CN107700215A - A kind of special-purpose aqueous slurry for polyamide fibre weaving and preparation method thereof - Google Patents
A kind of special-purpose aqueous slurry for polyamide fibre weaving and preparation method thereof Download PDFInfo
- Publication number
- CN107700215A CN107700215A CN201711062152.4A CN201711062152A CN107700215A CN 107700215 A CN107700215 A CN 107700215A CN 201711062152 A CN201711062152 A CN 201711062152A CN 107700215 A CN107700215 A CN 107700215A
- Authority
- CN
- China
- Prior art keywords
- mixed solution
- special
- monomer mixed
- polyamide fibre
- acrylates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
Abstract
A kind of good water solubility of present invention offer, permeability is strong, antistatic behaviour is good, cohesive force is strong, it is clear to strengthen silk tractive force, rub resistance, opening after Polyamide Yarns starching, do not fall slurry, easy to use, environmental pollution is small and can mitigate special-purpose aqueous slurry for being used for polyamide fibre weaving of final finishing factory destarch cost and environment influence and preparation method thereof.Special-purpose aqueous slurry for polyamide fibre weaving includes monomer mixed solution, small powder, process water, and the monomer mixed solution is made up of 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190 ㎏ butyl acrylates, 269 ㎏ methyl acrylates, 254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates；The small powder includes 3 ㎏ emulsifying agents, 6 ㎏ initiators, 8 ㎏ defoamers, 3 ㎏ antistatic additive, 16 ㎏ bleeding agents, 50 ㎏ ammoniacal liquor, 300 ㎏ alcohol.
Description
Technical field
The present invention relates to textile sizing formula technique field, more particularly to a kind of special-purpose aqueous slurry for polyamide fibre weaving
And preparation method thereof.
Background technology
Textile sizing is the key link of weaving process, and the purpose of starching is mainly to improve the wearability of yarn, is spun at present
Knit slurry and be broadly divided into starch, polyvinyl alcohol（PVA）, polyacrylic acid three major types slurry, at home and abroad occupy critical role；But
All there are problems that, as polyvinyl alcohol pulp can not be biodegradable, caused serious environmental issue；Starch Size viscosity
Fluctuation is big, is gelatinized poor performance；And viscosity is serious again for acid polyethylene slurry, stronger to fiber bonding force, starching is unstable, follow-up de-
Slurry is difficult, causes final finishing factory cost higher, has greater environmental impacts.
Application No. CN201510788266.1 Chinese patent discloses a kind of weaving water paste and preparation method thereof,
The weaving water paste include monomer mixed solution, small powder, process water, monomer include 16kg acrylic acid, 56kg methacrylic acids,
190kg butyl acrylates, 269kg methyl acrylates, 254kg methyl methacrylates and 8kg N-butyls, the slurry are applied to height
Shelves fabric weaving, there is preferable water solubility, permeability, antistatic behaviour and cohesive force, but above have one in polyamide fibre application
Definite limitation.
The content of the invention
It is an object of the invention to overcome above shortcomings in the prior art, and provide a kind of good water solubility, infiltration
Property it is strong, antistatic behaviour is good, cohesive force is strong, it is clear to strengthen silk tractive force, rub resistance, opening after Polyamide Yarns starching, does not fall slurry, uses
It is convenient, environmental pollution is small and can mitigate final finishing factory destarch cost and what environment influenceed is used for the special-purpose aqueous of polyamide fibre weaving
Slurry and preparation method thereof.
Technical scheme is used by the present invention solves the above problems：A kind of special-purpose aqueous slurry for polyamide fibre weaving,
Including monomer mixed solution, small powder, process water, the monomer mixed solution is by 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190
㎏ butyl acrylates, 269 ㎏ methyl acrylates, 254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates are formed；It is described small
Material includes 3 ㎏ emulsifying agents, 6 ㎏ initiators, 8 ㎏ defoamers, 3 ㎏ antistatic additive, 16 ㎏ bleeding agents, 50 ㎏ ammoniacal liquor, 300 ㎏ wine
Essence.
