CN107694329A - A kind of suspended state photochemical catalyst removes the device and its processing method of organic exhaust gas - Google Patents

A kind of suspended state photochemical catalyst removes the device and its processing method of organic exhaust gas Download PDF

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Publication number
CN107694329A
CN107694329A CN201710889405.9A CN201710889405A CN107694329A CN 107694329 A CN107694329 A CN 107694329A CN 201710889405 A CN201710889405 A CN 201710889405A CN 107694329 A CN107694329 A CN 107694329A
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CN
China
Prior art keywords
reactor
gas
exhaust gas
organic exhaust
photochemical catalyst
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Pending
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CN201710889405.9A
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Chinese (zh)
Inventor
陈金媛
魏秀珍
何军辉
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Zhejiang University of Technology ZJUT
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Zhejiang University of Technology ZJUT
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Priority to CN201710889405.9A priority Critical patent/CN107694329A/en
Publication of CN107694329A publication Critical patent/CN107694329A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light

Abstract

A kind of suspended state photochemical catalyst removes the device and its processing method of organic exhaust gas, including for being passed through the inlet duct of pending organic exhaust gas, the reactor for being catalyzed organic exhaust gas fractions, the ultraviolet irradiation device for providing ultraviolet light, the exhaust apparatus for the cooling back installation that is cooled to reactor and for discharging innocuous gas;Reactor bottom is equipped with the catalyst of the organic exhaust gas for being catalyzed;The ultraviolet irradiation device and exhaust apparatus are installed and penetrated in the top of reactor;Cooling back installation is covered in the outside of reactor, and inlet, the liquid outlet of cooling back installation store the equipment pipeline connection of coolant with the external world respectively;Processing method includes:The tail gas that can be discharged into air is changed into after the light-catalysed reaction of catalyst and ultraviolet light of the organic exhaust gas being introduced into reactor by suspension.The beneficial effects of the invention are as follows:Apparatus structure is simple, and photochemical catalyst need not be modified, and greatly reduces catalyst cost.

Description

A kind of suspended state photochemical catalyst removes the device and its processing method of organic exhaust gas
Technical field
The present invention relates to the device and its processing method that a kind of suspended state photochemical catalyst removes organic exhaust gas, belong to organic waste Gas purification techniques field.
Background technology
Developed rapidly as society is industrialized, problem of environmental pollution is increasingly shown especially, seeks a kind of environment of economical and efficient Treatment process is extremely urgent, by the irradiation can of uviol lamp to air under optically catalytic TiO 2 technology normal temperature and pressure Or the pollutant in water is degraded, non-secondary pollution, treatment effeciency is high, and catalyst is cheap and easy to get, stable performance, by Gradually turn into a kind of preferably environmental improvement technology and paid close attention to by domestic and international researcher.And reactor is then photocatalysis technology Core, its structure directly determines the effect of photocatalysis treatment pollutant.How to design and improve photo catalysis reactor with It is the problem of researcher extremely pays close attention to improve light-catalyzed reaction efficiency.
Improved at present in research and be directed to the load technology, element doping, noble metal of photochemical catalyst photocatalysis efficiency more and sink The research of product etc..This requires the carrier material of photochemical catalyst to have preferable photopermeability, chemical stability, higher Mechanical strength, larger specific surface area etc.;Although the doping of rare earth element and the deposition of noble metal can improve photocatalysis efficiency, But considerably increase economic input.Therefore, photo catalysis reactor structure is improved so that photochemical catalyst is mixed without load, element Miscellaneous and noble metal loading, it is possible to participate in light-catalyzed reaction and raising catalytic efficiency is necessary.
The content of the invention
The present invention needs to be loaded for traditional light-catalyzed reaction photochemical catalyst or rare element doping, noble metal loading The methods of it is complicated, economic input is higher the shortcomings that, there is provided a kind of photochemical catalyst removes the suspended state of organic exhaust gas in suspended state Photochemical catalyst removes the device and its processing method of organic exhaust gas.
