CN107674718A - Reversed micelle microemulsion and preparation method thereof, reversed micelle biology oil Microemulsions For Use and preparation method thereof - Google Patents
Reversed micelle microemulsion and preparation method thereof, reversed micelle biology oil Microemulsions For Use and preparation method thereof Download PDFInfo
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- CN107674718A CN107674718A CN201610622496.5A CN201610622496A CN107674718A CN 107674718 A CN107674718 A CN 107674718A CN 201610622496 A CN201610622496 A CN 201610622496A CN 107674718 A CN107674718 A CN 107674718A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/328—Oil emulsions containing water or any other hydrophilic phase
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2250/00—Structural features of fuel components or fuel compositions, either in solid, liquid or gaseous state
- C10L2250/08—Emulsion details
- C10L2250/086—Microemulsion or nanoemulsion
Abstract
The invention discloses a kind of reversed micelle microemulsion and preparation method thereof, reversed micelle biology oil Microemulsions For Use and preparation method thereof, the reversed micelle microemulsion includes diesel oil, surfactant, cosurfactant and ethanol, content of the cosurfactant in reversed micelle microemulsion is 0.07mL/mL~0.15mL/mL, and content of the ethanol in reversed micelle microemulsion is 0~0.16mL/mL；The molal volume of surfactant and diesel oil ratio is 0.15mol~0.50mol: 1L.Reversed micelle biology oil Microemulsions For Use is prepared by reversed micelle microemulsion and bio oil.The present invention carries out solubilising and upgrading to bio oil by the reversed micelle microemulsion using diesel oil as continuous phase, and the reversed micelle biology oil Microemulsions For Use built with this is reduced the limitation that bio oil is applied to diesel engine, adds potential of the bio oil as transportation fuel.
Description
Technical field
The invention belongs to petroleum-based energy field, and in particular to a kind of reversed micelle microemulsion and preparation method thereof, reversed micelle life
Thing oil Microemulsions For Use and preparation method thereof.
Background technology
In recent years, diesel oil dosage in China's is continuously increased, and imbalance between supply and demand causes rise in oil price.In addition, diesel oil is incomplete
Pollutant caused by burning largely discharges and causes the adverse effect that can not be despised to the mankind and environment.Therefore, finding one kind can
The green energy resource of regeneration becomes more and more important as alternative fuel.
Reproducible biomass energy such as agriculture and forestry residue, aquatic and terrestrial plant grease and life and Industry Waste
Gurry can obtain liquid fuel bio oil by liquefaction.Wherein, municipal sludge, which liquefies, to form bio oil and can not only handle
Substantial amounts of sludge is put, reduces the hazardous waste and is adversely affected to caused by environment, while the energy that will can be stored again in sludge
Discharge, used in us, avoid the defects of traditional treatment method can not utilize the energy in sludge.Although sludge liquefies
Oil has the advantages of raw material abundance is easy to get, and belongs to regenerative resource, but using high viscous existing for its bio oil as Typical Representative
The problems such as degree and low temperature flow difference, limits application of the bio oil in diesel engine.
The content of the invention
The technical problems to be solved by the invention are overcome the deficiencies in the prior art, there is provided a kind of reversed micelle microemulsion and its
Preparation method, additionally provide a kind of reversed micelle biology oil Microemulsions For Use and preparation method thereof as made from the reversed micelle microemulsion.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
A kind of reversed micelle microemulsion, the reversed micelle microemulsion include diesel oil, surfactant, cosurfactant and second
Alcohol；Content of the cosurfactant in the reversed micelle microemulsion is 0.07mL/mL~0.15mL/mL；The ethanol
Content in the reversed micelle microemulsion is 0~0.16mL/mL；The molal volume ratio of the surfactant and the diesel oil
For 0.15mol~0.50mol: 1L.
In above-mentioned reversed micelle microemulsion, it is preferred that the cosurfactant containing in the reversed micelle microemulsion
Measure as 0.08mL/mL~0.12mL/mL；Content of the ethanol in the reversed micelle microemulsion be 0.10mL/mL~
0.14mL/mL；The molal volume ratio of the surfactant and the diesel oil is 0.25mol~0.35mol: 1L.
In above-mentioned reversed micelle microemulsion, it is further preferred that the cosurfactant is in the reversed micelle microemulsion
In content be 0.095mL/mL；Content of the ethanol in the reversed micelle microemulsion is 0.136mL/mL；The surface
The molal volume ratio of activating agent and the diesel oil is 0.30mol: 1L.