Preferably, the emulsifying agent is dodecyl sodium sulfate.
Preferably, the initiator is ammonium persulfate.
The invention also discloses a kind of preparation method of the special-purpose aqueous slurry for polyamide fibre weaving, comprise the following steps：
The first step：Monomer mixes：By 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190 ㎏ butyl acrylates, 269 ㎏ propylene
Sour methyl esters, 254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates, 6 kinds of monomers are mixed to form monomer mixed solution；
Second step：Polymerization：Process water is added in existing 5 tons of reactors, 50 DEG C is heated to, is put into 3kg emulsifying agents, 6kg
Initiator, 80 DEG C are heated to, monomer mixed solution is instilled, temperature control carries out polymerisation, monomer mixed solution drop at 80 DEG C
Acceleration is uniform, and time for adding control temperature control during 130min, dropwise addition is protected after 80 DEG C, monomer mixed solution drip
Warm half an hour；
3rd step：Cooling：Polymer is cooled to 65~70 DEG C；
4th step：Neutralize：Neutralized in the polymer that 50kg ammoniacal liquor is added after cooling, control ph and viscosity；
5th step：Regulation, barrelling：Process water and auxiliary agent are added in polymer after neutralization, the auxiliary agent includes 8 ㎏ defoamers, 3
㎏ antistatic additive, 16 ㎏ bleeding agents and 300 ㎏ alcohol, cool to 30 DEG C, content and viscosity are controlled, finally by slurry barrelling
Or materials pump is squeezed into finished pot and kept in.
The present invention compared with prior art, has advantages below and effect：Slurry category water-soluble acrylic copolymerization it is cloudy from
Sub- compound, there is good mechanical stability, water spray, air-jet loom starching suitable for nylon fibre silk, have good water solubility,
Permeability is strong, antistatic behaviour is good, cohesive force is strong, it is clear to strengthen silk tractive force, rub resistance, opening after silk starching, does not fall slurry, uses
The advantages that facilitating, environmental pollution is small, while can mitigate destarch cost and the environment influence of final finishing factory.
Embodiment
Below by embodiment, the present invention is described in further detail, following examples be explanation of the invention and
The invention is not limited in following examples.
Embodiment.
A kind of special-purpose aqueous slurry for polyamide fibre weaving of the embodiment of the present invention, including monomer mixed solution, small powder, technique
Water, monomer mixed solution by 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190 ㎏ butyl acrylates, 269 ㎏ methyl acrylates,
254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates are formed；Small powder includes 3 ㎏ emulsifying agents, 6 ㎏ initiators, 8 ㎏ defoamings
Agent, 3 ㎏ antistatic additive, 16 ㎏ bleeding agents, 50 ㎏ ammoniacal liquor, 300 ㎏ alcohol, wherein emulsifying agent select dodecyl sodium sulfate, draw
Ammonium persulfate is selected in hair agent.
The above-mentioned preparation method of special-purpose aqueous slurry for polyamide fibre weaving of the present invention is：
The first step：Monomer mixes：By 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190 ㎏ butyl acrylates, 269 ㎏ propylene
Sour methyl esters, 254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates, 6 kinds of monomers are mixed to form monomer mixed solution；
Second step：Polymerization：Process water is added in existing 5 tons of reactors, 50 DEG C is heated to, is put into 3kg emulsifying agents, 6kg
Initiator, 80 DEG C are heated to, monomer mixed solution is instilled, temperature control carries out polymerisation, monomer mixed solution drop at 80 DEG C
Acceleration is uniform, and time for adding control temperature control during 130min, dropwise addition is protected after 80 DEG C, monomer mixed solution drip
Warm half an hour；
3rd step：Cooling：Polymer is cooled to 65~70 DEG C；
4th step：Neutralize：Neutralized in the polymer that 50kg ammoniacal liquor is added after cooling, control ph and viscosity；
5th step：Regulation, barrelling：Process water and auxiliary agent are added in polymer after neutralization, the auxiliary agent includes 8 ㎏ defoamers, 3
㎏ antistatic additive, 16 ㎏ bleeding agents and 300 ㎏ alcohol, cool to 30 DEG C, content and viscosity are controlled, finally by slurry barrelling
Or materials pump is squeezed into finished pot and kept in.
