CN107663358A - A kind of wear-resistant macromolecule material - Google Patents
A kind of wear-resistant macromolecule material Download PDFInfo
- Publication number
- CN107663358A CN107663358A CN201710809681.XA CN201710809681A CN107663358A CN 107663358 A CN107663358 A CN 107663358A CN 201710809681 A CN201710809681 A CN 201710809681A CN 107663358 A CN107663358 A CN 107663358A
- Authority
- CN
- China
- Prior art keywords
- parts
- wear
- macromolecule material
- resistant macromolecule
- zinc dihydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of wear-resistant macromolecule material, in parts by weight, including following component：60 80 parts of epoxy resin, 5 10 parts of glass fibres, 25 parts of graphite powders, 5 10 parts of isobutyl triethoxy silanes, 0.1 1 parts of zinc dihydrogen phosphates, 25 parts of zinc dihydrogen phosphate sodium sulfonates, 5 10 parts of Nano filling materials, 0.1 1 parts of crosslinking agents.It the advantage is that：The present invention adds the coordination synergistic effect between raw material by adjusting the proportioning between each raw material so that high polymer material possesses excellent combination property, while has superior wear-resisting and resistance to elevated temperatures, the use environment available for very fast friction and circulation friction.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of wear-resistant macromolecule material.
Background technology
With the rapid development of modern industry, the utilization of high polymer material is more and more extensive, and major colleges and universities, research institute all set
High polymer material research center is put.High polymer material is also referred to as polymeric material, is using high molecular polymer as matrix, is furnished with
The material that other auxiliary agents are formed, high polymer material are divided into rubber, fiber, plastics, polymer binder, macromolecule by characteristic and applied
Material and polymer-based composite etc..High polymer material is in electric and electronic industry, aerospace industry, construction industry, medicine equipment, medical treatment bag
Suffer from being widely applied in the every profession and trades such as dress, transportation, home electric, agricultural.
High polymer material obtains rapid hair because generally having the advantages of many metals and inorganic material can not substitute
Exhibition, the development of modern project technology, higher requirement is proposed to high polymer material, but there is machinery for existing high polymer material
Intensity with wear no resistance, the shortcoming such as heat resistance is low, especially materials'use environment for circulation friction or very fast friction when, produce
Friction high temperature cause high polymer material denaturation, aging, hard crisp, gradually lose the Optimality of high polymer material possessed itself
Energy.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of high temperature resistant, wear-resisting, technique is simply resistance to
Grind high polymer material.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of wear-resistant macromolecule material, its innovative point
It is：In parts by weight, including following component：
Epoxy resin 60-80 parts
Glass fibre 5-10 parts
Graphene powder 2-5 parts
Trimethylolpropane trimethacrylate 5-10 parts
Zinc dihydrogen phosphate 0.1-1 parts
Zinc dihydrogen phosphate sodium sulfonate 2-5 parts
Nano filling material 5-10 parts
Crosslinking agent 0.1-1 parts
Further, the graphene purity is more than 90%.
Further, the crosslinking agent is benzoyl peroxide and ethylene glycol dimethacrylate mass ratio 1:1 compound.
Further, the Nano filling material is the aluminium hydroxide of titanate coupling agent processing.