In above-mentioned reversed micelle microemulsion, it is preferred that the surfactant is span 20, span 40, sorbester p18 or department
Disk 80；
And/or the cosurfactant is n-octyl alcohol, n-hexyl alcohol or n-butanol.
The technical concept total as one, present invention also offers a kind of preparation method of above-mentioned reversed micelle microemulsion,
Comprise the following steps：Diesel oil, surfactant, cosurfactant and ethanol are well mixed, obtain reversed micelle microemulsion.
The technical concept total as one, present invention also offers a kind of reversed micelle biology oil Microemulsions For Use, the reversed micelle
Biological oil Microemulsions For Use is made up of reversed micelle microemulsion and bio oil；The reversed micelle microemulsion for above-mentioned reversed micelle microemulsion or
Reversed micelle microemulsion made from above-mentioned preparation method.
The technical concept total as one, present invention also offers a kind of preparation of above-mentioned reversed micelle biology oil Microemulsions For Use
Method, comprise the following steps：Bio oil is added to constant temperature oscillation in reversed micelle microemulsion, stood, is centrifuged, obtains inverse glue
Beam biology oil Microemulsions For Use.
In the preparation method of above-mentioned reversed micelle biology oil Microemulsions For Use, it is preferred that the bio oil and the reversed micelle are micro-
The volume ratio of diesel oil is 5%~20% in emulsion.
In the preparation method of above-mentioned reversed micelle biology oil Microemulsions For Use, it is further preferred that the bio oil is sludge liquid
Change bio oil, liquefaction microalgae oil or bio oil made from liquefaction of lignocellulose biomass；The liquefaction of lignocellulose biology
Bio oil made from matter is bio oil made from liquefied straw oil or liquefaction of lignocellulose class timber.
In the preparation method of above-mentioned reversed micelle biology oil Microemulsions For Use, it is preferred that the temperature of the constant temperature oscillation is 25 DEG C
~45 DEG C, rotating speed is 230rpm~290rpm, and the time is 20min~60min；
And/or the time of the standing is 20min~60min；
And/or the rotating speed of the centrifugation is 5500rpm~6500rpm, centrifugation time is 5min~7min.
Compared with prior art, the advantage of the invention is that：
1st, the invention provides a kind of reversed micelle microemulsion, including diesel oil, surfactant, cosurfactant and second
Alcohol.The present invention carries out solubilising and upgrading by the reversed micelle microemulsion using diesel oil as continuous phase to bio oil, is built with this
Reversed micelle biology oil Microemulsions For Use reduces the limitation that bio oil is applied to diesel engine, adds bio oil as transportation fuel
Potential.
2nd, in reversed micelle microemulsion of the invention, can be formed by adding surfactant between diesel oil and bio oil
One tunic, reduce diesel oil and the alternate surface tension of bio oil two, stable originally immiscible bio oil and diesel oil so that biology
Oil is stabilized in continuous phase diesel oil and occurs without lamination, solves because diesel oil belongs to non-polar oil, and bio oil
Belong to polar oil, the problem of incompatibility of mixing between them be present.The function of cosurfactant is increase polarity and non-
The elasticity of Surfactant Films between polar oil, make this film flexible, cosurfactant can also change the table of surfactant
Face activity and hydrophile-lipophile balance, the polarity of regulation system；By taking n-octyl alcohol as an example, the carbon chain length of n-octyl alcohol, from continuous phase
It is small to be transferred to the Gibbs free energy of oil-water interfaces, this advantageously forms reversed micelle microemulsion.The addition of ethanol can reduce viscous
Degree, such as biological oil viscosity are higher, and addition ethanol can reduce its viscosity, reduce the reversed micelle bio oil microemulsion fuel to engine
Cause the risk of obstruction.Ethanol can also improve low temperature flow, for example the low temperature flow of bio oil is poor, and the addition of ethanol makes
It must use the engine of the reversed micelle bio oil microemulsion fuel can normal operation in low temperature environment；Ethanol is molten as a kind of polarity
Agent, based on the similar principle that mixes, its presence also helps solubilising of the reversed micelle microemulsion for polarity bio oil.Namely
Say, ethanol while polarity phase and cosolvent as microemulsion.The presence of ethanol can not only help microemulsion solubilising more
Bio oil, and due to the relatively low viscosity of ethanol itself and pour point, its introducing can also reduce the viscosity of bio oil simultaneously, and
And improve low temperature flowability, tolerance of the increase reversed micelle biology oil Microemulsions For Use in low temperature environment.Further, since ethanol has
The higher latent heat of vaporization, it is ethanol evaporating to reduce ignition temperature, late ignition, NOx discharge is hindered, and substantial amounts of heat is due to point
Ignition delay and discharged in explosive stroke, so as to improve efficiency of combustion.
