CN107674647A - A kind of detergent and preparation method - Google Patents
A kind of detergent and preparation method Download PDFInfo
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- CN107674647A CN107674647A CN201710891005.1A CN201710891005A CN107674647A CN 107674647 A CN107674647 A CN 107674647A CN 201710891005 A CN201710891005 A CN 201710891005A CN 107674647 A CN107674647 A CN 107674647A
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- solution
- detergent
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- 239000003599 detergent Substances 0.000 title claims abstract description 67
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000011159 matrix material Substances 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 19
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 14
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 14
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 14
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 14
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 10
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 69
- 239000000843 powder Substances 0.000 claims description 37
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 29
- 241000758789 Juglans Species 0.000 claims description 28
- 235000009496 Juglans regia Nutrition 0.000 claims description 28
- 235000020234 walnut Nutrition 0.000 claims description 28
- 229910052709 silver Inorganic materials 0.000 claims description 26
- 239000004332 silver Substances 0.000 claims description 26
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 25
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 14
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 14
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 10
- 230000010355 oscillation Effects 0.000 claims description 9
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 9
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 8
- 229960000583 acetic acid Drugs 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 7
- 239000012362 glacial acetic acid Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 7
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000006073 displacement reaction Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 5
- 239000012279 sodium borohydride Substances 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 239000004575 stone Substances 0.000 claims description 5
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 3
- YWNYZQTZOONLGU-UHFFFAOYSA-N C(CC)Cl.[O] Chemical compound C(CC)Cl.[O] YWNYZQTZOONLGU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 239000005046 Chlorosilane Substances 0.000 claims 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 150000002500 ions Chemical class 0.000 abstract description 11
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 10
- 238000010521 absorption reaction Methods 0.000 abstract description 8
- 239000003209 petroleum derivative Substances 0.000 abstract description 8
- 230000001699 photocatalysis Effects 0.000 abstract description 7
- 238000007146 photocatalysis Methods 0.000 abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 3
- 229930195733 hydrocarbon Natural products 0.000 abstract description 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 3
- 239000011941 photocatalyst Substances 0.000 abstract description 2
- 239000004408 titanium dioxide Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 18
- 239000003921 oil Substances 0.000 description 16
- 238000001179 sorption measurement Methods 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004904 shortening Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- -1 stir and heat 2-3h Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003305 oil spill Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Analytical Chemistry (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Public Health (AREA)
- Toxicology (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention discloses a kind of detergent and preparation method, belong to detergent technical field, the matrix of above-mentioned detergent is titanium dioxide galapectite hydrophobic porous carboxymethyl cellulose composite, and it is loaded with Nano Silver and graphene on the matrix of detergent, the present invention is by the way that physisorphtion and Photocatalyst are combined, the detergent of preparation, which can be realized, to be adsorbed and degrades to water petrochina hydrocarbon and the absorption of heavy metal ion, detergent lipophile is good, adsorbing heavy metal ions, petroleum hydrocarbon can be adsorbed and degraded under photocatalysis, light weight, petroleum hydrocarbon and heavy metal ion adsorbed capacity are big.
Description
Technical field
The invention belongs to detergent technical field, and in particular to a kind of detergent and preparation method.
Background technology
With developing rapidly for seagoing vessel transport service and offshore oil production industry, oil spilling caused by steamer oil leak and Oil spills
Pollution has turned into each marine pollution type the pollution sources that occurrence frequency highest, distribution area are most wide, the extent of injury is maximum.Not only
Existence to marine organisms has grave danger, it is also possible to a large amount of marine organisms can be caused dead or made a variation, marine environment is pacified
There is very big destructiveness entirely.Detergent be processing oil spill accident when by the floating oil of large area condense into the small oil droplet of suspension with
Accelerate dissolving, contact cotton knot of the increase oil with air, oxygen content and increase degradation speed of the bacterium to oil spilling in nominal price oil spilling, from
And prevent oil spilling diffusion from further influenceing coastline and to oily sensitive ocean or terrestrial environment, but existing detergent is present point
Scattered speed is slower, and the more problems such as degradation rate is low.
