CN107674268B - A kind of artificial granite line rubber floor covering and its production method - Google Patents
A kind of artificial granite line rubber floor covering and its production method Download PDFInfo
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- CN107674268B CN107674268B CN201710941258.5A CN201710941258A CN107674268B CN 107674268 B CN107674268 B CN 107674268B CN 201710941258 A CN201710941258 A CN 201710941258A CN 107674268 B CN107674268 B CN 107674268B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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Abstract
The invention discloses a kind of artificial granite line rubber floor coverings, and the advantages of granite and rubber is integrated in one, and have visual effect and physical property glittering and translucent as similar stone material, to meet the decoration demand of rubber floor covering higher standard.The present invention also provides a kind of preparation methods of artificial granite line rubber floor covering, preparation, the preparation of flower pimpled rubber and the preparation of artificial granite line rubber floor covering including primer.This method is filled with the blank in market.Directly flower particle is mixed inside sizing material, entire product is homogeneous penetrating, and upper and lower external and internal compositions are consistent, and performance is consistent.Transparent texture makes the rubber floor covering show three-dimensional stereo effect, is peerless product currently on the market.
Description
Technical field
The invention belongs to rubber floor covering technical fields, and in particular to a kind of artificial granite line rubber floor covering further relates to imitative flower
The production method of hilllock rock line rubber floor covering.
Background technique
Floor decorative material is divided into that stone material, timber floor, ceramic tile, PVC floor, rubber floor covering etc. are a variety of, and every kind of floor has
Its merits and demerits, stone material become the symbol that people show status as representative most elegant, most illustrious in pavement
Article.And in recent years with the raising of living standards of the people and quality, everybody more paid attention to it is safe and healthy, comfortably enjoy
By.Colorful rubber floor is as a kind of novel house decorative material, the features such as high-elastic with its, comfortable, wear-resisting, anti-skidding, resistant
Liked by the majority of consumers.Continuous pursuit with people to beauty, the people outside the performance requirement of rubber floor covering high-quality
Propose higher cosmetic requirement.Colourful color change cannot fully meet the aesthetic requirement of people, with
The increasingly fierceness of market competition, leads the tendency of the day that could stand in the front end of innovation, can just catch the serious hope and demand of user.
The development of a artificial granite line rubber floor covering can enjoy again rubber mass while meeting user and enjoying stone material luxury texture
That feels is comfortable, is a multi-functional floor decorative material, however there is no the presence of this product currently on the market, but
There is such demand.
Summary of the invention
The present invention solves the deficiencies in the prior art, a kind of artificial granite line rubber floor covering is provided, by granite and rubber
The advantages of be integrated in one, there is visual effect glittering and translucent as similar stone material, and it is comfortable to have rubber floor covering high-elastic wear-resistant concurrently
Physical property, to meet the decoration demand of rubber floor covering higher standard.
The present invention also provides a kind of production methods of artificial granite line rubber floor covering, are filled with the blank in market.
The technical scheme adopted by the invention is that: a kind of artificial granite line rubber floor covering, which is characterized in that by following weight
Part sizing material matches, and 60~80 parts of primer；15~35 parts of pimpled rubber of flower；
The primer is formed by the raw material proportioning of following parts by weight, 5~80 parts of butadiene-styrene rubber, 30~40 parts of natural gum, transparent
3~5 parts of zinc oxide, 3~5 parts of stearic acid, 2~4 parts of promotor, 1~2 part of anti-aging agent, 30~50 parts of transparent white carbon black, mineral are filled out
40~80 parts of material, 30~50 parts of flame-retardant mixture, 3~6 parts of sulphur and 5~10 parts of pigment；
The colored pimpled rubber is matched by following raw material, 50~80 parts of butadiene-styrene rubber, 30~40 parts of natural gum, suitable
10~20 parts of fourth glue, 3~5 parts of zinc oxide, 3~5 parts of stearic acid, 2~4 parts of promotor, 1~2 part of anti-aging agent, white carbon black 30~50
Part, 40~80 parts of mineral filler, 30~50 parts of flame-retardant mixture, 3~6 parts of sulphur and 5~10 parts of pigment.
