CN107665865A - A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation method - Google Patents

A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation method Download PDF

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Publication number
CN107665865A
CN107665865A CN201710760261.7A CN201710760261A CN107665865A CN 107665865 A CN107665865 A CN 107665865A CN 201710760261 A CN201710760261 A CN 201710760261A CN 107665865 A CN107665865 A CN 107665865A
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jewel
cadmium
zinc
teiluride
reading circuit
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廖清君
胡晓宁
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Shanghai Institute of Technical Physics of CAS
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Shanghai Institute of Technical Physics of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/562Protection against mechanical damage
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/1446Devices controlled by radiation in a repetitive configuration
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1828Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIBVI compounds, e.g. CdS, ZnS, CdTe
    • H01L31/1832Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIBVI compounds, e.g. CdS, ZnS, CdTe comprising ternary compounds, e.g. Hg Cd Te
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73201Location after the connecting process on the same surface
    • H01L2224/73203Bump and layer connectors
    • H01L2224/73204Bump and layer connectors the bump connector being embedded into the layer connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73251Location after the connecting process on different surfaces
    • H01L2224/73253Bump and layer connectors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation method.Composite construction in the present invention includes cadmium-zinc-teiluride substrate, the infrared photosensor chip of mercury cadmium telluride, silicon reading circuit, jewel electrode base board and jewel deformation balance layer.The present invention obtains cadmium-zinc-teiluride base mercury-cadmium-tellurium focal plane module using customary preparation methods, then one layer of polyurethane modified epoxy resin is applied at the silicon reading circuit back side of module, paste last layer jewel deformation balance layer, wherein jewel deformation balance layer thickness is consistent with jewel electrode base board, and size is consistent with silicon reading circuit size;Then apply the power of 4~5 newton on jewel deformation balance layer, solidify 168~192 hours at 22~28 DEG C.The composite construction prepared using the method in the present invention effectively reduces the thermal mismatch stress that indirect inverse bonding interconnection cadmium-zinc-teiluride base HgCdTe infrared focal plane device works at low temperature, reduce because mercury cadmium telluride chip caused by thermal mismatching deforms, improve the Low-Temperature Reliability of device.