Beneficial effects of the present invention are as follows：The present invention is added between raw material by adjusting the proportioning between each raw material
Coordinate synergistic effect so that high polymer material possesses excellent combination property, while has superior wear-resisting and resistance to elevated temperatures,
Use environment available for very fast friction and circulation friction.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1
A kind of wear-resistant macromolecule material, in parts by weight, including following component：
60 parts of epoxy resin
5 parts of glass fibre
2 parts of Graphene powder
5 parts of trimethylolpropane trimethacrylate
0.1 part of zinc dihydrogen phosphate
2 parts of zinc dihydrogen phosphate sodium sulfonate
5 parts of the aluminium hydroxide of titanate coupling agent processing
0.1 part of benzoyl peroxide and ethylene glycol dimethacrylate compound
Embodiment 2
A kind of wear-resistant macromolecule material, in parts by weight, including following component：
80 parts of epoxy resin
10 parts of glass fibre
5 parts of Graphene powder
10 parts of trimethylolpropane trimethacrylate
1 part of zinc dihydrogen phosphate
5 parts of zinc dihydrogen phosphate sodium sulfonate
10 parts of the aluminium hydroxide of titanate coupling agent processing
1 part of benzoyl peroxide and ethylene glycol dimethacrylate compound
Embodiment 3
A kind of wear-resistant macromolecule material, in parts by weight, including following component：
70 parts of epoxy resin
7 parts of glass fibre
4 parts of Graphene powder
7 parts of trimethylolpropane trimethacrylate
0.5 part of zinc dihydrogen phosphate
4 parts of zinc dihydrogen phosphate sodium sulfonate
7 parts of the aluminium hydroxide of titanate coupling agent processing
0.5 part of benzoyl peroxide and ethylene glycol dimethacrylate compound
The present invention adds the coordination synergistic effect between raw material so that macromolecule material by adjusting the proportioning between each raw material
Material possesses excellent combination property, while has superior wear-resisting and resistance to elevated temperatures, available for very fast friction and circulation friction
Use environment.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (4)
- A kind of 1. wear-resistant macromolecule material, it is characterised in that：In parts by weight, including following component：
- A kind of 2. wear-resistant macromolecule material according to claim 1, it is characterised in that：The Graphene powder purity is more than 90%.
- A kind of 3. wear-resistant macromolecule material according to claim 1, it is characterised in that：The crosslinking agent is benzoyl peroxide With ethylene glycol dimethacrylate mass ratio 1:1 compound.
- A kind of 4. wear-resistant macromolecule material according to claim 1, it is characterised in that：The Nano filling material is titanate esters The aluminium hydroxide of coupling agent treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710809681.XA CN107663358A (en) | 2017-09-11 | 2017-09-11 | A kind of wear-resistant macromolecule material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710809681.XA CN107663358A (en) | 2017-09-11 | 2017-09-11 | A kind of wear-resistant macromolecule material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107663358A true CN107663358A (en) | 2018-02-06 |
Family
ID=61098362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710809681.XA Pending CN107663358A (en) | 2017-09-11 | 2017-09-11 | A kind of wear-resistant macromolecule material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107663358A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707243A (en) * | 2018-06-20 | 2018-10-26 | 安徽申科塑业有限公司 | A kind of novel high polymer plastic cement |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403276A (en) * | 2014-12-15 | 2015-03-11 | 苏州宽温电子科技有限公司 | High-temperature-resistant and abrasion-resistant macromolecular material |
| CN104830029A (en) * | 2015-06-07 | 2015-08-12 | 安徽华美高分子材料科技有限公司 | High-temperature-resistant and abrasion-resistant high-polymer material |
| CN106433037A (en) * | 2016-09-23 | 2017-02-22 | 张道松 | Graphene enhanced type carbon fiber composite pantograph pan and manufacturing technology thereof |
-
2017
- 2017-09-11 CN CN201710809681.XA patent/CN107663358A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403276A (en) * | 2014-12-15 | 2015-03-11 | 苏州宽温电子科技有限公司 | High-temperature-resistant and abrasion-resistant macromolecular material |
| CN104830029A (en) * | 2015-06-07 | 2015-08-12 | 安徽华美高分子材料科技有限公司 | High-temperature-resistant and abrasion-resistant high-polymer material |
| CN106433037A (en) * | 2016-09-23 | 2017-02-22 | 张道松 | Graphene enhanced type carbon fiber composite pantograph pan and manufacturing technology thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707243A (en) * | 2018-06-20 | 2018-10-26 | 安徽申科塑业有限公司 | A kind of novel high polymer plastic cement |
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Application publication date: 20180206 |