CN107673634A - A kind of glass-fiber reinforced size - Google Patents
A kind of glass-fiber reinforced size Download PDFInfo
- Publication number
- CN107673634A CN107673634A CN201711046031.0A CN201711046031A CN107673634A CN 107673634 A CN107673634 A CN 107673634A CN 201711046031 A CN201711046031 A CN 201711046031A CN 107673634 A CN107673634 A CN 107673634A
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- CN
- China
- Prior art keywords
- parts
- glass
- fiber reinforced
- water
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/36—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention discloses a kind of glass-fiber reinforced size, is made up of by weight the following raw material：20 30 parts of epoxy resin, 20 30 parts of polyvinyl acetate, 10 20 parts of acrylic acid ester emulsion, 58 parts of linseed oil, 35 parts of coupling agent, 0.5 2 parts of lubricant, 0.5 1 parts of preservative, 0.1 0.5 parts of organotin germicide, 0.3 0.5 parts of defoamer, 60 80 parts of water.The present invention can improve the physicochemical property of glass fibre electronic textile yarn comprehensively, and for stiffness between 50 80, tensile strength reaches more than 52CN/TEX, effectively solve the problems, such as the fracture of wire, the fluffing that occur in fabrication processes.
Description
Technical field
The present invention relates to glass fibre production technology, specifically a kind of glass-fiber reinforced size.
Background technology
Glass fibre is dispersed in the alcohol of water or water, ester solution medium, and then be used to produce glassfiber insulation bag
It is contour that package material, glass mat, particularly glass fibre mix manufacture galss fiber reinforced resin with macromolecule resin fiber
Strength-Glass-Fibre composite is a key areas of modem fibreglass application, there is wide market prospects and development
Prospect.
Currently used water dispersible glass-fiber reinforced size mostly using amine or alcohols single compound or
Dispersant is used as using the mixture of nonionic or cationic surface active agent.It is disadvantageous in that existing for it：It is difficult to basis
Industrial actual conditions are adjusted, and can not meet to disperse all kinds of variety classeses, the glass fibre or glass of chemical composition
Fiber different dispersion is actually needed.
The size in the conventional glass fibre field is mostly using urea as NMF, and heat endurance is poor, under high temperature
Peculiar smell is easily produced, has had a strong impact on the use of glass fibre, and easily causes environmental pollution, Application No.
CN201010252613.6 discloses a kind of glass fiber lubricant, is made up of two kinds of different nitrogen-containing surfactants scattered
Agent, birdsed of the same feather flock together the protective agent that compound forms by one or more polyhydroxy or oxo-alcohols, ester, acyl, be made up of polyol blends
The conventional zirconium class coupling agent of humectant, lubricant, fiber glass industry, remainder are distilled water or deionized water, the size
It is scattered aqueous medium suitable for various alkali-frees, medium-alkali glass fibre, glass dispersion after this product processing can it is good,
Heat endurance is good and pollution-free, but this kind of size wellability is poor, and enhancing effect is poor, and production cost is higher.
The content of the invention
The invention provides a kind of glass-fiber reinforced size, to solve above-mentioned technical problem.
A kind of glass-fiber reinforced size, it is made up of by weight the following raw material：
Epoxy resin 20-30 parts, polyvinyl acetate 20-30 parts, acrylic acid ester emulsion 10-20 parts, linseed oil 5-8 parts,
Coupling agent 3-5 parts, lubricant 0.5-2 parts, preservative 0.5-1 parts, organotin germicide 0.1-0.5 parts, defoamer 0.3-0.5
Part, water 60-80 parts.
Preferably, a kind of glass-fiber reinforced size, it is made up of by weight the following raw material：20 parts of epoxy resin,
20 parts of polyvinyl acetate, 10 parts of acrylic acid ester emulsion, 5 parts of linseed oil, 3 parts of coupling agent, 0.5 part of lubricant, preservative 0.5
Part, 0.1 part of organotin germicide, 0.3 part of defoamer, 60 parts of water.
Preferably, a kind of glass-fiber reinforced size, it is made up of by weight the following raw material：25 parts of epoxy resin,
25 parts of polyvinyl acetate, 15 parts of acrylic acid ester emulsion, 6.5 parts of linseed oil, 4 parts of coupling agent, 1.3 parts of lubricant, preservative 0.8
Part, 0.3 part of organotin germicide, 0.4 part of defoamer, 70 parts of water.
