CN107674666A - The preparation technology of heat and salinity tolerance foam discharging agent - Google Patents
The preparation technology of heat and salinity tolerance foam discharging agent Download PDFInfo
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- CN107674666A CN107674666A CN201711006660.0A CN201711006660A CN107674666A CN 107674666 A CN107674666 A CN 107674666A CN 201711006660 A CN201711006660 A CN 201711006660A CN 107674666 A CN107674666 A CN 107674666A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
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- Oil, Petroleum & Natural Gas (AREA)
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- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The invention discloses the preparation technology of heat and salinity tolerance foam discharging agent, solves the problems, such as that existing foam discharging agent can not meet that low cost, highly dissoluble, high temperature resistance, salt resistance, foaming and foam stabilizing ability significantly require simultaneously.The present invention is included N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium, dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine and neopelex are well mixed; after heating melting; are added galactomannans and be well mixed, 3 10min are incubated in whipping process, then add neopelex; natural cooling after being stirred for uniformly, the material after cooling are ground into powdery.The present invention is not only only capable of effectively reaching low cost, highly dissoluble, high temperature resistance, salt resistance, the significant effect of foaming, and foam stabilizing effect is more notable.
Description
Technical field
The present invention relates to foam discharging agent, and in particular to the preparation technology of heat and salinity tolerance foam discharging agent.
Background technology
Foam drainaging gas cutting process technology has played important function in the exploitation exploitation of water-beating gas well, not only significantly carries
The high band liquid energy power of gas, reduces wellbore effusion, moreover it is possible to extend the production time in gas well later stage, so as to improve ultimate recovery.
With the rise of environment temperature, the foamability and stability of foam discharging agent can substantially reduce, especially more than 100 DEG C
High-temperature stratum, foam can disappear within a few minutes caused by many foaming agents, not produce foam even.
During the field application of gas field, the high foam row containing oil environment in the market conventional products in the presence of gas well
Hydraulic art has a great influence so that can not form stable oil resistant foam carrier in the wellbore, and cause back pressure liter in lifting process
Height, therefore obvious foam drainage gas recovery effect can not be obtained.
And existing foam discharging agent has poor solubility property, foaming and foam stabilizing scarce capacity, or even the problem of can not bubble, no
It can meet that low cost, highly dissoluble, high temperature resistance, salt resistance, foaming and foam stabilizing ability significantly require simultaneously.
The content of the invention
The technical problems to be solved by the invention are：Foam discharging agent of the prior art can not meet low cost, Gao Rong simultaneously
Xie Xing, high temperature resistance, salt resistance, foaming and foam stabilizing ability significantly require, and it is an object of the present invention to provide it is a kind of solve the above problems it is anti-
The preparation technology of warm salt resistance foam discharging agent.
The present invention is achieved through the following technical solutions：
The preparation technology of heat and salinity tolerance foam discharging agent, including：
By N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium, dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine and
Neopelex is well mixed, and after heating melting, is added galactomannans and is well mixed, be incubated in whipping process
3-10min, neopelex is then added, natural cooling after being stirred for uniformly, the material after cooling is ground into powdery
；
Wherein, it is above-mentioned to the ratio of each component is：
N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium 3-8 parts by weight；Dodecyl-dimethyl amine second lactone 4-9 weights
Measure part；Neopelex 2-5 parts by weight；Galactomannans 1-2 parts by weight；Dodecyl dimethyl Hydroxypropyl phosphate
Fat glycine betaine 5-10 parts by weight.
By the ratio optimization of said components and technique, can effectively meet low cost, highly dissoluble, high temperature resistance, salt resistance,
Foaming significantly requires that effect is very notable with foam stabilizing ability.
Further, each component parts by weight of the invention are formed as follows：
N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium 3-5 parts by weight；Dodecyl-dimethyl amine second lactone 6-9 weights
Measure part；Neopelex 4-5 parts by weight；Galactomannans 1-2 parts by weight；Dodecyl dimethyl Hydroxypropyl phosphate
Fat glycine betaine 5-7 parts by weight.
Further, each component parts by weight of the invention are formed as follows：
N, N ', N "-parts by weight of alkyl diethylene triamine pentacetic acid (DTPA) sodium 5；The parts by weight of dodecyl-dimethyl amine second lactone 8；
The parts by weight of neopelex 5；The parts by weight of galactomannans 2；Dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine 6
Parts by weight.
