CN107712844A - A kind of preparation method and applications of meteoritic mineral ion - Google Patents
A kind of preparation method and applications of meteoritic mineral ion Download PDFInfo
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- CN107712844A CN107712844A CN201710952319.8A CN201710952319A CN107712844A CN 107712844 A CN107712844 A CN 107712844A CN 201710952319 A CN201710952319 A CN 201710952319A CN 107712844 A CN107712844 A CN 107712844A
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 71
- 239000011707 mineral Substances 0.000 title claims abstract description 71
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000002386 leaching Methods 0.000 claims abstract description 47
- 150000003839 salts Chemical class 0.000 claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 12
- 238000003860 storage Methods 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000005070 sampling Methods 0.000 claims abstract description 5
- 238000010790 dilution Methods 0.000 claims description 51
- 239000012895 dilution Substances 0.000 claims description 51
- 239000002608 ionic liquid Substances 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 34
- 239000000243 solution Substances 0.000 claims description 34
- 230000004913 activation Effects 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000011259 mixed solution Substances 0.000 claims description 21
- 238000001514 detection method Methods 0.000 claims description 18
- 150000007522 mineralic acids Chemical class 0.000 claims description 18
- 238000000855 fermentation Methods 0.000 claims description 15
- 230000004151 fermentation Effects 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- 238000005530 etching Methods 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 11
- 235000013305 food Nutrition 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 230000035800 maturation Effects 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- 239000000292 calcium oxide Substances 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 13
- 230000009467 reduction Effects 0.000 abstract description 9
- 238000005342 ion exchange Methods 0.000 abstract description 7
- 238000006555 catalytic reaction Methods 0.000 abstract description 5
- 150000002500 ions Chemical class 0.000 description 93
- 235000010755 mineral Nutrition 0.000 description 57
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 7
- 239000000920 calcium hydroxide Substances 0.000 description 7
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 7
- 239000002366 mineral element Substances 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 7
- 229910052796 boron Inorganic materials 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/015—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12G—WINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
- C12G3/00—Preparation of other alcoholic beverages
- C12G3/02—Preparation of other alcoholic beverages by fermentation
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Food Science & Technology (AREA)
- Nutrition Science (AREA)
- Biochemistry (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- General Health & Medical Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Inorganic Chemistry (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The present invention discloses a kind of preparation method and applications of meteoritic mineral ion, and the wherein preparation method of meteoritic mineral ion includes following technological process：A, dispensing；B, mix in proportion；C, acid leaching；D, pH value adjustment is carried out；E, mineral salt concentration proportioning, sampling analysis, filling, storage.The present invention a kind of meteoritic mineral ion preparation method the advantages of be：Features simple and practical process, production cost are low, and meteoritic mineral ion has superpower electron reduction and ion exchanging function, and stronger catalytic reaction power is possessed in terms of biologic applications.
Description
Technical field
The present invention relates to a kind of preparation of mineral ion, more particularly to a kind of preparation method of meteoritic mineral ion.
The invention further relates to meteoritic mineral ion maturation agent prepared by the above method in the industrialized production of based food of fermenting
In application.
Background technology
In existing mineral matter and micro- application technology, the single element minerals of finished product are generally adopted by, or
Once the complex that person is mixed with single element, its shortcoming are exactly the i.e. aobvious toxicity of excessive application, and safe to the human body are not ensured.It is general
Logical mineral matter easily causes the unstable or harmful material that dissociates in activating and reducing.
The content of the invention
The present invention is completed to solve deficiency of the prior art, and it is an object of the invention to provide a kind of letter of technique
List, there is superpower electron reduction and ion exchanging function, the ore deposit of stronger catalytic reaction power is possessed in terms of biologic applications
The preparation method of thing element ion.
It is an object of the invention to provide a kind of preparation method of meteoritic mineral ion, it is characterised in that：Comprise the following steps：
A, dispensing：White aerolite, Yi Ding aerolites and inorganic acid dilution；
B, white aerolite and the Yi Ding aerolite in step A is milled to the attritive powder between 5 μm -10 μm, it is inorganic with 5%
The mixing of sour dilution, obtains mixed solution, wherein the mass fraction ratio of white aerolite, Yi Ding aerolites and inorganic acid dilution according to
1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of -30 days 10 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered, the primary aerolite ion obtained after filtering
Liquid carries out pH value adjustment with pH regulators, and the aerolite ionic liquid pH value after adjustment obtains transparent activation between 1.0 to 3.0
Aerolite ionic liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is controlled between 2% to 6%, matches into purposes
The concentration respectively needed, then sampling carry out composition detection, and such as containing more than 12 kinds of mineral ion composition, the activated solution of gained is then
For qualified finished product is made, then packs, be put in storage.
