CN109749002B - Application of high-performance quick-drying high-speed water spraying slurry to high-speed water spraying loom - Google Patents
Application of high-performance quick-drying high-speed water spraying slurry to high-speed water spraying loom Download PDFInfo
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- CN109749002B CN109749002B CN201910019350.5A CN201910019350A CN109749002B CN 109749002 B CN109749002 B CN 109749002B CN 201910019350 A CN201910019350 A CN 201910019350A CN 109749002 B CN109749002 B CN 109749002B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an application of high-performance quick-drying high-speed water spraying slurry on a high-speed water spraying loom, wherein the preparation method of the slurry comprises the steps of pre-emulsifying, adding 30% of the weight of pre-emulsion, 150 parts of deionized water 130 and 0.1-0.3 part of initiator into a reaction kettle, stirring and heating to 80 ℃, and dropwise adding the rest of pre-emulsion, 40-50 parts of deionized water and 0.2-0.3 part of initiator into the reaction kettle within 1.5h after blue light appears in the reaction kettle; after the dropwise adding, heating to 88 ℃, and preserving the heat for 0.5 h; and (3) cooling the heat-insulated solution to 50 ℃, adding 3-5 parts of ammonia water to ensure that the pH value is 6-7, adding 15-20 parts of absolute ethyl alcohol, and finally discharging. The slurry has high adhesive force, low moisture absorption, re-adhesion, rapid film formation, higher solid content, smooth and wear-resistant film surface and softness; the moisture absorption rate, swelling rate and dissolution rate of the serous membrane are respectively 1.2%, 6% and 1%.
Description
The application is application number: 201710099687.2, filing date: 2017-02-23, entitled "a preparation method of high-performance quick-drying high-speed water spraying slurry".
Technical Field
The invention relates to the technical field of textile printing and dyeing slurry, in particular to high-performance quick-drying high-speed water spraying slurry and a production method thereof.
Background
As a new high-speed shuttleless loom, a water jet loom has been developed rapidly due to the advantages of high-grade weaving products of high weaving efficiency, and the like, and particularly, the water jet loom is heavily developed from weaving filaments to weaving filaments and short fibers in recent ten years. The development of the water-jet loom slurry is promoted, so that a new situation appears in the synthesis process research and product development of the special water-proof slurry for the water-jet loom.
The sizing agent that present hydraulic loom starching used all has certain problem, mainly is: (1) the water spraying slurry is used in an environment with too high humidity, so that the hardness of the water spraying slurry is not enough (2) the water resistance of the slurry is not strong to the yarn when the sizing is to be improved (3), and the sizing bundling performance is limited.
Disclosure of Invention
The invention aims to provide a preparation method of high-performance quick-drying high-speed water spraying slurry with excellent performance and convenient preparation.
The technical solution of the invention is as follows:
a preparation method of high-performance quick-drying high-speed water spraying slurry is characterized by comprising the following steps: comprises the following production steps:
1) pre-emulsification: adding 40-50 parts by weight of deionized water and 4-6 parts by weight of a composite emulsifier into a reaction kettle, then sequentially adding 5-6 parts by weight of styrene, 4-5 parts by weight of methyl methacrylate, 9-10 parts by weight of acrylic acid, 5-6 parts by weight of methacrylic acid, 26-27 parts by weight of methyl acrylate, 9-10 parts by weight of butyl acrylate and 40-50 parts by weight of deionized water, and emulsifying for 30min at a stirring speed of 200r/min and a temperature of 30 ℃; obtaining pre-emulsion;
2) adding 30% of the weight of the pre-emulsion, 150 parts of deionized water 130 and 0.1-0.3 part of the initiator into a reaction kettle, stirring and heating to 80 ℃, and dropwise adding the remaining pre-emulsion, 40-50 parts of deionized water and 0.2-0.3 part of the initiator into the reaction kettle within 1.5h after blue light appears in the reaction kettle; after the dropwise adding, heating to 88 ℃, and preserving the heat for 0.5 h;
3) and (3) cooling the heat-insulated solution to 50 ℃, adding 3-5 parts of ammonia water to ensure that the pH value is 6-7, adding 15-20 parts of absolute ethyl alcohol, and finally discharging.
The emulsifiers selected were OP-10 and 2A1And (4) a compound emulsifier. The emulsifier is OP-10 and 2A1The mass ratio of (A) to (B) is 2.5: 3. The initiator chosen is ammonium persulfate.