Another technical solution of the present invention is: a kind of production method of artificial granite line rubber floor covering, including
Following steps:
The preparation of step 1, primer；
S1, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, transparent zinc oxide, stearic acid, promotor, prevent always
Agent, transparent white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；
S2, plasticate: by the butadiene-styrene rubber of above-mentioned parts by weight and natural gum investment open mill plasticate, plasticating temperature be 80~
85 DEG C, 0.8~1.5mm of roll spacing, plasticate 10~12Min, obtains first and plasticates volume；
S3, mixing: above-mentioned first is plasticated and is rolled up in investment mixer, and sequentially adds transparent oxygen in the ratio in step S1
Change zinc, stearic acid, promotor, anti-aging agent, transparent white carbon black, mineral filler and flame-retardant mixture to be kneaded, melting temperature is
100~110 DEG C, be kneaded 12~13 minutes after discharge obtain the first rubber compound, to the first rubber compound temperature be cooled to temperature 40~
After 50 DEG C, sulphur and pigment is added, bottom sheet obtains primer after mixing, and room temperature cooling parks, is spare；
The preparation of step 2, flower pimpled rubber；
S01, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, cis-butadiene cement, zinc oxide, stearic acid, promotor, prevent
Old agent, white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；
S02, it plasticates: butadiene-styrene rubber, natural gum, cis-butadiene cement the investment open mill of above-mentioned parts by weight is plasticated, temperature of plasticating
Degree is 80~85 DEG C, and 0.8~1.5mm of roll spacing, plasticate 10~12Min, obtains second and plasticates volume；
S03, mixing: above-mentioned second is plasticated and is rolled up in investment mixer, and sequentially adds oxidation in the ratio in step S01
Zinc, stearic acid, promotor, anti-aging agent, white carbon black, mineral filler, fire retardant are kneaded, and melting temperature is 100~110 DEG C,
The second rubber compound is obtained after being kneaded 12~13Min, after the second rubber compound temperature is cooled to 40~50 DEG C, sulphur and face is added
Material, after mixing bottom sheet, room temperature cooling, park, be spare；
S04, slice: being more than above-mentioned second rubber compound rolling out film for 24 hours by the storage period, calendering with a thickness of 1.0~
1.5mm, width are 1200~1300mm, and temperature is cooled to 20~25 DEG C and is crimped, and park waiting vulcanization；
S05, vulcanization: the second rubber compound that S04 is pressed is imported into drum vulcanizer and is vulcanized, sulfuration steam pressure is
0.4~0.7MPa, vulcanization time are 5~6min, and curing temperature is 140~150 DEG C；
S06, system flower: the second rubber compound vulcanizated in S05 is cut, the glue of growth 400mm* wide 200mm is cut
Item and be put into floriation maker carry out spend pimpled rubber preparation, after making flower pimpled rubber collect it is spare；
The preparation of step 3, artificial granite line rubber floor covering；
S001, mixed flower: the primer prepared is parked and weighs a certain amount of be put into open mill afterwards for 24 hours and carries out heat refining, is controlled
Rod temperature is 60~80 DEG C, and a certain proportion of colored pimpled rubber is added in the primer of heat refining, mixing heat refining is carried out, mix heat refining 10~
Bottom sheet after 12Min, obtains blend glue stuff；
S002, slice: the blend glue stuff in S001 is subjected to equivalent slice according to mold size, obtains sheet material film；
S003, vulcanization: the sheet material film in S002 is fitted into 800T electric heating vulcanizer and is vulcanized, sulfide stress is
16~19MPa, vulcanization time are 10~12min, and curing temperature is 140~150 DEG C；
S004, the sheet material film vulcanizated cool down, polishes, cut, cleaning, examining, packing, that is, the hilllock Fang Hua is made
Rock line rubber floor covering.
Compared to the prior art, the invention has the benefit that
1, present invention employs the materials of transparent material, and product to be made to have certain transparency, therefore after flower particle is added
It can see that the rubber floor covering similar to the glittering and translucent effect as stone material, not only realizes the apparent visual effect of stone material from inside to outside
Fruit, but also the soft comfortable with rubber floor covering, functional and dicoration is combined together, make flooring decorated style and
Taste greatly promotes.