The content of the invention
Good with bond effect it is an object of the invention to provide a kind of absorption of matrix, product lipophile is good, an adsorbable huge sum of money
Belong to ion, petroleum hydrocarbon can adsorb and degraded under photocatalysis, light weight, petroleum hydrocarbon and heavy metal ion adsorbed capacity greatly one
Kind detergent and preparation method.
The technical scheme taken to achieve the above object of the present invention is：A kind of detergent, the matrix of above-mentioned detergent are
Titanium dioxide-galapectite-hydrophobic porous carboxymethyl cellulose composite, and Nano Silver and stone are loaded with the matrix of detergent
Black alkene, by the way that physisorphtion and Photocatalyst are combined, on gel rubber material carrying nano silver and graphene, raising disappear
The photocatalysis effect of finish, it can be achieved to adsorb water petrochina hydrocarbon and degrade and the absorption of heavy metal ion, the detergent of preparation
Cost is low.
A kind of preparation method of detergent, is comprised the following steps that：
1）Butyl titanate, galapectite powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol, toluene are mixed in mass ratio
Close, obtained solution A；Absolute ethyl alcohol, 0.5 ~ 1.5mol/L glacial acetic acid are mixed in mass ratio with water, obtained solution B；It is right
Solution A carries out supersonic oscillations processing at 53 ~ 57 DEG C, solution B is added drop-wise in the solution A of 2 times of quality；Simultaneously to solution A
Middle addition quality is 0.02 ~ 0.03 times of sodium bicarbonate powder of solution A and quality is solution A 0.002-0.003 times change
Property agent, after continuing 0.5 ~ 1h of stirring, be made sol solutionses；
2）Silver nitrate, graphene are added into sol solutionses and is stirred, salpeter solution is then added dropwise into sol solutionses to colloidal sol
The pH of liquid is 5, and sol solutionses are heated into 48 ~ 52 DEG C under the conditions of lucifuge and are incubated 1 ~ 2h, unreacted is washed with water to sol solutionses
After material, the 0.002-0.005 times of sodium borohydride and metatitanic acid fourth of butyl titanate quality are added into sol solutionses under agitation
The modified walnut shell powder of 0.007-0.01 times of ester quality, while sodium hydroxide solution is added dropwise and controls sol solutionses pH to be used between 7 ~ 8
It is made after water washing and carries silver sol liquid；
3）Silver sol liquid 28 ~ 40h of aging at room temperature will be carried, then adding n-hexane into load silver sol liquid carries out solvent displacement
30 ~ 60h, n-hexane is separated off, obtains carrying silver gel, with the mixed solution of organo-silicon compound and n-hexane to carrying silver gel
Hydrophobically modified is carried out, detergent is made after vacuum drying.
The present invention is using titanium dioxide-galapectite-hydrophobic porous carboxymethyl cellulose composite as matrix, and on matrix
It is loaded with Nano Silver and graphene, the galapectite in matrix is made up of countless fine tubuloses or fibrous crystal, titanium dioxide
Titanium and there is high stability, high transparency, high activity and polymolecularity, non-toxic and colour effect, hydrophobic porous methylol
Cellulose aqueous solution has the effects such as thickening, film forming, gluing, water tariff collection, colloid protection, emulsification and suspension, and three is mixed
The detergent material matrix being prepared into afterwards has very strong ageing-resistant, adsorption effect, is prepared using special ultrasonic oscillation method
Matrix, significantly increase the matrix porosity of preparation, and intensity is good, matrix has unexpected absorption and bond effect,
The matrix being prepared uploads silver and graphene, and graphene soilless sticking phenomenon makes the photocatalysis effect of detergent material significantly increase
By force, detergent is in use to Cr（Ⅳ）、Cr（Ⅲ）、As（Ⅴ）And Pb（Ⅱ）Adsorption effect it is notable, using above-mentioned side
Detergent has bactericidal action to Escherichia coli made from method.
