CN107665870A - A kind of copper palladium-silver bonding line - Google Patents

A kind of copper palladium-silver bonding line Download PDF

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Publication number
CN107665870A
CN107665870A CN201711128391.5A CN201711128391A CN107665870A CN 107665870 A CN107665870 A CN 107665870A CN 201711128391 A CN201711128391 A CN 201711128391A CN 107665870 A CN107665870 A CN 107665870A
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CN
China
Prior art keywords
plating
fixedly connected
bonding line
palladium
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711128391.5A
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Chinese (zh)
Inventor
汪新明
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Guixi Bo Yuan Metal Co Ltd
Original Assignee
Guixi Bo Yuan Metal Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guixi Bo Yuan Metal Co Ltd filed Critical Guixi Bo Yuan Metal Co Ltd
Priority to CN201711128391.5A priority Critical patent/CN107665870A/en
Publication of CN107665870A publication Critical patent/CN107665870A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/42Wire connectors; Manufacturing methods related thereto
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1646Characteristics of the product obtained
    • C23C18/165Multilayered product
    • C23C18/1653Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/42Coating with noble metals
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper
    • C25D3/40Electroplating: Baths therefor from solutions of copper from cyanide baths, e.g. with Cu+
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/50Electroplating: Baths therefor from solutions of platinum group metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/48Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
    • H01L23/481Internal lead connections, e.g. via connections, feedthrough structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/52Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Electrochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Abstract

The invention discloses a kind of copper palladium-silver bonding line, its structure includes spiral roller, the both sides up and down of the spiral roller are fixedly connected with baffle plate, the middle of the baffle plate is fixedly connected with bearing, the spiral roller is provided with bonding line, the mode of the outside plating of the bonding line is fixedly connected with copper plate, the outside of the copper plate is fixedly connected with silver coating by way of chemical plating, the outside of the silver coating is fixedly connected with plating palladium layers by way of plating, and the outside of the plating palladium layers is fixedly connected with insulating barrier by way of chimeric.With good electric conductivity and become clear and the surface of gloss, and there is very high corrosion resistance and fabulous dispersibility, in the process energy sulfuration resistant used, creep resistant is corroded and bending extension, it is used as the material of insulating barrier by polyamidoimide, mechanical strength, freon-resistant refrigerant can be effectively raised, there is good compatibility with impregnating varnish, the features such as heat resistance, impact resistance, oil resistivity can be met.