The special water paste of polyamide fibre weaving that is used for of the present invention belongs to water-soluble acrylic copolymerization anionic compound, tool
There is good mechanical stability, water spray, air-jet loom starching suitable for nylon fibre silk, have good water solubility, permeability strong, anti-
Static behaviour is good, cohesive force is strong, it is clear to strengthen silk tractive force, rub resistance, opening after silk starching, does not fall the advantages that starching, be easy to use,
Environmental pollution is small, while can mitigate destarch cost and the environment influence of final finishing factory.
Furthermore, it is necessary to illustrate, the embodiment described in this specification is only the more representational example of the present invention.
Obviously, technical scheme is not limited to above-described embodiment, can also there is many variations.One of ordinary skill in the art
All deformations that directly can be exported or associate from present disclosure, are considered as protection scope of the present invention.
Claims (4)
- A kind of 1. special-purpose aqueous slurry for polyamide fibre weaving, it is characterised in that：Including monomer mixed solution, small powder, process water, institute State monomer mixed solution by 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190 ㎏ butyl acrylates, 269 ㎏ methyl acrylates, 254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates are formed；The small powder includes 3 ㎏ emulsifying agents, 6 ㎏ initiators, 8 ㎏ Defoamer, 3 ㎏ antistatic additive, 16 ㎏ bleeding agents, 50 ㎏ ammoniacal liquor, 300 ㎏ alcohol.
- A kind of 2. special-purpose aqueous slurry for polyamide fibre weaving according to claim 1, it is characterised in that：The emulsifying agent For dodecyl sodium sulfate.
- A kind of 3. special-purpose aqueous slurry for polyamide fibre weaving according to claim 1, it is characterised in that：The initiator For ammonium persulfate.
- 4. a kind of preparation method of special-purpose aqueous slurry for polyamide fibre weaving according to claim 1-3, its feature exist In：Comprise the following steps：The first step：Monomer mixes：By 16 ㎏ acrylic acid, 29 ㎏ NMAs, 190 ㎏ butyl acrylates, 269 ㎏ propylene Sour methyl esters, 254 ㎏ methyl methacrylates, 10 ㎏ lauryl acrylates, 6 kinds of monomers are mixed to form monomer mixed solution；Second step：Polymerization：Process water is added in existing 5 tons of reactors, 50 DEG C is heated to, is put into 3kg emulsifying agents, 6kg Initiator, 80 DEG C are heated to, monomer mixed solution is instilled, temperature control carries out polymerisation, monomer mixed solution drop at 80 DEG C Acceleration is uniform, and time for adding control temperature control during 130min, dropwise addition is protected after 80 DEG C, monomer mixed solution drip Warm half an hour；3rd step：Cooling：Polymer is cooled to 65~70 DEG C；4th step：Neutralize：Neutralized in the polymer that 50kg ammoniacal liquor is added after cooling, control ph and viscosity；5th step：Regulation, barrelling：Process water and auxiliary agent are added in polymer after neutralization, the auxiliary agent includes 8 ㎏ defoamers, 3 ㎏ antistatic additive, 16 ㎏ bleeding agents and 300 ㎏ alcohol, cool to 30 DEG C, content and viscosity are controlled, finally by slurry barrelling Or materials pump is squeezed into finished pot and kept in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711062152.4A CN107700215A (en) | 2017-11-02 | 2017-11-02 | A kind of special-purpose aqueous slurry for polyamide fibre weaving and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711062152.4A CN107700215A (en) | 2017-11-02 | 2017-11-02 | A kind of special-purpose aqueous slurry for polyamide fibre weaving and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107700215A true CN107700215A (en) | 2018-02-16 |
Family