Preferably, a kind of glass-fiber reinforced size, it is made up of by weight the following raw material：30 parts of epoxy resin,
30 parts of polyvinyl acetate, 20 parts of acrylic acid ester emulsion, 8 parts of linseed oil, 5 parts of coupling agent, 2 parts of lubricant, 1 part of preservative, have
0.5 part of machine tin bactericide, 0.5 part of defoamer, 80 parts of water.
Preferably, the farina is high straight chain farina, and the cornstarch is cross-linked corn starch.
Beneficial effects of the present invention：
The present invention can improve the physicochemical property of glass fibre electronic textile yarn comprehensively, and stiffness is between 50-80, tension
Intensity reaches more than 52CN/TEX, effectively solves the problems, such as the fracture of wire, the fluffing that occur in fabrication processes.
Embodiment
Embodiments of the invention are described in detail below, but what the present invention can be defined by the claims and cover
Multitude of different ways is implemented.
Below by way of specific embodiment, the present invention will be described in detail.
The technical scheme that the present invention is embodied is：
Embodiment 1
A kind of glass-fiber reinforced size, it is made up of by weight the following raw material：20 parts of epoxy resin, poly-vinegar acid second
20 parts of alkene ester, 10 parts of acrylic acid ester emulsion, 5 parts of linseed oil, 3 parts of coupling agent, 0.5 part of lubricant, 0.5 part of preservative, organotin
0.1 part of bactericide, 0.3 part of defoamer, 60 parts of water；
Wherein, the farina is high straight chain farina, and the cornstarch is cross-linked corn starch.
Embodiment 2
A kind of glass-fiber reinforced size, it is made up of by weight the following raw material：25 parts of epoxy resin, poly-vinegar acid second
It is 25 parts of alkene ester, 15 parts of acrylic acid ester emulsion, 6.5 parts of linseed oil, 4 parts of coupling agent, 1.3 parts of lubricant, 0.8 part of preservative, organic
0.3 part of tin bactericide, 0.4 part of defoamer, 70 parts of water；
Wherein, the farina is high straight chain farina, and the cornstarch is cross-linked corn starch.
Embodiment 3
A kind of glass-fiber reinforced size, it is made up of by weight the following raw material：30 parts of epoxy resin, poly-vinegar acid second
30 parts of alkene ester, 20 parts of acrylic acid ester emulsion, 8 parts of linseed oil, 5 parts of coupling agent, 2 parts of lubricant, 1 part of preservative, organotin sterilization
0.5 part of agent, 0.5 part of defoamer, 80 parts of water；
Wherein, the farina is high straight chain farina, and the cornstarch is cross-linked corn starch.
The embodiments of the present invention described above are not intended to limit the scope of the present invention, any in the present invention
Spirit and principle within the modifications, equivalent substitutions and improvements made etc., should be included in the claim protection model of the present invention
Within enclosing.
Claims (5)
1. a kind of glass-fiber reinforced size, it is characterised in that be made up of by weight the following raw material：
Epoxy resin 20-30 parts, polyvinyl acetate 20-30 parts, acrylic acid ester emulsion 10-20 parts, linseed oil 5-8 parts, coupling
Agent 3-5 parts, lubricant 0.5-2 parts, preservative 0.5-1 parts, organotin germicide 0.1-0.5 parts, defoamer 0.3-0.5 parts, water
60-80 parts.
2. glass-fiber reinforced size according to claim 1, it is characterised in that by the following raw material group by weight
Into：20 parts of epoxy resin, 20 parts of polyvinyl acetate, 10 parts of acrylic acid ester emulsion, 5 parts of linseed oil, 3 parts of coupling agent, lubricant
0.5 part, 0.5 part of preservative, 0.1 part of organotin germicide, 0.3 part of defoamer, 60 parts of water.
3. glass-fiber reinforced size according to claim 1, it is characterised in that by the following raw material group by weight
Into：25 parts of epoxy resin, 25 parts of polyvinyl acetate, 15 parts of acrylic acid ester emulsion, 6.5 parts of linseed oil, 4 parts of coupling agent, lubrication
1.3 parts of agent, 0.8 part of preservative, 0.3 part of organotin germicide, 0.4 part of defoamer, 70 parts of water.