Description

A kind of copper palladium-silver bonding line
Technical field
The present invention relates to a kind of technical field of metal material, specially a kind of copper palladium-silver bonding line.
Background technology
At present, existing bonding line is also there is the place of some shortcomings, such as;Existing bonding line electric conductivity compares Difference, and corrosion resistance is low and dispersibility is weaker, is unable to sulfuration resistant in the process used, creep resistant corrosion and bending are prolonged Stretch, and the insulating barrier mechanical strength of existing bonding line is low, it is impossible to freon-resistant refrigerant, have with impregnating varnish poor compatible Property, it is impossible to the shortcomings of meeting heat resistance, impact resistance, oil resistivity.
The content of the invention
The technical problem to be solved in the present invention is the defects of overcoming prior art, there is provided a kind of copper palladium-silver bonding line, is had Good electric conductivity and the bright and surface of gloss, and there is very high corrosion resistance and fabulous dispersibility, The process energy sulfuration resistant used, creep resistant corrosion and bending extension, the material of insulating barrier is used as by polyamidoimide, can be had Effect improves mechanical strength, freon-resistant refrigerant, has good compatibility with impregnating varnish, can meet heat resistance, impact resistance The features such as property, oil resistivity.
To solve the above problems, the present invention provides following technical scheme:A kind of copper palladium-silver bonding line, including spiral roller, institute The both sides up and down for stating spiral roller are fixedly connected with baffle plate, and the middle of the baffle plate is fixedly connected with bearing, and the spiral roller is provided with Bonding line, the mode of the outside plating of the bonding line are fixedly connected with copper plate, and the outside of the copper plate passes through chemical plating Mode is fixedly connected with silver coating, and the outside of the silver coating is fixedly connected with plating palladium layers by way of plating, the plating palladium layers Outside is fixedly connected with insulating barrier by way of chimeric.
As the present invention a kind of preferred embodiment, the baffle plate is rounded, and by way of welding with it is described Spiral roller is connected, and the bearing is connected by way of chimeric with the baffle plate, and is communicated with the spiral roller.
As a kind of preferred embodiment of the present invention, the electrolyte of the copper plate is cyanide, the copper plate Thickness is 20gm~25gm, and the silver coating chemical liquids are silver potassium cyanide solution, and the silver coating needs to be placed in chromate Carry out plating posttreatment.
As the present invention a kind of preferred embodiment, it is described plating palladium layers electroplate liquid mainly have dichloro diamino palladium 10~ 40g/L, ammonium chloride 10g/L and ammonium sulfate 25g/L, solution ph 8.5~9, the thickness of the plating palladium layers is 2~5 μm.
As a kind of preferred embodiment of the present invention, the insulating barrier is connected by way of brushing with the plating palladium layers Connect, the insulating barrier is made using the material of polyamidoimide, and the heat resisting temperature of the insulating barrier is between 160-180 DEG C.
Compared with prior art, beneficial effects of the present invention are as follows:
A kind of copper palladium-silver bonding line of the present invention, there is good electric conductivity and become clear and the surface of gloss, and with very High corrosion resistance and fabulous dispersibility, in the process energy sulfuration resistant used, creep resistant corrosion and bending extension, by poly- Material of the amide imide as insulating barrier, mechanical strength can be effectively raised, freon-resistant refrigerant, is had with impregnating varnish good Good compatibility, the features such as heat resistance, impact resistance, oil resistivity can be met.
Brief description of the drawings
Fig. 1 is a kind of sectional view of copper palladium-silver bonding line of the present invention;
Fig. 2 is the structural representation of spiral roller of the present invention.
In figure:Spiral roller 1, baffle plate 2, bearing 3, bonding line 4, copper plate 5, silver coating 6, plate palladium layers 7, insulating barrier 8.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes.
Fig. 1-2 is referred to, the present invention provides a kind of technical scheme:A kind of copper palladium-silver bonding line, including spiral roller 1, it is described The both sides up and down of spiral roller 1 are fixedly connected with baffle plate 2, and the middle of the baffle plate 2 is fixedly connected with bearing 3, set on the spiral roller 1 There is bonding line 4, the mode of the outside plating of the bonding line 4 is fixedly connected with copper plate 5, the passing through of outside of the copper plate 5 The mode for learning plating is fixedly connected with silver coating 6, and the outside of the silver coating 6 is fixedly connected with plating palladium layers 7 by way of plating, described The outside for plating palladium layers 7 is fixedly connected with insulating barrier 8 by way of chimeric.
The baffle plate 2 is rounded, and is connected by way of welding with the spiral roller 1, and the bearing 3 is by embedding The mode of conjunction is connected with the baffle plate 2, and is communicated with the spiral roller 1, and its role is to can effectively raise bonding Convenience when line uses.
The electrolyte of the copper plate 5 is cyanide, and the thickness of the copper plate 5 is 20gm~25gm, has peracid low Copper feature, there are fabulous dispersibility and covering power, property that the layers of copper after plating is glossy, the chemical liquids of silver coating 6 are cyaniding Silver-colored potassium solution, the silver coating 6, which needs to be placed on, carries out plating posttreatment in chromate, its role is to good electric conductivity Can, and become clear and the surface of gloss, and silver layer has very high corrosion resistance.
The electroplate liquid of the plating palladium layers 7 mainly has dichloro diamino 10~40g/L of palladium, ammonium chloride 10g/L and ammonium sulfate 25g/ L, solution ph 8.5~9, the thickness of the plating palladium layers 7 is 2~5 μm, and its role is to the effective sulfuration resistant of energy, creep resistant are rotten The advantages that erosion and bending extend, and hardness is strong.
The insulating barrier 8 is connected by way of brushing with the plating palladium layers 7, and the insulating barrier 8 uses polyamide acyl The material of imines makes, and for the heat resisting temperature of the insulating barrier 8 between 160-180 DEG C, its role is to have higher machinery strong Degree, freon-resistant refrigerant, has good compatibility with impregnating varnish, the features such as meeting heat resistance, impact resistance, oil resistivity.
Bonding line 4 is put into the solution of electro-coppering first and carries out copper electroplating layer, will then cover the key of copper plate 5 again Zygonema 4 is put into the chemical liquids containing silver the formation for carrying out silver coating 6, and chromic acid is put it into again after the formation of silver coating 6 Plating posttreatment is carried out in salting liquid, the bonding line 4 for covering copper plate 5 and silver coating 6 is then put into dichloro diamino palladium 10 again ~40g/L, ammonium chloride 10g/L and ammonium sulfate 25g/L, solution ph 8.5~9 carry out the plating of Metal Palladium, finally bonding line 4 again Outer layer coat polyamidoimide material making insulating barrier 8.
The spiral roller 1 of the present invention, baffle plate 2, bearing 3, bonding line 4, copper plate 5, silver coating 6, plate palladium layers 7, insulating barrier 8 etc. The part that part is universal standard part or those skilled in the art know, its structure and principle all can lead to for this technology personnel Cross technical manual to learn or by normal experiment method know, there is good electric conductivity and become clear and the surface of gloss, And there is very high corrosion resistance and fabulous dispersibility, and in the process energy sulfuration resistant used, creep resistant corrosion and bending Extension, the material of insulating barrier 8 is used as by polyamidoimide, can effectively raise mechanical strength, freon-resistant refrigerant, There is good compatibility with impregnating varnish, the features such as heat resistance, impact resistance, oil resistivity can be met.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above, for this area skill For art personnel, it is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing substantially from the present invention spirit or In the case of essential characteristic, the present invention can be realized in other specific forms.Which point therefore, no matter from the point of view of, all should incite somebody to action Embodiment regards exemplary as, and be it is nonrestrictive, the scope of the present invention by appended claims rather than on state Bright restriction, it is intended that all changes fallen in the implication and scope of the equivalency of claim are included in the present invention It is interior.Any reference in claim should not be considered as to the involved claim of limitation.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (5)

