CN107639912A - A kind of compound PVC board - Google Patents
A kind of compound PVC board Download PDFInfo
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- CN107639912A CN107639912A CN201710894202.9A CN201710894202A CN107639912A CN 107639912 A CN107639912 A CN 107639912A CN 201710894202 A CN201710894202 A CN 201710894202A CN 107639912 A CN107639912 A CN 107639912A
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Abstract
The present invention relates to a kind of compound PVC board, belong to plastics arts, the compound PVC board includes the first weather-proof PVC composite beds, the first tack coat, PVC body layers, the second tack coat, PVC compound buffer layers and the second weather-proof PVC composite beds stacked gradually.Compared with prior art, beneficial effects of the present invention are：The present invention uses multi-layer compound structure, the PVC board of the present invention is compounded to form using the PVC material of difference in functionality so that it has excellent stability, resistance to ag(e)ing and shock resistance, to meet different use environments.
Description
Technical field
The present invention relates to plastics arts, and in particular to a kind of compound PVC board.
Background technology
PVC material is polyvinyl chloride, and it is one of plastic product that yield is maximum in the world, cheap, is widely used,
Corvic is white or buff powder, can not individually be used, it is necessary to by being modified.PVC is the white of impalpable structure
Color powder, the degree of branching is smaller, poor to the stability of light and heat.Different additives, polychlorostyrene can be added according to different purposes
Different physical property and mechanical property can be presented in vinyl plastics.The existing plastic plate performance using PVC material preparation is single.Such as
A kind of what compound PVC board of design, is industry urgent problem to be solved.
The content of the invention
The purpose of the present invention is to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of compound PVC board.
To achieve the above object, a kind of compound PVC board proposed by the present invention, the compound PVC board include layer successively
Folded the first weather-proof PVC composite beds, the first tack coat, PVC body layers, the second tack coat, PVC compound buffer layers and second are resistance to
Wait PVC composite beds；
The first weather-proof PVC composite beds are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；Second
Alkene-TFE copolymer 20-50 parts；Polyethylene 20-40 parts；2,4 dihydroxyl benzophenone 1-4 parts；Triphenyl phosphite 1-
2 parts；Peroxidating -2- ethylhexyl carbonate tert-pentyl ester 1-3 parts；Aluminum oxide nanoparticle 2-4 parts；Magnesium fluoride nano particle 1-3 parts；
Alkali-free glass fibre 5-15 parts；Silicon nanowires 3-6 parts；
The PVC body layers are by composed of the following components in percentage by weight：PVC100 parts；2- (2'- hydroxyl -5'- first
Base phenyl) BTA 1-3 parts；Trisnonyl phenyl phosphite 1-4 parts；1,1- (double tert-butyl peroxides) -3,3,5- trimethyls
Hexamethylene 1-3 parts；γ-methacryloxypropyl trimethoxy silane 1-3 parts；Glass fibre 10-15 parts；
The PVC compound buffer layers are by composed of the following components in percentage by weight：PVC100 parts；Silicon rubber 20-40
Part；EVA resin 10-30 parts；Methacrylate-butadiene-styrene 20-40 parts；2,4 dihydroxyl benzophenone 1-3
Part；Four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythritol ester 2-5 parts；Double (the tertiary fourths of 2,5- dimethyl -2,5-
Base peroxy) hexane 1-3 parts；Vinyltriacetoxy silane 2-4 parts；Carbon fiber 5-15 parts；Nano SiO 2 particle 2-6
Part；Cu9S5 nano particle 2-5 parts；Boron nitride nanometer particle 1-3 parts；
The second weather-proof PVC composite beds are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；Poly- three
Fluorine vinyl chloride 20-50 parts；PP resin 10-20 parts；PEN resin 5-15 parts；Three (2,4- di-tert-butyl-phenyls) phosphite ester 1-5
Part；Double -2,2,6,6- tetramethyl piperidine alcohol ester 1-3 the parts of decanedioic acid；2- (2'- hydroxyl -5'- aminomethyl phenyls) BTA 2-4 parts；
Peroxidating -2- ethylhexyl carbonate tert-pentyl ester 1-4 parts；The tert-butyl peroxide silane 1-4 parts of vinyl three；Black phosphorus alkene powder 1-3
Part；Molybdenum sulfide nanoparticles 2-5 parts；Titania nanoparticles 3-6 parts；Single-walled carbon nanotube 1-5 parts.
Preferably, first tack coat and the second tack coat are acrylic resin binder.