A kind of suspended state photochemical catalyst of the present invention removes the device of organic exhaust gas, it is characterised in that:Including for It is passed through the inlet duct of pending organic exhaust gas, the reactor for being catalyzed organic exhaust gas fractions, for providing ultraviolet light Ultraviolet irradiation device, filled with the exhaust for discharging innocuous gas for the cooling back installation that is cooled to reactor Put, the air inlet of the inlet duct connects with the pipeline gas outlet of extraneous logical organic exhaust gas, the gas outlet of the inlet duct It is passed through in the reactor;The reactor bottom is equipped with the catalyst for being used for being catalyzed organic exhaust gas;The top of the reactor The ultraviolet irradiation device and the exhaust apparatus are installed, and the ultraviolet light of ultraviolet irradiation device transmitting is entirely anti- Device inner chamber is answered, the organic exhaust gas and catalyst to reactor inner chamber carry out ultraviolet light;The cooling back installation is covered in The outside of the reactor, and the inlet of the cooling back installation, liquid outlet store setting for coolant with extraneous respectively Standby pipeline connection;
The inlet duct includes air induction conduit and filter, the air inlet of the air induction conduit and pending organic waste The air supply pipe connection of gas, and it is furnished with the air inlet control for being used for gas flow in control pipe at the air inlet of the air induction conduit Valve, the reactor inner chamber is stretched into the gas outlet of the air induction conduit, and assembles first filter in its gas outlet end;
The reactor includes being used to provide the reactor body of reacting environment, the electronic horse for providing rotary driving force Reach and the stirring blades for making catalyst suspend, the reactor body are divided into being divided into from top to bottom the peace on top Fill section, the conversion zone at middle part and the catalytic section of bottom, the tapered top formed for installing closure in construction section upper end Installing port, the top installing port of the construction section fill in the top rubber plug for sealing;The conversion zone is cylinder cartridge type knot Structure, the catalytic section are inverted round stage structure, and the bottom of the catalytic section is filled in for sealing reactor body bottom installing port Bottom rubber stopper, the inner surface of the bottom rubber stopper are laid for realizing the light-catalysed photochemical catalyst of organic exhaust gas;The electricity Dynamic motor seal is inlaid on the bottom rubber stopper, and the output shaft of the electro-motor is arranged in urging for reactor inner chamber Change section, the output the tip of the axis is furnished with stirring blades, and under photochemical catalyst static condition, stirring blades are located at directly over it;
The ultraviolet irradiation device includes lamp socket, uviol lamp and ballast, and the lamp socket sealing is inlaid in the top On rubber stopper, and the part for being used to install uviol lamp of the lamp socket, the part for connecting ballast falls outside reactor Portion;The uviol lamp is arranged on the installation portion that the lamp is located in reactor inner chamber, and the control lead of the ballast is with falling Lamp socket lead outside reactor is electrically connected, and realizes the control to uviol lamp;
The exhaust apparatus includes two blast pipes, filtered with the one-to-one gas exhausting valve of blast pipe and second Device, the exhaust seal of tube runs through the top rubber plug, and the bottom inflow end of the blast pipe is furnished with the second filter, The top outlet side of the blast pipe is discharged into ambient atmosphere after importing same root exhaust main, wherein, it is corresponding on every blast pipe Installation one is used for the gas exhausting valve for controlling gas alternately to discharge;
The cooling back installation is coated on the conversion zone outer wall of the reactor body, and inlet, liquid outlet point The equipment pipeline connection of coolant is not stored with the external world.
The lamp socket is insulating ceramics lamp socket, falls the upper end outside reactor and is provided with the wiring card for being used for connecting ballast Groove, the lower end for being placed in inside reactor are provided with the screw socket for being used for installing uviol lamp, and the air induction conduit and the blast pipe Divide the relative both sides for being listed in the lamp socket.
The uviol lamp along reactor axis to being vertically mounted on the reactor inner chamber, and uviol lamp through whole anti- Answer the conversion zone of device.
