CN107675048B - Highly conductive middle strength aluminium alloy of one kind and preparation method thereof - Google Patents

Highly conductive middle strength aluminium alloy of one kind and preparation method thereof Download PDF

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CN107675048B
CN107675048B CN201710784940.8A CN201710784940A CN107675048B CN 107675048 B CN107675048 B CN 107675048B CN 201710784940 A CN201710784940 A CN 201710784940A CN 107675048 B CN107675048 B CN 107675048B
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alloy
temperature
aluminium alloy
highly conductive
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CN107675048A (en
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聂宝华
陈东初
梁文灼
孙海波
聂德建
常萌蕾
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Kunming Metallurgical Research Institute
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Foshan University
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/053Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023Alloys based on aluminium

Abstract

Public a kind of highly conductive middle strength aluminium alloy of the present invention and preparation method thereof, the aluminium alloy each component and its weight percent are as follows: Mg content is 0.35~0.65%, it be 0.20~0.40%, Zr content is 0.30~0.60% that Zn content, which is 0.4~1.0%, Cu content, Er content is 0.15~0.35%, B content 0.01~0.06%, impurity element S i content≤0.1%, Fe content≤0.15%, the total content≤0.15%, Al of other impurity elements is balance-element.Its preparation process includes proportion raw material, raw material melting, refining, casting, three-level Homogenization Treatments, extrusion deformation processing, ageing treatment, stretcher strain processing, and preparation process is simple and easy.The Mechanical Properties of Aluminum Alloys is good, and has high electric conductivity.