2, directly flower particle is mixed inside sizing material, entire product is homogeneous penetrating, and upper and lower external and internal compositions are consistent, performance one
It causes.Transparent texture makes the rubber floor covering show three-dimensional stereo effect, and market prospects are very considerable.
Detailed description of the invention
Fig. 1 is the photo of artificial granite line rubber floor covering obtained by the embodiment of the present invention 1.
Specific embodiment
The following describes the present invention in detail with reference to the accompanying drawings and specific embodiments.
A kind of artificial granite line rubber floor covering, is matched by following part by weight size, and 60~80 parts of primer；Flower pimpled rubber
15~35 parts；
Primer is formed by the raw material proportioning of following parts by weight, 5~80 parts of butadiene-styrene rubber, 30~40 parts of natural gum, transparent Indium
3~5 parts of zinc, 3~5 parts of stearic acid, 2~4 parts of promotor, 1~2 part of anti-aging agent, 30~50 parts of transparent white carbon black, mineral filler 40
~80 parts, 30~50 parts of flame-retardant mixture, 3~6 parts of sulphur and 5~10 parts of pigment；
Flower pimpled rubber is matched by following raw material, 50~80 parts of butadiene-styrene rubber, 30~40 parts of natural gum, cis-butadiene cement
10~20 parts, 3~5 parts of zinc oxide, 3~5 parts of stearic acid, 2~4 parts of promotor, 1~2 part of anti-aging agent, 30~50 parts of white carbon black,
40~80 parts of mineral filler, 30~50 parts of flame-retardant mixture, 3~6 parts of sulphur and 5~10 parts of pigment.
The promotor that primer and flower pimpled rubber contain is that sulfenamide type accelerators and dithiocarbamates promote
Agent composition, and amount ratio is 3:2, mineral filler is clay, and fire retardant is inorganic fire retardants and zinc borate, pigment be it is inorganic or
The serial pigments such as organic pigment, specially carbon black, phthalocyanine blue, dark green, everbright fast yellow, permanent bordeaux, iron oxide red, titanium white powder pigment.
Embodiment 1
A kind of artificial granite line rubber floor covering, is matched by following part by weight size, and 75 parts of primer；Flower pimpled rubber 18
Part；
Primer is formed by the raw material proportioning of following parts by weight, 45 parts of butadiene-styrene rubber, 38 parts of natural gum, 4 parts of transparent zinc oxide, hard
4 parts of resin acid, 3 parts of promotor, 1.5 parts of anti-aging agent, 38 parts of transparent white carbon black, 65 parts of mineral filler, 45 parts of flame-retardant mixture, sulphur
5 parts and 9 parts of pigment；
Flower pimpled rubber is matched by following raw material, 65 parts of butadiene-styrene rubber, 38 parts of natural gum, 18 parts of cis-butadiene cement, oxygen
Change 3.8 parts of zinc, 4.2 parts of stearic acid, 3 parts of promotor, 1.5 parts of anti-aging agent, 45 parts of white carbon black, 70 parts of mineral filler, fire-retardant mixing
45 parts of object, 4 parts of sulphur and 6 parts of pigment.