Preferably, the thickness of the first weather-proof PVC composite beds is 900-1500 microns, the thickness of the PVC body layers
Spend for 3-6 millimeters, the thickness of the PVC compound buffer layers is 600-1000 microns, the thickness of the second weather-proof PVC composite beds
For 1000-1500 microns, the thickness of first tack coat and the second tack coat is 20-100 microns.
Preferably, the particle diameter of the aluminum oxide nanoparticle in the first weather-proof PVC composite beds is received for 500-700
Rice, the particle diameter of the magnesium fluoride nano particle is 600-900 nanometers, and the length of the alkali-free glass fibre is 3-6 microns, described
The length of silicon nanowires is 1-3 microns.
Preferably, the length of the glass fibre in the PVC body layers is 3-5 microns.
Preferably, the length of the carbon fiber in the PVC compound buffer layers is 2-6 microns, the silica nanometer
The particle diameter of particle is 600-1000 nanometers, and the particle diameters of the Cu9S5 nano particles is 100-300 nanometers, the boron nitride nanometer
The particle diameter of particle is 300-700 nanometers.
Preferably, the particle diameter of the molybdenum sulfide nanoparticles in the second weather-proof PVC composite beds is 200-900 nanometers,
The particle diameter 600-1000 nanometers of the titania nanoparticles.
Beneficial effects of the present invention are as follows：
The compound PVC board of the present invention uses multi-layer compound structure, is compounded to form the present invention's using the PVC material of difference in functionality
PVC board so that it has excellent stability, resistance to ag(e)ing and shock resistance, to meet different use environments.
By adding ethylene-tetrafluoroethylene copolymer in the polyvinyl chloride resin of the first weather-proof PVC composite beds, it is effectively improved
Weather resistance, while aluminum oxide nanoparticle, magnesium fluoride nano particle, alkali-free glass are added in the first weather-proof PVC composite beds
Fiber and silicon nanowires, effectively improve its heat conductivility, decay resistance, mechanical performance and antistatic property.
Ordinary adjuvants and glass fibre are added in selection only in PVC body layers, it can be ensured that it has very good mechanical properties
While effectively reduce production cost
By adding silicon rubber and EVA resin in the PVC of PVC compound buffer layers, its shock resistance can be improved, and carbon is fine
The addition of dimension, nano SiO 2 particle, Cu9S5 nano particles, boron nitride nanometer particle, by above-mentioned material with cooperation
With effectively improving its mechanical performance and antistatic property.
Select to add polytrifluorochloroethylene in the polyvinyl chloride resin of the second weather-proof PVC composite beds, effectively improve its weather resistance,
Black phosphorus alkene powder, molybdenum sulfide nanoparticles, titania nanoparticles, single wall are added in the second weather-proof PVC composite beds simultaneously
CNT can improve its ageing resistace, antistatic property, heat conductivility, mechanical performance and anti-microbial property.
Brief description of the drawings
Fig. 1 is the structural representation of the compound PVC board of the present invention.
Embodiment
Referring to Fig. 1, a kind of compound PVC board proposed by the present invention, the compound PVC board includes first stacked gradually
Weather-proof PVC composite beds 1, the first tack coat 2, PVC body layers 3, the second tack coat 4, PVC compound buffer layers 5 and second are weather-proof
PVC composite beds 6；The first weather-proof PVC composite beds 1 are by composed of the following components in percentage by weight：Polyvinyl chloride resin
100 parts；Ethylene-tetrafluoroethylene copolymer 20-50 parts；Polyethylene 20-40 parts；2,4 dihydroxyl benzophenone 1-4 parts；Phosphorous acid
Triphenylmethyl methacrylate 1-2 parts；Peroxidating -2- ethylhexyl carbonate tert-pentyl ester 1-3 parts；Aluminum oxide nanoparticle 2-4 parts；Magnesium fluoride nanometer
Grain 1-3 parts；Alkali-free glass fibre 5-15 parts；Silicon nanowires 3-6 parts；The PVC body layers 3 by calculate in percentage by weight by
Following components forms：PVC100 parts；2- (2'- hydroxyl -5'- aminomethyl phenyls) BTA 1-3 parts；Trisnonyl phenyl phosphite 1-
4 parts；1,1- (double tert-butyl peroxides) -3,3,5- trimethyl-cyclohexane 1-3 parts；γ-methacryloxypropyl trimethoxy
Base silane 1-3 parts；Glass fibre 10-15 parts；The PVC compound buffer layers 5 by calculating by following components in percentage by weight
Composition：PVC100 parts；Silicon rubber 20-40 parts；EVA resin 10-30 parts；Methacrylate-butadiene-styrene 20-
40 parts；2,4 dihydroxyl benzophenone 1-3 parts；Four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythritol ester 2-5
Part；2,5- dimethyl -2,5- bis(t-butylperoxy) hexane 1-3 parts；Vinyltriacetoxy silane 2-4 parts；Carbon fiber
5-15 parts；Nano SiO 2 particle 2-6 parts；Cu9S5 nano particle 2-5 parts；Boron nitride nanometer particle 1-3 parts；Described second
Weather-proof PVC composite beds 6 are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；Polytrifluorochloroethylene 20-
50 parts；PP resin 10-20 parts；PEN resin 5-15 parts；Three (2,4- di-tert-butyl-phenyls) phosphite ester 1-5 parts；Decanedioic acid pair-
2,2,6,6- tetramethyl piperidine alcohol ester 1-3 parts；2- (2'- hydroxyl -5'- aminomethyl phenyls) BTA 2-4 parts；Peroxidating -2- second
Base hexyl carbonic acid tert-pentyl ester 1-4 parts；The tert-butyl peroxide silane 1-4 parts of vinyl three；Black phosphorus alkene powder 1-3 parts；Molybdenum sulfide is received
Rice grain 2-5 parts；Titania nanoparticles 3-6 parts；Single-walled carbon nanotube 1-5 parts.
