CN107699063A - A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property and preparation method thereof - Google Patents
A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property and preparation method thereof Download PDFInfo
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- CN107699063A CN107699063A CN201710832093.8A CN201710832093A CN107699063A CN 107699063 A CN107699063 A CN 107699063A CN 201710832093 A CN201710832093 A CN 201710832093A CN 107699063 A CN107699063 A CN 107699063A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, it is made up of the raw material of following parts by weight:40 ~ 70 parts of fluorocarbon resin, 10 ~ 20 parts of filler auxiliary agent, 50 ~ 80 parts of ethyl acetate, 10 ~ 20 parts of diethylene glycol monobutyl ether, 5 ~ 10 parts of neopentylglycol diglycidyl ether, 1 ~ 3 part of Triallyl isocyanurate, 3 ~ 8 parts of chlorinated paraffin, 1 ~ 3 part of hyper-dispersant.The coating transparency of the present invention is high, daylighting on photovoltaic cell panel is without influence, the wear-resisting antifouling property on photovoltaic cell panel cover glass surface can efficiently be strengthened simultaneously, the reliability and electric power output characteristic of photoelectric cell are kept in the case of long-term is uncleanly, the output of human and material resources is greatly reduced, improves operating efficiency.
Description
Technical field
The present invention relates to photoelectric cell field of material technology, and in particular to a kind of photovoltaic cell panel cover glass high-cooling property
Transparent antifouling paint and preparation method thereof.
Background technology
The available new energy of the mankind mainly has solar energy, geothermal energy, wind energy, ocean energy and nuclear energy etc. at present.Ocean energy
Only specifically side can utilize with geothermal energy.Photovoltaic has aboundresources, energy conversion most compared with other energy
Directly, the advantages that most clean environment firendly, zero-emission, photovoltaic is that disposable transformation efficiency is most in the workable energy at present
Height, use is most simple, most reliable, most economical new energy, therefore photovoltaic power generation technology has obtained quick development and extensive
Using.
Photoelectric cell is a kind of major way of Solar use, and electric energy is converted light energy into based on photovoltaic effect,
The transformation efficiency of photovoltaic cell panel and life-span be an important factor for influenceing photovoltaic development, its characteristic with battery in itself and extraneous
Environmental factor is closely bound up.The monocrystalline silicon and polysilicon photovoltaic cells plate used at present generally can be divided into five layers in structure:It is poly-
Fluoride composite film(TPT), lower floor's ethylene-vinyl acetate copolymer(EVA)Material, cell matrix, upper strata ethene-vinyl acetate
Copolymer material and cover glass, the cover glass of cell panel directly contacts with extraneous environment, while its light transmittance and radiating
Property governs the photoelectric transformation efficiency of battery again, therefore cover glass is the main portions by such environmental effects.
Either in terrestrial environment still in marine environment, one kind including dust, gravel, water stain, salt fog etc.
Or several fouling products on the one hand can be another by reducing the solar irradiation intensity for being projected into cell panel to blocking for cover glass
Aspect can also aggravate the abrasion of photoelectric cell particularly cover glass, abrasion, reduce its reliability and influence electric power output characteristic.
Rational cleaning means can reduce influence of the fouling product to cover glass, peak power output and system operating efficiency is significantly carried
It is high.Traditional cleaning mode mainly using cleaning car or coordinates washing away, wiping clean contaminated photovoltaic cell panel for artificial large area
To realize, it is necessary to expend huge human and material resources.Influence of the temperature for photovoltaic battery panel is significant, and high temperature can cause half
Conductor P-N junction band-gap energy, which declines, causes the valence electron for being capable of transition to become more, produces more electron-hole pairs, causes short circuit
The faint increase of electric current, open-circuit voltage and fill factor, curve factor significantly decline, and so as to cause the decline of electromotive power output, therefore, protect
It is very necessary to hold the preferable thermal diffusivity of cell panel, and the nonpolluting coating mainly used in the prior art often influences glass
The heat dispersion of cover plate, it further have impact on the photoelectric transformation efficiency of battery.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of the transparent antifouling of photovoltaic cell panel cover glass high-cooling property
Coating and preparation method thereof.