It is produced using following methods:
The preparation of step 1, primer；
S1, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, transparent zinc oxide, stearic acid, promotor, prevent always
Agent, transparent white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；S2, it plasticates: by the butadiene-styrene rubber and day of above-mentioned parts by weight
Right glue investment open mill is plasticated, and plasticating temperature is 83 DEG C, and roll spacing 1.2mm, plasticate 11Min, is obtained first and is plasticated volume；S3,
It is kneaded: above-mentioned first being plasticated and is rolled up in investment mixer, and sequentially adds transparent zinc oxide, tristearin in the ratio in step S1
Acid, promotor, anti-aging agent, transparent white carbon black, mineral filler and flame-retardant mixture are kneaded, and melting temperature is 108 DEG C, are kneaded
Discharge obtains the first rubber compound after 12.2Min, and after the first rubber compound temperature is cooled to 46 DEG C of temperature, sulphur and pigment is added,
Bottom sheet obtains primer after mixing, and room temperature cooling parks, is spare；
The preparation of step 2, flower pimpled rubber；
S01, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, cis-butadiene cement, zinc oxide, stearic acid, promotor, prevent
Old agent, white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；S02, it plasticates: by the butadiene-styrene rubber of above-mentioned parts by weight, naturally
Glue, cis-butadiene cement investment open mill are plasticated, and plasticating temperature is 83 DEG C, and roll spacing 1.2mm, plasticate 11Min, obtains second and plasticates
Volume；S03, mixing: above-mentioned second is plasticated in volume investment mixer, and sequentially adds zinc oxide, hard in the ratio in step S01
Resin acid, promotor, anti-aging agent, white carbon black, mineral filler, fire retardant are kneaded, and melting temperature is 108 DEG C, are kneaded 12.5Min
After obtain the second rubber compound, after the second rubber compound temperature is cooled to 46 DEG C, sulphur and pigment is added, after mixing bottom sheet,
Room temperature cooling parks, is spare；S04, slice: by the storage period more than above-mentioned second rubber compound rolling out film for 24 hours, calendering is thick
Spending is 1.2mm, width 1250mm, and temperature is cooled to 23 DEG C and is crimped, and parks waiting vulcanization；S05, vulcanization: S04 is pressed
The second rubber compound import drum vulcanizer vulcanized, sulfuration steam pressure be 0.5MPa, vulcanization time 5.4min, vulcanization
Temperature is 142 DEG C；S06, system flower: the second rubber compound vulcanizated in S05 is cut, and cuts growth 400mm* wide 200mm
Adhesive tape and be put into floriation maker carry out spend pimpled rubber preparation, after making flower pimpled rubber collect it is spare；
The preparation of step 3, artificial granite line rubber floor covering；
S001, mixed flower: the primer prepared is parked and weighs a certain amount of be put into open mill afterwards for 24 hours and carries out heat refining, is controlled
Rod temperature is 72 DEG C, and a certain proportion of colored pimpled rubber is added in the primer of heat refining, mixing heat refining is carried out, mixes heat refining 11.5Min
Bottom sheet afterwards obtains blend glue stuff；S002, slice: the blend glue stuff in S001 is subjected to equivalent slice according to mold size, is obtained
Sheet material film；S003, vulcanization: the sheet material film in S002 being fitted into 800T electric heating vulcanizer and is vulcanized, sulfide stress
For 17MPa, vulcanization time 10.5min, curing temperature is 142 DEG C；S004, the sheet material film vulcanizated is subjected to cooling, is beaten
It grinds, cut, clean, examine, pack, that is, artificial granite line rubber floor covering is made.
By the embodiment 1 prepare artificial granite line rubber floor covering have excellent performance, exquisite appearance, three-dimensional stereo effect compared with
It is obvious.Physical mechanical property testing result is as follows:
Embodiment 2
A kind of artificial granite line rubber floor covering, is matched by following part by weight size, and 65 parts of primer；Flower pimpled rubber 20
Part；
Primer is formed by the raw material proportioning of following parts by weight, 35 parts of butadiene-styrene rubber, 37 parts of natural gum, 4.2 parts of transparent zinc oxide,
3.3 parts of stearic acid, 3.5 parts of promotor, 1.6 parts of anti-aging agent, 46 parts of transparent white carbon black, 52 parts of mineral filler, flame-retardant mixture 49
Part, 5 parts of sulphur and 9 parts of pigment；
Flower pimpled rubber is matched by following raw material, 72 parts of butadiene-styrene rubber, 38 parts of natural gum, 17 parts of cis-butadiene cement, oxygen
Change 4.5 parts of zinc, 3.6 parts of stearic acid, 3.5 parts of promotor, 1.2 parts of anti-aging agent, 46 parts of white carbon black, 53 parts of mineral filler, fire-retardant mixed
39 parts of object of conjunction, 4.6 parts of sulphur and 7.8 parts of pigment.