Description

Highly conductive middle strength aluminium alloy of one kind and preparation method thereof
Technical field
The invention belongs to non-ferrous metal technical field, in particular to a kind of highly conductive middle strength aluminium alloy.
Background technique
With the development of economy and society, electricity needs is constantly promoted, it is higher and higher to the electric conductivity of material.Aluminium alloy with By means of good electric conductivity, forming property and relative moderate price and have become main conductive material.Traditional conduction material Material mostly uses copper alloy to be process greatly, but higher cost.Aluminium alloy quality is only copper alloy under the conditions of same resistivity 50%.Moreover, aluminum alloy surface forms oxide layer, corrosion resistance is preferable, and " replacing copper with aluminium " has become current development trend.Aluminium closes There are the contradictions of essence with electric conductivity for the intensity of gold.For conductive 6000 line aluminium alloys, need to further decrease The ingredient of aluminium alloy to improve alloy conductive, but can reduce alloy strength.Therefore, it is necessary to develop a kind of Novel high-conductivity Aluminium alloy.
Microalloying and working hardening are the effective means for improving alloy property.For example, adding micro Sc can be improved Al- The mechanical property and recrystallization temperature of Mg alloy, but Sc price is prohibitively expensive.Rare earth element er is similar with Sc, can with aluminium formed with Matrix coherence Al3Er disperse phase improves alloy strength.On the other hand, aluminium alloy carries out processing hardening, and it is strong to effectively improve alloy Degree, but electric conductivity is influenced smaller.Therefore, the present invention is improved by combined microalloying and working hardening with intensity of aluminum alloy With electric conductivity.
Summary of the invention
The present invention provides highly conductive middle strength aluminium alloy of one kind and preparation method thereof, and the aluminium alloy has high conduction performance And good mechanical property, and preparation method is simple and easy.
To solve the above problems, the present invention adopts the following technical scheme:
A kind of highly conductive middle strength aluminium alloy, each component and its weight percent are as follows: Mg content is 0.35~0.65%, Zn Content be 0.4~1.0%, Cu content be 0.20~0.40%, Zr content be 0.30~0.60%, Er content be 0.15~ 0.35%, B content 0.01~0.06%, impurity element S i content≤0.1%, Fe content≤0.15%, other impurity elements are total Content≤0.15%, Al be balance-element.
Further, the weight percent of Zn and Mg is 1: 1~2: 1.
Further, the weight percent of Cu and Mg is 1: 3~1.2: 1.
A kind of preparation method of highly conductive middle strength aluminium alloy, comprising the following steps:
(1) according to the ingredient and content proportion raw material described in claim 1;
(2) raw material melting: under conditions of 750~770 DEG C of temperature, first rafifinal aluminium ingot is melted, Al- is then added Pure zinc, pure magnesium and coverture is added after intermediate alloy fusing in Zr, Al-Er, Al-Cu, Al-B intermediate alloy,
(3) it refines: carbon trichloride being added in molten metal and carries out degassing processing, and is sufficiently stirred, Metal Temperature when refining In the range of degree maintains 730 DEG C~750 DEG C, sufficient standing should be carried out after refining, time of repose is not less than 25 minutes;
(4) be poured: when temperature is down to 710 DEG C~730 DEG C, it is 430 DEG C that the alloy molten solution after sufficient standing, which is poured into temperature, In~450 DEG C of metal dies, alloy cast ingot can be obtained;
(5) three-level Homogenization Treatments: three-level homogenization is carried out to the alloy casting blank that step (4) obtain, the first stage is 330 3~15h is kept the temperature at~350 DEG C, second stage keeps the temperature 15~35h at 400~440 DEG C, and the phase III is at 450~480 DEG C Keep the temperature 15~35h;
(6) extrusion deformation is handled: carrying out extrusion deformation processing to the alloy cast ingot that step (5) obtain, squeezing temperature is 470 DEG C~500 DEG C, deformation coefficient is 15~20, after extrusion deformation processing, to alloy with using the forced air-cooling type of cooling;
(7) ageing treatment: carrying out ageing treatment to the alloy that step (6) obtain, and 100~140 DEG C of aging temp, when timeliness Between be 10~30h;
(8) stretcher strain handle: to step (7) obtain alloy be draw textured, stretcher strain amount be 50%~ 80%, after stretcher strain processing, finally obtain the aluminium alloy.
The invention has the benefit that 1. rationally adding appropriate Cu, Zn element, T can be precipitated in artificial aging treatment process Phase, to improve the intensity of the aluminium alloy;2. adding micro B element, eliminating or weakening the microelements such as V, Ti to described The adverse effect of aluminium alloy electric conductivity, further increases electric conductivity;3. refining crystal grain, pure alloy melt using Er element Quality inhibits high temperature extrusion recrystallization, improves the intensity of aluminum alloy toughness;4. using multistage uniform treatment process, make Al3Er、Al3Even dispersion is precipitated Zr phase in the tissue, on the basis of not reducing alloy conductive, further increases the aluminium Alloy strength and fracture toughness;4. using working hardening technique, the intensity of aluminum alloy is further increased, and significantly reduces institute State aluminium alloy electric conductivity;5. substituting Sc element using Er, good mechanical property is obtained, while reducing the aluminium alloy Preparation cost.
Specific embodiment
Embodiment 1
Table 1 is composition component and weight percent in highly conductive middle strength aluminium alloy.