The invention has the beneficial effects that: the slurry has high adhesive force, low moisture absorption, re-adhesion and rapid film formation, high solid content, and smooth, wear-resistant and soft film surface; the moisture absorption rate, swelling rate and dissolution rate of the size film are respectively about 1.2%, 6% and 1%, and the size yarn has good bundling property, quick drying property, good wear resistance, certain hardness and high efficiency when used on a high-speed water-jet loom.
The present invention will be further described with reference to the following examples.
Detailed Description
The following emulsifiers are OP-10 and 2A1The production method of the high-performance quick-drying high-speed water spraying slurry is described by adopting a semi-continuous emulsion polymerization method as a specific example, and comprises the following specific production steps:
1) pre-emulsifying, mixing deionized water 40 weight parts and compound emulsifier 5.5 weight parts (OP-102.5 weight parts, 2A weight parts)13 portions) of the raw materials are added into a reaction kettle, and then 6 portions of styrene, 4 portions of methyl acrylate, 9.5 portions of acrylic acid, 5.5 portions of methacrylic acid, 26.5 portions of methyl acrylate, 10 portions of butyl acrylate and 40 portions of deionized water are sequentially added for emulsification for 30min, wherein the stirring speed is 200r/min and the temperature is 30 ℃; obtaining pre-emulsion;
2) adding 30% of the mass of the pre-emulsion, 130 parts of deionized water and 0.1 part of ammonium persulfate into a reaction kettle, stirring and heating to 80 ℃, and after blue light appears in the reaction kettle, dropwise adding the rest of the pre-emulsion, 40 parts of deionized water and 0.2 part of ammonium persulfate into the reaction kettle within 1.5 h. After the dropwise adding, heating to 88 ℃, and preserving the heat for 0.5 h;
3) and (3) cooling the heat-preserved solution to 50 ℃, adding 3 parts of ammonia water to ensure that the pH value is 6-7, adding 15 parts of absolute ethyl alcohol, and finally discharging.
The parts are all parts by weight.
The high-performance quick-drying high-speed terylene water spraying slurry produced by the method is milky white blue liquid, has better water solubility, the solid content of the water spraying slurry reaches about 25 percent, the viscosity (diluted to 3 percent concentration) of the water spraying slurry is 3-5mPa.s, the adhesive force (roving method) of the water spraying slurry is about 200N, and the surface of the film is smooth, wear-resistant and soft; the moisture absorption rate, swelling rate and dissolution rate of the size film are respectively about 1.2%, 6% and 1%, the size yarn has good bundling property, quick drying property, good wear resistance and certain hardness, and the efficiency of the water jet loom can be improved compared with the common water jet size.
Claims (1)
1. The application of the high-performance quick-drying high-speed water spraying slurry on the high-speed water spraying loom is characterized in that: the high-performance quick-drying high-speed water spraying slurry is prepared by the following method:
1) pre-emulsifying, namely mixing 40 parts by weight of deionized water and 5.5 parts by weight of composite emulsifier, wherein the weight parts are OP-102.5 parts and 2A1 3 parts of the raw materials are added into a reaction kettle, and then 6 parts of styrene, 4 parts of methyl methacrylate, 9.5 parts of acrylic acid, 5.5 parts of methacrylic acid, 26.5 parts of methyl acrylate, 10 parts of butyl acrylate and 40 parts of deionized water are sequentially added for emulsification for 30min, wherein the stirring speed is 200r/min and the temperature is 30 ℃; obtaining pre-emulsion;
2) adding 30% of the mass of the pre-emulsion, 130 parts of deionized water and 0.1 part of ammonium persulfate into a reaction kettle, stirring and heating to 80 ℃, and after blue light appears in the reaction kettle, dropwise adding the rest of the pre-emulsion, 40 parts of deionized water and 0.2 part of ammonium persulfate into the reaction kettle within 1.5 h; after the dropwise adding, heating to 88 ℃, and preserving the heat for 0.5 h;
3) cooling the heat-preserved solution to 50 ℃, adding 3 parts of ammonia water to ensure that the pH value is 6-7, then adding 15 parts of absolute ethyl alcohol, and finally discharging;
