CN107674773A - One kind is exclusively used in marmorean cleaning and protective agent - Google Patents

One kind is exclusively used in marmorean cleaning and protective agent Download PDF

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Publication number
CN107674773A
CN107674773A CN201611137921.8A CN201611137921A CN107674773A CN 107674773 A CN107674773 A CN 107674773A CN 201611137921 A CN201611137921 A CN 201611137921A CN 107674773 A CN107674773 A CN 107674773A
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China
Prior art keywords
parts
cleaning
protective agent
marble
marmorean
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CN201611137921.8A
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Chinese (zh)
Inventor
王立
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Qingdao University
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Qingdao University
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Priority to CN201611137921.8A priority Critical patent/CN107674773A/en
Publication of CN107674773A publication Critical patent/CN107674773A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5072—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with oxides or hydroxides not covered by C04B41/5025
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/65—Coating or impregnation with inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1233—Carbonates, e.g. calcite or dolomite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

It is an object of the invention to provide one kind to be exclusively used in marmorean cleaning and protective agent; cleaning marmorean while changing marmorean surface nature; combined with firmness of the pollutant in marble surface are reduced, only marble need to be rinsed with water when making subsequently to clean, it is i.e. bright as new to dry rear marble.Meanwhile cleaning and protective agent of the invention has good repair to the pit-hole of the ND marble surface of naked eyes and crack.Further, since the use of marble cleaning and protective agent of the present invention, marble can keep cleaning for a long time, greatly reduce cleaning frequency, not only saved the energy but also reduced manual labor.