The present invention solve the technical scheme that uses of above-mentioned technical problem for:A kind of photovoltaic cell panel cover glass high-cooling property
Transparent antifouling paint, be made up of the raw material of following parts by weight:40 ~ 70 parts of fluorocarbon resin, 10 ~ 20 parts of filler auxiliary agent, acetic acid
50 ~ 80 parts of ethyl ester, 10 ~ 20 parts of diethylene glycol monobutyl ether, 5 ~ 10 parts of neopentylglycol diglycidyl ether, triallyl isocyanuric acid
1 ~ 3 part of ester, 3 ~ 8 parts of chlorinated paraffin, 1 ~ 3 part of hyper-dispersant.
Further, described filler auxiliary agent be the nano titanium oxide of coated with silica, fluorinated graphene and transparent
Powder, its mass parts ratio are 1:1~3:3~7.
Further, the mesh of granularity 800 ~ 1200 of the transparent powder.
Described hyper-dispersant may be selected Disperbyk-163, SOLSPERSE, Disperbyk-2050, Tilo5161,
One or more in the hyper-dispersants such as Disperbyk-2150.
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, including it is following
Step:
(1)Ultrasonic disperse handles 1 ~ 2h after filler auxiliary agent, the ethyl acetate of half volume, hyper-dispersant are mixed, and obtains mixed liquor
One;
(2)By fluorocarbon resin, the ethyl acetate of half volume, diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether and chlorine
Fossil waxes mix, and are heated to 40 ~ 60 DEG C and are incubated 1 ~ 2h of stirring at low speed, obtain mixed liquor two;
(3)By step(1)Obtained mixed liquor liquid one and step(2)Obtain mixed liquor liquid two mixing and high-speed stirred 30 ~
60min, the coating of the present invention is obtained after grinding, filtering.
The coating that the present invention is obtained is coated or is sprayed on photovoltaic cell panel cover glass, for protecting photovoltaic cell panel
Cover glass, strengthen wear-resisting antifouling property.
The characteristics of on fluorocarbon resin molecular structure itself, makes it have excellent hydrophobic and lyophobic property, durability, weatherability etc.
Performance, antifouling capacity is very strong, can slow down dirty and damage for cover glass;Filler auxiliary agent has high transparency, contributes to
Thermal diffusivity, weatherability, corrosion resistance, surface smoothness and the wear-resisting scratch resistance of product are improved, coating hardness of film is significantly increased
Add, while tack and surface self-cleaning greatly improve;The coating transparency of the present invention is high, and the daylighting to photovoltaic cell panel is without shadow
Ring, while can efficiently strengthen the wear-resisting antifouling property on photovoltaic cell panel cover glass surface, in the case of long-term is uncleanly
The reliability and electric power output characteristic of photoelectric cell are kept, the output of human and material resources is greatly reduced, improves operating efficiency.
Embodiment
With reference to specific embodiment, the present invention is described further.
Embodiment 1:A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, by following parts by weight
Raw material forms:55 parts of fluorocarbon resin, 15 parts of filler auxiliary agent, 65 parts of ethyl acetate, 15 parts of diethylene glycol monobutyl ether, neopentyl glycol two
8 parts of glycidol ether, 2 parts of Triallyl isocyanurate, 6 parts of chlorinated paraffin, 2 parts of hyper-dispersant.
Further, described filler auxiliary agent be the nano titanium oxide of coated with silica, fluorinated graphene and transparent
Powder, its mass parts ratio are 1:2:5;The mesh of granularity 800 ~ 1200 of the transparent powder;Described hyper-dispersant is hyper-dispersant
Disperbyk-163。
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, including it is following
Step:
(1)Ultrasonic disperse processing 1.5h, obtains mixed liquor after filler auxiliary agent, the ethyl acetate of half volume, hyper-dispersant are mixed
One;
(2)By fluorocarbon resin, the ethyl acetate of half volume, diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether and chlorine
Fossil waxes mix, and are heated to 50 DEG C and are incubated stirring at low speed 1.5h, obtain mixed liquor two;
(3)By step(1)Obtained mixed liquor liquid one and step(2)The obtained mixing of mixed liquor liquid two and high-speed stirred 45min,
The coating of the present invention is obtained after grinding, filtering.
