CN107694293A - A kind of hypergravity ammonia removal device and ammonia-removal method - Google Patents
A kind of hypergravity ammonia removal device and ammonia-removal method Download PDFInfo
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- CN107694293A CN107694293A CN201711097792.9A CN201711097792A CN107694293A CN 107694293 A CN107694293 A CN 107694293A CN 201711097792 A CN201711097792 A CN 201711097792A CN 107694293 A CN107694293 A CN 107694293A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1418—Recovery of products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/24—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by centrifugal force
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
- B01D2252/103—Water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
Abstract
The invention discloses a kind of hypergravity ammonia removal device, including casing, fire-proof motor, liquid circulation loop and gas circulation loop.The hypergravity ammonia removal device of the present invention, liquid film is formed by plastic wire using powerful centrifugal force caused by high speed rotation and increases contact area, so that gas-liquid speed of related movement increases, alternate contact interface product is greatly increased and updated rapidly, so that mass-transfer efficiency improves 13 orders of magnitude than spray tower, so as to which ammonia can more fully be dissolved in water.The characteristics of water circulation use, reduces the energy consumption of water, while improves the recovery utilization rate of ammonia, and small with device volume, and simple in construction, the residence time is short, microcosmic well mixed, and mass-transfer efficiency is high, and investment and operating cost are low.The invention also discloses a kind of ammonia-removal method of hypergravity ammonia removal device.
Description
Technical field
The present invention relates to a kind of hypergravity ammonia removal device and application method, is a kind of ammonia decontamination processing unit, belongs to work
Industry handles the technical field of ammonia equipment.
Background technology
Ammonia is a kind of hydronitrogen, is toxic gas that is a kind of colourless but having intense irritation smell, it is easily molten
Yu Shui, 1 volume of water can dissolve 700 volume ammonias, and the hydration of chemical reaction generation one occurs for Yi Yushui when ammonia is dissolved in water
Ammonia.The boiling point of ammonia is -33.5 degrees Celsius, easily liquefaction, industrially usually uses this characteristic, refrigeration working medium is used as using ammonia.Ammonia
Due to containing nitrogen in gas, soda ash, nitric acid, ammonium salt and chemical fertilizer processed etc. are widely used in.
The ammonia explosion limit is 15.7~27.4%, and its fire risk belongs to 2 articles of Class B.Therefore, ammonia and sky
Gas or oxygen mix can form explosive mixture.Ammonia can attack moist skin, mucous membrane and eyes, can cause deep coughs, branch
Tracheospasm, acute pulmonary edema, or even blindness and death by suffocation can be caused.Current ammonia decontamination technology both domestic and external mainly has：
Chemical absorbing, catalytic decomposition, aerobic breakdown is catalyzed, biodegradable, Physical Absorption, but have its limitation.
Ammonia chemical absorbing is ammonia and acidic materials is reacted using the alkalescence of ammonia and then produce low value-added nitrogenous fertilizer,
The method recovered solvent volatility is big, and corrosivity is strong, not disposable, and can not recycle gaseous ammonia, causes resource
Waste.
Ammonia catalytic decomposition technology is that ammonia is thoroughly decomposed into nitrogen and hydrogen in the presence of catalyst, but be presently, there are
The shortcomings that be, the decomposition of ammonia need to be carried out at high temperature.When temperature be less than 900 DEG C when, easily occur catalyst sulfur poisoning or
Phenomena such as producing ammonium salt blockage catalyst, but when temperature is more than 1200 DEG C, then Catalyst Steam can be made to press through high and accelerate to urge
The loss of agent, directly affect the service life of catalyst.Ammonia decomposition reaction thermal discharge is big, is not easily recycled utilization, causes ammonia to urge
Change and decompose power consumption height, operating cost is high, is not suitable in industrial production.