It is prepared using following methods:
The preparation of step 1, primer；
S1, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, transparent zinc oxide, stearic acid, promotor, prevent always
Agent, transparent white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；S2, it plasticates: by the butadiene-styrene rubber and day of above-mentioned parts by weight
Right glue investment open mill is plasticated, and plasticating temperature is 83 DEG C, and roll spacing 1.4mm, plasticate 11.6Min, is obtained first and is plasticated volume；
S3, mixing: above-mentioned first is plasticated in volume investment mixer, and sequentially adds transparent zinc oxide, hard in the ratio in step S1
Resin acid, promotor, anti-aging agent, transparent white carbon black, mineral filler and flame-retardant mixture are kneaded, and melting temperature is 107 DEG C, are mixed
Discharge obtains the first rubber compound after refining 12.7 minutes, and after the first rubber compound temperature is cooled to 44 DEG C of temperature, sulphur and face is added
Material, bottom sheet obtains primer after mixing, and room temperature cooling parks, is spare；
The preparation of step 2, flower pimpled rubber；
S01, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, cis-butadiene cement, zinc oxide, stearic acid, promotor, prevent
Old agent, white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；S02, it plasticates: by the butadiene-styrene rubber of above-mentioned parts by weight, naturally
Glue, cis-butadiene cement investment open mill are plasticated, and plasticating temperature is 83 DEG C, and roll spacing 1.3mm, plasticate 11.6Min, obtains second and plasticates
Volume；S03, mixing: above-mentioned second is plasticated in volume investment mixer, and sequentially adds zinc oxide, hard in the ratio in step S01
Resin acid, promotor, anti-aging agent, white carbon black, mineral filler, fire retardant are kneaded, and melting temperature is 107 DEG C, are kneaded 12.3Min
After obtain the second rubber compound, after the second rubber compound temperature is cooled to 47 DEG C, sulphur and pigment is added, after mixing bottom sheet,
Room temperature cooling parks, is spare；S04, slice: by the storage period more than above-mentioned second rubber compound rolling out film for 24 hours, calendering is thick
Spending is 1.4mm, width 1280mm, and temperature is cooled to 23 DEG C and is crimped, and parks waiting vulcanization；S05, vulcanization: S04 is pressed
The second rubber compound import drum vulcanizer vulcanized, sulfuration steam pressure be 0.6MPa, vulcanization time 5.7min, vulcanization
Temperature is 147 DEG C；S06, system flower: the second rubber compound vulcanizated in S05 is cut, and cuts growth 400mm* wide 200mm
Adhesive tape and be put into floriation maker and smash, obtain spending particle.S07, flower particle addition buffing machine is subjected to mill pressure, adjusts buffing machine
It is spare that distance collects flower pimpled rubber collection.
The preparation of step 3, artificial granite line rubber floor covering；
S001, mixed flower: the primer prepared is parked and weighs a certain amount of be put into open mill afterwards for 24 hours and carries out heat refining, is controlled
Rod temperature is 77 DEG C, and a certain proportion of colored pimpled rubber is added in the primer of heat refining, mixing heat refining is carried out, mixes heat refining 11.3Min
Bottom sheet afterwards obtains blend glue stuff；S002, slice: the blend glue stuff in S001 is subjected to equivalent slice according to mold size, is obtained
Sheet material film；S003, vulcanization: the sheet material film in S002 being fitted into 800T electric heating vulcanizer and is vulcanized, sulfide stress
For 18MPa, vulcanization time 11.4min, curing temperature is 147 DEG C；S004, the sheet material film vulcanizated is subjected to cooling, is beaten
It grinds, cut, clean, examine, pack, that is, artificial granite line rubber floor covering is made.