Preferably, there is 0.1T-0.2T to being added in solution A ultrasonic oscillation processing procedure in solution A in step 1
Magnetic ball, ultrasonic power 100w-200w, solution A is handled using ultrasonic oscillation technology when preparing matrix, it is molten
Liquid A solution composition stable reactions in the presence of ultrasonic wave and the magnetic magnetic ball of tool, are obtained by magnetized and ultrasonic oscillation
Adsorption effect and bond effect to matrix are greatly improved, and are advantageous to be lifted the detergent material being finally prepared to stone
The adsorption effect of petroleum hydrocarbon and heavy metal ion.
Preferably, modifying agent is by stearic acid 2-3 parts by weight, erucyl amide 3-4 parts by weight and aluminium dihydrogen tripolyphosphate
0.2-0.4 parts by weight form, and after stirring 0.5 ~ 1h under the conditions of 76-90 DEG C, sol solutionses are made, add in the preparation process of matrix
Enter sodium bicarbonate powder and modifying agent, improve the decomposition temperature of sodium bicarbonate powder, shorten and decompose section, beneficial to shortening matrix
Preparation time, and further lift the matrix high-temperature resistant result of preparation.
Preferably, in step 1 by butyl titanate, galapectite powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol,
Toluene in mass ratio 1:0.1~0.27:0.05~0.2:20~30:0.03 ~ 0.05 is mixed, obtained solution A；By absolute ethyl alcohol,
0.5 ~ 1.5mol/L glacial acetic acid and water in mass ratio 10 ~ 15:4~6:1 is mixed, obtained solution B, using aforementioned proportion system
Standby matrix porosity is high, but intensity is also high, easily shaping, and the hole of galapectite is specific to self structure, not by
Crosslinking gained, therefore the lifting to base-material intensity has effect well, and the base-material prepared is not easy by illumination ageing in water.
Preferably, the preparation method of modified walnut shell powder is：Walnut is cleaned, pulverized and sieved after drying, in 85-100
Epoxychloropropane 3-6 parts by weight, DMF 2-4 weights are added under the conditions of DEG C into the walnut powder of 20-35 parts by weight
Part is measured, adds the pyridine of 1-2 parts by weight after heating stirring 1-1.5h, continuous heating 0.5-1h, adds the diformazans of 3-7 parts by weight
Amine aqueous solution, stir and heat 2-3h, by product successively with 0.1-0.15mol/L sodium hydroxides, 0.1-0.2mol/L hydrochloric acid, 45% ~
50% ethanol solution and deionized water are cleaned and air-dried, and obtain modified walnut powder, and amino group generation band is introduced by chemically reacting
The amine salt material of positive charge, the surface property of walnut shell powder is set to be changed into lipophile from hydrophily, modified walnut powder can be carried effectively
The lipophile and hydrophobicity of detergent prepared by height, oil absorbency and shortening action time beneficial to detergent.
Preferably, the silver nitrate of 0.04-0.1 times of butyl titanate quality, butyl titanate quality 0.02- are added in sol solutionses
0.5 times of graphene, loading nano silvery and graphene on matrix, the Nano Silver and graphene in detergent are in practice
Titanium dioxide can be coordinated further to lift the photocatalysis effect of detergent, realize detergent absorption and the photocatalytic degradation stone of preparation
The effect of petroleum hydrocarbon and absorption heavy metal ion.
Preferably, organo-silicon compound are selected from HMDO, HMDS, hexamethyl in step 3
One kind in disilazane, MTMS, trim,ethylchlorosilane, the detergent of preparation are to be used for the stone that adsorbs and degrade
Oil, it is necessary to good adsorptivity and adsorption capacity improve the adsorption effect to oil, and avoid in water suction detergent
The adsorbance of oil is have impact on, therefore hydrophobically modified is carried out to detergent in step 3.