Described uviol lamp is 125W, dominant wavelength 365nm.
The photochemical catalyst is titanium dioxide.
The air inlet of the air induction conduit extends to the conversion zone bottom of reactor.
The exhaust apparatus includes two blast pipes, filtered with the one-to-one gas exhausting valve of blast pipe and second Device, the outlet side of every blast pipe are furnished with a gas exhausting valve, and the air inlet of the blast pipe falls after top rubber plug In construction section, and second filter is configured at the air inlet of every blast pipe, the gas exhausting valve is staggered the time unlatching
, form interactive outlet system.
Described reactor body is quartz glass, reacts segment length 200mm, internal diameter 95mm, catalytic section top internal diameter 95mm, Bottom internal diameter 30mm, high 70mm.
Described first filter is the stainless (steel) wire of national standard 304 of 250 mesh, and the second filter is the nylon wire of 500 mesh.
Described electro-motor is direct-current electric motor of the F130 types with stirring blades.
Organic exhaust gas is removed using a kind of suspended state photochemical catalyst described in claim 1~9 any one claim Device carry out processing method, comprise the following steps:
1) pending volatile organic waste gas is imported in reactor by air induction conduit, until air quilt in reactor Cement out completely;
2) electro-motor of reactor bottom is opened, the regulating and controlling voltage stirring blades that electro-motor is accessed by adjusting turn Speed, that is, wind-force size is controlled, make photochemical catalyst that suspended state be presented and contacted with volatile organic waste gas;
3) while step 2) is carried out, the switch and ultraviolet irradiation device of cooling back installation are opened, in uviol lamp Irradiation under, volatile organic waste gas is converted into innoxious material through photocatalysis;
4) photochemical catalyst is retained by the second filter, the exhaust apparatus by the tail gas that step 3) obtains from alternately unlatching Discharge.
The beneficial effects of the invention are as follows:Make titanium dioxide optical catalyst that suspended state, device be presented using the perturbation of air-flow Simple in construction, photochemical catalyst need not be modified, and greatly reduce catalyst cost, and the device is than traditional photocatalysis apparatus The stability of catalyst load is needed not worry about, improves catalyst and VOCs contacts area, promotes the progress of reaction, is adapted to Industrial organic exhaust gas administers promoting the use of for industry..
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
Embodiment
The present invention is further illustrated below in conjunction with the accompanying drawings
Referring to the drawings:
A kind of suspended state photochemical catalyst of the present invention of embodiment 1 removes the device of organic exhaust gas, including for being passed through The inlet duct 1 of pending organic exhaust gas, the reactor 2 for being catalyzed organic exhaust gas fractions, for providing ultraviolet light Ultraviolet irradiation device 3, the exhaust apparatus for the cooling back installation 4 that is cooled to reactor and for discharging innocuous gas 5, the air inlet of the inlet duct 1 connects with the pipeline gas outlet of extraneous logical organic exhaust gas, the gas outlet of the inlet duct 1 It is passed through the inner chamber of reactor 2;The bottom of reactor 2 is equipped with the photochemical catalyst for being used for being catalyzed organic exhaust gas;The reactor 2 Top the ultraviolet irradiation device 3 and the exhaust apparatus 5, and the ultraviolet light that the ultraviolet irradiation device 3 is launched are installed The whole inner chamber of reactor 2 is irradiated, the organic exhaust gas and catalyst to the inner chamber of reactor 2 carry out ultraviolet light;The circulation is cold But device 4 is covered in the outside of the reactor 2, and the inlet of the cooling back installation 4, liquid outlet respectively with the external world Store the equipment pipeline connection of coolant;
The inlet duct 1 includes air induction conduit 11 and first filter 12, the air inlet of the air induction conduit 11 with The air supply pipe connection of pending organic exhaust gas, and be furnished with the air inlet of the air induction conduit 11 and be used for gas stream in control pipe The inner chamber of reactor 2 is stretched into the air inlet control valve 13 of amount, the gas outlet of the air induction conduit 11, and at its gas outlet end End assembling first filter 12;