Ammonia catalysis aerobic breakdown technology is that ammonia is catalytically conveted into nitrogen and water under conditions of aerobic, and decomposition reaction exists
300 DEG C can be carried out, and completely eliminate the harm of ammonia, while also not produce secondary pollution.But the ammonia of method processing is dense
Spend relatively low, be not suitable for the processing of higher concentration ammonia, otherwise need to improve temperature, not only add energy consumption, and it can be promoted
The generation of his nitrogen ammoniate.The research of catalytic active component is concentrated mainly on noble metal and mistake in the aerobic breakdown of ammonia catalysis at present
Cross on metal oxide, noble metal catalyst typically has higher catalytic activity to ammonia catalysis aerobic breakdown, and reaction temperature exists
250 DEG C to 400 DEG C, but noble metal catalyst is poor to the selectivity of nitrogen, and be catalyzed aerobic breakdown and side reaction often be present, it is raw
Into nitric oxide, secondary pollution is caused, while noble metal catalyst is general costly, limits its application.Transiting metal oxidation
Thing catalyst has higher nitrogen selective with respect to noble metal catalyst, and cheap, but metal oxide oxidation catalyst activity
Not high, reaction temperature is higher.Therefore, either single supported precious metal catalyst or single carrying transition metal oxide catalyst
Agent, it can not all meet many requirements in industrial production to catalyst simultaneously.
Biological degradation method is the aerobic-anaerobic process using microorganism, and ammonia is converted into the nutrient source of microorganism so as to reach
To the purpose of purification air, but in industrial production, the ammonia of required purification is large-minded, and ammonia has toxic, and biological
Degradation treatment technology is not met by the demand in industrial production in the resistance to poison of biological inoculum and degradation efficiency.
The Physical Absorption of ammonia is the most common technology of ammonia removal, and the characteristic of water is highly soluble in using ammonia, with soft water or
Weak aqua ammonia is that absorbent absorbs ammonia, obtains low concentration ammoniacal liquor and then further distill to obtain concentrated ammonia liquor, and rectifying is concentrated ammonia liquor, then
Pressurized, liquefied ammonia use is made in condensation.In traditional chemical technique, absorption operation is a kind of important separation method, influences it
The factor of absorption is mainly solubility of the ammonia in water, and its absorption efficiency depends mainly on gas phase or liquid phase and ammonia on interface
Concentration difference, and ammonia is from gas phase to the diffuser efficiency of liquid phase transmission.This technique is disadvantageous in that ammonia is anti-with water
Substantial amounts of heat is released during answering, causes temperature drastically to raise, prevents ammonia to be dissolved in water so that liquid phase water is easy to tend to saturation
State, therefore, it is necessary to consume substantial amounts of water.And the recovery utilization rate of ammonia is not high, a large amount of weak aqua ammonias are produced in absorption process must
20% ammoniacal liquor must be condensed into by heating to be applied, and cost recovery is high, consumes big energy.
《Henan chemical industry》In《Spray column tail gas removes the experimental study of ammonia》Paper by spray absorber, with
Ammonia, air, dilute nitric acid solution are experiment thing system, have investigated sprinkle density, empty tower gas velocity, entrance ammonia density, absorbing liquid respectively
The influence of pH value and liquid phase temperature to ammonia absorptivity.Absorbent is delivered to absorption through circulating pump with certain flow in experiment flow
Column overhead, and be uniformly distributed into by liquid distributing board after droplet and gas is sprayed, the heat transfer of gas-liquid two-phase counter current contacting
Mass transfer, gas phase empty after tower top cyclone defroster.The spray of this device is uniformly distributed into droplet by liquid distributing board, compared to
Extensive packed tower, simple in construction, energy consumption is low.But its gas liquid interfacial area is small, absorbing the liquid phase after ammonia can not upgrade in time,
Mass-transfer efficiency is low.