A kind of preparation method of meteoritic mineral ion of the present invention can also be：
The inorganic acid dilution is HCL dilutions or H2SO4Dilution.
The regulator is calcium hydroxide or sodium hydroxide.
A kind of preparation method of meteoritic mineral ion of the present invention, comprises the following steps：A, dispensing：White aerolite, Yi Ding fall from the sky or outer space
Stone and inorganic acid dilution；B, white aerolite and the Yi Ding aerolite in step A is milled to the attritive powder between 5 μm -10 μm, with
5% inorganic acid dilution mixing, obtains mixed solution, wherein the mass parts of white aerolite, Yi Ding aerolites and inorganic acid dilution
Number ratio is according to 1:1：4 mixing；C, the mixed solution obtained in step B is put into leaching groove, leaches the pressure control in groove
In 1.3 to 2 atmospheric pressure, the acid etching leaching of -30 days 10 days by a definite date normal temperature is carried out, and the leaching containing aerolite ion can be obtained
Solution；D, the leaching solution containing aerolite ion obtained in step C is filtered, the primary aerolite ionic liquid obtained after filtering is used
PH regulators carry out pH value adjustment, and the aerolite ionic liquid pH value after adjustment obtains transparent activation aerolite between 1.0 to 3.0
Ionic liquid；E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is controlled between 2% to 6%, matches into purposes
The concentration respectively needed, then sampling carry out composition detection, and such as containing more than 12 kinds of mineral ion composition, the activated solution of gained is then
For qualified finished product is made, then packs, be put in storage.So, it is because aerolite using aerolite as mineral element ion extractuin raw material
Burnt via atmosphere high temperature with after friction, generally there is very high magnetic energy, after aerolite atomizing/ionizing is reduced, its
Element ion has superpower electron reduction and ion exchanging function.The present invention uses inorganic acid isolation technics, in inorganic acid
When carrying out combination reaction with mineral molecule, it may occur that the chemical combination reduction of minerals, reduce later atom and have ionic condition
Afterwards, its electronics is accessible motion state, and the element of this state is called " ion " in chemistry.Because aerolite has very high magnetic
Property, so, after aerolite atomizing/ionizing is reduced, its ion has superpower electron reduction and ion exchanging function,
Possess stronger catalytic reaction power in terms of biologic applications.And aerolite class minerals extraction element ion is used, still it is first in the world
Secondary, its meteoritic mineral ion is diversity, is either quoted in terms of human body, animal, plant, or environment, is had safe and reliable
Property.
The present invention also provides a kind of mineral ion and ferments maturation agent as described in the preparation method of above-mentioned meteoritic mineral ion
Application of the mineral ion in the industrialized production of fermentation based food.Comprise the following steps：A, dispensing：White aerolite, Yi Ding aerolites
With inorganic acid dilution；B, white aerolite and the Yi Ding aerolite in step A is milled to the attritive powder between 5 μm -10 μm, with
5% inorganic acid dilution mixing, obtains mixed solution, wherein the mass parts of white aerolite, Yi Ding aerolites and inorganic acid dilution
Number ratio is according to 1:1：4 mixing；C, the mixed solution obtained in step B is put into leaching groove, leaches the pressure control in groove
In 1.3 to 2 atmospheric pressure, the acid etching leaching of -30 days 10 days by a definite date normal temperature is carried out, and the leaching containing aerolite ion can be obtained
Solution；D, the leaching solution containing aerolite ion obtained in step C is filtered, the primary aerolite ionic liquid obtained after filtering is used
PH regulators carry out pH value adjustment, and the aerolite ionic liquid pH value after adjustment obtains transparent activation aerolite between 1.0 to 3.0
Ionic liquid；E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is controlled between 2% to 6%, matches into purposes
The concentration respectively needed, then sampling carry out composition detection, and such as containing more than 12 kinds of mineral ion composition, the activated solution of gained is then
For qualified finished product is made, then packs, be put in storage.So, due in traditional fermentation drinks, fruit vegetables food industry, normal
Under the conditions of temperature, fermentation time is typically not less than 15 days, and for hundreds of years, fermentation time and condition required by these technologies are all never
Change.And aerolite is burnt with after friction, generally having very high magnetic energy, by aerolite atomizing/ionizing via atmosphere high temperature
After reduction, its element ion has superpower electron reduction and ion exchanging function, and combination reaction is being carried out with microorganism
When, there is activation of microorganism to accelerate Fermentation Function, also possess the living things catalysis energy and ability of quick maturation.Therefore, as food
Product fermenting additive, fermentation time can be greatly shortened.The fermentation maturation agent of meteoritic mineral ion is that have several mineral materials and micro-
The solion of secondary element, for based food industrialized production of fermenting, production capacity can be not only improved, reduces cost, moreover it is possible to
Improving quality and mouthfeel, a reliable, sustainable development is provided to fermentation based food industry.