Description

A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation method
Technical field
The present invention relates to HgCdTe infrared focal plane device, in particular to a kind of scale with high reliability in 256x1 And the cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction of inverse bonding alluded to above.
Background technology
Infrared detection technique earth observation from space, missile homing, precise guidance, industry and medical thermography etc. it is military and Civil area has important application.With requirement more and more higher of the application to infrared detection technique, as IRDS In core component, high-performance, the infrared focal plane detector of high reliability be development trend and target.
HgCdTe infrared focal plane detector is most important developing direction in current infrared detector, infrared Jiao of mercury cadmium telluride Planar detector includes the infrared photosensor chip of mercury cadmium telluride, silicon reading circuit and electrode base board, the wherein infrared photosensor chip of mercury cadmium telluride It is the extension mercury cadmium telluride thin film on substrate, mercury cadmium telluride photosensor chip is prepared using semiconductor technology.The lining of extension mercury cadmium telluride thin film There are cadmium-zinc-teiluride, GaAs and silicon etc. in bottom, is cadmium-zinc-teiluride substrate with mercury cadmium telluride Lattice Matching, particularly infrared to long wave mercury cadmium telluride For detector, compared to the mercury cadmium telluride thin film quality of materials of other replacement substrate growths, the mercury cadmium telluride of extension on cadmium-zinc-teiluride substrate Film quality is optimal.
Long wavelength's Linear FPA device obtains infrared image by pushing away the mode of sweeping, long line array device by 256x1 and more than The focal plane module of scale is spliced, 256x1 focal planes module typically using indirect inverse bonding interconnection mode realize photosensitive member and Reading circuit is electrically connected, that is, grown indium post salient point mercury cadmium telluride chip and silicon reading circuit inverse bonding grown indium respectively On the jewel electrode base board of post.Cadmium-zinc-teiluride base mercury cadmium telluride is grown in 400~500 degree of high temperature, and device is prepared in room temperature extremely 65 degree, device is operated in about 80K low temperature, due to silicon, jewel piece, cadmium-zinc-teiluride, mercury cadmium telluride and polyurethane modified epoxy resin this The thermal coefficient of expansion of different materials is different, and it is larger that huge thermal mismatching can cause mercury-cadmium-tellurium focal plane device to bear at low temperature Thermal mismatch stress, cause the failure of device.The face battle array focal plane device interconnected using direct inverse bonding can be by changing substrate material Material, substrate thickness and increase invar or kovar in laminated construction to reduce the stress of mercury cadmium telluride (" silicon substrate HgCdTe faces battle array Focal plane device structure thermal stress is analyzed ", laser is with infrared, 2006,11 (6);" HgCdTe infrared focal plane device thermal mismatching should Power research ", infrared and millimeter wave journal, 2008,27 (6);" thermal-stress analysis of infrared focal plane detector encapsulating structure ", laser With infrared, 2014,44 (6)).Because the intensity of Cdl-x_Znx_Te will be small than the intensity of other replacement substrates, even if smaller rule The cadmium-zinc-teiluride base mercury-cadmium tellurid detector of mould is also due to thermal mismatch stress causes to fail, the cadmium-zinc-teiluride base focal plane device of indirect inverse bonding Part structure and direct inverse bonding device architecture are different, can not solve the integrity problem of low-temperature working using above method, it is necessary to Find other solutions.
The content of the invention
The purpose of the present invention is to propose to one kind to be used for cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation Method, the alignment cadmium-zinc-teiluride base HgCdTe infrared focal plane device that the composite construction can improve indirect inverse bonding work at low temperature Reliability.
A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation method in the present invention, wherein described Composite construction include cadmium-zinc-teiluride substrate 1, the infrared photosensitive element chip 2 of mercury cadmium telluride, silicon reading circuit 6, jewel electrode base board 4 and treasured Stone deformation balance layer 8.The infrared photosensor chip 2 of mercury cadmium telluride being grown on cadmium-zinc-teiluride substrate 1 passes through indium post 3 with silicon reading circuit 6 On jewel electrode base board 4, one layer of jewel is fixed in the back side of silicon reading circuit 6 by polyurethane modified epoxy resin 7 for inverse bonding respectively Piece is as jewel deformation balance layer 8, and the thickness of jewel deformation balance layer 8 is consistent with jewel electrode base board 4, jewel deformation balance layer 8 Size is consistent with the size of silicon reading circuit 6.
The heretofore described method for preparing composite construction, including following preparation process:
1) it is infrared photosensitive that the mercury cadmium telluride being grown on cadmium-zinc-teiluride substrate (1) is prepared with the focal plane device preparation method of routine Chip (2), silicon reading circuit (6) and jewel electrode base board (4);
2) the infrared photosensor chip of cadmium-zinc-teiluride base mercury cadmium telluride (2) and silicon reading circuit (6) are passed through into indium post (3) inverse bonding respectively again On jewel electrode base board (4), and filled polyurethane modified epoxy (5) in inverse bonding gap;
3) one layer of polyurethane modified epoxy resin (7) and then at silicon reading circuit (6) back side is applied, pastes last layer jewel shape Become balance layer (8), jewel deformation balance layer (8) thickness and jewel electrode base board (4) unanimously, size and silicon reading circuit (6) chi It is very little consistent;Apply the power of 4~5 newton on jewel deformation balance layer (8);
4) solidify 168~192 hours at 22~28 DEG C.
It is an advantage of the invention that:
1. the present invention is suitable for the cadmium-zinc-teiluride base HgCdTe infrared focal plane device of indirect inverse bonding interconnection, fallen indirectly conventional The jewel piece of one layer of size particular design of increase and polyurethane modified epoxy resin can carry as deformation balance layer on welding structure High/low temperature reliability, preparation method is easy easily to be implemented.