《Chemical intermediate》Middle publication《The research of ammonia in rotary packed bed absorption phosphate tail gas》Describe it is a kind of with
Acid waste water is absorbing liquid, replaces traditional tower using rotary packed bed, the reality carried out to the ammonia in removing phosphate tail gas
Test.This experiment absorbs ammonia using acid, not equilibrium limited because sour absorption efficiency is higher.But ammonia absorption efficiency mainly takes
Acid content certainly in acid waste water, if acid amount deficiency, its absorption process translate into absorption process of the water to ammonia, limited
Acid is to its assimilation effect.And in the deamination experiment carried out to its tail gas, the device is applied to the suction of reaction of quick and moment
, certain risk be present in receipts process.Rotation filler inner edge is directly sprayed onto when waste water is passed through into liquid distribution trough, reacts contact surface
Product is small, and gas-liquid speed of related movement is low, and absorption efficiency is low, the problem of being also required to overcome gas-liquid skewness in tower during design.
The content of the invention
The field that the purpose of the present invention is assembled primarily directed to ammonias such as the freezer using ammonia as refrigeration working medium and chemical fertilizer factories
Carried out by avoid that ammonia is revealed and ammonia explosion accident, design provide a kind of ammonia decontamination processing unit and ammonia-removal method, it is and existing
Precautionary measures are compared, the low, small volume of present apparatus power consumption, simple in construction, reliable, and easy to operate, purification efficiency is high, does not produce
Secondary pollution, product can continue with.
To reach above-mentioned purpose, the present invention realizes that purpose is adopted the technical scheme that：
A kind of hypergravity ammonia removal device, including casing, fire-proof motor, liquid circulation loop and gas circulation loop, institute
State liquid circulation loop include the delivery port being located on the casing and sequentially connected with the delivery port the 4th regulating valve,
Water pump, heat exchanger and spray head, the gas circulation loop include sequentially connecting blower fan, the first regulating valve, are located at the casing
The air inlet of side, the gas outlet for being located at the casing opposite side and ammonia concentration detection device, the ammonia concentration detection
The outlet of equipment is also connected by the pipeline provided with the 5th regulating valve with the inlet scoop of the blower fan, and the ammonia concentration detection is set
Standby outlet is additionally provided with the 6th regulating valve and leads directly to air, and the spray head is arranged at the top of the box inside, the spray
The lower section of leaching head is provided with plastic wire, and the bottom half is provided with water inlet and discharge outlet, and the water inlet is provided with the second regulation
Valve, the discharge outlet are sequentially installed with ammonia concn and examine equipment and the 3rd regulating valve, and the middle part of the plastic wire is provided with rotation
Drive shaft, the rotation driving axle of the fire-proof motor and the plastic wire are connected.
Further, in order to avoid superpressure in casing, ensure safety, the safety valve is additionally provided with the top of the casing.
Further, the air inlet and the gas outlet are set using the plastic wire as with reference to diagonal, the gas outlet with
The angle of horizontal plane is 0 °~60 °.Optimize the path of gas flowing, when increase gas is with the contact with liquid in the casing
Between improve absorption efficiency.
Further, the mesh number of the plastic wire is 10~500 mesh, the surface area of liquid can be increased into rational area
Between, both avoid ammonia from absorbing slow, and avoid the too fast waste power of liquid flowing speed again.
Further, the rotating speed of the fire-proof motor is 200~400r/min, and rational rotary speed can improve ammonia
Purification efficiency.
Further, the spray head fills for gondola water faucet, and its hole density is 5~15PPI, so that on the plastic wire preferably
Form liquid film.