The artificial granite line rubber floor covering physical mechanical property testing result prepared by the embodiment 2 is as follows:
Embodiment 3
A kind of artificial granite line rubber floor covering, is matched by following part by weight size, and 78 parts of primer；Flower pimpled rubber 30
Part；
Primer is formed by the raw material proportioning of following parts by weight, 68 parts of butadiene-styrene rubber, 38 parts of natural gum, 3.6 parts of transparent zinc oxide,
3.3 parts of stearic acid, 2.8 parts of promotor, 1.8 parts of anti-aging agent, 39 parts of transparent white carbon black, 58 parts of mineral filler, flame-retardant mixture 48
Part, 5.5 parts of sulphur and 7 parts of pigment；
Flower pimpled rubber is matched by following raw material, 77 parts of butadiene-styrene rubber, 39 parts of natural gum, 14 parts of cis-butadiene cement, oxygen
Change 4.2 parts of zinc, 3.9 parts of stearic acid, 2.8 parts of promotor, 1.6 parts of anti-aging agent, 36 parts of white carbon black, 68 parts of mineral filler, fire-retardant mixed
45 parts of object of conjunction, 5.2 parts of sulphur and 6.8 parts of pigment.
It is prepared using following methods:
The preparation of step 1, primer；
S1, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, transparent zinc oxide, stearic acid, promotor, prevent always
Agent, transparent white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；S2, it plasticates: by the butadiene-styrene rubber and day of above-mentioned parts by weight
Right glue investment open mill is plasticated, and plasticating temperature is 81 DEG C, and roll spacing 0.9mm, plasticate 11.4Min, is obtained first and is plasticated volume；
S3, mixing: above-mentioned first is plasticated in volume investment mixer, and sequentially adds transparent zinc oxide, hard in the ratio in step S1
Resin acid, promotor, anti-aging agent, transparent white carbon black, mineral filler and flame-retardant mixture are kneaded, and melting temperature is 101 DEG C, are mixed
Discharge obtains the first rubber compound after refining 12.7 minutes, and after the first rubber compound temperature is cooled to 41 DEG C of temperature, sulphur and face is added
Material, bottom sheet obtains primer after mixing, and room temperature cooling parks, is spare；
The preparation of step 2, flower pimpled rubber；
S01, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, cis-butadiene cement, zinc oxide, stearic acid, promotor, prevent
Old agent, white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；S02, it plasticates: by the butadiene-styrene rubber of above-mentioned parts by weight, naturally
Glue, cis-butadiene cement investment open mill are plasticated, and plasticating temperature is 81 DEG C, and roll spacing 1.0mm, plasticate 10.8Min, obtains second and plasticates
Volume；S03, mixing: above-mentioned second is plasticated in volume investment mixer, and sequentially adds zinc oxide, hard in the ratio in step S01
Resin acid, promotor, anti-aging agent, white carbon black, mineral filler, fire retardant are kneaded, and melting temperature is 106 DEG C, are kneaded 12.3Min
After obtain the second rubber compound, after the second rubber compound temperature is cooled to 42 DEG C, sulphur and pigment is added, after mixing bottom sheet,
Room temperature cooling parks, is spare；S04, slice: by the storage period more than above-mentioned second rubber compound rolling out film for 24 hours, calendering is thick
Spending is 1.1mm, width 1255mm, and temperature is cooled to 21 DEG C and is crimped, and parks waiting vulcanization；S05, vulcanization: S04 is pressed
The second rubber compound import drum vulcanizer vulcanized, sulfuration steam pressure be 0.65MPa, vulcanization time 5.9min, sulphur
Changing temperature is 148 DEG C；S06, system flower: the second rubber compound vulcanizated in S05 is cut, and cuts growth 400mm* wide
The adhesive tape of 200mm and be put into floriation maker carry out spend pimpled rubber preparation, after making flower pimpled rubber collect it is spare；
The preparation of step 3, artificial granite line rubber floor covering；
S001, mixed flower: the primer prepared is parked and weighs a certain amount of be put into open mill afterwards for 24 hours and carries out heat refining, is controlled
Rod temperature is 73 DEG C, and a certain proportion of colored pimpled rubber is added in the primer of heat refining, mixing heat refining is carried out, mixes heat refining 10.3Min
Bottom sheet afterwards obtains blend glue stuff；S002, slice: the blend glue stuff in S001 is subjected to equivalent slice according to mold size, is obtained
Sheet material film；S003, vulcanization: the sheet material film in S002 being fitted into 800T electric heating vulcanizer and is vulcanized, sulfide stress
For 16.8MPa, vulcanization time 10.3min, curing temperature is 149 DEG C；S004, by the sheet material film vulcanizated carry out it is cooling,
It polishes, cut, clean, examine, pack, that is, artificial granite line rubber floor covering is made.