Embodiment
A kind of preparation method of meteoritic mineral ion of the present invention is made with reference to specific embodiment further detailed
Explanation.
A kind of preparation method of meteoritic mineral ion of the present invention, comprises the following steps：
A, dispensing：White aerolite, Yi Ding aerolites (being called the red aerolites of Yi Ding or Mars Yi Ding aerolites) and inorganic acid dilution；
White aerolite and Yi Ding aerolite in step A is milled to 5~10 μm of fine-powder, be with mass percent B,
5% HCL dilutions or mass percent is 5% H2SO4Dilution is mixed, wherein white aerolite, Yi Ding aerolites and inorganic
The mass fraction ratio of sour dilution is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of -30 days 10 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, obtained after filtering
Primary aerolite ionic liquid carries out pH value adjustment with calcium hydroxide or sodium hydroxide, and the aerolite ionic liquid after adjustment is examined with pH meter
Survey, the transparent activation aerolite ionic liquid of the various application approaches using different, pH value between 1.0 to 3.0 can be configured；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is controlled between 2% to 6%, matches into purposes
The concentration respectively needed, then sample and composition detection is carried out with spectra methods, such as containing more than 12 kinds of mineral ion composition, gained
Soluble transparent solution then for qualified finished product is made, then pack, be put in storage.
The present invention a kind of meteoritic mineral ion preparation method, when screen raw material, first have to reject containing heavy metal with
The aerolite of radioactive element, aerolite is then being carried out to above-mentioned ionization reduction, resulting solution ph is below 3.0
Acidic liquid, measured with dioptric salinometer, aerolite ion mineral salt percent concentration is between 2%-6%, without any precipitation
Thing.It is relative to the advantages of prior art：The mineral matter and micro- single application approach, exploitation to break traditions has height
The aerolite ion of magnetic, high ion-exchange capacity, one is opened up in terms of biochemistry for mineral matter from now on and trace element
New way.
A kind of preparation method of meteoritic mineral ion of the present invention, can be specifically on the basis of previous technique scheme：
The inorganic acid dilution is HCL dilutions or H2SO4Dilution.HCL and H2SO4It is safer in biochemistry application
Inorganic acid species.Certainly can also be：The pH regulators are calcium hydroxide or sodium hydroxide.Because with calcium hydroxide or hydrogen-oxygen
Change sodium when adjust pH value, the ionic condition of aerolite element will not be changed, will not chemical combination go out other harmful elements, be protect element
The optimal compound of ionic condition.
The mineral matter and micro- species that a kind of mineral ion liquid prepared with aerolite contains ionic state have：Calcium Ca, phosphorus
P, magnesium Mg, potassium K, sodium Na, strontium Sr, sulphur S, manganese Mn, chromium Cr, cobalt Co, nickel, copper Cu, iron Fe, vanadium V, zinc Zn, boron, aluminium Al.
The present invention also provides a kind of mineral ion and ferments maturation agent as made from the preparation method of above-mentioned meteoritic mineral ion
Application of the mineral ion in the industrialized production of fermentation based food.It can be used as sending out using mineral ion made from this method
Ferment maturation agent uses.Meteoritic mineral ion has superpower electron reduction and ion exchanging function, with microorganismization
When closing reaction, there is activation of microorganism to accelerate Fermentation Function, also possess the living things catalysis energy and ability of quick maturation, therefore,
As food fermentation additive, fermentation time can be greatly shortened.And the fermentation maturation agent of meteoritic mineral ion is that have a variety of ore deposits
The solion of material and trace element, for based food industrialized production of fermenting, production capacity can be not only improved, is reduced into
This, moreover it is possible to improving quality and mouthfeel, a reliable, sustainable development is provided to fermentation based food industry.
