CN107686691A - A kind of release silicone oil of water soluble acrylic acid and its preparation method and application - Google Patents
A kind of release silicone oil of water soluble acrylic acid and its preparation method and application Download PDFInfo
- Publication number
- CN107686691A CN107686691A CN201710800933.2A CN201710800933A CN107686691A CN 107686691 A CN107686691 A CN 107686691A CN 201710800933 A CN201710800933 A CN 201710800933A CN 107686691 A CN107686691 A CN 107686691A
- Authority
- CN
- China
- Prior art keywords
- silicone oil
- water soluble
- acrylic acid
- soluble acrylic
- release silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 42
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 29
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000013530 defoamer Substances 0.000 claims abstract description 7
- 239000000080 wetting agent Substances 0.000 claims abstract description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003921 oil Substances 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
- 238000007046 ethoxylation reaction Methods 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000013557 residual solvent Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 229920001558 organosilicon polymer Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
The invention discloses release silicone oil of a kind of water soluble acrylic acid and its preparation method and application.The release silicone oil of water soluble acrylic acid of the present invention is made up of aqueous acrylic emulsion, waterborne organic silicon oil, wetting agent, defoamer and levelling agent etc., acrylic emulsion is with the addition of on the basis of waterborne organic silicon oil, form uniformly miscible structure, it is good to be coated with spreadability, adhesive force reaches 1 grade, and coating comfortable feel is smooth.The coating that the release silicone oil of the present invention obtains is clear, colorless, can produce good release effect, painting face is smoothly bright, can be applied to the extexines such as sanitary napkin and paper diaper.
Description
Technical field
The present invention relates to paint field, and in particular to a kind of water soluble acrylic acid for being exclusively used in making specific coating on Special Products
Release silicone oil.
Background technology
Organic silicone oil is an important product in current anti-stick coating field, with the implementation of national all standard, peace
Loopful protects the rise of concept, and the technology of application industry is also constantly improving, and the characteristic of product will be more and more specialized.It is water-based organic
Silicone oil is a kind of using water as solvent, the principle based on anti-adhesive silicone, answers the product of market and life.Because it has transparent, nothing
The advantages that poison, surface tension are low, high temperature resistant, weatherability, it is widely used in the outer of the base materials such as paper, plastic sheeting, yarn fabric
Top layer uses as anti-sticking nonpolluting coating.
However, existing release silicone oil product performance does not reach requirement still on the market, porous substrate is especially applicable to
On extexine, it is difficult to soft comfortable smooth release coating is prepared, because conventional release silicone oil is more using single
One organic silicone oil is prepared by primary raw material, and solidification temperature is higher, and obtained coating becomes that stiff, frictional force is big, and feel is natural
It is bad.
The content of the invention
The main object of the present invention, be to provide a kind of water soluble acrylic acid release silicone oil, with efficiently against it is above-mentioned not
Foot.
To achieve these goals, the release silicone oil of water soluble acrylic acid of the invention is by aqueous acrylic emulsion, water-based had
Machine silicone oil, wetting agent, defoamer and levelling agent etc. form.
The percentage by weight of the release silicone oil each component of water soluble acrylic acid of the present invention is：
Described aqueous acrylic emulsion, its glass transition temperature are 10~15 DEG C, molecular weight >=200000, acid number 50~
60, pH value is 8.0~9.0, and film forming is excellent, has preferable weatherability and water resistance.
Described organic silicone oil be hydrophilic radical be modified organosilicon polymer, its appearance transparent, viscosity be 1000~
3000mpas, pH value is between 5.0~7.0, effective content 100%, can provide good release effect, assigns coating and feels well
The feel such as sliding, bright, soft and comfortable.
Described solvent is the mixture of water and ethanol, and its volume range is 1:1 to 3:Between 1.
Preferably, described aqueous wetting agent is the poly- silicon alkoxide of polyether-modified ethoxylation dimethyl of low molecule amount
Compound, its effective content 100%, 50~300mPa of viscosity, there is splendid wetting and diffusion effect, release silicon can be effectively improved
The adhesive force of oil.
Preferably, described aqueous defoamer is the mixture of fatty race's mineral oil, its effective content 100%, glue
Spend 50~300mPa.
Preferably, described aqueous levelling agent is the aqueous emulsion of dimethyl polysiloxane fluid of HMW, its effective content
100%, 50~300mPa of viscosity, play excellent levelling, increase sliding and preventing adhesiving effect, and be effectively improved scraping and wiping resistance performance.
The preparation method of the release silicone oil of water soluble acrylic acid of the present invention is as follows：First weigh by weight proportion acrylic emulsion,
Organic silicone oil and each auxiliary agent, after each component is diluted with a small amount of solvent, mix while stirring, then residual solvent is added, at a high speed
Stir, filtering is the release silicone oil of water soluble acrylic acid.
The release silicone oil of the present invention can be coated on the extexine of base material in application using spraying or by the way of brushing,
After the solvent is volatilized, 80~120 DEG C of solidifications are heated to, hardening time is generally 5~60min.