A kind of ammonia-removal method of hypergravity ammonia removal device of the present invention, comprises the following steps：
1st, open second regulating valve and soft water is injected into the casing by the water inlet；
2nd, when water reaches institute's water requirement, water filling highly higher than the delivery port and less than the gas outlet and will avoid
The water pump is emptied, and closes second regulating valve；
3rd, the inlet scoop of blower fan described in the pipeline connection containing ammonia that purifies will be needed or be placed in the blower fan to contain
Have in the environment of ammonia；
4th, the 4th regulating valve, the water pump, the heat exchanger and the fire-proof motor are opened, the water in the casing
In the presence of the water pump, sprayed through the heat exchanger into the spray head and form liquid film on the plastic wire；
5th, the blower fan and first regulating valve, gas is opened in the presence of the blower fan by the air inlet to enter
Enter the casing, wherein most ammonias are absorbed by the liquid film on the plastic wire, form ammoniacal liquor and flow under gravity
The bottom half；
6 then gas be discharged into the ammonia concentration detection device from the gas outlet, through the ammonia concentration detect
Equipment detects, if ammonia in gas gas concentration is higher than limit value, opens the 5th regulating valve, gas is passed through the blower fan again
It is secondary to be purified into the casing, if ammonia in gas gas concentration is less than limit value, opens the 6th regulating valve and be discharged into
Air.
Further, by controlling the opening adjustment of first regulating valve except the speed of ammonia.
Further, the circulation rate of liquid is adjusted by adjusting the 4th regulating valve, so as to adjust except ammonia speed and effect
Fruit.
Further, the ammonia concn detection device monitors the ammonia density of liquid in the casing in real time, as liquid follows
The increase of ring number, after ammonia density reaches limit value, the ammonia concn detection device controls the 3rd regulating valve to open, will
Liquid discharge recovery in the casing.
The present invention has advantages below compared with prior art：
Hypergravity ammonia removal device provided by the invention, the centrifugation for producing hundreds of times of gravity (hypergravity) is rotated using high speed
The field of force, nano level liquid film is formed by plastic wire and carries out ammonia absorption.
Existing ammonia removal equipment main body is typically various absorption towers, based on plate column and packed tower, separately there is spray-type absorption
Device, surface absorber and mix the other kinds of absorber such as absorber.The present apparatus is formed by super gravity field on plastic wire
Liquid film increases contact area so that gas-liquid speed of related movement increases, and alternate contact interface product is greatly increased and updated rapidly, micro-
See well mixed so that the mass-transfer efficiency ratio spray tower 1-3 order of magnitude of raising, and the 1/10 of the insufficient the latter of its volume,
So as to which ammonia can more fully be dissolved in water.Water circulation use, reduces the energy consumption of water, while improves the recycling of ammonia
Rate.
Packed tower empty tower gas velocity is usually 0.5~1.2m/s, and gas velocity crosses conference and forms liquid flooding.In the present apparatus, water due to by
Acted on to larger super gravity field, its flow velocity is much bigger more than in tower, can control higher gas flow rate, high-gravity rotating bed
Flooding point apparently higher than packed tower, plate column and conventional absorber, thus gas-liquid contact is typically not susceptible to liquid flooding, handles gas
Amount is bigger, is suitable for the operational unstability that the fluctuation of solution-air parameter may be brought.
Brief description of the drawings
Fig. 1 is the principle schematic diagram of the embodiment of the present invention；
In figure：1 be blower fan, 2 be the first regulating valve, 3 be bevel gear, 4 be spray head, 5 be safety valve, 6 be fire-proof motor,
7 be water pump, 8 be casing, 9 be the second regulating valve, 10 be the 3rd regulating valve, 11 be the 4th regulating valve, 12 be plastic wire, 13 be into
Gas port, 14 be delivery port, 15 be ammonia concentration detection device, 16 be gas outlet, 17 be water inlet, 18 be discharge outlet, 19 be ammonia
Water concentration examine equipment, 20 be the 5th regulating valve, 21 be the 6th regulating valve, 22 be heat exchanger.
Embodiment
It is understandable to enable the above objects, features and advantages of the present invention to become apparent, below in conjunction with the accompanying drawings to the present invention
Specific embodiment be described in detail.