Embodiment 2:A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, by following parts by weight
Raw material forms:55 parts of fluorocarbon resin, 10 parts of filler auxiliary agent, 50 parts of ethyl acetate, 10 parts of diethylene glycol monobutyl ether, neopentyl glycol two
5 parts of glycidol ether, 1 part of Triallyl isocyanurate, 3 parts of chlorinated paraffin, 1 part of hyper-dispersant.
Further, described filler auxiliary agent be the nano titanium oxide of coated with silica, fluorinated graphene and transparent
Powder, its mass parts ratio are 1: 3: 7;The mesh of granularity 800 ~ 1200 of the transparent powder;Described hyper-dispersant is hyper-dispersant
SOLSPERSE。
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, including it is following
Step:
(1)Ultrasonic disperse processing 1h, obtains mixed liquor one after filler auxiliary agent, the ethyl acetate of half volume, hyper-dispersant are mixed;
(2)By fluorocarbon resin, the ethyl acetate of half volume, diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether and chlorine
Fossil waxes mix, and are heated to 60 DEG C and are incubated stirring at low speed 1h, obtain mixed liquor two;
(3)By step(1)Obtained mixed liquor liquid one and step(2)The obtained mixing of mixed liquor liquid two and high-speed stirred 30min,
The coating of the present invention is obtained after grinding, filtering.
Embodiment 3:A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, by following parts by weight
Raw material forms:55 parts of fluorocarbon resin, 20 parts of filler auxiliary agent, 80 parts of ethyl acetate, 20 parts of diethylene glycol monobutyl ether, neopentyl glycol two
10 parts of glycidol ether, 3 parts of Triallyl isocyanurate, 8 parts of chlorinated paraffin, 3 parts of hyper-dispersant.
Further, described filler auxiliary agent be the nano titanium oxide of coated with silica, fluorinated graphene and transparent
Powder, its mass parts ratio are 1:1:3;The mesh of granularity 800 ~ 1200 of the transparent powder;Described hyper-dispersant is hyper-dispersant
Tilo5161。
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, including it is following
Step:
(1)Ultrasonic disperse processing 2h, obtains mixed liquor one after filler auxiliary agent, the ethyl acetate of half volume, hyper-dispersant are mixed;
(2)By fluorocarbon resin, the ethyl acetate of half volume, diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether and chlorine
Fossil waxes mix, and are heated to 40 DEG C and are incubated stirring at low speed 2h, obtain mixed liquor two;
(3)By step(1)Obtained mixed liquor liquid one and step(2)The obtained mixing of mixed liquor liquid two and high-speed stirred 60min,
The coating of the present invention is obtained after grinding, filtering.
Embodiment 4:A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, by following parts by weight
Raw material forms:70 parts of fluorocarbon resin, 10 parts of filler auxiliary agent, 80 parts of ethyl acetate, 10 parts of diethylene glycol monobutyl ether, neopentyl glycol two
10 parts of glycidol ether, 3 parts of Triallyl isocyanurate, 3 parts of chlorinated paraffin, 3 parts of hyper-dispersant.
Further, described filler auxiliary agent be the nano titanium oxide of coated with silica, fluorinated graphene and transparent
Powder, its mass parts ratio are 1: 3:3;The mesh of granularity 800 ~ 1200 of the transparent powder;Described hyper-dispersant is hyper-dispersant
Disperbyk-163 and Tilo5161.
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, its specific step
Suddenly with embodiment 1.
Embodiment 5:A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, by following parts by weight
Raw material forms:50 parts of fluorocarbon resin, 18 parts of filler auxiliary agent, 70 parts of ethyl acetate, 12 parts of diethylene glycol monobutyl ether, neopentyl glycol two
6 parts of glycidol ether, 2 parts of Triallyl isocyanurate, 6 parts of chlorinated paraffin, 2 parts of hyper-dispersant.
Further, described filler auxiliary agent be the nano titanium oxide of coated with silica, fluorinated graphene and transparent
Powder, its mass parts ratio are 2:5:9;The mesh of granularity 800 ~ 1200 of the transparent powder;Described hyper-dispersant is hyper-dispersant
Disperbyk-2150。
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, its specific step
Suddenly with embodiment 1.