Description

One kind is exclusively used in marmorean cleaning and protective agent
Technical field
The present invention relates to a kind of cleaning and protective agent, especially one kind to be exclusively used in marmorean cleaning and protective agent.
Background technology
With the horizontal raising of social life, the marble application more and more extensive as finishing material and interior and Exterior finish, however, with the extension of usage time, marble surface can inevitably be infected with various obstinate dusts and dirt Stain, finishing effect is greatly reduced, cause its cleaning to be wasted time and energy.Used cleaning agent is mainly during cleaning marble now Universal cleaning agent, not only cleaning effect is poor, and irreversible damage also can be caused to marble in its slight corrosivity Evil.In the market seldom sees the special cleaning and protective agent of the gratifying marble of effect.
The content of the invention
In view of the above-mentioned problems, the present inventor, which have developed with great concentration one kind, is exclusively used in marmorean cleaning and protective agent, it not only may be used For clearing up marble surface dirt, the effect of protection marble surface is more had concurrently.
The marble cleaning and protective agent of the present invention, its component and its mass fraction are：
Anatase titanium dioxide nano particle：15-20 parts；
Nano-calcium carbonate calcium powder：30-40 parts；
Diethylene triamine pentacetic acid (DTPA) iron-sodium complex：6-10 parts；
Iron-tartaric acid-sodium complex：2-5 parts；
Modified starch：10-12 parts；
Antistatic additive：1-2 parts；
Surfactant：1-2 parts；
Sodium carboxymethylcellulose：0.5-1 parts；
APES：5-7 parts；
1-hydroxy ethylidene-1,1-diphosphonic acid：3-6 parts；
Glycerine three (1,2- epoxies) propyl ether：3-5 parts；
Essence：0-3 parts；
Deionized water：80-100 parts；
Described modified starch may be selected from the one or more in hydroxypropul starch or octenyl succinic acid starch.
The antistatic additive may be selected from one kind or more in dodecyldimethylammonium hydroxide inner salt or AEO Kind.
The surfactant may be selected from APES, sorbitan ester, fatty acid methyl ester ethoxylation One or more in thing (FMEE).
The average diameter of the nano-calcium carbonate calcium powder is 100nm-120nm.
The distribution of SMD of the anatase titanium dioxide nano particle is in 30-50nm or so, by test of many times, Inventor has found that the anatase titanium dioxide nano particle of the particle size range can both play the hydrophobic effect of maximum, reduces big Reason stone surface blot be firmly combined with degree and so that next time cleaning be easier to make for, while can suppress bacterium and virus life Long speed, prevent marble surface from growing bacterial plaque, and lift the health degree of living environment.
Protective agent is cleared up according to the marble that the specific components of above-mentioned formula and usage ratio produce, can be sent out Synergistic The effect of waving, reach best cleaning effect and so that cleaning next time is more prone to, can also repair the abrasion of marble surface and split Seam, delays its situation further to deteriorate, while suppress the effect that bacterial plaque grows and increases fragrant.
It is an object of the invention to provide a kind of multi-functional marble cleaning and protective agent, is cleaning marmorean while is changing big The surface nature of reason stone, combined with firmness of the pollutant in marble surface are reduced, need to only be rinsed when making subsequently to clean with water big Reason stone, it is i.e. bright as new to dry rear marble.Meanwhile cleaning and protective agent of the invention is to the ND marble surface of naked eyes Pit-hole and crack there is good repair.Further, since the use of marble cleaning and protective agent of the present invention, marble energy Keep cleaning for a long time, greatly reduce cleaning frequency, not only saved the energy but also reduced manual labor.
Embodiment
The marble cleaning and protective agent of the present invention is described in more detail with reference to embodiment.
1. embodiment 1
A kind of marble cleaning and protective agent, its component and its mass fraction are：
Anatase titanium dioxide nano particle：15 parts；
Nano-calcium carbonate calcium powder：30 parts；
Diethylene triamine pentacetic acid (DTPA) iron-sodium complex：6 parts；
Iron-tartaric acid-sodium complex：2 parts；
Modified starch：10 parts；
Antistatic additive：1 part；
Surfactant：1 part；
Sodium carboxymethylcellulose：0.5 part；
APES：5 parts；
1-hydroxy ethylidene-1,1-diphosphonic acid：3 parts；
Glycerine three (1,2- epoxies) propyl ether：3 parts；
Deionized water：80 parts；
Described modified starch is hydroxypropul starch.
The antistatic additive is dodecyldimethylammonium hydroxide inner salt.
The surfactant is APES.
The multi-functional marble cleaning and protective agent is prepared by the following method：
1) deionized water, APES, 1-hydroxy ethylidene-1,1-diphosphonic acid, glycerine three are sequentially added by above-mentioned parts by weight Stirring and dissolving after (1,2- epoxies) propyl ether；
2) surplus materials is added, stirring is allowed to dissolve.
3) packed after being filtered with 300 mesh filter screens.
2. embodiment 2
A kind of marble cleaning and protective agent, its component and its mass fraction are：
Anatase titanium dioxide nano particle：20 parts；
Nano-calcium carbonate calcium powder：40 parts；
Diethylene triamine pentacetic acid (DTPA) iron-sodium complex：10 parts；
Iron-tartaric acid-sodium complex：5 parts；
Modified starch：12 parts；
Antistatic additive：2 parts；
Surfactant：2 parts；
Sodium carboxymethylcellulose：1 part；
APES：7 parts；
1-hydroxy ethylidene-1,1-diphosphonic acid：6 parts；
Glycerine three (1,2- epoxies) propyl ether：5 parts；
Essence：3 parts；
Deionized water：100 parts；
Described modified starch is octenyl succinic acid starch.
The antistatic additive is AEO.
The surfactant is sorbitan ester.
The preparation method of the multi-functional marble cleaning and protective agent is identical with preparation method used in embodiment 1.
3. embodiment 3
A kind of marble cleaning and protective agent, its component and its mass fraction are：
Anatase titanium dioxide nano particle：17 parts；
Nano-calcium carbonate calcium powder：35 parts；
Diethylene triamine pentacetic acid (DTPA) iron-sodium complex：8 parts；
Iron-tartaric acid-sodium complex：4 parts；
Modified starch：12 parts；
Antistatic additive：2 parts；
Surfactant：1 part；
Sodium carboxymethylcellulose：1 part；
APES：7 parts；
1-hydroxy ethylidene-1,1-diphosphonic acid：3 parts；
Glycerine three (1,2- epoxies) propyl ether：3 parts；
Essence：1 part；
Deionized water：90 parts；
Described modified starch is octenyl succinic acid starch.
The antistatic additive is dodecyldimethylammonium hydroxide inner salt.
The surfactant is fatty acid methyl ester ethoxylate (FMEE).
The preparation method of the multi-functional marble cleaning and protective agent is identical with preparation method used in embodiment 1.
4. comparative example
Chinese patent CN201210579363.6 describes a kind of marble cleaning agent, public according to the embodiment 1 of the patent The formula opened prepares contrast cleaning agent 1.Chinese patent CN201010102807.8 describes a kind of cleaning agent, according to the patent The disclosed formula of embodiment 1 prepares contrast cleaning agent 2.
Experimental method：Marble (15 × 15cm) is taken, about 50g dirts are coated in experimental group and marble surface, in air Middle exposure 1 month, the composition of the dirt is 40wt% lards, 20wt% vegetable oil, 20wt% stearic acid, 10wt% tomatoes Sauce, 10wt% particulate sugars mix composition.
Cleaned with above-mentioned six groups of cleaning and protective agents according to identical time and method, its cleaning is evaluated by soil removal efficiency Effect.After marble after cleaning dries, continue the exposure in same dirtier environment and taken out after three months with same water Stream is rinsed, and its clean-up performance is evaluated after flushing is dried.
The method for evaluating marmorean cleaning performance or clean-up performance is：Using new marmorean clean level as 10 points, with The dirty marble for just having smeared dirt is 0 point, asks 10 volunteers to be given a mark for clean-up performance, calculates average mark.
Bacteriostatic experiment：After above-mentioned six groups of experimental groups have been cleaned with cleaning and protective agent dry for the first time, the miscellaneous of surface is wiped Bacterium, it is placed in surface medium and is cultivated,.The diameter of bacterial plaque after determining one week.
Experimental result is as follows：
From the above results, marble cleaning and protective agent of the invention is in cleaning effect, easy cleaning and antibacterial bacteriostatic The positive effect of aspect is better than existing Chinese patent CN201210579363.6 and CN201010102807.8.
What deserves to be explained is the preparation method in above example is only presently preferred embodiments of the present invention, it is not intended to limit Determine protection scope of the present invention.It will be apparent to a skilled person that protection scope of the present invention will with appended right Book is asked to be defined.