2. composite construction provided by the present invention and preparation method are gathered by using the method for increase jewel piece by controlling The thickness of urethane modified epoxy and the dimensional thickness of jewel piece, cadmium-zinc-teiluride base HgCdTe infrared focal plane device can be reduced The thermal mismatch stress to work at low temperature, reduce because mercury cadmium telluride chip caused by thermal mismatching deforms, improve the reliability of device.
3. composite construction provided by the present invention and preparation method can also be used for the indirect inverse bonding tellurium cadmium that other substitute substrate Mercury infrared focal plane device, to improve its Low-Temperature Reliability.
Brief description of the drawings
Fig. 1 is cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction schematic diagram
Wherein 1 is cadmium-zinc-teiluride substrate;2 be the infrared photosensor chip of mercury cadmium telluride;3 be indium post;4 be jewel electrode base board;5 and 7 It is polyurethane modified epoxy resin;6 be silicon reading circuit;8 be jewel deformation balance layer.
Fig. 2 is the deformation map of the mercury cadmium telluride chip of cadmium-zinc-teiluride base in composite construction.10 be the inflection curves under low temperature, and 9 are Inflection curves at room temperature.
Fig. 3 is the cadmium-zinc-teiluride base mercury cadmium telluride core of the cadmium-zinc-teiluride base HgCdTe infrared focal plane device of conventional indirect inverse bonding interconnection The deformation map of piece.11 be inflection curves at room temperature, and 12 be the inflection curves under low temperature.
Embodiment
Below in conjunction with the accompanying drawings, the cadmium-zinc-teiluride base HgCdTe infrared focal plane device using photosensitive element array as 256x1 is example Embodiments of the present invention are elaborated:
Described cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction in the present invention, including the life with indium post 3 Grow the infrared photosensor chip 2 of 256x1 mercury cadmium tellurides on cadmium-zinc-teiluride substrate 1, the infrared photosensor chip 2 of mercury cadmium telluride and silicon reading circuit 6 It is interconnected respectively with the jewel electrode base board 4 with indium post 3 using indirect inverse bonding interconnection technique, by jewel deformation balance layer 8 are attached on silicon reading circuit 6 by one layer of polyurethane modified epoxy resin 7, obtain cadmium-zinc-teiluride base HgCdTe infrared focal plane Device composite construction.The thickness of jewel deformation balance layer 8 is consistent with jewel electrode base board 4, is 0.33 millimeter;Jewel deformation balances The size of layer 8 is consistent with the size of silicon reading circuit 6, a length of 8.7 millimeters, a width of 3.7 millimeters.
The preparation method of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction in the present invention is:Using routine The infrared photosensitive core of 256 × 1 mercury cadmium tellurides for being grown in cadmium-zinc-teiluride substrate 1 with indium post 3 prepared by focal plane device preparation method (size is 9.3 × 6.5 for piece 2,256 × 1 silicon reading circuits 6 (size is 8.7 × 3.7 × 0.5 millimeter) and jewel electrode base board 4 × 0.33 millimeter);The infrared photosensor chip 2 of mercury cadmium telluride and silicon reading circuit 6 are distinguished into inverse bonding in jewel electrode base by indium post 3 again On plate 4, the filled polyurethane modified epoxy 5 in inverse bonding gap;Then one layer of poly- ammonia is applied at the back side of silicon reading circuit 6 Ester modified epoxy resin 7, the jewel deformation balance layer 8 of 8.7 × 3.7 × 0.33 millimeter of last layer is pasted, in jewel deformation balance layer 8 The upper power for applying about 5 newton is to control the thickness of polyurethane modified epoxy resin 7;The cadmium-zinc-teiluride base mercury cadmium telluride of composite construction is red Outer focal plane device solidifies 168~192 hours at a temperature of being placed on 22~28 DEG C.Composite construction is in preparation process, in order to have Effect reduce due to each layer thermal coefficient of expansion formed thermal mismatch stress and caused by cadmium-zinc-teiluride base mercury cadmium telluride chip failure, it is necessary to it is right The thickness for being coated in the polyurethane modified epoxy resin 7 at the silicon reading circuit back side is controlled, while jewel deformation must also be balanced The physical dimension of layer 8 is controlled.The thickness of polyurethane modified epoxy resin 7 is consistent with inverse bonding gap width, and generally 5~10 Micron;The size of jewel deformation balance layer 8 is 8.7 × 3.7 × 0.33 millimeter, and length and width are consistent with silicon reading circuit 6, thickness and treasured Stone electrode base board 4 is consistent.The composite construction obtained using method made above can effectively contain that detector works at low temperature When due to the deformation of cadmium-zinc-teiluride base mercury cadmium telluride chip caused by thermal mismatching, so as to avoid detector failure.Fig. 2 is this example reality The inflection curves for the cadmium-zinc-teiluride base mercury cadmium telluride chip that testing measures, 9 and 10 be respectively room temperature and low temperature about 80K deformation song Line.Fig. 3 is the cadmium-zinc-teiluride base mercury cadmium telluride chip of the cadmium-zinc-teiluride base HgCdTe infrared focal plane device of conventional indirect inverse bonding interconnection Deformation map, curve 11 and 12 are respectively room temperature and low temperature about 80K inflection curves.It can be seen that tellurium in composite construction The deformation of zinc cadmium base mercury cadmium telluride chip at low temperature is obviously reduced.Cycle-index of the composite construction between room temperature and liquid nitrogen temperature 100 times can be brought up to and retention property is constant.
The result of the present invention has been successfully applied to the long wave cadmium-zinc-teiluride base HgCdTe infrared focal plane device such as 256x1,400x1 Part, it is burnt flat that the long alignment LONG WAVE INFRARED obtained is spliced by the 256x1 cadmium-zinc-teiluride base HgCdTe infrared focal planes device of composite construction Surface detector has been successfully applied to remote sensing satellite in orbit.

