CN106242319A - A kind of high-performance glass fiber wetting agent - Google Patents
A kind of high-performance glass fiber wetting agent Download PDFInfo
- Publication number
- CN106242319A CN106242319A CN201610614312.0A CN201610614312A CN106242319A CN 106242319 A CN106242319 A CN 106242319A CN 201610614312 A CN201610614312 A CN 201610614312A CN 106242319 A CN106242319 A CN 106242319A
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- CN
- China
- Prior art keywords
- parts
- agent
- glass fiber
- lubricant
- dcpd
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/36—Epoxy resins
Abstract
The invention discloses a kind of high-performance glass fiber wetting agent, be made up of the component of following weight portion: epoxy DCPD-containing epoxy resin 30 40 parts, ring pentanediol 20 30 parts, trimethylolethane 10 20 parts, polyvinyl acetate 5 10 parts, Oleum Ricini 58 parts, coupling agent 35 parts, lubricant 0.5 2 parts, preservative 0.5 1 parts, pH adjusting agent 0.5 1 parts, 0 0.5 parts of antistatic additive, compatilizer 0.5 1 parts, water is appropriate.The present invention uses epoxy DCPD-containing epoxy resin, ring pentanediol, trimethylolethane, polyvinyl acetate is as film former, there is heat-resisting quantity and the electrical property of excellence, heatproof is up to more than 300 DEG C, there is higher stiffness simultaneously, toughness, tensile strength, bending strength, high cohesive force, good film property and protectiveness, be conducive to protection and collection number that glass fibre collects in high velocity jet and the process of kneading, improve production efficiency, improve the mechanical performance of glass fibre, give glass with good cutting, dispersibility, lubricity, antistatic behaviour, textile and mobility.
Description
Technical field
The present invention relates to glass fibre production technology, specifically a kind of high-performance glass fiber wetting agent.
Background technology
Glass fibre is dispersed in water or the alcohol of water, ester solution medium, and then is used for producing glassfiber insulation bag
It is contour that package material, glass mat, particularly glass fibre mix manufacture galss fiber reinforced resin with macromolecule resin fiber
Strength-Glass-Fibre composite is a key areas of modem fibreglass application, has wide market prospect and development
Prospect.
At present conventional water dispersable glass fiber sizing mostly use amine or alcohols single compound or with non-from
The mixture of son or cationic surface active agent is as dispersant.Its existence is disadvantageous in that: be difficult to according to industry raw
The practical situation produced is adjusted, it is impossible to meets and disperses all kinds of variety classeses, the glass fibre of chemical composition or glass fibre not
Being actually needed with disperse medium.
The wetting agent in this field of glass fibre used carbamide as wetting agent mostly in the past, and heat stability is poor, under high temperature
Easily produce abnormal flavour, had a strong impact on the use of glass fibre, and easily caused environmental pollution, Application No.
CN201010252613.6 discloses a kind of glass fiber lubricant, the dispersion being made up of two kinds of different nitrogen-containing surfactants
Agent, the protective agent being made up of one or more polyhydroxy or oxo-alcohols, ester, acyl base polymer, it is made up of polyol blends
The silane coupler that wetting agent, lubricant, fiber glass industry are conventional, remainder is distilled water or deionized water, this infiltration
Agent is applicable to various alkali-free, medium-alkali glass fibre in the dispersion of aqueous medium, and the glass dispersion after this product treatment can be good
Good, Heat stability is good and pollution-free, but this kind of wetting agent wellability is poor, and reinforced effects is poor, and production cost is higher.
Summary of the invention
It is an object of the invention to provide a kind of high-performance glass fiber wetting agent, to solve above-mentioned background technology proposes
Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of high-performance glass fiber wetting agent, is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 30-40 part, ring pentanediol 20-30 part, trimethylolethane 10-20 part is poly-
Vinylacetate 5-10 part, Oleum Ricini 5-8 part, coupling agent 3-5 part, lubricant 0.5-2 part, preservative 0.5-1 part, pH adjusting agent
0.5-1 part, antistatic additive 0-0.5 part, compatilizer 0.5-1 part, water is appropriate.
Preferably, described a kind of high-performance glass fiber wetting agent, it is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 30 parts, ring pentanediol 20 parts, trimethylolethane 10 parts, polyvinyl acetate
5 parts, Oleum Ricini 5 parts, coupling agent 3 parts, lubricant 0.5 part, preservative 0.5 part, pH adjusting agent 0.5 part, 0.1 part of antistatic additive,
Compatilizer 0.5 part, water is appropriate.
Preferably, described a kind of high-performance glass fiber wetting agent, it is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 40 parts, ring pentanediol 30 parts, trimethylolethane 20 parts, polyvinyl acetate
10 parts, Oleum Ricini 8 parts, coupling agent 5 parts, lubricant 2 parts, preservative 1 part, pH adjusting agent 1 part, 0.5 part of antistatic additive, compatilizer
1 part, water is appropriate.
