CN107662390A - Spot jacquard weave high temperature resistant artificial leather - Google Patents

Spot jacquard weave high temperature resistant artificial leather Download PDF

Info

Publication number
CN107662390A
CN107662390A CN201610598621.3A CN201610598621A CN107662390A CN 107662390 A CN107662390 A CN 107662390A CN 201610598621 A CN201610598621 A CN 201610598621A CN 107662390 A CN107662390 A CN 107662390A
Authority
CN
China
Prior art keywords
fabric
hypothallus
polyol
jacquard weave
small molecule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610598621.3A
Other languages
Chinese (zh)
Inventor
季建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Hualian Plastic Products Co Ltd
Original Assignee
Wuxi Hualian Plastic Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Hualian Plastic Products Co Ltd filed Critical Wuxi Hualian Plastic Products Co Ltd
Priority to CN201610598621.3A priority Critical patent/CN107662390A/en
Publication of CN107662390A publication Critical patent/CN107662390A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/18—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by an internal layer formed of separate pieces of material which are juxtaposed side-by-side
    • B32B3/20—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by an internal layer formed of separate pieces of material which are juxtaposed side-by-side of hollow pieces, e.g. tubes; of pieces with channels or cavities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202—Two or more polyesters of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant

Abstract

The present invention relates to a kind of spot jacquard weave high temperature resistant artificial leather, lower floor is hypothallus（1）, upper strata is surface layer（2）, hypothallus is the flame-retardant fibre fabric of bottom（11）With the vacuum plated aluminum film on top（12）It is made, surface layer（2）Made for PU.The hypothallus back side is compounded with backing fabric layers, the backing fabric layers, for a kind of spot jacquard fabric, for front-back two-sided jacquard fabric, its front has uniformly been independently distributed salient point, the salient point is formed on base fabric using the first yarn jacquard weave, and its reverse side is that the vertical striped of base fabric reverse side is formed at by the second yarn jacquard weave, parallel between adjacent stripes.The present invention is made due to composite of the hypothallus for flame-retardant fibre fabric and vacuum plated aluminum film so that can play effective protective action when the artificial leather makes dress ornament or sofa epidermis to high temperature.Spot jacquard weave of the present invention.