The reactor 2 includes being used to provide the reactor body 21 of reacting environment, the electricity for providing rotary driving force Dynamic motor 22 and the stirring blades 23 for making catalyst 24 suspend, the reactor body 21 are divided into drawing from top to bottom It is divided into the catalytic section of the construction section on top, the conversion zone at middle part and bottom, the construction section upper end is tapered to be formed for installing The top installing port of closure, the top installing port of the construction section fill in the top rubber plug 211 for sealing;The reaction Section is cylinder cylindrical structure, and the catalytic section is inverted round stage structure, and the bottom of the catalytic section is filled in for sealing reactor sheet The bottom rubber stopper 212 of body bottom installing port, the inner surface of the bottom rubber stopper 212 are laid for realizing that organic exhaust gas light is urged The photochemical catalyst 24 of change;The sealing of electro-motor 22 is inlaid in the center of bottom rubber stopper 212, and the electro-motor 22 output shaft is arranged in the catalytic section of the inner chamber of reactor 2, and the output the tip of the axis is furnished with stirring blades 23, in photochemical catalyst Under 24 static conditions, stirring blades 23 are located at directly over it;
The ultraviolet irradiation device 3 includes lamp socket 31, uviol lamp 32 and ballast 33, and the sealing of lamp socket 31 is inlaid in The top rubber plug center, and the part for being used to install uviol lamp 32 of the lamp socket 31, for connecting ballast 33 Part falls outside reactor 2;The uviol lamp peace 32 falls the installation portion in reactor inner chamber, the town mounted in the lamp socket 31 The control lead of stream device 33 is electrically connected with falling the lead of lamp socket 31 outside reactor, realizes the control to uviol lamp;
The exhaust apparatus 5 includes two blast pipes 51 and the one-to-one gas exhausting valve 52 and second of blast pipe Filter 53, the sealing of blast pipe 51 runs through the top rubber plug 211, and the bottom inflow end of the blast pipe 51 is matched somebody with somebody There is the second filter 53, ambient atmosphere is discharged into after the top outlet side remittance same root exhaust main of the blast pipe 51, wherein, Corresponding installation one is used for the gas exhausting valve 52 for controlling gas alternately to discharge on every blast pipe 51;
The cooling back installation 4 is coated on the conversion zone outer wall of the reactor body 21, and inlet, liquid outlet The equipment pipeline connection of coolant is stored with the external world respectively.
The lamp socket 31 is insulating ceramics lamp socket, falls the upper end outside reactor and is provided with the wiring for being used for connecting ballast Neck, the lower end for being placed in inside reactor are provided with the screw socket for being used for installing uviol lamp, and the air induction conduit and the exhaust Pipe point is listed in the relative both sides of the lamp socket.
The uviol lamp 32 along reactor axis to being vertically mounted on the reactor inner chamber, and uviol lamp through whole The conversion zone of reactor.
Described uviol lamp 32 is 125W, dominant wavelength 365nm.
The photochemical catalyst 24 is titanium dioxide.
The air inlet of the air induction conduit 11 extends to the conversion zone bottom of reactor.
The exhaust apparatus 5 includes two blast pipes 51 and the one-to-one gas exhausting valve 52 and second of blast pipe Filter 53, the outlet side of every blast pipe are furnished with a gas exhausting valve, and the air inlet of the blast pipe runs through top rubber Fall after plug in construction section, and second filter is configured at the air inlet of every blast pipe, the gas exhausting valve is staggered the time Open, form interactive outlet system.
Described reactor body is quartz glass, reacts segment length 200mm, internal diameter 95mm, catalytic section top internal diameter 95mm, Bottom internal diameter 30mm, high 70mm.
Described first filter is the stainless (steel) wire of national standard 304 of 250 mesh, and the second filter is the nylon wire of 500 mesh.