As shown in Figure 1：Returned for a kind of hypergravity ammonia removal device of the present invention, including casing 8, fire-proof motor 6, liquid circulation
Road and gas circulation loop, the liquid circulation loop include being located at delivery port 14 on the casing 8 and with it is described go out
The 4th regulating valve 11, water pump 7, heat exchanger 22 and the spray head 4 that the mouth of a river 14 sequentially connects, the gas circulation loop are included sequentially
Connect blower fan 1, the first regulating valve 2, the air inlet 13 for being located at the side of casing 8, the gas outlet for being located at the opposite side of casing 8
16 and ammonia concentration detection device 15, the outlet of the ammonia concentration detection device 15 is also by provided with the 5th regulating valve 20
Pipeline connects with the inlet scoop of the blower fan 1, and the outlet of the ammonia concentration detection device 15 is additionally provided with the 6th regulating valve
21 straight-through air, the spray head 4 are arranged on the inside top of casing 8, and the lower section of the spray head 4 is provided with plastic wire 12,
The bottom of casing 8 is provided with water inlet 17 and discharge outlet 18, and the water inlet 17 is provided with the second regulating valve 9, the discharge outlet
18, which are sequentially installed with ammonia concn, examines the regulating valve 10 of equipment 19 and the 3rd, and the middle part of the plastic wire 12 is provided with rotation driving
Axle, the rotation driving axle of the fire-proof motor 6 and the plastic wire 12 are connected.
The top of the casing 8 is additionally provided with the safety valve 5.
Fire-proof motor 6 described in the embodiment of the present invention is arranged horizontally in outside the casing 8, and by bevel gear 3 with it is described
The rotation driving axle drive connection of plastic wire 12, the air inlet 13 and the gas outlet 16 are ginseng with the plastic wire 12
Set according to diagonal, the gas outlet 16 and the angle of horizontal plane are 30 °, and the mesh number of the plastic wire 12 is 300 mesh, described explosion-proof
The rotating speed of motor 6 is 300r/min, and the spray head 4 fills for gondola water faucet, and its hole density is 10PPI.
Certainly, the fire-proof motor 6 can also use other arrangements, the gas outlet 16 and the angle of horizontal plane
Can be other 0 °~60 ° of angles, the mesh number of the plastic wire 12 can be 10~500 mesh, and the rotating speed of the fire-proof motor 6 can
Think 200~400r/min, the spray head 4 fills for gondola water faucet, and its hole density can be 5~15PPI.
A kind of ammonia-removal method of hypergravity ammonia removal device of the present invention, comprises the following steps：
The first step：Open second regulating valve 9 and soft water is injected into the casing 8 by the water inlet 17；
Second step：When water reaches institute's water requirement, water filling highly higher than the delivery port 14 and is less than the gas outlet
16 and to avoid the water pump 7 from being emptied, close second regulating valve 9；
3rd step：The inlet scoop of blower fan 1 described in the pipeline connection containing ammonia that purifies will be needed or by the blower fan 1
It is placed in the environment containing ammonia；
4th step：Open the 4th regulating valve 11, the water pump 7, the heat exchanger 22 and the fire-proof motor 6, institute
The water in casing 8 is stated in the presence of the water pump 7, is sprayed through the heat exchanger 22 into the spray head 4 in the modeling
Liquid film is formed on material net 12；
5th step：The blower fan 1 and first regulating valve 2 are opened, gas is in the presence of the blower fan 1 by described
Air inlet 13 enters the casing 8, wherein most ammonias are absorbed by the liquid film on the plastic wire 12, forms ammoniacal liquor in weight
The bottom of casing 8 is flowed under power effect；
6th step：Then gas is discharged into the ammonia concentration detection device 15 from the gas outlet 16, through the ammonia
Gas concentration detection device 15 detects, if ammonia in gas gas concentration is higher than limit value, opens the 5th regulating valve 20, gas
It is passed through the blower fan 1 and is again introduced into the casing 8 and purified, if ammonia in gas gas concentration is less than limit value, opens institute
State the 6th regulating valve 21 and be discharged into air；
Can be by controlling the opening adjustment of first regulating valve 2 except the speed of ammonia.