Claims (2)

1. a kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction, including cadmium-zinc-teiluride substrate (1), mercury cadmium telluride infrared light Quick chip (2), silicon reading circuit (6), jewel electrode base board (4) and jewel deformation balance layer (8), it is characterised in that:
The infrared photosensor chip of mercury cadmium telluride (2) on cadmium-zinc-teiluride substrate (1) is grown in silicon reading circuit (6) difference inverse bonding in jewel On electrode base board (4), it is jewel that one layer of jewel piece is fixed in silicon reading circuit (6) back side by polyurethane modified epoxy resin (7) Deformation balance layer (8), jewel deformation balance layer (8) thickness and jewel electrode base board (4) unanimously, jewel deformation balance layer (8) chi It is very little consistent with silicon reading circuit (6) size.
2. a kind of prepare a kind of side of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction as claimed in claim 1 Method, it is characterised in that including following preparation process:
1) the infrared photosensor chip of mercury cadmium telluride being grown on cadmium-zinc-teiluride substrate (1) is prepared with the focal plane device preparation method of routine (2), silicon reading circuit (6) and jewel electrode base board (4);
2) by the infrared photosensor chip of the mercury cadmium telluride of cadmium-zinc-teiluride base (2) and silicon reading circuit (6), by indium post (3), inverse bonding exists respectively again On jewel electrode base board (4), and filled polyurethane modified epoxy (5) in inverse bonding gap;
3) one layer of polyurethane modified epoxy resin (7) and then at silicon reading circuit (6) back side is applied, patch last layer jewel deformation is put down Weigh layer (8), jewel deformation balance layer (8) thickness and jewel electrode base board (4) unanimously, size and silicon reading circuit (6) size one Cause;Apply the power of 4~5 newton on jewel deformation balance layer (8);
4) solidify 168~192 hours at 22~28 DEG C.
CN201710760261.7A 2017-08-30 2017-08-30 A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction and preparation method Pending CN107665865A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0829907A1 (en) * 1996-09-16 1998-03-18 Rockwell International Corporation Hybrid focal plane array comprising stabilizing structure
US20020024110A1 (en) * 2000-04-28 2002-02-28 Satoshi Iwatsu Semiconductor device using bumps, method for fabricating same, and method for forming bumps
CN2511954Y (en) * 2001-12-29 2002-09-18 中国科学院上海技术物理研究所 Infrared coke surface detector with multiple chip reversed welding interconnection of wire matrix
JP2010027926A (en) * 2008-07-22 2010-02-04 Toshiba Corp Semiconductor device and manufacturing method thereof
CN207282478U (en) * 2017-08-30 2018-04-27 中国科学院上海技术物理研究所 A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0829907A1 (en) * 1996-09-16 1998-03-18 Rockwell International Corporation Hybrid focal plane array comprising stabilizing structure
US20020024110A1 (en) * 2000-04-28 2002-02-28 Satoshi Iwatsu Semiconductor device using bumps, method for fabricating same, and method for forming bumps
CN2511954Y (en) * 2001-12-29 2002-09-18 中国科学院上海技术物理研究所 Infrared coke surface detector with multiple chip reversed welding interconnection of wire matrix
JP2010027926A (en) * 2008-07-22 2010-02-04 Toshiba Corp Semiconductor device and manufacturing method thereof
CN207282478U (en) * 2017-08-30 2018-04-27 中国科学院上海技术物理研究所 A kind of cadmium-zinc-teiluride base HgCdTe infrared focal plane device composite construction

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Application publication date: 20180206