Effect of the invention is that with the addition of acrylic emulsion into silicone release coating, uniformly miscible knot is formed
Structure, promote the smooth handle effect of coating, effectively reduce skin-friction force.The coating that the release silicone oil of the present invention obtains is transparent
Colourless, good release effect can be produced, painting face is smoothly bright, can be applied to the extexines such as sanitary napkin and paper diaper.
Embodiment
Below by example, the present invention is described in further detail, and these examples are only used for helping to understand the present invention's
Method and core concept, do not limit the scope of the invention.It should be pointed out that under the premise of not departing from the present invention, this area
Technical staff can still carry out some improvement and modification to the present invention, and these are improved and modification also falls into the claims in the present invention
In protection domain.
Embodiment 1
Raw material and reagent described in the present embodiment mainly have：Aqueous acrylic emulsion comes from Fujian Green spring new material stock
The product of part Co., Ltd, Tg values are 10~15 DEG C, molecular weight >=200000, acid number 50~60, and pH value is 8.0~9.0；It is water-based
Wetting agent is the poly- silicon alkyl oxide of polyether-modified ethoxylation dimethyl of low molecule amount, light from Si Luoke Silok8000
Yellow liquid；Aqueous defoamer is the mixture of Tego Foamex K8 Aliphatic mineral oils；Aqueous levelling agent is HMW
Aqueous emulsion of dimethyl polysiloxane fluid, from the high Glide100 of German enlightening, white emulsion；Solvent is the mixture of water and ethanol, its
Volume ratio is 3:1.Silicone oil is DOW CORNING DC193 silicone oil.
The formula of the present embodiment is following (score ratio by weight)：
Fraction scale weighs acrylic emulsion and organic silicone oil in stirred tank by weight, adds the solvent of half amount, rises
Temperature is to 50 DEG C, and stirring at low speed mixes half an hour, then each auxiliary agent and residual solvent are added, and high-speed stirred stops after one hour, cold
But room temperature is down to, after shutting down defoaming, the as described release silicone oil of water soluble acrylic acid.
By the way of spraying or brushing, release silicone oil described in the present embodiment is coated on the extexine of paper diaper, applied
Cloth amount is 1.2g/m2, after the solvent is volatilized, it is heated to 100 DEG C and solidifies 1 hour, obtained silicone release coating coating covering
Property it is good, the pencil hardness of coating is 5B~6B, adhesion 1 grade, caking property confining force be more than 95%, with finger frustrate erasing in base
Release coating on material comes off without silicone oil, and comfortable feel is smooth.
Embodiment 2
Raw material and reagent described in the present embodiment mainly have：Aqueous acrylic emulsion comes from Fujian Green spring new material stock
The product of part Co., Ltd, Tg values are 10~15 DEG C, molecular weight >=200000, acid number 50~60, and pH value is 8.0~9.0；It is water-based
Wetting agent is the poly- silicon alkyl oxide of polyether-modified ethoxylation dimethyl of low molecule amount, light from Si Luoke Silok8000
Yellow liquid；Aqueous defoamer is the mixture of Tego Foamex K8 Aliphatic mineral oils；Aqueous levelling agent is HMW
Aqueous emulsion of dimethyl polysiloxane fluid, from the high Glide100 of German enlightening, white emulsion；Solvent is the mixture of water and ethanol, its
Volume ratio is 1:1.Silicone oil is DOW CORNING DC193 silicone oil.
The formula of the present embodiment is following (score ratio by weight)：
Fraction scale weighs acrylic emulsion and organic silicone oil in stirred tank by weight, adds the solvent of half amount, rises
Temperature is to 50 DEG C, and stirring at low speed mixes half an hour, then each auxiliary agent and residual solvent are added, and high-speed stirred stops after one hour, cold
But room temperature is down to, after shutting down defoaming, the as described release silicone oil of water soluble acrylic acid.
By the way of spraying or brushing, release silicone oil described in the present embodiment is coated on the extexine of sanitary napkin, applied
Cloth amount is 1.0g/m2, after the solvent is volatilized, it is heated to 120 DEG C and solidifies 1 hour, obtained silicone release coating coating covering
Property it is good, the pencil hardness of coating is 4B~5B, adhesion 1 grade, caking property confining force be more than 95%, with finger frustrate erasing in base
Release coating on material comes off without silicone oil, and comfortable feel is smooth.
Claims (7)
- A kind of 1. release silicone oil of water soluble acrylic acid, it is characterised in that：By weight, raw material includes following component：Wherein, the glass transition temperature of described aqueous acrylic emulsion is 10~15 DEG C, molecular weight >=200000, acid number 50~ 60, pH value is 8.0~9.0；Described waterborne organic silicon oil be hydrophilic radical be modified organosilicon polymer, its appearance transparent, viscosity be 1000~ 3000mpas, pH value is between 5.0~7.0, effective content 100%；Described solvent is the mixture of water and ethanol, and its volume range is 1:1 to 3:Between 1；Described aqueous defoamer is the mixture of fatty race's mineral oil；Described aqueous wetting agent is the poly- silicon alkyl oxide of polyether-modified ethoxylation dimethyl of low molecule amount；Described aqueous levelling agent is the aqueous emulsion of dimethyl polysiloxane fluid of HMW.