Embodiment 1
A, dispensing：White aerolite, Yi Ding aerolites and H2SO4Dilution；
White aerolite and Yi Ding aerolite in step A is milled to 10 μm of attritive powder, the H with 5% B,2SO4Dilution mixes
Close, mixed solution is obtained, wherein white aerolite, Yi Ding aerolites and H2SO4The mass fraction ratio of dilution is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of 10 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, with dioptric after filtering
Salinometer detects, and can obtain the primary aerolite solion that mineral salt percent concentration is 3%, pH value is carried out with calcium hydroxide
Adjustment, is detected with pH meter, and the aerolite ionic liquid pH value after adjustment is 1.2, then obtains transparent activation aerolite ionic liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is 2%, then sample with spectra methods carry out into
Go-on-go is surveyed, and containing 12 kinds of mineral element ion components, then the soluble transparent activated solution finally given is obtained finished product, so
Pack, be put in storage afterwards.
Embodiment 2
A, dispensing：White aerolite, Yi Ding aerolites and H2SO4Dilution；
White aerolite and Yi Ding aerolite in step A is milled to 8 μm of attritive powder, the H with 5% B,2SO4Dilution mixes
Close, mixed solution is obtained, wherein white aerolite, Yi Ding aerolites and H2SO4The mass fraction ratio of dilution is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of 20 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, with dioptric after filtering
Salinometer detects, and can obtain the primary aerolite solion that mineral salt percent concentration is 5%, pH value is carried out with calcium hydroxide
Adjustment, is detected with pH meter, and the aerolite ionic liquid pH value after adjustment is 2.5, then obtains transparent activation aerolite ionic liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is 2%, then sample with spectra methods carry out into
Go-on-go is surveyed, and containing 16 kinds of mineral element ion components, then the soluble transparent activated solution finally given is obtained finished product, so
Pack, be put in storage afterwards.
Embodiment 3
A, dispensing：White aerolite, Yi Ding aerolites and H2SO4Dilution；
White aerolite and Yi Ding aerolite in step A is milled to 5 μm of attritive powder, the H with 5% B,2SO4Dilution mixes
Close, mixed solution is obtained, wherein white aerolite, Yi Ding aerolites and H2SO4The mass fraction ratio of dilution is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of 30 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, with dioptric after filtering
Salinometer detects, and can obtain the primary aerolite solion that mineral salt percent concentration is 6%, pH value is carried out with calcium hydroxide
Adjustment, is detected with pH meter, and the aerolite ionic liquid pH value after adjustment is 3.0, then obtains transparent activation aerolite ionic liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is 5.8%, then samples and is carried out with spectra methods
Composition detection, containing 17 kinds of mineral element ion components, then the soluble transparent activated solution finally given is obtained finished product,
Then pack, be put in storage.
Embodiment 4
A, dispensing：White aerolite, Yi Ding aerolites and HCL dilutions；
White aerolite and Yi Ding aerolite in step A is milled to 10 μm of attritive powder, the HCL dilutions with 5% mix B,
Close, mixed solution is obtained, wherein the mass fraction ratio of white aerolite, Yi Ding aerolites and HCL dilutions is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of 10 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, with dioptric after filtering
Salinometer detects, and can obtain the primary aerolite solion that mineral salt percent concentration is 5%, pH value is carried out with sodium hydroxide
Adjustment, is detected with pH meter, and the aerolite ionic liquid pH value after adjustment is 1.4, then obtains transparent activation aerolite ionic liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is 4%, then sample with spectra methods carry out into
Go-on-go is surveyed, and containing 12 kinds of mineral element ion components, then the soluble transparent activated solution finally given is obtained finished product, so
Pack, be put in storage afterwards.
Embodiment 5
A, dispensing：White aerolite, Yi Ding aerolites and HCL dilutions；
White aerolite and Yi Ding aerolite in step A is milled to 8 μm of attritive powder, the HCL dilutions with 5% mix B,
Close, mixed solution is obtained, wherein the mass fraction ratio of white aerolite, Yi Ding aerolites and HCL dilutions is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of 20 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, with dioptric after filtering
Salinometer detects, and can obtain the primary aerolite solion that mineral salt percent concentration is 4.5%, pH is carried out with sodium hydroxide
Value adjustment, is detected with pH meter, and the aerolite ionic liquid pH value after adjustment is 2.9, then obtains transparent activation aerolite ion
Liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is 3.5%, then samples and is carried out with spectra methods
Composition detection, containing 15 kinds of mineral element ion components, then the soluble transparent activated solution finally given is obtained finished product,
Then pack, be put in storage.