Described electro-motor is direct-current electric motor of the F130 types with stirring blades.
Processing technological flow is that the pending gas containing dichloromethane is imported reactor 2 by air induction conduit 11, first Ventilation a period of time so that air is completely displaced in reactor 2, then opens the electro-motor 22 of reactor bottom, By adjusting the controllable rotating speed of stirring blades 23 of voltage, that is, wind-force size is controlled, photochemical catalyst 24 (i.e. titanium dioxide) is presented Suspended state and with dichloromethane exhaust gas contact.Meanwhile open the switch of cooling back installation 4, under the irradiation of uviol lamp 32, light The surface of catalyst 24 produces electronics (e-)-hole (h+) right, the oxygen and water oxygen that adsorb on surface are melted into superoxide anion and hydroxyl Free radical, these active materials have stronger oxidisability, dichloromethane can be oxidized to final product CO2And H2O, and Other a small amount of chlorine-containing compounds etc., by the second filter by photochemical catalyst 24 (i.e. titanium dioxide) retention, tail gas is from exhaust Device 5 is discharged.
The structural parameters of the reactor of embodiment 2:React segment length 200mm, internal diameter 95mm, the top of top rubber plug and construction section Portion's installing port is sealed by polytetrafluoroethylene (PTFE) degreasing raw material band, and inleakage is less than 1%;Catalytic section top internal diameter 95mm, bottom End internal diameter 30mm, high 70mm, bottom are fixed with the electro-motor with stirring blades, voltage 1.5-6V direct currents, and lower end carries out close Envelope;Uviol lamp long 110mm, external diameter 28mm, gas are discharged by filter B 16.
Experiment condition is:
Gas flow:0.5m3/ h, carrier gas are air;
Uviol lamp parameter:Power 125W, dominant wavelength 365nm;
Experimental result is as shown in table 1.
The dichloromethane removal effect of table 1
Embodiment 3
Reference picture 1:A kind of suspended state photochemical catalyst removes the device of organic exhaust gas, and processing technological flow is pending Gas containing dichloromethane imports reactor 2 by air induction conduit 11, first ventilation a period of time so that air quilt in reactor 2 Cement out completely, then open the electro-motor 22 of reactor bottom, by adjusting the controllable rotating speed of stirring blades 23 of voltage, I.e. control wind-force size, make titanium deoxide catalyst present suspended state and with dichloromethane exhaust gas contact.Meanwhile it is cold to open circulation But the switch of device 4, under the irradiation of uviol lamp 32, the surface of photochemical catalyst 24 produces electronics (e-)-hole (h+) right, it will adsorb Oxygen and water oxygen on surface, which are melted into superoxide anion and hydroxyl radical free radical, these active materials, has stronger oxidisability, can Dichloromethane is oxidized to final product CO2And H2O, and other a small amount of chlorine-containing compounds etc., by the second filter by two Titanium oxide is retained, and tail gas is discharged from exhaust apparatus 5.
Experimental provision structure is as shown in Figure 1.The structural parameters of reactor:React segment length 200mm, internal diameter 95mm, top rubber The top installing port of plug and construction section is sealed by polytetrafluoroethylene (PTFE) degreasing raw material band, and inleakage is less than 1%;Catalytic section Top internal diameter 95mm, bottom internal diameter 30mm, high 70mm, bottom are fixed with the electro-motor with stirring blades, and voltage 1.5-6V is straight Stream electricity, lower end is sealed;Uviol lamp long 110mm, external diameter 28mm, gas are discharged by the second filter.
Experiment condition is:
Gas flow:0.5m3/ h, carrier gas are air;
Uviol lamp parameter:Power 125W, dominant wavelength 365nm;
Experimental result is as shown in table 2.
The dichloromethane removal effect of table 2
Content described in this specification embodiment is only enumerating to the way of realization of inventive concept, protection of the invention Scope is not construed as being only limitted to the concrete form that embodiment is stated, protection scope of the present invention also includes art technology Personnel according to present inventive concept it is conceivable that equivalent technologies mean.