the parts are all parts by weight;
the prepared high-performance quick-drying high-speed terylene water spraying slurry is milky-white blue-light liquid, the solid content reaches 25%, the viscosity is 3-5mPa.s when the concentration is diluted to 3%, and the adhesive force of a roving method is 200N; the moisture absorption rate, swelling rate and dissolution rate of the serous membrane are respectively 1.2%, 6% and 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910019350.5A CN109749002B (en) | 2017-02-23 | 2017-02-23 | Application of high-performance quick-drying high-speed water spraying slurry to high-speed water spraying loom |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710099687.2A CN106832096B (en) | 2017-02-23 | 2017-02-23 | A kind of high-performance quick-drying high-speed spray slurry preparation method |
| CN201910019350.5A CN109749002B (en) | 2017-02-23 | 2017-02-23 | Application of high-performance quick-drying high-speed water spraying slurry to high-speed water spraying loom |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710099687.2A Division CN106832096B (en) | 2017-02-23 | 2017-02-23 | A kind of high-performance quick-drying high-speed spray slurry preparation method |
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| Publication Number | Publication Date |
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| CN109749002A CN109749002A (en) | 2019-05-14 |
| CN109749002B true CN109749002B (en) | 2021-01-05 |
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| CN201910019350.5A Active CN109749002B (en) | 2017-02-23 | 2017-02-23 | Application of high-performance quick-drying high-speed water spraying slurry to high-speed water spraying loom |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107573455A (en) * | 2017-09-05 | 2018-01-12 | 南通大学 | Slurry for close and distant amphoteric fibers textile starching and preparation method thereof |
| CN113622192A (en) * | 2021-07-09 | 2021-11-09 | 泰兴市兴港医药化工有限公司 | High-speed water-jet loom slurry and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5082896A (en) * | 1989-01-17 | 1992-01-21 | Milliken Research Corporation | Polymeric materials useful for sizing synthetic yarns to be used in water jet weaving |
| CN101050597A (en) * | 2007-05-17 | 2007-10-10 | 太仓市南方纺织粘合剂厂 | Propylene series ester emulsion copolymerized size |
| CN101974851A (en) * | 2010-11-12 | 2011-02-16 | 吴江福华织造有限公司 | Environmental protection pulp for fine denier filament pulp yarn |
| CN102532399A (en) * | 2011-12-10 | 2012-07-04 | 江阴市尼美达助剂有限公司 | Acrylic acid textile size and preparation method thereof |
| CN102787495A (en) * | 2012-07-24 | 2012-11-21 | 苏州市华元化工有限公司 | High-speed terylene water-jetting slurry and production method thereof |
| CN103146107A (en) * | 2013-03-28 | 2013-06-12 | 南通市鸿瑞化工有限公司 | Production method of spray water paste |
| CN103255620A (en) * | 2013-04-28 | 2013-08-21 | 桐乡市星邦科技发展有限公司 | Formula and production process of chinlon aqueous sizing agent |
-
2017
- 2017-02-23 CN CN201710099687.2A patent/CN106832096B/en active Active
- 2017-02-23 CN CN201910019350.5A patent/CN109749002B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5082896A (en) * | 1989-01-17 | 1992-01-21 | Milliken Research Corporation | Polymeric materials useful for sizing synthetic yarns to be used in water jet weaving |
| CN101050597A (en) * | 2007-05-17 | 2007-10-10 | 太仓市南方纺织粘合剂厂 | Propylene series ester emulsion copolymerized size |
| CN101974851A (en) * | 2010-11-12 | 2011-02-16 | 吴江福华织造有限公司 | Environmental protection pulp for fine denier filament pulp yarn |
| CN102532399A (en) * | 2011-12-10 | 2012-07-04 | 江阴市尼美达助剂有限公司 | Acrylic acid textile size and preparation method thereof |
| CN102787495A (en) * | 2012-07-24 | 2012-11-21 | 苏州市华元化工有限公司 | High-speed terylene water-jetting slurry and production method thereof |
| CN103146107A (en) * | 2013-03-28 | 2013-06-12 | 南通市鸿瑞化工有限公司 | Production method of spray water paste |
| CN103255620A (en) * | 2013-04-28 | 2013-08-21 | 桐乡市星邦科技发展有限公司 | Formula and production process of chinlon aqueous sizing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106832096A (en) | 2017-06-13 |
| CN106832096B (en) | 2019-03-05 |
| CN109749002A (en) | 2019-05-14 |
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