The coating that above-described embodiment 1-5 is obtained is coated or is sprayed on photovoltaic cell panel cover glass, for protecting light
Electric cell panel cover glass, strengthens wear-resisting antifouling property.
Comparative example 1:A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, by following parts by weight
Raw material forms:45 parts of fluorocarbon resin, 65 parts of ethyl acetate, 15 parts of diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether 8
Part, 2 parts of Triallyl isocyanurate, 6 parts of chlorinated paraffin, 2 parts of hyper-dispersant.
Further, the mesh of granularity 800 ~ 1200 of the transparent powder;Described hyper-dispersant is hyper-dispersant
Disperbyk-163。
A kind of preparation method of the transparent antifouling paint of described photovoltaic cell panel cover glass high-cooling property, including it is following
Step:
(1)Ultrasonic disperse processing 1.5h, obtains mixed liquor one after the ethyl acetate of half volume, hyper-dispersant are mixed;
(2)By fluorocarbon resin, the ethyl acetate of half volume, diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether and chlorine
Fossil waxes mix, and are heated to 50 DEG C and are incubated stirring at low speed 1.5h, obtain mixed liquor two;
(3)By step(1)Obtained mixed liquor liquid one and step(2)The obtained mixing of mixed liquor liquid two and high-speed stirred 45min,
The coating of the present invention is obtained after grinding, filtering.
The coating that above-described embodiment 1-5 and comparative example 1 are obtained carries out performance test, in addition, the fluorine that in the market is commonly used
Carbon resin coating 2 does identical performance test as a comparison case, as a result as shown in the table.
Specifically, on the plate glass cover plate for being 100mm × 100mm × 10mm coated on specification by obtained coating
Face.According to the average thickness of GB/T 13452.2-2008 mark testing coating, carried out according to GB/T 9286-1998 mark
The test of adhesive force, the static contact angle of specimen surface and distilled water is measured using contact angle instrument(The μ L of droplet size 4), press
According to the measurement request of ultraviolet specrophotometer translucency, obtained result such as following table institute are determined by reference of uncoated cover glass
Show.
Average thickness/μm | Adhesive force/level | Water contact angle/° | Light transmittance/% | |
Embodiment 1 | 15.6 | 0 | 148 | 85 |
Embodiment 2 | 16.1 | 0 | 139 | 87 |
Embodiment 3 | 15.5 | 0 | 150 | 82 |
Embodiment 4 | 16.7 | 0 | 142 | 84 |
Embodiment 5 | 16.3 | 0 | 147 | 84 |
Comparative example 1 | 16.0 | 1 | 101 | 85 |
Comparative example 2 | 15.8 | 1 | 97 | 86 |
Coating and comparative example 2 that above-described embodiment 1-5 and comparative example 1 are obtained are carried out to the test of thermal diffusivity, 10 μm of left sides
Right coating layer thickness is under the irradiation of artificial light sources, embodiment 1-5 coating cover glass temperature change and uncoated cover glass
Temperature change alternately rises to balance, without obvious difference, the coating cover glass temperature change of comparative example 1 and comparative example 2
Apparently higher than uncoated cover glass.
Test result shows that the present invention is a kind of with excellent thermal diffusivity, hydrophobic and lyophobic property, tack and the transparency
Protective coating material, antifouling heat-sinking capability is very strong, can effectively slow down dirty and damage for cover glass.In above-described embodiment
Performance test has only been carried out as a comparison case to the combination without filler auxiliary agent, divided likewise, other raw materials omit
Analysis also shows certain influence to performance test results.
It should be pointed out that the preferred embodiment of the present invention is the foregoing is only, for the ordinary skill people of the art
For member, some improvements and modifications for being made under the premise without departing from the principles of the invention, it also will be regarded as the present invention and covered
Protection domain.