1. a kind of copper palladium-silver bonding line, including spiral roller(1), it is characterised in that:The spiral roller(1)Both sides up and down fix connect Connect baffle plate(2), the baffle plate(2)Middle be fixedly connected with bearing(3), the spiral roller(1)It is provided with bonding line(4), institute State bonding line(4)Outside plating mode be fixedly connected with copper plate(5), the copper plate(5)Outside pass through chemical plating Mode is fixedly connected with silver coating(6), the silver coating(6)Outside plating palladium layers are fixedly connected with by way of plating(7), it is described Plate palladium layers(7)Outside be fixedly connected with insulating barrier by way of chimeric(8).
A kind of 2. copper palladium-silver bonding line according to claim 1, it is characterised in that:The baffle plate(2)It is rounded, and lead to Cross the mode of welding and the spiral roller(1)It is connected, the bearing(3)By way of chimeric with the baffle plate(2)It is connected Connect, and with the spiral roller(1)Communicate.
A kind of 3. copper palladium-silver bonding line according to claim 1, it is characterised in that:The copper plate(5)Electrolyte be Cyanide, the copper plate(5)Thickness be 20gm~25gm, the silver coating(6)Chemical liquids are silver potassium cyanide solution, described Silver coating(6)Need to be placed on and plating posttreatment is carried out in chromate.
A kind of 4. copper palladium-silver bonding line according to claim 1, it is characterised in that:The plating palladium layers(7)Electroplate liquid master There are dichloro diamino 10~40g/L of palladium, ammonium chloride 10g/L and ammonium sulfate 25g/L, solution ph 8.5~9, the plating palladium layers 7 (7)Thickness be 2~5 μm.
A kind of 5. copper palladium-silver bonding line according to claim 1, it is characterised in that:The insulating barrier(8)Pass through brushing Mode and the plating palladium layers(7)It is connected, the insulating barrier(8)Made using the material of polyamidoimide, the insulating barrier (8)Heat resisting temperature between 160-180 DEG C.
CN201711128391.5A 2017-11-15 2017-11-15 A kind of copper palladium-silver bonding line Pending CN107665870A (en)