Preferably, described a kind of high-performance glass fiber wetting agent, it is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 35 parts, ring pentanediol 25 parts, trimethylolethane 15 parts, polyvinyl acetate
7 parts, Oleum Ricini 6 parts, coupling agent 4 parts, lubricant 1 part, preservative 0.7 part, pH adjusting agent 0.7 part, 0.2 part of antistatic additive, phase
Holding agent 0.7 part, water is appropriate.
Preferably, described a kind of high-performance glass fiber wetting agent, it is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 38 parts, ring pentanediol 27 parts, trimethylolethane 17 parts, polyvinyl acetate
9 parts, Oleum Ricini 7 parts, coupling agent 4.5 parts, lubricant 1.5 parts, preservative 0.9 part, pH adjusting agent 0.8 part, antistatic additive 0.4
Part, compatilizer 0.8 part, water is appropriate.
Preferably, described coupling agent is silane coupler.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.5-1:0.5-1:0.02-0.15.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole epoxy epoxy DCPD-containing epoxy resins, ring pentanediol, trimethylolethane, poly-acetic acid second
Alkene ester, Oleum Ricini, coupling agent, preservative, pH adjusting agent, compatilizer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Compared with prior art, the invention has the beneficial effects as follows: the present invention uses epoxy DCPD-containing epoxy resin, ring
Pentanediol, trimethylolethane, polyvinyl acetate as film former, have heat-resisting quantity and the electrical property of excellence, and heatproof can
Reach more than 300 DEG C, there is higher stiffness, toughness, tensile strength, bending strength, high cohesive force, good film property simultaneously
And the protection that collects in high velocity jet and the process of kneading of protectiveness, beneficially glass fibre and collection number, improve production efficiency, improve
The mechanical performance of glass fibre, gives glass with good cutting, dispersibility, lubricity, antistatic behaviour, textile and flowing
Property.
Detailed description of the invention
Embodiment 1
A kind of high-performance glass fiber wetting agent, is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 30 parts, ring pentanediol 20 parts, trimethylolethane 10 parts, polyvinyl acetate
5 parts, Oleum Ricini 5 parts, coupling agent 3 parts, lubricant 0.5 part, preservative 0.5 part, pH adjusting agent 0.5 part, 0.1 part of antistatic additive,
Compatilizer 0.5 part, water is appropriate.
Preferably, described coupling agent is silane coupler.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.5:0.5:0.02.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole epoxy epoxy DCPD-containing epoxy resins, ring pentanediol, trimethylolethane, poly-acetic acid second
Alkene ester, Oleum Ricini, coupling agent, preservative, pH adjusting agent, compatilizer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Embodiment 2
A kind of high-performance glass fiber wetting agent, is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 40 parts, ring pentanediol 30 parts, trimethylolethane 20 parts, polyvinyl acetate
10 parts, Oleum Ricini 8 parts, coupling agent 5 parts, lubricant 2 parts, preservative 1 part, pH adjusting agent 1 part, 0.5 part of antistatic additive, compatilizer
1 part, water is appropriate.
Preferably, described coupling agent is silane coupler.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:1:1:0.15.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole epoxy epoxy DCPD-containing epoxy resins, ring pentanediol, trimethylolethane, poly-acetic acid second
Alkene ester, Oleum Ricini, coupling agent, preservative, pH adjusting agent, compatilizer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Embodiment 3
A kind of high-performance glass fiber wetting agent, is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 35 parts, ring pentanediol 25 parts, trimethylolethane 15 parts, polyvinyl acetate
7 parts, Oleum Ricini 6 parts, coupling agent 4 parts, lubricant 1 part, preservative 0.7 part, pH adjusting agent 0.7 part, 0.2 part of antistatic additive, phase
Holding agent 0.7 part, water is appropriate.
Preferably, described coupling agent is silane coupler.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.6:0.6:0.1.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole epoxy epoxy DCPD-containing epoxy resins, ring pentanediol, trimethylolethane, poly-acetic acid second
Alkene ester, Oleum Ricini, coupling agent, preservative, pH adjusting agent, compatilizer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Embodiment 4
A kind of high-performance glass fiber wetting agent, is made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 38 parts, ring pentanediol 27 parts, trimethylolethane 17 parts, polyvinyl acetate
9 parts, Oleum Ricini 7 parts, coupling agent 4.5 parts, lubricant 1.5 parts, preservative 0.9 part, pH adjusting agent 0.8 part, antistatic additive 0.4
Part, compatilizer 0.8 part, water is appropriate.
Preferably, described coupling agent is silane coupler.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.8:0.8:0.12.