Claims (5)
1. a kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property, it is characterised in that by following parts by weight
Raw material composition:40 ~ 70 parts of fluorocarbon resin, 10 ~ 20 parts of filler auxiliary agent, 50 ~ 80 parts of ethyl acetate, diethylene glycol monobutyl ether 10 ~
20 parts, it is 5 ~ 10 parts of neopentylglycol diglycidyl ether, 1 ~ 3 part of Triallyl isocyanurate, 3 ~ 8 parts of chlorinated paraffin, ultra-dispersed
1 ~ 3 part of agent.
2. according to a kind of transparent antifouling paint of the above-mentioned photovoltaic cell panel cover glass high-cooling property of claim 1, its feature
It is:It is made up of the raw material of following parts by weight:55 parts of fluorocarbon resin, 15 parts of filler auxiliary agent, 65 parts of ethyl acetate, diethylene glycol
15 parts of monobutyl ether, 8 parts of neopentylglycol diglycidyl ether, 2 parts of Triallyl isocyanurate, 6 parts of chlorinated paraffin, hyper-dispersant
2 parts.
3. according to a kind of transparent antifouling paint of the above-mentioned photovoltaic cell panel cover glass high-cooling property of claim 1 or 2, it is special
Sign is:Described filler auxiliary agent be coated with silica nano titanium oxide, fluorinated graphene and transparent powder, its mass parts
Than for 1:1~3:3~7.
4. according to a kind of transparent antifouling paint of the above-mentioned photovoltaic cell panel cover glass high-cooling property of claim 1 or 2, it is special
Sign is:The mesh of granularity 800 ~ 1200 of the transparent powder.
A kind of 5. preparation side of the transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property described in claim 1 or 2
Method, it is characterised in that comprise the following steps:
(1)Ultrasonic disperse handles 1 ~ 2h after filler auxiliary agent, the ethyl acetate of half volume, hyper-dispersant are mixed, and obtains mixed liquor
One;
(2)By fluorocarbon resin, the ethyl acetate of half volume, diethylene glycol monobutyl ether, neopentylglycol diglycidyl ether and chlorine
Fossil waxes mix, and are heated to 40 ~ 60 DEG C and are incubated 1 ~ 2h of stirring at low speed, obtain mixed liquor two;
(3)By step(1)Obtained mixed liquor liquid one and step(2)Obtain mixed liquor liquid two mixing and high-speed stirred 30 ~
60min, the coating of the present invention is obtained after grinding, filtering.
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CN201710832093.8A CN107699063A (en) | 2017-09-15 | 2017-09-15 | A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property and preparation method thereof |
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CN201710832093.8A CN107699063A (en) | 2017-09-15 | 2017-09-15 | A kind of transparent antifouling paint of photovoltaic cell panel cover glass high-cooling property and preparation method thereof |
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Citations (3)
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CN1791635A (en) * | 2003-05-15 | 2006-06-21 | 捷时雅股份有限公司 | Liquid resin composition, cured film and laminate |
CN105484390A (en) * | 2015-12-10 | 2016-04-13 | 尚高建材(长沙)有限公司 | Thermal insulation glass wall |
CN106905807A (en) * | 2015-12-22 | 2017-06-30 | 北京奥托米特电子有限公司 | Transparent hydrophobic oleophobic functional paint and its transparent hydrophobic oleophobic functional coating of formation |
-
2017
- 2017-09-15 CN CN201710832093.8A patent/CN107699063A/en not_active Withdrawn
Patent Citations (3)
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---|---|---|---|---|
CN1791635A (en) * | 2003-05-15 | 2006-06-21 | 捷时雅股份有限公司 | Liquid resin composition, cured film and laminate |
CN105484390A (en) * | 2015-12-10 | 2016-04-13 | 尚高建材(长沙)有限公司 | Thermal insulation glass wall |
CN106905807A (en) * | 2015-12-22 | 2017-06-30 | 北京奥托米特电子有限公司 | Transparent hydrophobic oleophobic functional paint and its transparent hydrophobic oleophobic functional coating of formation |
Non-Patent Citations (3)
Title |
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MIN ZHANG等: "Two-dimensional transparent hydrophobic coating", 《CARBON》 * |
薛峰峰等: "氟化石墨烯性能及其研究进展", 《河南化工》 * |
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Application publication date: 20180216 |