4. glass-fiber reinforced size according to claim 1, it is characterised in that by the following raw material group by weight
Into：30 parts of epoxy resin, 30 parts of polyvinyl acetate, 20 parts of acrylic acid ester emulsion, 8 parts of linseed oil, 5 parts of coupling agent, lubricant 2
Part, 1 part of preservative, 0.5 part of organotin germicide, 0.5 part of defoamer, 80 parts of water.
5. glass-fiber reinforced size according to claim 1, it is characterised in that the farina is Gao Zhi
Chain farina, the cornstarch are cross-linked corn starch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711046031.0A CN107673634A (en) | 2017-10-31 | 2017-10-31 | A kind of glass-fiber reinforced size |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711046031.0A CN107673634A (en) | 2017-10-31 | 2017-10-31 | A kind of glass-fiber reinforced size |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107673634A true CN107673634A (en) | 2018-02-09 |
Family
ID=61143523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711046031.0A Pending CN107673634A (en) | 2017-10-31 | 2017-10-31 | A kind of glass-fiber reinforced size |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107673634A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108821610A (en) * | 2018-08-07 | 2018-11-16 | 苏州华龙化工有限公司 | A kind of glass fiber infiltration agent and preparation method thereof |
| CN108840581A (en) * | 2018-08-07 | 2018-11-20 | 苏州华龙化工有限公司 | A kind of enhanced type glass fiber impregnating agent and preparation method thereof |
| CN108911533A (en) * | 2018-08-07 | 2018-11-30 | 苏州华龙化工有限公司 | A kind of permanent protective property glass fiber infiltration agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844018A (en) * | 2015-04-28 | 2015-08-19 | 安徽丹凤集团桐城玻璃纤维有限公司 | Glass fiber impregnating compound |
| CN105110656A (en) * | 2015-04-28 | 2015-12-02 | 安徽丹凤集团桐城玻璃纤维有限公司 | Glass fiber impregnating compound |
| CN106186732A (en) * | 2016-07-29 | 2016-12-07 | 安徽丹凤集团桐城玻璃纤维有限公司 | A kind of novel glass fiber wetting agent and preparation method thereof |
| CN106220003A (en) * | 2016-07-29 | 2016-12-14 | 安徽丹凤集团桐城玻璃纤维有限公司 | A kind of glass-fiber reinforced wetting agent |
| CN106242319A (en) * | 2016-07-29 | 2016-12-21 | 安徽丹凤集团桐城玻璃纤维有限公司 | A kind of high-performance glass fiber wetting agent |
-
2017
- 2017-10-31 CN CN201711046031.0A patent/CN107673634A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844018A (en) * | 2015-04-28 | 2015-08-19 | 安徽丹凤集团桐城玻璃纤维有限公司 | Glass fiber impregnating compound |
| CN105110656A (en) * | 2015-04-28 | 2015-12-02 | 安徽丹凤集团桐城玻璃纤维有限公司 | Glass fiber impregnating compound |
| CN106186732A (en) * | 2016-07-29 | 2016-12-07 | 安徽丹凤集团桐城玻璃纤维有限公司 | A kind of novel glass fiber wetting agent and preparation method thereof |
| CN106220003A (en) * | 2016-07-29 | 2016-12-14 | 安徽丹凤集团桐城玻璃纤维有限公司 | A kind of glass-fiber reinforced wetting agent |
| CN106242319A (en) * | 2016-07-29 | 2016-12-21 | 安徽丹凤集团桐城玻璃纤维有限公司 | A kind of high-performance glass fiber wetting agent |
Non-Patent Citations (1)
| Title |
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| 张耀明等: "《玻璃纤维与矿物棉全书》", 31 March 2001, 化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108821610A (en) * | 2018-08-07 | 2018-11-16 | 苏州华龙化工有限公司 | A kind of glass fiber infiltration agent and preparation method thereof |
| CN108840581A (en) * | 2018-08-07 | 2018-11-20 | 苏州华龙化工有限公司 | A kind of enhanced type glass fiber impregnating agent and preparation method thereof |
| CN108911533A (en) * | 2018-08-07 | 2018-11-30 | 苏州华龙化工有限公司 | A kind of permanent protective property glass fiber infiltration agent and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180209 |