Claims (9)

1. a kind of suspended state photochemical catalyst removes the device of organic exhaust gas, it is characterised in that:Including pending organic for being passed through The inlet duct of waste gas, the reactor for being catalyzed organic exhaust gas fractions, the ultraviolet irradiation device for providing ultraviolet light, Exhaust apparatus for the cooling back installation to be cooled to reactor and for discharging innocuous gas, the inlet duct Air inlet is connected with the pipeline gas outlet of extraneous logical organic exhaust gas, and the gas outlet of the inlet duct is passed through in the reactor; The reactor bottom is equipped with the catalyst for being used for being catalyzed organic exhaust gas;The top of the reactor is installed by the ultraviolet irradiation dress Put with the exhaust apparatus, and the ultraviolet irradiation device transmitting the whole reactor inner chamber of ultraviolet light, to reactor The organic exhaust gas and catalyst of inner chamber carry out ultraviolet light;The cooling back installation is covered in the outside of the reactor, And inlet, the liquid outlet of the cooling back installation store the equipment pipeline connection of coolant with the external world respectively;
The inlet duct includes air induction conduit and filter, the air inlet of the air induction conduit and pending organic exhaust gas Air supply pipe connects, and is furnished with the air inlet control valve for being used for gas flow in control pipe at the air inlet of the air induction conduit, The reactor inner chamber is stretched into the gas outlet of the air induction conduit, and assembles first filter in its gas outlet end;
The reactor include be used for provide reacting environment reactor body, for the electro-motor of rotary driving force is provided with And the stirring blades for making catalyst suspend, the reactor body are divided into being divided into from top to bottom the installation on top Section, the conversion zone at middle part and the catalytic section of bottom, the tapered top formed for installing closure in the construction section upper end are pacified Mouth is filled, the top installing port of the construction section fills in the top rubber plug for sealing;The conversion zone is cylinder cylindrical structure, The catalytic section is inverted round stage structure, and the bottom for sealing reactor body bottom installing port is filled in the bottom of the catalytic section Rubber stopper, the inner surface of the bottom rubber stopper are laid for realizing the light-catalysed photochemical catalyst of organic exhaust gas;The electronic horse It is inlaid in up to sealing on the bottom rubber stopper, and the output shaft of the electro-motor is arranged in the catalysis of reactor inner chamber Section, the output the tip of the axis are furnished with stirring blades, and under photochemical catalyst static condition, stirring blades are located at directly over it;
The ultraviolet irradiation device includes lamp socket, uviol lamp and ballast, and the lamp socket sealing is inlaid in the top rubber Beyond the Great Wall, and the lamp socket be used for the part of uviol lamp is installed, the part for connecting ballast falls outside reactor;Institute The installation portion that uviol lamp is located in reactor inner chamber installed in the lamp is stated, the control lead of the ballast is with falling in reactor Outside lamp socket lead is electrically connected, and realizes the control to uviol lamp;
The exhaust apparatus includes two blast pipes and the one-to-one gas exhausting valve of blast pipe and the second filter, institute State the exhaust seal of tube and run through the top rubber plug, and the bottom inflow end of the blast pipe is furnished with the second filter, it is described The top outlet side of blast pipe is discharged into ambient atmosphere after importing same root exhaust main, wherein, corresponding installation on every blast pipe One gas exhausting valve for being used to control gas alternately to discharge;
The cooling back installation is coated on the conversion zone outer wall of the reactor body, and inlet, liquid outlet respectively with The equipment pipeline connection of external world's storage coolant.
2. a kind of suspended state photochemical catalyst as claimed in claim 1 removes the device of organic exhaust gas, it is characterised in that:The lamp Seat is insulating ceramics lamp socket, falls the upper end outside reactor and is provided with the wiring neck for being used for connecting ballast, is placed in reactor Internal lower end is provided with the screw socket for being used for installing uviol lamp, and the air induction conduit and the blast pipe point are listed in the lamp socket Relative both sides.