Preferably, oleophobic modification temperature is 45 ~ 50 DEG C, modification time 24-44h in step 3, to lift detergent material
The hydrophobic and effect of oleophylic of material, is defined to said temperature and time, significantly improves the hydrophobicity and oleophylic of detergent
Property.
Compared with prior art, beneficial effects of the present invention are：The present invention is by by physisorphtion and photocatalytic degradation
Technology combines, and carrying nano silver and graphene on gel rubber material, improves the photocatalysis effect of detergent, the detergent of preparation can be real
Now water petrochina hydrocarbon is adsorbed and degraded and the absorption of heavy metal ion, modified walnut powder can effectively improve the detergent of preparation
Lipophile and hydrophobicity, detergent lipophile prepared by oil absorbency and the shortening action time present invention beneficial to detergent is good, can
Absorption heavy metal ion, can adsorb and degrade to petroleum hydrocarbon under photocatalysis, light weight, petroleum hydrocarbon and heavy metal ion adsorbed appearance
Amount is big.
Embodiment
The present invention is described in further detail with reference to embodiments：
Embodiment 1：
A kind of detergent, the matrix of above-mentioned detergent is titanium dioxide-galapectite-hydrophobic porous carboxymethyl cellulose composite wood
Material, and Nano Silver and graphene are loaded with the matrix of detergent.
A kind of preparation method of detergent, is comprised the following steps that：
1）By butyl titanate, galapectite powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol, toluene in mass ratio 1:0.15:
0.07:28:0.033 is mixed, obtained solution A；By absolute ethyl alcohol, 0.6mol/L glacial acetic acid and water in mass ratio 12:4:1
Mixed, obtained solution B；Supersonic oscillations processing is carried out at 55 DEG C to solution A, added in solution A with 0.1T
Magnetic ball, ultrasonic power 120w, solution B is added drop-wise in the solution A of 2 times of quality；It is molten to add quality into solution A simultaneously
Liquid A 0.02 ~ 0.03 times of sodium bicarbonate powder and quality is 0.0022 times of modifying agent of solution A, is stirred under the conditions of 84 DEG C
After mixing 45min, sol solutionses are made；Modifying agent is by the parts by weight of stearic acid 2, the parts by weight of erucyl amide 4 and aluminium dihydrogen tripolyphosphate
0.25 parts by weight form；
2）The silver nitrate that 0.05 times of butyl titanate quality is added in sol solutionses, 0.08 times of butyl titanate quality are added into sol solutionses
Graphene, and stir, the pH that salpeter solution is then added dropwise into sol solutionses to sol solutionses is 5, will under the conditions of lucifuge
Sol solutionses are heated to 50 DEG C and are incubated 2h, after unreacting substance is washed with water to sol solutionses, under agitation into sol solutionses
0.004 times of sodium borohydride of butyl titanate quality and 0.008 times of modified walnut shell powder of butyl titanate quality are added, is added dropwise simultaneously
Sodium hydroxide solution controls sol solutionses pH between 7.8-8.0, is made after being washed with water and carries silver sol liquid；Modified walnut shell powder
Preparation method is：Walnut is cleaned, pulverized and sieved after drying, epoxy is added into the walnut powder of 27 parts by weight under the conditions of 88 DEG C
The parts by weight of chloropropane 4, the parts by weight of DMF 3, the pyridine of 1 parts by weight is added after heating stirring 70min, persistently plus
Hot 45min, add the dimethylamine solution of 4 parts by weight, stir and heat 2h, by product successively with 0.12mol/L sodium hydroxides,
0.17mol/L hydrochloric acid, 47% ethanol solution and deionized water are cleaned and air-dried, and obtain modified walnut powder；
3）Silver sol liquid aging 34h at room temperature will be carried, then adding n-hexane into load silver sol liquid carries out solvent displacement
44h, n-hexane is separated off, obtains carrying silver gel, with the mixed solution of HMDS and n-hexane to carrying silver gel
Hydrophobically modified is carried out, oleophobic modification temperature is 48 DEG C, modification time 40h, and detergent is made after vacuum drying.