Glass fiber infiltration agent of the present invention is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole epoxy epoxy DCPD-containing epoxy resins, ring pentanediol, trimethylolethane, poly-acetic acid second
Alkene ester, Oleum Ricini, coupling agent, preservative, pH adjusting agent, compatilizer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Claims (9)
1. a high-performance glass fiber wetting agent, it is characterised in that be made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 30-40 part, ring pentanediol 20-30 part, trimethylolethane 10-20 part, poly-acetic acid
Vinyl acetate 5-10 part, Oleum Ricini 5-8 part, coupling agent 3-5 part, lubricant 0.5-2 part, preservative 0.5-1 part, pH adjusting agent 0.5-
1 part, antistatic additive 0-0.5 part, compatilizer 0.5-1 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 30 parts, ring pentanediol 20 parts, trimethylolethane 10 parts, polyvinyl acetate 5 parts,
Oleum Ricini 5 parts, coupling agent 3 parts, lubricant 0.5 part, preservative 0.5 part, pH adjusting agent 0.5 part, 0.1 part of antistatic additive, compatible
Agent 0.5 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 40 parts, ring pentanediol 30 parts, trimethylolethane 20 parts, polyvinyl acetate 10
Part, Oleum Ricini 8 parts, coupling agent 5 parts, lubricant 2 parts, preservative 1 part, pH adjusting agent 1 part, 0.5 part of antistatic additive, compatilizer 1
Part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 35 parts, ring pentanediol 25 parts, trimethylolethane 15 parts, polyvinyl acetate 7 parts,
Oleum Ricini 6 parts, coupling agent 4 parts, lubricant 1 part, preservative 0.7 part, pH adjusting agent 0.7 part, 0.2 part of antistatic additive, compatilizer
0.7 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Epoxy DCPD-containing epoxy resin 38 parts, ring pentanediol 27 parts, trimethylolethane 17 parts, polyvinyl acetate 9 parts,
Oleum Ricini 7 parts, coupling agent 4.5 parts, lubricant 1.5 parts, preservative 0.9 part, pH adjusting agent 0.8 part, 0.4 part of antistatic additive, phase
Holding agent 0.8 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described coupling agent is silane coupler.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described lubricant is imidazoline sun profit
Lubrication prescription.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described antistatic additive is by lithium nitrate, chlorine
Change lithium, ammonium chloride and anti-static agent SN form, and wherein in lithium nitrate, lithium chloride, ammonium chloride, mass ratio with anti-static agent SN is 1:
0.5-1:0.5-1:0.02-0.15.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described glass fiber infiltration agent uses such as
Lower section method is prepared from, and specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole epoxy epoxy DCPD-containing epoxy resins, ring pentanediol, trimethylolethane, polyvinyl acetate 9
Part, Oleum Ricini, coupling agent, preservative, pH adjusting agent, compatilizer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the infiltration of the present invention
Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614312.0A CN106242319A (en) | 2016-07-29 | 2016-07-29 | A kind of high-performance glass fiber wetting agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614312.0A CN106242319A (en) | 2016-07-29 | 2016-07-29 | A kind of high-performance glass fiber wetting agent |
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| Publication Number | Publication Date |
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| CN106242319A true CN106242319A (en) | 2016-12-21 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107601923A (en) * | 2017-10-31 | 2018-01-19 | 安徽丹凤电子材料股份有限公司 | A kind of high-performance glass fiber size and preparation method thereof |
| CN107673634A (en) * | 2017-10-31 | 2018-02-09 | 安徽丹凤电子材料股份有限公司 | A kind of glass-fiber reinforced size |
| CN108975730A (en) * | 2018-08-24 | 2018-12-11 | 巨石集团有限公司 | A kind of glass fiber infiltration agent and its application |
| CN112724466A (en) * | 2020-12-29 | 2021-04-30 | 江苏绿材谷新材料科技发展有限公司 | Impregnating compound for basalt fiber reinforced polyethylene resin and preparation method thereof |
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| CN105601130A (en) * | 2015-12-23 | 2016-05-25 | 晏玲莉 | Special impregnating agent for basalt fiber |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101439937A (en) * | 2008-11-24 | 2009-05-27 | 上海世鹏聚氨酯科技发展有限公司 | Reinforced textile type glass fiber treating compound and preparation thereof |
| CN101723603A (en) * | 2009-12-03 | 2010-06-09 | 巨石集团有限公司 | Special sizing agent for chopped strands for strengthening phenolic resin |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107601923A (en) * | 2017-10-31 | 2018-01-19 | 安徽丹凤电子材料股份有限公司 | A kind of high-performance glass fiber size and preparation method thereof |
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| CN108975730A (en) * | 2018-08-24 | 2018-12-11 | 巨石集团有限公司 | A kind of glass fiber infiltration agent and its application |
| CN108975730B (en) * | 2018-08-24 | 2021-04-09 | 巨石集团有限公司 | Glass fiber impregnating compound and application thereof |
| CN112724466A (en) * | 2020-12-29 | 2021-04-30 | 江苏绿材谷新材料科技发展有限公司 | Impregnating compound for basalt fiber reinforced polyethylene resin and preparation method thereof |
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Application publication date: 20161221 |