Embodiment 6
A, dispensing：White aerolite, Yi Ding aerolites and HCL dilutions；
White aerolite and Yi Ding aerolite in step A is milled to 5 μm of attritive powder, the HCL dilutions with 5% mix B,
Close, mixed solution is obtained, wherein the mass fraction ratio of white aerolite, Yi Ding aerolites and HCL dilutions is according to 1:1:4 mixing；
C, the mixed solution obtained in step B is put into leaching groove, the pressure control leached in groove is big at 1.3 to 2
In air pressure, the acid etching leaching of 30 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；
D, the leaching solution containing aerolite ion obtained in step C is filtered with filter, with dioptric after filtering
Salinometer detects, and can obtain the primary aerolite solion that mineral salt percent concentration is 5.8%, pH is carried out with sodium hydroxide
Value adjustment, is detected with pH meter, and the aerolite ionic liquid pH value after adjustment is 3.0, then obtains transparent activation aerolite ion
Liquid；
E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and with pure
Water matches its concentration dilution, and the mineral salt percent concentration of aerolite ion is 5%, then sample with spectra methods carry out into
Go-on-go is surveyed, and containing 16 kinds of mineral element ion components, then the soluble transparent activated solution finally given is obtained finished product, so
Pack, be put in storage afterwards.
A kind of preparation method of meteoritic mineral ion of the present invention, element species and constituent content, according to the time of leaching
Difference, its element species are also different from content.It is presented below according to leaching time 10 days, 20 days, 30 days, three members leached
Element control content table.
A kind of mineral ion liquid mineral prepared with aerolite and Trace Elements table：Composition is with mg/L Meter：
The aerolite ion elements component list of table 1, embodiment 1：Composition is with mg/L Meter：
| Composition | Content (mg/L) | Composition | Content (mg/L) |
| Ca | 7.1 | Co | -- |
| P | 8.4 | Ni | 0.78 |
| Mg | 602 | Cu | -- |
| K | 57.5 | Fe | 254 |
| Na | 9.6 | V | -- |
| Sr | 0.05 | Zn | -- |
| S | 231 | B | -- |
| Mn | 6.67 | Al | 1.29 |
| Cr | 0.90 | Hg | -- |
| Pb | -- | As | -- |
| Cd | -- | Total salinity | 2% |
The aerolite ion elements component list of table 2, embodiment 2：Composition is with mg/L Meter：
| Composition | Content (mg/L) | Composition | Content (mg/L) |
| Ca | 18.8 | Co | 0.21 |
| P | 20.1 | Ni | 1.37 |
| Mg | 1856 | Cu | 0.31 |
| K | 47.6 | Fe | 676 |
| Na | 25.6 | V | -- |
| Sr | -- | Zn | 0.65 |
| S | 885 | B | 0.52 |
| Mn | 17.6 | Al | 3.93 |
| Cr | 1.40 | Hg | -- |
| Pb | -- | As | ＜ 0.18 |
| Cd | -- | Total salinity | 2% |
The aerolite ion elements component list of table 3, embodiment 3：Composition is with mg/L Meter：
| Composition | Content (mg/L) | Composition | Content (mg/L) |
| Ca | 22.4 | Co | 0.25 |
| P | 24.3 | Ni | 1.48 |
| Mg | 2012 | Cu | -- |
| K | 57.5 | Fe | 706 |
| Na | 25.6 | V | -- |
| Sr | 0.19 | Zn | 0.82 |
| S | 791 | B | 0.58 |
| Mn | 20.6 | Al | 4.13 |
| Cr | 1.70 | Hg | ＜ 0.01 |
| Pb | -- | As | -- |
| Cd | ＜ 0.02 | Total salinity | 5.8% |
The aerolite ion elements component list of table 4, embodiment 4：Composition is with mg/L Meter：
| Composition | Content (mg/L) | Composition | Content (mg/L) |
| Ca | 6.9 | Co | -- |
| P | 7.2 | Ni | 0.68 |
| Mg | 713 | Cu | -- |
| K | 58.1 | Fe | 354 |
| Na | 11.9 | V | -- |
| Sr | -- | Zn | -- |
| S | 43 | B | 0.58 |
| Mn | 5.57 | Al | 2.59 |
| Cr | 0.97 | Hg | -- |
| Pb | -- | As | -- |
| Cd | -- | Total salinity | 4% |
The aerolite ion elements component list of table 5, embodiment 5：Composition is with mg/L Meter：