Embodiment 2：
A kind of detergent, the matrix of above-mentioned detergent is titanium dioxide-galapectite-hydrophobic porous carboxymethyl cellulose composite wood
Material, and Nano Silver and graphene are loaded with the matrix of detergent.
A kind of preparation method of detergent, is comprised the following steps that：
1）By butyl titanate, galapectite powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol, toluene in mass ratio 1:0.25:
0.11:27:0.05 is mixed, obtained solution A；By absolute ethyl alcohol, 1.2mol/L glacial acetic acid and water in mass ratio 11:5:1
Mixed, obtained solution B；Supersonic oscillations processing is carried out at 54 DEG C to solution A, added in solution A with 0.2T
Magnetic ball, ultrasonic power 150w, solution B is added drop-wise in the solution A of 2 times of quality；It is molten to add quality into solution A simultaneously
Liquid A 0.02 ~ 0.03 times of sodium bicarbonate powder and quality is 0.0024 times of modifying agent of solution A, is stirred under the conditions of 84 DEG C
After mixing 0.5h, sol solutionses are made；Modifying agent is by the parts by weight of stearic acid 3, the parts by weight of erucyl amide 3 and aluminium dihydrogen tripolyphosphate 0.24
Parts by weight form；
2）The silver nitrate that 0.08 times of butyl titanate quality is added in sol solutionses, 0.08 times of butyl titanate quality are added into sol solutionses
Graphene, and stir, the pH that salpeter solution is then added dropwise into sol solutionses to sol solutionses is 5, will under the conditions of lucifuge
Sol solutionses are heated to 51 DEG C and are incubated 1h, after unreacting substance is washed with water to sol solutionses, under agitation into sol solutionses
0.003 times of sodium borohydride of butyl titanate quality and 0.008 times of modified walnut shell powder of butyl titanate quality are added, is added dropwise simultaneously
Sodium hydroxide solution controls sol solutionses pH between 7.2-7.5, is made after being washed with water and carries silver sol liquid；Modified walnut shell powder
Preparation method is：Walnut is cleaned, pulverized and sieved after drying, epoxy is added into the walnut powder of 22 parts by weight under the conditions of 87 DEG C
The parts by weight of chloropropane 3.4, the parts by weight of DMF 4, the pyridine of 1 parts by weight is added after heating stirring 68min, continued
50min is heated, the dimethylamine solution of 4 parts by weight is added, stirs and heat 2h, product is used into 0.11mol/L hydroxides successively
Sodium, 0.14mol/L hydrochloric acid, 47% ethanol solution and deionized water are cleaned and air-dried, and obtain modified walnut powder；
3）Silver sol liquid aging 32h at room temperature will be carried, then adding n-hexane into load silver sol liquid carries out solvent displacement
45h, n-hexane is separated off, obtains carrying silver gel, with the mixed solution of HMDS and n-hexane to carrying silver gel
Hydrophobically modified is carried out, oleophobic modification temperature is 48 DEG C, modification time 40h, and detergent is made after vacuum drying.
Embodiment 3：
A kind of detergent, the matrix of above-mentioned detergent is titanium dioxide-galapectite-hydrophobic porous carboxymethyl cellulose composite wood
Material, and Nano Silver and graphene are loaded with the matrix of detergent.