- 2. the release silicone oil of water soluble acrylic acid according to claim 1, it is characterised in that：Described aqueous defoamer is Tego Foamex K8。
- 3. the release silicone oil of water soluble acrylic acid according to claim 1, it is characterised in that：Described aqueous wetting agent is Si Luo Ke Silok8000.
- 4. the release silicone oil of water soluble acrylic acid according to claim 1, it is characterised in that：Described aqueous levelling agent is Germany The high Glide100 of enlightening.
- 5. the release silicone oil of water soluble acrylic acid according to claim 1, it is characterised in that：Waterborne organic silicon oil is DOW CORNING DC193 silicone oil.
- 6. the preparation method of the release silicone oil of water soluble acrylic acid according to claim 1, comprises the following steps：First by weight Example weighs acrylic emulsion, organic silicone oil and each auxiliary agent, after each component is diluted with a small amount of solvent, mixes while stirring, then will Residual solvent adds, and high-speed stirred is uniform.
- 7. the purposes of the release silicone oil of water soluble acrylic acid according to claim 1, it is used for the appearance of sanitary napkin and paper diaper Layer coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710800933.2A CN107686691B (en) | 2017-09-07 | 2017-09-07 | Water-based acrylic release silicone oil and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710800933.2A CN107686691B (en) | 2017-09-07 | 2017-09-07 | Water-based acrylic release silicone oil and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107686691A true CN107686691A (en) | 2018-02-13 |
| CN107686691B CN107686691B (en) | 2021-01-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710800933.2A Active CN107686691B (en) | 2017-09-07 | 2017-09-07 | Water-based acrylic release silicone oil and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107686691B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109183499A (en) * | 2018-09-17 | 2019-01-11 | 江苏创客新材料科技有限公司 | A kind of dust sticky paper weight off-type force silicone oil and preparation method thereof |
| CN110760259A (en) * | 2019-11-05 | 2020-02-07 | 深圳市百泉河实业有限公司 | Aluminum-plastic film smooth coating liquid and coating process thereof |
| CN114773939A (en) * | 2022-04-13 | 2022-07-22 | 华南理工大学 | Transparent super-hydrophilic coating and preparation method and application thereof |
| CN114958118A (en) * | 2022-07-05 | 2022-08-30 | 浙江广印通新材料科技有限公司 | Knife coating release coating for PET film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827537A (en) * | 2012-09-15 | 2012-12-19 | 合肥华清金属表面处理有限责任公司 | Aqueous normal temperature curing peelable paint and preparation method of paint |
| CN103254706A (en) * | 2013-05-21 | 2013-08-21 | 佛山市皇冠化工有限公司 | Water-based release agent and preparation method thereof |
| CN103351812A (en) * | 2013-07-17 | 2013-10-16 | 浙江池河科技有限公司 | Water-based mold release and preparation method thereof and release paper prepared by utilizing water-based mold release |
| CN103436125A (en) * | 2013-08-29 | 2013-12-11 | 中科院广州化学有限公司 | Acrylic organosilicone water-emulsion coating as well as preparation method and application for same |
-
2017
- 2017-09-07 CN CN201710800933.2A patent/CN107686691B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827537A (en) * | 2012-09-15 | 2012-12-19 | 合肥华清金属表面处理有限责任公司 | Aqueous normal temperature curing peelable paint and preparation method of paint |
| CN103254706A (en) * | 2013-05-21 | 2013-08-21 | 佛山市皇冠化工有限公司 | Water-based release agent and preparation method thereof |
| CN103351812A (en) * | 2013-07-17 | 2013-10-16 | 浙江池河科技有限公司 | Water-based mold release and preparation method thereof and release paper prepared by utilizing water-based mold release |
| CN103436125A (en) * | 2013-08-29 | 2013-12-11 | 中科院广州化学有限公司 | Acrylic organosilicone water-emulsion coating as well as preparation method and application for same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109183499A (en) * | 2018-09-17 | 2019-01-11 | 江苏创客新材料科技有限公司 | A kind of dust sticky paper weight off-type force silicone oil and preparation method thereof |
| CN110760259A (en) * | 2019-11-05 | 2020-02-07 | 深圳市百泉河实业有限公司 | Aluminum-plastic film smooth coating liquid and coating process thereof |
| CN114773939A (en) * | 2022-04-13 | 2022-07-22 | 华南理工大学 | Transparent super-hydrophilic coating and preparation method and application thereof |
| CN114958118A (en) * | 2022-07-05 | 2022-08-30 | 浙江广印通新材料科技有限公司 | Knife coating release coating for PET film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107686691B (en) | 2021-01-26 |
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Effective date of registration: 20240116 Address after: Room 101, Building G, No. 18 Zhenxing Road, Fugong Town, Longhai District, Zhangzhou City, Fujian Province, 363100 Patentee after: Zhangzhou Green Spring Science and Technology Co.,Ltd. Address before: 361000 South 101A room, Chuang Chuang business park, torch high tech Zone, Xiamen, Fujian Patentee before: FUJIAN GREEN SPRING NEW MATERIAL CO.,LTD. |
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