Description

Spot jacquard weave high temperature resistant artificial leather
Technical field
The present invention relates to a kind of artificial leather.
Background technology
People can allow cigarette end to touch clothes, sofa etc. unavoidably when smoking, and some make with artificial leather day on surface Regular supplies, because in general artificial leather does not possess heat-resisting ability, cigarette end can cause surface a scar occur, influence it is attractive in appearance and Using effect.
The content of the invention
It is an object of the invention to overcome above-mentioned deficiency, there is provided a kind of resistant to elevated temperatures artificial leather.
The object of the present invention is achieved like this：A kind of spot jacquard weave high temperature resistant artificial leather, lower floor are hypothallus, and upper strata is Surface layer, the hypothallus are made for the flame-retardant fibre fabric of bottom and the vacuum plated aluminum film on top, and the surface layer does for PU Into the formula of the surface layer is by polyester polyols alcohol mixture, polycarbonate polyol, small molecule polyol, 4,4- diphenylmethyls Two different isocyanates of alkane, organic solvent, catalyst, terminator, antioxidant, slipping agent, Ricinate composition, described is poly- Polyethylene glycol adipate glycol and number-average molecular weight of the ester polyol mixture by number-average molecular weight for 2000 ~ 3000g/mol Formed for 2000 ~ 3000g/mol polybutylene glyool adipate, wherein it is more to account for polyester for polyethylene glycol adipate glycol 20 ~ 80wt% of first alcohol mixture, polybutylene glyool adipate accounts for 80 ~ 20wt% of polyester polyols alcohol mixture, described Polycarbonate polyol is poly- carbonic acid 1, and 6- hexylene glycol esterdiols, described small molecule polyol is by ethylene glycol and Isosorbide-5-Nitrae-fourth two Alcohol forms, and wherein ethylene glycol accounts for 50 ~ 100wt% of small molecule polyol, Isosorbide-5-Nitrae-butanediol account for small molecule polyol 50 ~ 0wt%, in terms of the gross mass of polyurethane resin, the mass content of above-mentioned each component is as follows：Polyester polyols alcohol mixture 2 ~ 12%； Polycarbonate polyol 8 ~ 20%；Small molecule polyol 0.5 ~ 1%；The different isocyanates 8 ~ 12% of 4,4- diphenyl methanes two；Have Solvent 55 ~ 78%；Catalyst 0.01 ~ 0.2%；Terminator 0.04 ~ 0.06%；Antioxidant 0.8 ~ 1.5%；Slipping agent 0.8 ~ 1.5% ；Wetting dispersing agent 0.8 ~ 1.5%.The hypothallus back side is compounded with backing fabric layers, the backing fabric layers, for one kind Spot jacquard fabric, it is front-back two-sided jacquard fabric, its front has uniformly been independently distributed salient point, and the salient point is carried using the first yarn Flower is formed on base fabric, and its reverse side is that the vertical striped of base fabric reverse side is formed at by the second yarn jacquard weave, parallel between adjacent stripes.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention due to hypothallus be flame-retardant fibre fabric be made with vacuum plated aluminum film so that the artificial leather make dress ornament or Effective protective action can be played during person's sofa epidermis to high temperature.
The no graphic structure of tow sides jacquard weave of the present invention, can suitable different demand, it is raised that spot can with base fabric Two kinds of colors of color collision are dyed, third dimension is strong, has beautiful outward appearance, and the vertical striped of base fabric reverse side can strengthen fabric Standing sense.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
Wherein：Hypothallus 1, flame-retardant fibre fabric 11, vacuum plated aluminum film 12, surface layer 2.
Embodiment
Referring to Fig. 1, a kind of spot jacquard weave high temperature resistant artificial leather of the present invention, lower floor is hypothallus 1, and upper strata is surface layer 2, the hypothallus 1 is made for the flame-retardant fibre fabric 11 and the vacuum plated aluminum film 12 on top of bottom, and the surface layer 2 is PU Make.The formula of the surface layer 2 is by polyester polyols alcohol mixture, polycarbonate polyol, small molecule polyol, 4,4- hexichol Two different isocyanates of methylmethane, organic solvent, catalyst, terminator, antioxidant, slipping agent, Ricinate composition, it is described Polyester polyols alcohol mixture by number-average molecular weight be 2000 ~ 3000g/mol polyethylene glycol adipate glycol sum divide equally Son amount forms for 2000 ~ 3000g/mol polybutylene glyool adipate, and wherein polyethylene glycol adipate glycol accounts for poly- 20 ~ 80wt% of ester polyol mixture, polybutylene glyool adipate account for 80 ~ 20wt% of polyester polyols alcohol mixture, institute The polycarbonate polyol stated is poly- carbonic acid 1,6- hexylene glycol esterdiols, described small molecule polyol by ethylene glycol and Isosorbide-5-Nitrae- Butanediol forms, and wherein ethylene glycol accounts for 50 ~ 100wt% of small molecule polyol, Isosorbide-5-Nitrae-butanediol account for small molecule polyol 50 ~ 0wt%, in terms of the gross mass of polyurethane resin, the mass content of above-mentioned each component is as follows：Polyester polyols alcohol mixture 2 ~ 12%； Polycarbonate polyol 8 ~ 20%；Small molecule polyol 0.5 ~ 1%；The different isocyanates 8 ~ 12% of 4,4- diphenyl methanes two；Have Solvent 55 ~ 78%；Catalyst 0.01 ~ 0.2%；Terminator 0.04 ~ 0.06%；Antioxidant 0.8 ~ 1.5%；Slipping agent 0.8 ~ 1.5% ；Wetting dispersing agent 0.8 ~ 1.5%.
The hypothallus back side is compounded with backing fabric layers, the backing fabric layers, is a kind of spot jacquard fabric, for just Anti- double-faced jacquard fabric, its front have uniformly been independently distributed salient point, and the salient point is formed on base fabric using the first yarn jacquard weave, its Reverse side is that the vertical striped of base fabric reverse side is formed at by the second yarn jacquard weave, parallel between adjacent stripes.