Claims (4)

1. one kind is exclusively used in marmorean cleaning and protective agent, it is characterised in that：The component and its mass parts of the cleaning and protective agent Number is：
Anatase titanium dioxide nano particle：15-20 parts；
Nano-calcium carbonate calcium powder：30-40 parts；
Diethylene triamine pentacetic acid (DTPA) iron-sodium complex：6-10 parts；
Iron-tartaric acid-sodium complex：2-5 parts；
Modified starch：10-12 parts；
Antistatic additive：1-2 parts；
Surfactant：1-2 parts；
Sodium carboxymethylcellulose：0.5-1 parts；
APES：5-7 parts；
1-hydroxy ethylidene-1,1-diphosphonic acid：3-6 parts；
Glycerine three (1,2- epoxies) propyl ether：3-5 parts；
Essence：0-3 parts；
Deionized water：80-100 parts；
Described modified starch may be selected from the one or more in hydroxypropul starch or octenyl succinic acid starch；
The antistatic additive may be selected from the one or more in dodecyldimethylammonium hydroxide inner salt or AEO；
The surfactant may be selected from APES, sorbitan ester, fatty acid methyl ester ethoxylate (FMEE) one or more in.
2. according to claim 1 be exclusively used in marmorean cleaning and protective agent, wherein the nano-calcium carbonate powder is averaged A diameter of 100nm-120nm.
3. according to claim 1 be exclusively used in marmorean cleaning and protective agent, wherein the anatase titanium dioxide is received The distribution of SMD of rice grain is in 30-50nm or so.
4. it is exclusively used in application of the marble cleaning and protective agent in marble is cleaned described in claim 1-4.
CN201611137921.8A 2016-12-12 2016-12-12 One kind is exclusively used in marmorean cleaning and protective agent Pending CN107674773A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611137921.8A CN107674773A (en) 2016-12-12 2016-12-12 One kind is exclusively used in marmorean cleaning and protective agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611137921.8A CN107674773A (en) 2016-12-12 2016-12-12 One kind is exclusively used in marmorean cleaning and protective agent

Publications (1)

Publication Number Publication Date
CN107674773A true CN107674773A (en) 2018-02-09

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768532A (en) * 2010-01-29 2010-07-07 马知岗 Cleanser and preparation method thereof
CN102153139A (en) * 2010-12-28 2011-08-17 华中师范大学 Method for preparing water-soluble titanium dioxide superfine nano crystal powder
CN103060134A (en) * 2012-12-27 2013-04-24 上海艳紫化工科技有限公司 Marble cleaning agent
CN104635438A (en) * 2013-11-12 2015-05-20 安集微电子科技(上海)有限公司 Photoresist stripping liquid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768532A (en) * 2010-01-29 2010-07-07 马知岗 Cleanser and preparation method thereof
CN102153139A (en) * 2010-12-28 2011-08-17 华中师范大学 Method for preparing water-soluble titanium dioxide superfine nano crystal powder
CN103060134A (en) * 2012-12-27 2013-04-24 上海艳紫化工科技有限公司 Marble cleaning agent
CN104635438A (en) * 2013-11-12 2015-05-20 安集微电子科技(上海)有限公司 Photoresist stripping liquid

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Application publication date: 20180209