3rd, present invention also offers a kind of preparation method of reversed micelle microemulsion, this method, and there is production process to simplify, set
For the advantages that simple, cost is cheap, energy-conserving and environment-protective, without substantial amounts of chemicals is added in preparation process, also without complexity
Chemical reaction.
4th, the invention provides a kind of reversed micelle biology oil Microemulsions For Use, sludge liquid bio oil solubilising is arrived into reversed micelle micro emulsion
In liquid, the reversed micelle biology oil Microemulsions For Use of formation store at room temperature 3 months it is not stratified, also produce, have good without precipitation
Stability.Meanwhile the viscosity of reversed micelle biology oil Microemulsions For Use of the invention far below raw sewage liquefaction bio oil, and its calorific value with
Diesel oil is suitable, and pour point is lower than diesel oil.I.e. reversed micelle biology oil Microemulsions For Use of the invention has the characteristics that viscosity is low, calorific value is high, together
When relatively low pour point present its good low temperature flowability.In addition, sulfur-bearing in the reversed micelle biology oil Microemulsions For Use of the present invention
Measure as 0.0242%, carbon left 0.56%, sulfur content (0.1601%) in the bio oil that liquefied far below raw sewage and residual
Charcoal amount (6.70%), have the characteristics that sulfur content is low, carbon left is low, which increase the durable of the feature of environmental protection of bio oil and engine
Property.
5th, in reversed micelle biology oil Microemulsions For Use of the invention, sludge liquid bio oil is entered by using reversed micelle microemulsion
Row solubilising and upgrading, on the one hand, sludge liquefaction prepares the processing handling problems that bio oil solves bulky sludge, with biography
The method of system processing disposing sludge is as filled, and burning etc. is compared, and the present invention does not produce secondary pollution, is a kind of green place
Reason technology；On the other hand, sludge liquid bio oil and diesel oil are mutually mixed in diesel engine, can partly substitute bavin
Oil, reduce dependence of the people for fossil fuel.Moreover, sludge liquid bio oil is a kind of oxidizing combustible, contribute to fuel
Completely burned, capacity usage ratio is improved, reduces the discharge of pollutant.Therefore, the reversed micelle biology oil Microemulsions For Use that prepared by the present invention
It is a kind of regenerative resource for saving environmental protection again.
6th, in reversed micelle biology oil Microemulsions For Use of the invention, by sludge liquid bio oil solubilising into reversed micelle microemulsion,
Bio oil and diesel oil is mixed and made into a kind of clean energy resource, substantially reduce bio oil and the incompatibility of diesel engine, simultaneously
Microemulsified can increase sludge liquid bio oil and the being mutually dissolved property of diesel oil, reduce the risk of layering and precipitation, be formed homogeneous
Stable microemulsion fuel, meets requirement of the engine to fuel oil stability.
Embodiment
Below in conjunction with specific preferred embodiment, the invention will be further described, but not thereby limiting the invention
Protection domain.
Material and instrument employed in following examples are commercially available.
Embodiment 1：
A kind of reversed micelle microemulsion of the invention, the reversed micelle microemulsion include diesel oil, surfactant sorbester p17 and helped
Surfactant n-octyl alcohol, wherein using diesel oil as continuous phase.In the reversed micelle microemulsion of the present embodiment, surfactant sorbester p17
It is 0.15mol: 1L with diesel oil molal volume ratio, content of the cosurfactant n-octyl alcohol in reversed micelle microemulsion is
0.116mL/mL。
A kind of preparation method of the reversed micelle microemulsion of above-mentioned the present embodiment, comprises the following steps：By 3.2g surface-actives
Agent sorbester p17 and 7mL n-octyl alcohols are dissolved in 50mL diesel oil, and mixing shakes up, and obtain the reversed micelle microemulsion of clear.By institute
The reversed micelle microemulsion of preparation stands a period of time at room temperature, treats that reversed micelle microemulsion is stable, standby.