By the optimization of composition and ratio, dissolubility, high temperature resistance, salt resistance, foaming and foam stabilizing ability can be made more notable, imitated
Fruit is more excellent, and by the optimization of said ratio, usage amount can be made greatly to reduce.
The present invention compared with prior art, has the following advantages and advantages：
1st, the present invention can effectively meet that low cost, highly dissoluble, high temperature resistance, salt resistance, foaming and foam stabilizing ability are significant
It is required that effect is very notable；
2nd, the present invention can make that dissolubility, high temperature resistance, salt resistance, foaming and foam stabilizing ability are more notable, and effect is more excellent,
And by the optimization of said ratio, usage amount can be made greatly to reduce.
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, with reference to embodiment, the present invention is made
Further to describe in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this
The restriction of invention.
Embodiment 1
The preparation technology of heat and salinity tolerance foam discharging agent, including：
By N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium, dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine and
Neopelex is well mixed, and after heating melting, is added galactomannans and is well mixed, be incubated in whipping process
3-10min, neopelex is then added, natural cooling after being stirred for uniformly, the material after cooling is ground into powdery
.The N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium are NDDTP.
Wherein, N, N ', N "-parts by weight of alkyl diethylene triamine pentacetic acid (DTPA) sodium 5；The weight of dodecyl-dimethyl amine second lactone 8
Measure part；The parts by weight of neopelex 5；The parts by weight of galactomannans 2；Dodecyl dimethyl Hydroxypropyl phosphate fat sweet tea
The parts by weight of dish alkali 6.
The present invention can effectively meet low cost, highly dissoluble, high temperature resistance, salt resistance, foaming and foam stabilizing by above-mentioned setting
Ability significantly requires that effect is very notable.
Embodiment 2
The present embodiment is comparative example, and the difference with embodiment 1 is, specific preparation method is different in the present embodiment,
Specific setting is as follows：
By N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium, dodecyl-dimethyl amine second lactone, detergent alkylate sulphur
Sour sodium, galactomannans, dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine are well mixed.
Embodiment 3
The present embodiment and the difference of embodiment 1 are that the proportioning of each component is different, and specific setting is as follows：
N, N ', N "-parts by weight of alkyl diethylene triamine pentacetic acid (DTPA) sodium 7；The parts by weight of dodecyl-dimethyl amine second lactone 5；
The parts by weight of neopelex 4；The parts by weight of galactomannans 1；Dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine 8
Parts by weight.
Embodiment 4
The present embodiment is comparative example, and the difference with embodiment 1 is, the present embodiment by following parts by weight component structure
Into：
N, N ', N "-parts by weight of alkyl diethylene triamine pentacetic acid (DTPA) sodium 1；The weight of dodecyl-dimethyl amine second lactone 10
Part；The parts by weight of neopelex 6；The parts by weight of galactomannans 3；Dodecyl dimethyl Hydroxypropyl phosphate fat beet
The parts by weight of alkali 3.
To finished product made of above-described embodiment in the oil field that saline formation water thereby coexists with oil (containing oil quality 0.5, containing salt quality
0.12) detected in, finished product addition is 1.25wt%, and detection foam volume V (ml), testing result is as shown in table 1.
Table 1
Compounding by the present invention is understood by above table, is not only only capable of effectively reaching low cost, highly dissoluble, anti-height
Temperature, salt resistance, the significant effect of foaming, and foam stabilizing effect is more notable.
Above-described embodiment, the purpose of the present invention, technical scheme and beneficial effect are carried out further
Describe in detail, should be understood that the embodiment that the foregoing is only the present invention, be not intended to limit the present invention
Protection domain, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc., all should include
Within protection scope of the present invention.
Claims (3)
1. the preparation technology of heat and salinity tolerance foam discharging agent, it is characterised in that including：
By N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium, dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine and 12
Sodium alkyl benzene sulfonate is well mixed, and after heating melting, is added galactomannans and is well mixed, 3- is incubated in whipping process
10min, neopelex is then added, natural cooling after being stirred for uniformly, the material after cooling is ground into powdery i.e.
Can；
Wherein, it is above-mentioned to the ratio of each component is：
N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium 3-8 parts by weight；Dodecyl-dimethyl amine second lactone 4-9 parts by weight；
Neopelex 2-5 parts by weight；Galactomannans 1-2 parts by weight；Dodecyl dimethyl Hydroxypropyl phosphate fat sweet tea
Dish alkali 5-10 parts by weight.