The artificial granite line rubber floor covering physical mechanical property testing result prepared by the embodiment 3 is as follows:
Above-described embodiment, only presently preferred embodiments of the present invention, the practical range being not intended to limit the invention, thus it is all with
The equivalent variations that content described in the claims in the present invention is done should all be included within scope of the invention as claimed.
Claims (2)
1. a kind of artificial granite line rubber floor covering, which is characterized in that matched by following part by weight size, primer 60~80
Part；15~35 parts of pimpled rubber of flower；
The primer is formed by the raw material proportioning of following parts by weight, 5~80 parts of butadiene-styrene rubber, 30~40 parts of natural gum, transparent Indium
3~5 parts of zinc, 3~5 parts of stearic acid, 2~4 parts of promotor, 1~2 part of anti-aging agent, 30~50 parts of transparent white carbon black, mineral filler 40
~80 parts, 30~50 parts of flame-retardant mixture, 3~6 parts of sulphur and 5~10 parts of pigment；
The colored pimpled rubber is matched by following raw material, 50~80 parts of butadiene-styrene rubber, 30~40 parts of natural gum, cis-butadiene cement
10~20 parts, 3~5 parts of zinc oxide, 3~5 parts of stearic acid, 2~4 parts of promotor, 1~2 part of anti-aging agent, 30~50 parts of white carbon black,
40~80 parts of mineral filler, 30~50 parts of flame-retardant mixture, 3~6 parts of sulphur and 5~10 parts of pigment.
2. a kind of production method of artificial granite line rubber floor covering described in claim 1, which is characterized in that including following step
It is rapid:
The preparation of step 1, primer；
S1, stock: the butadiene-styrene rubbers of the parts by weight, natural gum, transparent zinc oxide, stearic acid, promotor, anti-aging agent, thoroughly are weighed
Understand carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；
S2, it plasticates: the butadiene-styrene rubber of above-mentioned parts by weight and natural gum investment open mill being plasticated, plasticating temperature is 80~85
DEG C, 0.8~1.5mm of roll spacing, plasticate 10~12Min, obtains first and plasticates volume；
S3, mixing: above-mentioned first is plasticated and is rolled up in investment mixer, and sequentially adds transparent Indium in the ratio in step S1
Zinc, stearic acid, promotor, anti-aging agent, transparent white carbon black, mineral filler and flame-retardant mixture are kneaded, melting temperature 100
~110 DEG C, discharge obtains the first rubber compound after being kneaded 12~13 minutes, is cooled to 40~50 DEG C of temperature to the first rubber compound temperature
Afterwards, sulphur and pigment is added, bottom sheet obtains primer after mixing, and room temperature cooling parks, is spare；
The preparation of step 2, flower pimpled rubber；
S01, stock: it weighs the butadiene-styrene rubber of the parts by weight, natural gum, cis-butadiene cement, zinc oxide, stearic acid, promotor, prevent always
Agent, white carbon black, mineral filler, flame-retardant mixture, sulphur and pigment；
S02, it plasticates: butadiene-styrene rubber, natural gum, cis-butadiene cement the investment open mill of above-mentioned parts by weight being plasticated, plasticating temperature is
80~85 DEG C, 0.8~1.5mm of roll spacing, plasticate 10~12Min, obtains second and plasticates volume；
S03, mixing: by above-mentioned second plasticate volume investment mixer in, and in the ratio in step S01 sequentially add zinc oxide,
Stearic acid, promotor, anti-aging agent, white carbon black, mineral filler, fire retardant are kneaded, and melting temperature is 100~110 DEG C, are kneaded
The second rubber compound is obtained after 12~13Min, and after the second rubber compound temperature is cooled to 40~50 DEG C, sulphur and pigment is added, mixes
Uniform rear bottom sheet is closed, room temperature cooling, parks, is spare；
S04, slice: by the storage period more than above-mentioned second rubber compound rolling out film for 24 hours, rolling with a thickness of 1.0~1.5mm,