ID=61177586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711062152.4A Pending CN107700215A (en) | 2017-11-02 | 2017-11-02 | A kind of special-purpose aqueous slurry for polyamide fibre weaving and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107700215A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110606911A (en) * | 2019-09-16 | 2019-12-24 | 桐乡市星邦科技发展有限公司 | Water-based sizing agent for all-cotton spinning and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103255620A (en) * | 2013-04-28 | 2013-08-21 | 桐乡市星邦科技发展有限公司 | Formula and production process of chinlon aqueous sizing agent |
| CN105622829A (en) * | 2015-11-17 | 2016-06-01 | 桐乡市星邦科技发展有限公司 | Textile size and preparation method thereof |
| CN105622830A (en) * | 2015-11-17 | 2016-06-01 | 桐乡市星邦科技发展有限公司 | Water-based textile size and preparation method thereof |
-
2017
- 2017-11-02 CN CN201711062152.4A patent/CN107700215A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103255620A (en) * | 2013-04-28 | 2013-08-21 | 桐乡市星邦科技发展有限公司 | Formula and production process of chinlon aqueous sizing agent |
| CN105622829A (en) * | 2015-11-17 | 2016-06-01 | 桐乡市星邦科技发展有限公司 | Textile size and preparation method thereof |
| CN105622830A (en) * | 2015-11-17 | 2016-06-01 | 桐乡市星邦科技发展有限公司 | Water-based textile size and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110606911A (en) * | 2019-09-16 | 2019-12-24 | 桐乡市星邦科技发展有限公司 | Water-based sizing agent for all-cotton spinning and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105622829A (en) | Textile size and preparation method thereof | |
| CN105622830A (en) | Water-based textile size and preparation method thereof | |
| CN107794759A (en) | A kind of anti pilling weaving water paste and preparation method thereof | |
| CN106832106A (en) | A kind of water polyacrylic acid emulsion and preparation method thereof | |
| CN101476246B (en) | Burn-out printing flock fabric and preparation thereof | |
| CN106637975A (en) | Preparation method for textile size | |
| CN103232826B (en) | Heat-stabilized acrylate adhesive used for waterproof coiled material blank base cloth, and preparation method thereof | |
| CN101429727B (en) | Two-component acrylic acid series polymer/montmorillonite nano composite spinning sizing agent and its preparation method | |
| CN105002603A (en) | Super-fine-denier polyester fiber and manufacturing method thereof | |
| CN107488246A (en) | A kind of micro- tertiary acrylate and vinyl acetate emulsion of crosslinking and preparation method and application | |
| CN107700215A (en) | A kind of special-purpose aqueous slurry for polyamide fibre weaving and preparation method thereof | |
| CN107419563A (en) | A kind of polymer overmold dispersible pigment color paste and preparation method thereof | |
| CN107815867A (en) | A kind of water-fastness anti-flaming function spinning coating water paste of Halogen and preparation method thereof | |
| CN104831536B (en) | A kind of formaldehyde-free durable-press finishing method of cellulose base fiber fabric unsaturated carboxylic acid in-situ polymerization crosslinking | |
| CN106283654A (en) | A kind of spinning sizing agent | |
| US20060052018A1 (en) | Vinyl acetate/ethylene and vinyl chloride polymer blends as binders for nonwoven products | |
| CN103233364B (en) | Self-cross-linking type waterborne polyacrylate powder-free base slurry for clothing fusible interlining | |
| CN106245332A (en) | A kind of spinning sizing agent and preparation method thereof | |
| CN102492103A (en) | Tackifying polymer and preparation method thereof | |
| CN111321479B (en) | Preparation method of graphene/polyacrylonitrile spinning solution | |
| CN104693343A (en) | Preparation method of emulsification slurry used for weaving | |
| CN103897107A (en) | Method for preparing paper stiffness agent | |
| CN110606911A (en) | Water-based sizing agent for all-cotton spinning and preparation method thereof | |
| CN109749002B (en) | Application of high-performance quick-drying high-speed water spraying slurry to high-speed water spraying loom | |
| CN106366234A (en) | Acrylate copolymer and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180216 |
|
| RJ01 | Rejection of invention patent application after publication |