Table 1
Ingot casting number Mg Zn Cu Zr Er B Fe Si Al
1# 0.38 0.90 0.30 0.45 0.25 0.03 <0.15 <0.10 Surplus
2# 0.55 0.7 0.35 0.5 0.225 0.05 <0.15 <0.10 Surplus
3# 0.63 0.60 0.24 0.35 0.30 0.06 <0.15 <0.10 Surplus
Preparation process are as follows:
(1) feed proportioning is carried out according to composition component shown in table 1 and weight percent;
(2) melting: under the conditions of 760 DEG C of temperature, first melting rafifinal aluminium ingot, and Al-Zr, Al-Er, Al- is then added Pure zinc, pure magnesium and coverture is added after intermediate alloy fusing in Cu, Al-B intermediate alloy;
(3) it refines: carbon trichloride being added in alloy molten solution and carries out degassing processing, and is sufficiently stirred, metal is molten when refining In the range of liquid temperature maintains 740 DEG C, sufficient standing should be carried out after refining, time of repose is not less than 25 minutes;
(4) it is poured: when temperature is down to 720 DEG C, alloy solution being poured into the metal die that temperature is 440 DEG C after sufficient standing In, it can be obtained alloy cast ingot;
(5) three-level Homogenization Treatments, first stage three-level Homogenization Treatments: are carried out to the resulting alloy casting blank of step (4) 12h is kept the temperature at 340 DEG C, second stage is kept the temperature for 24 hours at 420 DEG C, and the phase III keeps the temperature for 24 hours at 460 DEG C;
(6) extrusion deformation is handled: carrying out extrusion deformation processing to the alloy cast ingot obtained in step (5), squeezing temperature is 480 DEG C, deformation coefficient 22 uses the forced air-cooling type of cooling after extrusion deformation processing;
(7) ageing treatment: ageing treatment is carried out to the alloy that step (6) obtain, 120 DEG C of aging temp, aging time is 24h;
(8) stretcher strain is handled: being draw textured processing to alloy after step (7) timeliness, is stretched variable 60%, finally Obtain heretofore described aluminium alloy.
Table 2 is is obtained alloy property list.
Table 2
As can be seen from Table 2: it is anti-that what aluminium alloy of the present invention can be stable under the preparation process prepares timeliness Tensile strength is more than 250MPa, and elongation percentage reaches 3.0%, and conductivity is more than 59.0ICAS%.It is identical in elongation percentage and conductivity Under the premise of, the mechanical property of the aluminium alloy is more than conventional conductive aluminium alloy (tensile strength is lower than 200MPa), and cost is relatively It is low, thus there is very big application potential in fields such as conductive electric wire, electric conductors.
Embodiment 2
Table 3 is composition component and weight percent in highly conductive middle strength aluminium alloy.
Table 3
Ingot casting number Mg Zn Cu Zr Er B Fe Si Al
4# 0.46 0.85 0.30 0.55 0.25 0.03 <0.15 <0.10 Surplus
5# 0.38 0.92 0.25 0.46 0.225 0.05 <0.15 <0.10 Surplus
6# 0.60 0.70 0.35 0.35 0.25 0.06 <0.15 <0.10 Surplus
Preparation process are as follows:
(1) feed proportioning is carried out according to composition component shown in table 3 and weight percent;
(2) melting: under the conditions of 750 DEG C of temperature, first melting rafifinal aluminium ingot, and Al-Zr, Al-Er, Al- is then added Pure zinc, pure magnesium and coverture is added after intermediate alloy fusing in Cu, Al-B intermediate alloy;
(3) it refines: carbon trichloride being added in alloy molten solution and carries out degassing processing, and is sufficiently stirred, metal is molten when refining In the range of liquid temperature maintains 750 DEG C, sufficient standing should be carried out after refining, time of repose is not less than 25 minutes;
(4) it is poured: when temperature is down to 730 DEG C, alloy solution being poured into the metal die that temperature is 450 DEG C after sufficient standing In, it can be obtained alloy cast ingot;
(5) three-level Homogenization Treatments, first stage three-level Homogenization Treatments: are carried out to the resulting alloy casting blank of step (4) 12h is kept the temperature at 350 DEG C, second stage is kept the temperature for 24 hours at 440 DEG C, and the phase III keeps the temperature for 24 hours at 450 DEG C;
(6) extrusion deformation is handled: carrying out extrusion deformation processing to the alloy cast ingot obtained in step (5), squeezing temperature is 490 DEG C, deformation coefficient 16 uses the forced air-cooling type of cooling after extrusion deformation processing;
(7) ageing treatment: ageing treatment is carried out to the alloy that step (6) obtain, 140 DEG C of aging temp, aging time is 24h;
(8) stretcher strain is handled: being draw textured processing to alloy after step (7) timeliness, is stretched variable 80%, finally Obtain heretofore described aluminium alloy.
Table 4 is to be obtained alloy property list.
Table 4
As can be seen from Table 4: it is anti-that what aluminium alloy of the present invention can be stable under the preparation process prepares timeliness Tensile strength is more than 250MPa, and elongation percentage reaches 3.0%, and conductivity is more than 59.0ICAS%.It is identical in elongation percentage and conductivity Under the premise of, the mechanical property of the aluminium alloy is more than conventional conductive aluminium alloy (tensile strength is lower than 200MPa), and cost is relatively It is low, thus there is very big application potential in fields such as conductive electric wire, electric conductors.
Better embodiment of the invention is illustrated above, but the invention is not limited to the implementation Example, those skilled in the art can also make various equivalent modifications on the premise of without prejudice to spirit of the invention or replace It changes, these equivalent variation or replacement are all included in the scope defined by the claims of the present application.