3. a kind of suspended state photochemical catalyst as claimed in claim 2 removes the device of organic exhaust gas, it is characterised in that:The purple Outer lamp is along reactor axis to being vertically mounted on the reactor inner chamber, and the conversion zone through whole reactor of uviol lamp; Described uviol lamp is 125W, dominant wavelength 365nm.
4. a kind of suspended state photochemical catalyst as claimed in claim 1 removes the device of organic exhaust gas, it is characterised in that:The light Catalyst is titanium dioxide.
5. a kind of suspended state photochemical catalyst as claimed in claim 1 removes the device of organic exhaust gas, it is characterised in that:It is described enter The air inlet of airway extends to the conversion zone bottom of reactor.
6. a kind of suspended state photochemical catalyst as claimed in claim 1 removes the device of organic exhaust gas, it is characterised in that:The row Device of air include two blast pipes, with the one-to-one gas exhausting valve of blast pipe and the second filter, every blast pipe Outlet side is furnished with a gas exhausting valve, and the air inlet of the blast pipe falls in construction section after top rubber plug, and often Second filter is configured at the air inlet of root blast pipe, the gas exhausting valve is staggered the time unlatching, forms interactive outlet system.
7. a kind of suspended state photochemical catalyst as claimed in claim 1 removes the device of organic exhaust gas, it is characterised in that:Described Reactor body is quartz glass, reacts segment length 200mm, internal diameter 95mm, catalytic section top internal diameter 95mm, bottom internal diameter 30mm, High 70mm.
8. a kind of suspended state photochemical catalyst as claimed in claim 1 removes the device of organic exhaust gas, it is characterised in that:Described First filter is the stainless (steel) wire of national standard 304 of 250 mesh, and the second filter is the nylon wire of 500 mesh.
9. remove organic exhaust gas using a kind of suspended state photochemical catalyst described in claim 1~8 any one claim The processing method that device is carried out, comprises the following steps:
1) pending volatile organic waste gas is imported in reactor by air induction conduit, until air is complete in reactor Cement out;
2) electro-motor of reactor bottom is opened, the regulating and controlling voltage stirring blades rotating speed of electro-motor is accessed by adjusting, i.e., Wind-force size is controlled, makes photochemical catalyst that suspended state be presented and is contacted with volatile organic waste gas;
3) while step 2) is carried out, the switch and ultraviolet irradiation device of cooling back installation are opened, in the photograph of uviol lamp Penetrate down, be converted into innoxious material in volatile organic waste gas through photocatalysis;
4) photochemical catalyst is retained by the second filter, the tail gas that step 3) obtains is arranged from the exhaust apparatus alternately opened Go out.
CN201710889405.9A 2017-09-27 2017-09-27 A kind of suspended state photochemical catalyst removes the device and its processing method of organic exhaust gas Pending CN107694329A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109827215A (en) * 2019-03-01 2019-05-31 陕西青朗万城环保科技有限公司 A kind of Full-automatic tobacco Flash Gas Compression Skid System

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040059420A (en) * 2002-12-28 2004-07-05 (주)에이엔티이십일 Processing methode for air purification and equipment therefor
CN105381673A (en) * 2015-10-29 2016-03-09 中国科学院广州地球化学研究所 Method and equipment for treating complex industrial organic waste gas containing oil fume and dust and application

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040059420A (en) * 2002-12-28 2004-07-05 (주)에이엔티이십일 Processing methode for air purification and equipment therefor
CN105381673A (en) * 2015-10-29 2016-03-09 中国科学院广州地球化学研究所 Method and equipment for treating complex industrial organic waste gas containing oil fume and dust and application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
袁一: "《化学工程师手册》", 31 January 2001 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109827215A (en) * 2019-03-01 2019-05-31 陕西青朗万城环保科技有限公司 A kind of Full-automatic tobacco Flash Gas Compression Skid System

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Application publication date: 20180216