A kind of preparation method of reversed micelle biology oil Microemulsions For Use of the invention, the reversed micelle biology oil Microemulsions For Use is by above-mentioned
Reversed micelle microemulsion and sludge liquid bio oil prepared by embodiment is made, and comprises the following steps：By 10mL sludge liquid metaplasia things
Oily and above-mentioned reversed micelle microemulsion mixing manufactured in the present embodiment, is placed in 25 DEG C of waters bath with thermostatic control and vibrates 20min, oscillation rate is
230rpm (being the rotating speed in oscillatory process), stands 20min, the system for the treatment of reaches balance, is put into centrifuge after vibration
Rotating speed is to centrifuge 5min under 5500rpm.There is obvious layering in solution after centrifugation, and two layers up and down of separation, upper strata is inverse for the present invention's
Micella biology oil Microemulsions For Use, lower floor for can not solubilising enter microemulsion residual phase.
After centrifugation, the volume fraction of upper strata microemulsion phase (i.e. reversed micelle biology oil Microemulsions For Use of the invention) is 75%.
National standard GB/T 384-198 are used to measure the calorific value of reversed micelle biology oil Microemulsions For Use as 43.54MJ/kg.It is inverse made from the present embodiment
Each the performance test results are as shown in table 1 in micella biology oil Microemulsions For Use.
Embodiment 2：
A kind of reversed micelle microemulsion of the invention, the reversed micelle microemulsion include diesel oil, surfactant sorbester p17, help table
Face activating agent n-octyl alcohol and ethanol, wherein using diesel oil as continuous phase.In the reversed micelle microemulsion of the present embodiment, surfactant department
Disk 80 is 0.30mol: 1L with diesel oil molal volume ratio, and content of the cosurfactant n-octyl alcohol in reversed micelle microemulsion is
0.095mL/mL, content of the ethanol in reversed micelle microemulsion are 0.136mL/mL.
A kind of preparation method of the reversed micelle microemulsion of above-mentioned the present embodiment, comprises the following steps：By 6.4g surface-actives
Agent sorbester p17,7mL n-octyl alcohols and 10mL ethanol are dissolved in 50mL diesel oil, and mixing shakes up, and the reversed micelle for obtaining clear is micro-
Emulsion.Prepared reversed micelle microemulsion is stood into a period of time at room temperature, treats that reversed micelle microemulsion is stable, it is standby.
A kind of preparation method of reversed micelle biology oil Microemulsions For Use of the invention, the reversed micelle biology oil Microemulsions For Use is by above-mentioned
Reversed micelle microemulsion and sludge liquid bio oil prepared by embodiment is made, and comprises the following steps：By 10mL sludge liquid metaplasia things
Oily and above-mentioned reversed micelle microemulsion mixing manufactured in the present embodiment, is placed in 35 DEG C of waters bath with thermostatic control and vibrates 40min, oscillation rate is
260rpm, 40min is stood after vibration, the system for the treatment of reaches balance, is put into centrifuge and is centrifuged in the case where rotating speed is 6000rpm
6min.There is substantially layering in solution after centrifugation, and two layers up and down of separation, upper strata is reversed micelle biology oil Microemulsions For Use of the invention, under
Layer for can not solubilising enter microemulsion residual phase.
After centrifugation, the volume fraction of upper strata microemulsion phase (i.e. reversed micelle biology oil Microemulsions For Use of the invention) is 90%.
National standard GB/T 384-198 are used to measure the calorific value of reversed micelle biology oil Microemulsions For Use as 41.54MJ/kg.It is inverse made from the present embodiment
Each the performance test results are as shown in table 1 in micella biology oil Microemulsions For Use.
Embodiment 3：
A kind of reversed micelle microemulsion of the invention, the reversed micelle microemulsion include diesel oil, surfactant sorbester p17, help table
Face activating agent n-octyl alcohol and ethanol, wherein using diesel oil as continuous phase.In the reversed micelle microemulsion of the present embodiment, surfactant department
Disk 80 is 0.50mol: 1L with diesel oil molal volume ratio, and content of the cosurfactant n-octyl alcohol in reversed micelle microemulsion is
0.09mL/mL, content of the ethanol in reversed micelle microemulsion are 0.129mL/mL.