Claims (1)

1. a kind of spot jacquard weave high temperature resistant artificial leather, lower floor are hypothallus（1）, upper strata is surface layer（2）, it is characterised in that the base Matter layer（1）For the flame-retardant fibre fabric of bottom（11）With the vacuum plated aluminum film on top（12）It is made, the surface layer（2）For PU Make, the formula of the surface layer 2 is by polyester polyols alcohol mixture, polycarbonate polyol, small molecule polyol, 4,4- hexichol Two different isocyanates of methylmethane, organic solvent, catalyst, terminator, antioxidant, slipping agent, Ricinate composition, it is described Polyester polyols alcohol mixture by number-average molecular weight be 2000 ~ 3000g/mol polyethylene glycol adipate glycol sum divide equally Son amount forms for 2000 ~ 3000g/mol polybutylene glyool adipate, and wherein polyethylene glycol adipate glycol accounts for poly- 20 ~ 80wt% of ester polyol mixture, polybutylene glyool adipate account for 80 ~ 20wt% of polyester polyols alcohol mixture, institute The polycarbonate polyol stated is poly- carbonic acid 1,6- hexylene glycol esterdiols, described small molecule polyol by ethylene glycol and Isosorbide-5-Nitrae- Butanediol forms, and wherein ethylene glycol accounts for 50 ~ 100wt% of small molecule polyol, Isosorbide-5-Nitrae-butanediol account for small molecule polyol 50 ~ 0wt%, in terms of the gross mass of polyurethane resin, the mass content of above-mentioned each component is as follows：Polyester polyols alcohol mixture 2 ~ 12%； Polycarbonate polyol 8 ~ 20%；Small molecule polyol 0.5 ~ 1%；The different isocyanates 8 ~ 12% of 4,4- diphenyl methanes two；Have Solvent 55 ~ 78%；Catalyst 0.01 ~ 0.2%；Terminator 0.04 ~ 0.06%；Antioxidant 0.8 ~ 1.5%；Slipping agent 0.8 ~ 1.5% ；Wetting dispersing agent 0.8 ~ 1.5%；The hypothallus back side is compounded with backing fabric layers, the backing fabric layers, for one kind Spot jacquard fabric, it is front-back two-sided jacquard fabric, its front has uniformly been independently distributed salient point, and the salient point is carried using the first yarn Flower is formed on base fabric, and its reverse side is that the vertical striped of base fabric reverse side is formed at by the second yarn jacquard weave, parallel between adjacent stripes.
CN201610598621.3A 2016-07-28 2016-07-28 Spot jacquard weave high temperature resistant artificial leather Pending CN107662390A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610598621.3A CN107662390A (en) 2016-07-28 2016-07-28 Spot jacquard weave high temperature resistant artificial leather

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610598621.3A CN107662390A (en) 2016-07-28 2016-07-28 Spot jacquard weave high temperature resistant artificial leather

Publications (1)

Publication Number Publication Date
CN107662390A true CN107662390A (en) 2018-02-06

Family

ID=61114953

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610598621.3A Pending CN107662390A (en) 2016-07-28 2016-07-28 Spot jacquard weave high temperature resistant artificial leather

Country Status (1)

Country Link
CN (1) CN107662390A (en)

Similar Documents

Publication Publication Date Title
CN206607380U (en) New shirt composite
US20200071879A1 (en) Napped artificial leather
WO2015019287A1 (en) Manufactured product made of resin
CN107662390A (en) Spot jacquard weave high temperature resistant artificial leather
KR100959637B1 (en) Funtional fabrics process using silk yarn or silk union cloth and product by that process
US20140050878A1 (en) Foamed surface covering with coherent layer
CN107663786A (en) The favourable high temperature resistant artificial leather of effect of heat insulation
CN201044982Y (en) Polychloroethylene leather
CN107663779A (en) High supportive high temperature resistant artificial leather
US7491439B2 (en) Shelf liner with natural fibers
CN107663775A (en) Wash the low high temperature resistant artificial leather of deformation rate
CN103088658A (en) Antiflaming artificial leather
CN106087439A (en) The good artificial leather of high temperature resistant serviceability
CN206956438U (en) Two-sided PU leathers
CN107663782A (en) Permanently release a large amount of anion imitated artificial leathers
CN102050049A (en) Anti-slip structure of automobile mat body
CN107663789A (en) Add the siphonage imitated artificial leather multiplied to internal layer sweat
CN202559651U (en) Woven artistic floor
US8124186B2 (en) Method of forming a shelf liner
CN107662389A (en) Light emitting artificial artificial leather
CN105082640A (en) Textured multilayer composite fabric
CN107663776A (en) With superior Memorability double-color artificial leather
CN105274859A (en) Difficultly-deformable artificial leather
CN215243473U (en) Super-tough flame-retardant nylon belt
JP2018048435A (en) Artificial leather substrate, napped artificial leather, shoes and artificial leather with resin layer

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180206

WD01 Invention patent application deemed withdrawn after publication