base material is passing through from flattening device (2) first in the presence of drawing conveyer belt, by nip rolls and correction Mechanism effect become it is more smooth with it is neat;
C, swing coating head (3) is swung in the range of 5~50mm according to operating mode, and make it that casting solution is equably coated in into nothing Spin on cloth base material;
D, the non-woven fabrics base material for scribbling casting solution is shaped in the first fixed slot (4), forms the counterdie of MULTILAYER COMPOSITE Flat Membrane;
E, spray coating head (5) to be further uniformly coated to coating medium on the counterdie of MULTILAYER COMPOSITE Flat Membrane, then in gas Knife puts down the lower rapid draing of purging effect of device (6);
F, dried coating counterdie, which is resent in the second fixed slot (7), carries out secondary sizing, forms MULTILAYER COMPOSITE Flat Membrane Semi-finished product film;
G, after the semi-finished product film of MULTILAYER COMPOSITE Flat Membrane comes out from the second fixed slot (7), then by surface modification apparatus for coating (8) spray coating liquor is uniformly coated on the extexine of MULTILAYER COMPOSITE Flat Membrane semi-finished product by effect;
H, the MULTILAYER COMPOSITE Flat Membrane finished product finally hot briquetting in heat setting device (9), and by automatic of spray coating liquor is scribbled The winding of wrap-up (10) acts on forming web-like, completes to prepare.
CN201711092756.3A 2017-11-08 2017-11-08 Production device and method of multilayer composite flat plate film Active CN107715703B (en)

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CN109772938A (en) * 2019-01-28 2019-05-21 苏州天立达胶粘制品有限公司 Silverskin coiled material warpage changes flattening device

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Publication number Priority date Publication date Assignee Title
CN109772938A (en) * 2019-01-28 2019-05-21 苏州天立达胶粘制品有限公司 Silverskin coiled material warpage changes flattening device
CN109772938B (en) * 2019-01-28 2020-07-10 苏州天立达胶粘制品有限公司 Silver membrane coiled material warpage changes and levels device

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