A kind of preparation method of the reversed micelle microemulsion of above-mentioned the present embodiment, comprises the following steps：By 10.7g surface-actives
Agent sorbester p17,7mL n-octyl alcohols and 10mL ethanol are dissolved in 50mL diesel oil, and mixing shakes up, and the reversed micelle for obtaining clear is micro-
Emulsion.Prepared reversed micelle microemulsion is stood into a period of time at room temperature, treats that reversed micelle microemulsion is stable, it is standby.
A kind of preparation method of reversed micelle biology oil Microemulsions For Use of the invention, the reversed micelle biology oil Microemulsions For Use is by above-mentioned
Reversed micelle microemulsion and sludge liquid bio oil prepared by embodiment is made, and comprises the following steps：By 10mL sludge liquid metaplasia things
Oily and above-mentioned reversed micelle microemulsion mixing manufactured in the present embodiment, is placed in 45 DEG C of waters bath with thermostatic control and vibrates 60min, oscillation rate is
290rpm, 60min is stood after vibration, the system for the treatment of reaches balance, is put into centrifuge and is centrifuged in the case where rotating speed is 6500rpm
7min.There is substantially layering in solution after centrifugation, and two layers up and down of separation, upper strata is reversed micelle biology oil Microemulsions For Use of the invention, under
Layer for can not solubilising enter microemulsion residual phase.
After centrifugation, the volume fraction of upper strata microemulsion phase (i.e. reversed micelle biology oil Microemulsions For Use of the invention) is 92%.
National standard GB/T 384-198 are used to measure the calorific value of reversed micelle biology oil Microemulsions For Use as 42.23MJ/kg.It is inverse made from the present embodiment
Each the performance test results are as shown in table 1 in micella biology oil Microemulsions For Use.
Reversed micelle biology oil Microemulsions For Use made from the embodiment of the present invention 1~3 of table 1 and diesel oil, each property of sludge liquid bio oil
The comparing result of energy
As shown in table 1, the viscosity of obtained reversed micelle biology oil Microemulsions For Use compares sludge liquid in the embodiment of the present invention 1~3
To change bio oil to be greatly reduced, the viscosity of wherein embodiment 2 is minimum, and closest to the viscosity of diesel oil.In the embodiment of the present invention 1~3
The calorific value of obtained reversed micelle biology oil Microemulsions For Use has a raising by a relatively large margin compared to sludge liquid bio oil, and with diesel oil
Calorific value is suitable.Ethanol is added in embodiment 2 will certainly reduce its calorific value, but its calorific value is still higher than sludge liquid bio oil
Calorific value；Compared to embodiment 1 and 3, the calorific value of embodiment 2 is slightly lower, but the range of decrease is little.It is obtained inverse in the embodiment of the present invention 1~3
The pour point of micella biology oil Microemulsions For Use reduces significantly compared to sludge liquid bio oil tool, wherein the pour point of embodiment 2
Minimum, the even below pour point of diesel oil shows that the low temperature flow of reversed micelle biology oil Microemulsions For Use made from the embodiment is preferable,
It is stronger than diesel oil to the tolerance of low temperature environment.The sulfur content phase of reversed micelle biology oil Microemulsions For Use made from the embodiment of the present invention 1~3
Having than sludge liquid bio oil significantly reduces, and the sulfur content ratio embodiment 1 of wherein embodiment 2 and 3 is small.The present invention is implemented
The carbon left of reversed micelle biology oil Microemulsions For Use made from example 1~3 also has and largely reduced compared to sludge liquid bio oil, wherein
The carbon left of embodiment 2 is minimum.In addition, reversed micelle biology oil Microemulsions For Use made from embodiment 2 and 3 has good stability, neither
Layering is also without precipitation.It can be seen that obtained each performance tool of reversed micelle biology oil Microemulsions For Use is good in the embodiment of the present invention 2.
The above described is only a preferred embodiment of the present invention, any formal limitation not is made to the present invention.Though
So the present invention is disclosed as above with preferred embodiment, but is not limited to the present invention.It is any to be familiar with those skilled in the art
Member, in the case where not departing from the Spirit Essence of the present invention and technical scheme, all using in the methods and techniques of the disclosure above
Appearance makes many possible changes and modifications to technical solution of the present invention, or is revised as the equivalent embodiment of equivalent variations.Therefore,
Every content without departing from technical solution of the present invention, the technical spirit according to the present invention is to made for any of the above embodiments any simple
Modification, equivalent substitution, equivalence changes and modification, still fall within technical solution of the present invention protection in the range of.