Width is 1200~1300mm, and temperature is cooled to 20~25 DEG C and is crimped, and parks waiting vulcanization；
S05, vulcanization: importing drum vulcanizer for the second rubber compound that S04 is pressed and vulcanize, and sulfuration steam pressure is 0.4~
0.7MPa, vulcanization time are 5~6min, and curing temperature is 140~150 DEG C；
S06, system flower: the second rubber compound vulcanizated in S05 is cut, and cuts the adhesive tape of growth 400mm* wide 200mm simultaneously
It is put into floriation maker to carry out spending pimpled rubber preparation, flower pimpled rubber is collected spare after making；
The preparation of step 3, artificial granite line rubber floor covering；
S001, mixed flower: the primer prepared is parked and weighs a certain amount of be put into open mill afterwards for 24 hours and carries out heat refining, controls rod temperature
Be 60~80 DEG C, a certain proportion of colored pimpled rubber be added in the primer of heat refining, mixing heat refining is carried out, mix heat refining 10~
Bottom sheet after 12Min, obtains blend glue stuff；
S002, slice: the blend glue stuff in S001 is subjected to equivalent slice according to mold size, obtains sheet material film；
S003, vulcanization: the sheet material film in S002 being fitted into 800T electric heating vulcanizer and is vulcanized, sulfide stress be 16~
19MPa, vulcanization time are 10~12min, and curing temperature is 140~150 DEG C；
S004, the sheet material film vulcanizated cool down, polishes, cut, cleaning, examining, packing, that is, artificial granite line is made
Rubber floor covering.
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| CN111560129A (en) * | 2019-02-14 | 2020-08-21 | 上海加富新材料科技有限公司 | Rubber floor with surface printing and preparation process thereof |
| CN113773563A (en) * | 2021-08-24 | 2021-12-10 | 北京圣特华科橡胶有限公司 | Preparation method of rubber floor containing sericin particles and rubber floor |
| CN113665200A (en) * | 2021-08-24 | 2021-11-19 | 北京圣特华科橡胶有限公司 | Conductive rubber floor and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138653A (en) * | 1995-12-31 | 1996-12-25 | 霍跻永 | Elastic rubber floor brick and manufacturing method thereof |
| CN101112782A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Method for making rubber floor tile |
| CN101260205A (en) * | 2008-04-21 | 2008-09-10 | 兰斯登（福建）科技建材有限公司 | Rubber floor capable of releasing negative oxygen ion and manufacturing method thereof |
| CN104805995A (en) * | 2015-04-27 | 2015-07-29 | 安徽美祥实业有限公司 | Production process of rubber floorboard |
| CN105860355A (en) * | 2016-05-06 | 2016-08-17 | 江苏润大橡塑材料有限公司 | High-speed rail high-flame retardant and high-weather resistant rubber floor and preparation method thereof |
| CN107057133A (en) * | 2017-05-27 | 2017-08-18 | 南京东润特种橡塑有限公司 | A kind of fiber reinforced graphite rubber plate and its preparation technology |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3267187A (en) * | 1963-10-10 | 1966-08-16 | American Biltrite Rubber Co | Textured sheet material |
-
2017
- 2017-10-11 CN CN201710941258.5A patent/CN107674268B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138653A (en) * | 1995-12-31 | 1996-12-25 | 霍跻永 | Elastic rubber floor brick and manufacturing method thereof |
| CN101112782A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Method for making rubber floor tile |
| CN101260205A (en) * | 2008-04-21 | 2008-09-10 | 兰斯登（福建）科技建材有限公司 | Rubber floor capable of releasing negative oxygen ion and manufacturing method thereof |
| CN104805995A (en) * | 2015-04-27 | 2015-07-29 | 安徽美祥实业有限公司 | Production process of rubber floorboard |
| CN105860355A (en) * | 2016-05-06 | 2016-08-17 | 江苏润大橡塑材料有限公司 | High-speed rail high-flame retardant and high-weather resistant rubber floor and preparation method thereof |
| CN107057133A (en) * | 2017-05-27 | 2017-08-18 | 南京东润特种橡塑有限公司 | A kind of fiber reinforced graphite rubber plate and its preparation technology |
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