Claims (1)

1. a kind of preparation method of highly conductive middle strength aluminium alloy, which comprises the following steps:
Component and its weight percent in the highly conductive middle strength aluminium alloy are as follows: Mg content is that 0.35~0.65%, Zn contains Amount be 0.4~1.0%, Cu content be 0.20~0.40%, Zr content be 0.30~0.60%, Er content be 0.15~ 0.35%, B content 0.01~0.06%, impurity element S i content≤0.1%, Fe content≤0.15%, other impurity elements are total Content≤0.15%, Al be balance-element;The weight percent of Zn and Mg is 1: 1~2: 1;The weight percent of Cu and Mg is 1: 3~1.2: 1;The preparation method of the highly conductive middle strength aluminium alloy includes the following steps:
(1) raw material is matched according to described among the above ingredient and content;
(2) raw material melting: under conditions of 750~770 DEG C of temperature, first melting rafifinal aluminium ingot, and Al-Zr, Al- is then added Pure zinc, pure magnesium and coverture is added after intermediate alloy fusing in Er, Al-Cu, Al-B intermediate alloy,
(3) it refines: carbon trichloride being added in molten metal and carries out degassing processing, and is sufficiently stirred, metal temperature is tieed up when refining It holds in the range of 730 DEG C~750 DEG C, sufficient standing should be carried out after refining, time of repose is not less than 25 minutes;
(4) be poured: when temperature is down to 710 DEG C~730 DEG C, it is 430 DEG C~450 that the alloy molten solution after sufficient standing, which is poured into temperature, In DEG C metal die, alloy cast ingot can be obtained;
(5) three-level Homogenization Treatments: carrying out three-level homogenization to the alloy casting blank that step (4) obtain, the first stage 330~ 3~15h is kept the temperature at 350 DEG C, second stage keeps the temperature 15~35h at 400~440 DEG C, and the phase III protects at 450~480 DEG C 15~35h of temperature;
(6) extrusion deformation is handled: the alloy cast ingot obtained to step (5) carries out extrusion deformation processing, squeeze temperature be 470 DEG C~ 500 DEG C, deformation coefficient is 15~20, after extrusion deformation processing, is doomed alloy with using the forced air-cooling type of cooling;
(7) ageing treatment: ageing treatment is carried out to the alloy that step (6) obtain, aging temp is 100~140 DEG C, aging time For 10~30h;
(8) stretcher strain is handled: the alloy obtained to step (7) is draw textured, and stretcher strain amount is 50%~80%, is drawn After stretching deformation process, the aluminium alloy is finally obtained.
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CN108642332A (en) * 2018-06-13 2018-10-12 中北大学 A kind of high-performance beryllium alumin(i)um alloy and preparation method thereof
CN109295359B (en) * 2018-10-16 2019-11-12 东莞市东兴铝业有限公司 A kind of aluminium alloy and preparation method thereof of highly conductive high intensity
CN109161738B (en) * 2018-10-16 2019-11-12 东莞市东兴铝业有限公司 A kind of highly conductive corrosion resistant aluminum alloy and preparation method thereof
CN110714174A (en) * 2019-09-23 2020-01-21 四川阳光坚端铝业有限公司 Homogenization treatment process of aluminum alloy ingot
CN111485150A (en) * 2020-06-09 2020-08-04 天津忠旺铝业有限公司 Preparation method of high-conductivity aluminum alloy plate strip
CN115233055B (en) * 2022-07-25 2023-09-22 安徽工业大学 Aluminum extrusion profile convenient to recycle and preparation method thereof

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JP2001342577A (en) * 2000-06-05 2001-12-14 Nippon Steel Corp Aluminum alloy plate superior in press formability
CN103866167A (en) * 2014-03-27 2014-06-18 北京科技大学 Aluminum alloy and alloy sheet thereof as well as preparation method of alloy sheet
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JP2001342577A (en) * 2000-06-05 2001-12-14 Nippon Steel Corp Aluminum alloy plate superior in press formability
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