| Composition | Content (mg/L) | Composition | Content (mg/L) |
| Ca | 19.9 | Co | 0.21 |
| P | 17.1 | Ni | 1.37 |
| Mg | 1055 | Cu | -- |
| K | 41.6 | Fe | 675 |
| Na | 55.2 | V | -- |
| Sr | -- | Zn | 0.63 |
| S | 57 | B | 0.48 |
| Mn | 18.4 | Al | 3.13 |
| Cr | -- | Hg | -- |
| Pb | -- | As | ＜ 0.17 |
| Cd | ＜ 0.02 | Total salinity | 3.5% |
The aerolite ion elements component list of table 6, embodiment 6：Composition is with mg/L Meter：
| Composition | Content (mg/L) | Composition | Content (mg/L) |
| Ca | 20.3 | Co | 0.21 |
| P | 22.9 | Ni | 1.39 |
| Mg | 1711 | Cu | -- |
| K | 51.7 | Fe | 712 |
| Na | 95.6 | V | -- |
| Sr | -- | Zn | 0.73 |
| S | 791 | B | 0.56 |
| Mn | 19.2 | Al | 4.01 |
| Cr | 1.70 | Hg | -- |
| Pb | ＜ 0.05 | As | -- |
| Cd | ＜ 0.02 | Total salinity | 5% |
It is above-mentioned that only several specific embodiments in the present invention are illustrated, but can not be as the protection model of the present invention
Enclose, the equivalent change or modification or equal proportion made by every design spirit according in the present invention zoom in or out, all should
Think to fall into protection scope of the present invention.
Claims (4)
- A kind of 1. preparation method of meteoritic mineral ion, it is characterised in that：Comprise the following steps：A, dispensing：White aerolite, Yi Ding aerolites and inorganic acid dilution；B, white aerolite and the Yi Ding aerolite in step A is milled to the attritive powder between 5-10 μm, the inorganic acid with 5% dilutes Liquid mixes, and mixed solution is obtained, wherein the mass fraction ratio of white aerolite, Yi Ding aerolites and inorganic acid is according to 1:1:4 mixing；C, the mixed solution obtained in step B is put into leaching groove, leaches the pressure control in groove in 1.3 to 2 atmospheric pressure It is interior, the acid etching leaching of -30 days 10 days by a definite date normal temperature is carried out, and the leaching solution containing aerolite ion can be obtained；D, the leaching solution containing aerolite ion obtained in step C is filtered, the aerolite ionic liquid that primary is obtained after filtering is used PH regulators carry out pH value adjustment, and the aerolite ionic liquid pH value after adjustment obtains transparent activation aerolite between 1.0 to 3.0 Ionic liquid；E, the activation aerolite ionic liquid that will be obtained in D steps, aerolite ion detection is carried out with dioptric salinometer, and will with pure water Its concentration dilution matches, and the mineral salt percent concentration of aerolite ion is controlled between 2% to 6%, matching into purposes respectively needs Concentration, then sampling carries out composition detection, and such as containing more than 12 kinds of mineral ion composition, the activated solution of gained is then to make Qualified finished product is obtained, then packs, be put in storage.
- A kind of 2. preparation method of meteoritic mineral ion according to claim 1, it is characterised in that：Described inorganic acid is dilute It is HCL dilutions or H to release liquid2SO4Dilution.
- A kind of 3. preparation method of meteoritic mineral ion according to claim 1, it is characterised in that：The regulator is hydrogen Calcium oxide or sodium hydroxide.
- A kind of 4. mineral ion maturation agent, it is characterised in that：Including as a kind of meteoritic mineral described in claim 1 or 2 or 3 from Application of the mineral ion in the industrialized production of fermentation based food described in the preparation method of son.
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| CN111019783A (en) * | 2020-01-02 | 2020-04-17 | 舒文一 | Ionic calcium water-soluble agent applied to brewing process and application method thereof |
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