Claims (10)
1. a kind of reversed micelle microemulsion, it is characterised in that the reversed micelle microemulsion includes diesel oil, surfactant, helps surface
Activating agent and ethanol；Content of the cosurfactant in the reversed micelle microemulsion is 0.07mL/mL~0.15mL/
mL；Content of the ethanol in the reversed micelle microemulsion is 0~0.16mL/mL；The surfactant and the diesel oil
Molal volume ratio be 0.15mol~0.50mol: 1L.
2. reversed micelle microemulsion according to claim 1, it is characterised in that the cosurfactant is in the reversed micelle
Content in microemulsion is 0.08mL/mL~0.12mL/mL；Content of the ethanol in the reversed micelle microemulsion be
0.10mL/mL~0.14mL/mL；The molal volume ratio of the surfactant and the diesel oil is 0.25mol~0.35mol:
1L。
3. reversed micelle microemulsion according to claim 2, it is characterised in that the cosurfactant is in the reversed micelle
Content in microemulsion is 0.095mL/mL；Content of the ethanol in the reversed micelle microemulsion is 0.136mL/mL；Institute
The molal volume ratio for stating surfactant and the diesel oil is 0.30mol: 1L.
4. according to reversed micelle microemulsion according to any one of claims 1 to 3, it is characterised in that the surfactant is
Span 20, span 40, sorbester p18 or sorbester p17；
And/or the cosurfactant is n-octyl alcohol, n-hexyl alcohol or n-butanol.
It is 5. a kind of such as the preparation method of reversed micelle microemulsion according to any one of claims 1 to 4, it is characterised in that including
Following steps：Diesel oil, surfactant, cosurfactant and ethanol are well mixed, obtain reversed micelle microemulsion.
6. a kind of reversed micelle biology oil Microemulsions For Use, it is characterised in that the reversed micelle biology oil Microemulsions For Use is by reversed micelle microemulsion
It is made with bio oil；The reversed micelle microemulsion is that reversed micelle microemulsion according to any one of claims 1 to 4 or right will
Seek reversed micelle microemulsion made from the preparation method described in 5.
7. a kind of preparation method of reversed micelle biology oil Microemulsions For Use as claimed in claim 6, it is characterised in that including following step
Suddenly：Bio oil is added to constant temperature oscillation in reversed micelle microemulsion, stood, centrifuges, obtains reversed micelle biology oil Microemulsions For Use.
8. the preparation method of reversed micelle biology oil Microemulsions For Use according to claim 7, it is characterised in that the bio oil with
The volume ratio of diesel oil is 5%~20% in the reversed micelle microemulsion.
9. according to the preparation method of the reversed micelle biology oil Microemulsions For Use described in claim 8, it is characterised in that the bio oil
For bio oil made from sludge liquid bio oil, liquefaction microalgae oil or liquefaction of lignocellulose biomass；The wooden fibre of liquefaction
It is bio oil made from liquefied straw oil or liquefaction of lignocellulose class timber to tie up bio oil made from cellulosic biomass.
10. the preparation method of the reversed micelle biology oil Microemulsions For Use according to any one of claim 7~9, it is characterised in that
The temperature of the constant temperature oscillation is 25 DEG C~45 DEG C, and rotating speed is 230rpm~290rpm, and the time is 20min~60min；
And/or the time of the standing is 20min~60min；
And/or the rotating speed of the centrifugation is 5500rpm~6500rpm, centrifugation time is 5min~7min.
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|---|---|---|---|---|
| CN110702840A (en) * | 2019-10-14 | 2020-01-17 | 刘芳 | Analysis device based on energy utilization rate of carbonized urban domestic sewage biomass |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906338A (en) * | 2010-09-08 | 2010-12-08 | 浙江大学 | Environmental-friendly emulsion fuel and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906338A (en) * | 2010-09-08 | 2010-12-08 | 浙江大学 | Environmental-friendly emulsion fuel and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110702840A (en) * | 2019-10-14 | 2020-01-17 | 刘芳 | Analysis device based on energy utilization rate of carbonized urban domestic sewage biomass |
| CN110702840B (en) * | 2019-10-14 | 2022-06-07 | 河北地质大学华信学院 | Analysis device based on energy utilization rate of carbonized urban domestic sewage biomass |
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Application publication date: 20180209 |