The circulation rate of liquid can be adjusted by adjusting the 4th regulating valve 11, so as to adjust except ammonia speed and effect
Fruit.
The ammonia concn detection device 19 monitors the ammonia density concentration of liquid in the casing 8 in real time, as liquid follows
The increase of ring number, after ammonia density reaches limit value, the ammonia concn detection device 19 controls the 3rd regulating valve 10 to open
Open, the liquid in the casing 8 is discharged into recovery.
Although present disclosure is as above, the present invention is not limited to this.Any those skilled in the art, this is not being departed from
In the spirit and scope of invention, it can make various changes or modifications, therefore protection scope of the present invention should be with claim institute
The scope of restriction is defined.
Claims (10)
- A kind of 1. hypergravity ammonia removal device, it is characterised in that：Including casing (8), fire-proof motor (6), liquid circulation loop and Gas circulation loop, the liquid circulation loop include being arranged on delivery port (14) on the casing (8) and with it is described go out The 4th regulating valve (11), water pump (7), heat exchanger (22) and the spray head (4) that the mouth of a river (14) connects in order, the gas circulation Loop includes connecting blower fan (1), the first regulating valve (2) in order, the air inlet (13) for being arranged on the casing (8) side, set Put and set in the gas outlet (16) of the casing (8) opposite side and ammonia concentration detection device (15), the ammonia concentration detection The outlet of standby (15) is also connected by the pipeline provided with the 5th regulating valve (20) with the inlet scoop of the blower fan (1), the ammonia The outlet of concentration detection device (15) is additionally provided with the 6th regulating valve (21) and leads directly to air, and the spray head (4) is arranged on institute State the top in casing (8), be provided with plastic wire (12) below the spray head (4), casing (8) bottom be provided with into The mouth of a river (17) and discharge outlet (18), the water inlet (17) are provided with the second regulating valve (9), and the discharge outlet (18) is installed successively There is ammonia concn to examine equipment (19) and the 3rd regulating valve (10), rotation driving axle be provided with the middle part of the plastic wire (12), The fire-proof motor (6) and the rotation driving axle of the plastic wire (12) are connected.
- A kind of 2. hypergravity ammonia removal device according to claim 1, it is characterised in that：The top of the casing (8) is also set There is the safety valve (5).
- A kind of 3. hypergravity ammonia removal device according to claim 1, it is characterised in that：The air inlet (13) and it is described go out Gas port (16) is to be set with reference to diagonal with the plastic wire (12), and the gas outlet (16) and the angle of horizontal plane are 0 °~60 °.
- A kind of 4. hypergravity ammonia removal device according to claim 1, it is characterised in that：The mesh number of the plastic wire (12) is 10~500 mesh.
- A kind of 5. hypergravity ammonia removal device according to claim 1, it is characterised in that：The rotating speed of the fire-proof motor (6) For 200~400r/min.
- A kind of 6. hypergravity ammonia removal device according to claim 1, it is characterised in that：The spray head (4) fills for gondola water faucet, Its hole density is 5~15PPI.