A kind of preparation method of detergent, is comprised the following steps that：
1）By butyl titanate, galapectite powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol, toluene in mass ratio 1:0.17:
0.12:24:0.04 is mixed, obtained solution A；By absolute ethyl alcohol, 0.8mol/L glacial acetic acid and water in mass ratio 14:4:1
Mixed, obtained solution B；Supersonic oscillations processing is carried out at 54 DEG C to solution A, added in solution A with 0.2T
Magnetic ball, ultrasonic power 100w, solution B is added drop-wise in the solution A of 2 times of quality；It is molten to add quality into solution A simultaneously
Liquid A 0.02 ~ 0.03 times of sodium bicarbonate powder and quality is 0.003 times of modifying agent of solution A, is stirred under the conditions of 78 DEG C
After 0.6h, sol solutionses are made；Modifying agent is by the parts by weight of stearic acid 2, the parts by weight of erucyl amide 3 and the weight of aluminium dihydrogen tripolyphosphate 0.3
Measure part composition；
2）The silver nitrate that 0.05 times of butyl titanate quality is added in sol solutionses, 0.08 times of butyl titanate quality are added into sol solutionses
Graphene, and stir, the pH that salpeter solution is then added dropwise into sol solutionses to sol solutionses is 5, will under the conditions of lucifuge
Sol solutionses are heated to 48 DEG C and are incubated 1h, after unreacting substance is washed with water to sol solutionses, under agitation into sol solutionses
0.005 times of sodium borohydride of butyl titanate quality and 0.01 times of modified walnut shell powder of butyl titanate quality are added, is added dropwise simultaneously
Sodium hydroxide solution controls sol solutionses pH between 7.0-7.2, is made after being washed with water and carries silver sol liquid；Modified walnut shell powder
Preparation method is：Walnut is cleaned, pulverized and sieved after drying, ring is added into the walnut powder of 27 parts by weight under the conditions of 100 DEG C
The parts by weight of oxygen chloropropane 4, the parts by weight of DMF 4, the pyridine of 2 parts by weight is added after heating stirring 1.5h, continued
Heat 0.5h, add the dimethylamine solution of 7 parts by weight, stir and heat 2h, by product successively with 0.1mol/L sodium hydroxides,
0.18mol/L hydrochloric acid, 50% ethanol solution and deionized water are cleaned and air-dried, and obtain modified walnut powder；
3）Silver sol liquid aging 30h at room temperature will be carried, then adding n-hexane into load silver sol liquid carries out solvent displacement
35h, n-hexane is separated off, obtains carrying silver gel, it is solidifying to carrying silver with the mixed solution of MTMS and n-hexane
Glue carries out hydrophobically modified, and oleophobic modification temperature is 48 DEG C, modification time 27h, and detergent is made after vacuum drying.
The performance such as following table of detergent prepared by embodiment 1-3：
| Porosity | Specific surface area | Density | Oil suction multiplying power | Tensile strength | |
| Embodiment 1 | 94% | 537 m2/g | 3.91 Kg/m3 | 14 | 26.2Gpa |
| Embodiment 2 | 96% | 552 m2/g | 3.81 Kg/m3 | 14 | 27.0Gpa |
| Embodiment 3 | 93% | 523 m2/g | 3.76 Kg/m3 | 12 | 26.4Gpa |
Raw materials used in the present invention, equipment, it is the conventional raw material, equipment of this area unless otherwise noted；It is used in the present invention
Method, it is the conventional method of this area unless otherwise noted.
Routine operation in above-described embodiment 1-3 is well known to those skilled in the art, herein without repeating.
Technical scheme is described in detail embodiment described above, it should be understood that it is described above only
For the specific embodiment of the present invention, it is not intended to limit the invention, all any modifications made in the spirit of the present invention,
Supplement or similar fashion replacement etc., should be included in the scope of the protection.
Claims (9)
- A kind of 1. detergent, it is characterised in that：The matrix of the detergent is titanium dioxide-galapectite-hydrophobic porous carboxymethyl Cellulose composite material, and Nano Silver and graphene are loaded with the matrix of detergent.