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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1559355A (en) * 1976-11-05 1980-01-16 Empire Plating Co Coating of metal articles
JPH10233121A (en) * 1997-02-18 1998-09-02 Hitachi Cable Ltd Lead wire
JPH11189891A (en) * 1997-12-25 1999-07-13 Matsuda Sangyo Co Ltd Palladium electroplating solution
US6178623B1 (en) * 1997-12-16 2001-01-30 Totoku Electric Co., Ltd. Composite lightweight copper plated aluminum wire
US20050040535A1 (en) * 2003-08-05 2005-02-24 Fuji Photo Film Co., Ltd. Conductive film and method for preparing the same
US20060027462A1 (en) * 2004-08-05 2006-02-09 Shinko Electric Industries Co., Ltd. Copper strike plating bath
JP2007179871A (en) * 2005-12-28 2007-07-12 Totoku Electric Co Ltd Fullerene composite plated wire, method of manufacturing same and fullerene composite-plated enameled wire
JP2007291448A (en) * 2006-04-25 2007-11-08 Hitachi Chem Co Ltd Copper foil surface treatment method, and copper foil
CN102130068A (en) * 2011-01-07 2011-07-20 四川威纳尔特种电子材料有限公司 Alloy-type bonding wire with composite plating on surface
US20120118610A1 (en) * 2009-07-30 2012-05-17 Nippon Micrometal Corporation Bonding wire for semiconductor
CN103219246A (en) * 2013-03-01 2013-07-24 溧阳市虹翔机械制造有限公司 Manufacturing method of palladium-plated silver-plated double-plating bonding copper wire
CN106757281A (en) * 2016-12-29 2017-05-31 广东工业大学 A kind of protective agent composition and anticorrosive bonding wire and preparation method thereof
WO2017155469A1 (en) * 2016-03-10 2017-09-14 Rokko Leadframes Pte Ltd Semiconductor device and method of manufacture
CN207441693U (en) * 2017-11-15 2018-06-01 贵溪博远金属有限公司 A kind of copper palladium-silver bonding line

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1559355A (en) * 1976-11-05 1980-01-16 Empire Plating Co Coating of metal articles
JPH10233121A (en) * 1997-02-18 1998-09-02 Hitachi Cable Ltd Lead wire
US6178623B1 (en) * 1997-12-16 2001-01-30 Totoku Electric Co., Ltd. Composite lightweight copper plated aluminum wire
JPH11189891A (en) * 1997-12-25 1999-07-13 Matsuda Sangyo Co Ltd Palladium electroplating solution
US20050040535A1 (en) * 2003-08-05 2005-02-24 Fuji Photo Film Co., Ltd. Conductive film and method for preparing the same
US20060027462A1 (en) * 2004-08-05 2006-02-09 Shinko Electric Industries Co., Ltd. Copper strike plating bath
JP2007179871A (en) * 2005-12-28 2007-07-12 Totoku Electric Co Ltd Fullerene composite plated wire, method of manufacturing same and fullerene composite-plated enameled wire
JP2007291448A (en) * 2006-04-25 2007-11-08 Hitachi Chem Co Ltd Copper foil surface treatment method, and copper foil
US20120118610A1 (en) * 2009-07-30 2012-05-17 Nippon Micrometal Corporation Bonding wire for semiconductor
CN102130068A (en) * 2011-01-07 2011-07-20 四川威纳尔特种电子材料有限公司 Alloy-type bonding wire with composite plating on surface
CN103219246A (en) * 2013-03-01 2013-07-24 溧阳市虹翔机械制造有限公司 Manufacturing method of palladium-plated silver-plated double-plating bonding copper wire
WO2017155469A1 (en) * 2016-03-10 2017-09-14 Rokko Leadframes Pte Ltd Semiconductor device and method of manufacture
CN106757281A (en) * 2016-12-29 2017-05-31 广东工业大学 A kind of protective agent composition and anticorrosive bonding wire and preparation method thereof
CN207441693U (en) * 2017-11-15 2018-06-01 贵溪博远金属有限公司 A kind of copper palladium-silver bonding line

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Application publication date: 20180206