2. the preparation technology of heat and salinity tolerance foam discharging agent according to claim 1, it is characterised in that the ratio of each component is：
N, N ', N "-alkyl diethylene triamine pentacetic acid (DTPA) sodium 3-5 parts by weight；Dodecyl-dimethyl amine second lactone 6-9 parts by weight；
Neopelex 4-5 parts by weight；Galactomannans 1-2 parts by weight；Dodecyl dimethyl Hydroxypropyl phosphate fat sweet tea
Dish alkali 5-7 parts by weight.
3. the preparation technology of heat and salinity tolerance foam discharging agent according to claim 2, it is characterised in that by the group of following parts by weight
Divide and form：
N, N ', N "-parts by weight of alkyl diethylene triamine pentacetic acid (DTPA) sodium 5；The parts by weight of dodecyl-dimethyl amine second lactone 8；12
The parts by weight of sodium alkyl benzene sulfonate 5；The parts by weight of galactomannans 2；The weight of dodecyl dimethyl Hydroxypropyl phosphate fat glycine betaine 6
Part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711006660.0A CN107674666A (en) | 2017-10-25 | 2017-10-25 | The preparation technology of heat and salinity tolerance foam discharging agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711006660.0A CN107674666A (en) | 2017-10-25 | 2017-10-25 | The preparation technology of heat and salinity tolerance foam discharging agent |
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| Publication Number | Publication Date |
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| CN107674666A true CN107674666A (en) | 2018-02-09 |
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| CN201711006660.0A Pending CN107674666A (en) | 2017-10-25 | 2017-10-25 | The preparation technology of heat and salinity tolerance foam discharging agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679630A (en) * | 2017-10-18 | 2019-04-26 | 中国石油化工股份有限公司 | High temperature resistant acid resistant form solid foam water discharge agent and preparation method and application |
| CN116042202A (en) * | 2022-11-17 | 2023-05-02 | 成都科能石油技术有限公司 | High-mineralization-resistant and high-temperature-resistant nanoparticle foam discharging agent and preparation method thereof |
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| CN104962272A (en) * | 2015-06-10 | 2015-10-07 | 天津大港油田滨港集团博弘石油化工有限公司 | Foaming agent for tertiary oil recovery and preparation method thereof |
| CN105199700A (en) * | 2015-10-13 | 2015-12-30 | 西南石油大学 | Oligomeric betanine type foam drainage agent and preparation method |
| CN105670832A (en) * | 2014-11-17 | 2016-06-15 | 天津橙垄达环保科技开发有限公司 | Environment-friendly foam detergent |
| CN105994338A (en) * | 2016-08-03 | 2016-10-12 | 孙长恩 | Microemulsion containing epoxiconazole and iprodione |
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2017
- 2017-10-25 CN CN201711006660.0A patent/CN107674666A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105670832A (en) * | 2014-11-17 | 2016-06-15 | 天津橙垄达环保科技开发有限公司 | Environment-friendly foam detergent |
| CN104962272A (en) * | 2015-06-10 | 2015-10-07 | 天津大港油田滨港集团博弘石油化工有限公司 | Foaming agent for tertiary oil recovery and preparation method thereof |
| CN105199700A (en) * | 2015-10-13 | 2015-12-30 | 西南石油大学 | Oligomeric betanine type foam drainage agent and preparation method |
| CN105994338A (en) * | 2016-08-03 | 2016-10-12 | 孙长恩 | Microemulsion containing epoxiconazole and iprodione |
Non-Patent Citations (1)
| Title |
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| 黄秋霞，等: "起泡剂的起泡性能及使用浓度优选研究", 《精细与专用化学品》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679630A (en) * | 2017-10-18 | 2019-04-26 | 中国石油化工股份有限公司 | High temperature resistant acid resistant form solid foam water discharge agent and preparation method and application |
| CN109679630B (en) * | 2017-10-18 | 2021-05-11 | 中国石油化工股份有限公司 | High-temperature-resistant acid-resistant solid foam drainage agent, and preparation method and application thereof |
| CN116042202A (en) * | 2022-11-17 | 2023-05-02 | 成都科能石油技术有限公司 | High-mineralization-resistant and high-temperature-resistant nanoparticle foam discharging agent and preparation method thereof |
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Application publication date: 20180209 |
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