- A kind of 2. preparation method of detergent, it is characterised in that：The preparation method is as follows：1）Butyl titanate, galapectite powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol, toluene are mixed in mass ratio Close, obtained solution A；Absolute ethyl alcohol, 0.5 ~ 1.5mol/L glacial acetic acid are mixed in mass ratio with water, obtained solution B；It is right Solution A carries out supersonic oscillations processing at 53 ~ 57 DEG C, solution B is added drop-wise in the solution A of 2 times of quality；Simultaneously to solution A Middle addition quality is 0.02 ~ 0.03 times of sodium bicarbonate powder of solution A and quality is solution A 0.002-0.003 times change Property agent, after continuing 0.5 ~ 1h of stirring, be made sol solutionses；2）Silver nitrate, graphene are added into sol solutionses and is stirred, salpeter solution is then added dropwise into sol solutionses to colloidal sol The pH of liquid is 5, and sol solutionses are heated into 48 ~ 52 DEG C under the conditions of lucifuge and are incubated 1 ~ 2h, unreacted is washed with water to sol solutionses After material, the 0.002-0.005 times of sodium borohydride and metatitanic acid fourth of butyl titanate quality are added into sol solutionses under agitation The modified walnut shell powder of 0.007-0.01 times of ester quality, while sodium hydroxide solution is added dropwise and controls sol solutionses pH to be used between 7 ~ 8 It is made after water washing and carries silver sol liquid；3）Silver sol liquid 28 ~ 40h of aging at room temperature will be carried, then adding n-hexane into load silver sol liquid carries out solvent displacement 30 ~ 60h, n-hexane is separated off, obtains carrying silver gel, with the mixed solution of organo-silicon compound and n-hexane to carrying silver gel Hydrophobically modified is carried out, detergent is made after vacuum drying.
- A kind of 3. preparation method of detergent according to claim 2, it is characterised in that：To solution A ultrasonic wave in step 1 Shake and add the magnetic ball with 0.1T-0.2T, ultrasonic power 100w-200w in processing procedure in solution A.
- A kind of 4. preparation method of detergent according to claim 2, it is characterised in that：The preparation of modified powdered sodium carbonate Method is：Modifying agent is by stearic acid 2-3 parts by weight, erucyl amide 3-4 parts by weight and aluminium dihydrogen tripolyphosphate 0.2-0.4 parts by weight Composition, after stirring 0.5 ~ 1h under the conditions of 76-90 DEG C, sol solutionses are made.
- A kind of 5. preparation method of detergent according to claim 2, it is characterised in that：In step 1 by butyl titanate, angstrom Lip river stone powder, hydrophobic porous carboxymethyl cellulose, absolute ethyl alcohol, toluene in mass ratio 1:0.1~0.27:0.05~0.2:20~30: 0.03 ~ 0.05 is mixed, obtained solution A；By absolute ethyl alcohol, 0.5 ~ 1.5mol/L glacial acetic acid and water in mass ratio 10 ~ 15: 4~6:1 is mixed, obtained solution B.
- A kind of 6. preparation method of detergent according to claim 2, it is characterised in that：The preparation side of modified walnut shell powder Method is：Walnut is cleaned, pulverized and sieved after drying, ring is added into the walnut powder of 20-35 parts by weight under the conditions of 85-100 DEG C Oxygen chloropropane 3-6 parts by weight, DMF 2-4 parts by weight, the pyrrole of 1-2 parts by weight is added after heating stirring 1-1.5h Pyridine, continuous heating 0.5-1h, the dimethylamine solution of 3-7 parts by weight is added, stirs and heats 2-3h, product is used into 0.1- successively 0.15mol/L sodium hydroxides, 0.1-0.2mol/L hydrochloric acid, 45% ~ 50% ethanol solution and deionized water are cleaned and air-dried, and must be changed Property walnut powder.
- A kind of 7. preparation method of detergent according to claim 2, it is characterised in that：Butyl titanate is added in sol solutionses The silver nitrate of 0.04-0.1 times of quality, the graphene of 0.02-0.5 times of butyl titanate quality.
- A kind of 8. preparation method of detergent according to claim 2, it is characterised in that：It is siliconated described in step 3 Compound is selected from HMDO, HMDS, HMDS, MTMS, trimethyl One kind in chlorosilane.
- A kind of 9. preparation method of detergent according to claim 2, it is characterised in that：Oleophobic is modified in the step 3 Temperature is 45 ~ 50 DEG C, modification time 24-44h.
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