- A kind of 7. ammonia-removal method according to a kind of any described hypergravity ammonia removal device of claim 1 to 6, it is characterised in that bag Include following steps：The first step：Open second regulating valve (9) and soft water is injected into the casing (8) by the water inlet (17)；Second step：When soft water amount reaches set water, i.e. water filling goes out highly higher than the delivery port (14) and less than described in Gas port (16), close second regulating valve (9)；3rd step：The inlet scoop of blower fan (1) described in the pipeline connection containing ammonia that purifies will be needed or by the blower fan (1) It is placed in the environment containing ammonia；4th step：Open the 4th regulating valve (11), water pump (7), heat exchanger (22) and fire-proof motor (6), the casing (8) Interior soft water enters the spray head (4) in the presence of the water pump (7), through the heat exchanger (22) and sprayed in the modeling Liquid film is formed on material net (12)；5th step：The blower fan (1) and first regulating valve (2) are opened, gas passes through institute in the presence of the blower fan (1) State air inlet (13) and enter the casing (8), wherein most ammonias are absorbed by the liquid film on the plastic wire (12), formed Ammoniacal liquor flows to the casing (8) bottom under gravity；6th step：Then gas is discharged into the ammonia concentration detection device (15) from the gas outlet (16), through the ammonia Gas concentration detection device (15) detects, and when ammonia in gas gas concentration is higher than limit value, then opens the 5th regulating valve (20), gas Body, which is passed through the blower fan (1) and is again introduced into the casing (8), to be purified, and when ammonia in gas gas concentration is less than limit value, is then opened Open the 6th regulating valve (21) and be discharged into air.
- A kind of 8. ammonia-removal method of hypergravity ammonia removal device according to claim 7, it is characterised in that：By controlling described The openings of sizes regulation of one regulating valve (2) is except the speed of ammonia.
- A kind of 9. ammonia-removal method of hypergravity ammonia removal device according to claim 7, it is characterised in that：By adjusting described The circulation rate of the openings of sizes regulation liquid of four regulating valves (11).
- A kind of 10. ammonia-removal method of hypergravity ammonia removal device according to claim 7, it is characterised in that：Using ammonia concn Detection device (19) monitors the ammonia density of the casing (8) interior liquid in real time, with the increase of liquid circulation number, when ammonia density reaches During to setting value, the ammonia concn detection device (19) controls the 3rd regulating valve (10) to open, by the casing (8) Liquid discharge recovery.
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| CN108627601A (en) * | 2018-06-28 | 2018-10-09 | 山东五岳电器有限公司 | Oil spray vacuum degasser and application method for oil chromatography on-line monitoring |
| CN108744894A (en) * | 2018-05-07 | 2018-11-06 | 江苏科技大学 | For confined space carbon dioxide absorption purifier and method |
| CN110756018A (en) * | 2019-12-11 | 2020-02-07 | 谢云真 | Controllable fertilizer production of gas concentration filters peculiar smell equipment that removes |
| CN110833034A (en) * | 2019-11-29 | 2020-02-25 | 东北农业大学 | Ammonia-removing air purification device in pickling water curtain type pigsty |
| CN112933885A (en) * | 2021-03-05 | 2021-06-11 | 中北大学 | Method and device for selectively absorbing ammonia in melamine tail gas through supergravity non-equilibrium |
| CN113134285A (en) * | 2021-05-17 | 2021-07-20 | 华能国际电力股份有限公司营口电厂 | Novel ammonia fog purification system |
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| CN108744894A (en) * | 2018-05-07 | 2018-11-06 | 江苏科技大学 | For confined space carbon dioxide absorption purifier and method |
| CN108627601A (en) * | 2018-06-28 | 2018-10-09 | 山东五岳电器有限公司 | Oil spray vacuum degasser and application method for oil chromatography on-line monitoring |
| CN110833034A (en) * | 2019-11-29 | 2020-02-25 | 东北农业大学 | Ammonia-removing air purification device in pickling water curtain type pigsty |
| CN110756018A (en) * | 2019-12-11 | 2020-02-07 | 谢云真 | Controllable fertilizer production of gas concentration filters peculiar smell equipment that removes |
| CN112933885A (en) * | 2021-03-05 | 2021-06-11 | 中北大学 | Method and device for selectively absorbing ammonia in melamine tail gas through supergravity non-equilibrium |
| CN113134285A (en) * | 2021-05-17 | 2021-07-20 | 华能国际电力股份有限公司营口电厂 | Novel ammonia fog purification system |
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