Wherein, the tack coat 4 of the first tack coat 2 and second is acrylic resin binder.The first weather-proof PVC
The thickness of composite bed 1 is 900-1500 microns, and the thickness of the PVC body layers 3 is 3-6 millimeters, the PVC compound buffer layers 5
Thickness be 600-1000 microns, the thickness of the second weather-proof PVC composite beds 6 is 1000-1500 microns, it is described first bond
The thickness of the tack coat 4 of layer 2 and second is 20-100 microns.The aluminium oxide nano in the first weather-proof PVC composite beds 1
The particle diameter of grain is 500-700 nanometers, and the particle diameter of the magnesium fluoride nano particle is 600-900 nanometers, the alkali-free glass fibre
Length be 3-6 microns, the length of the silicon nanowires is 1-3 microns.The length of glass fibre in the PVC body layers 3
For 3-5 microns.The length of carbon fiber in the PVC compound buffer layers 5 is 2-6 microns, the nano SiO 2 particle
Particle diameter is 600-1000 nanometers, and the particle diameter of the Cu9S5 nano particles is 100-300 nanometers, the boron nitride nanometer particle
Particle diameter is 300-700 nanometers.The particle diameter of molybdenum sulfide nanoparticles in the second weather-proof PVC composite beds 6 is received for 200-900
Rice, the particle diameter 600-1000 nanometers of the titania nanoparticles.
Embodiment 1
Referring to Fig. 1, a kind of compound PVC board proposed by the present invention, the compound PVC board includes stacking gradually first weather-proof
PVC composite beds 1, the first tack coat 2, PVC body layers 3, the second tack coat 4,5 and second weather-proof PVC of PVC compound buffer layers are answered
Close layer 6；The first weather-proof PVC composite beds 1 are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；
30 parts of ethylene-tetrafluoroethylene copolymer；30 parts of polyethylene；2 parts of 2,4 dihydroxyl benzophenone；1 part of triphenyl phosphite；Peroxide
2 parts of change -2- ethylhexyl carbonates tert-pentyl ester；3 parts of aluminum oxide nanoparticle；2 parts of magnesium fluoride nano particle；Alkali-free glass fibre 10
Part；4 parts of silicon nanowires；The PVC body layers 3 are by composed of the following components in percentage by weight：PVC100 parts；2-
(2'- hydroxyl -5'- aminomethyl phenyls) 2 parts of BTA；2 parts of trisnonyl phenyl phosphite；1,1- (double tert-butyl peroxides) -3,
2 parts of 3,5- trimethyl-cyclohexanes；2 parts of γ-methacryloxypropyl trimethoxy silane；12 parts of glass fibre；The PVC
Compound buffer layer 5 is by composed of the following components in percentage by weight：PVC100 parts；30 parts of silicon rubber；EVA resin 20
Part；30 parts of Methacrylate-butadiene-styrene；2 parts of 2,4 dihydroxyl benzophenone；Four [β-(bis- tertiary fourths of 3,5-
Base -4- hydroxy phenyls) propionic acid] 3 parts of pentaerythritol ester；2 parts of 2,5- dimethyl -2,5- bis(t-butylperoxy)s hexane；Ethene
3 parts of base triacetoxysilane；10 parts of carbon fiber；4 parts of nano SiO 2 particle；3 parts of Cu9S5 nano particles；Boron nitride is received
2 parts of rice grain；The second weather-proof PVC composite beds 6 are by composed of the following components in percentage by weight：Polyvinyl chloride resin 100
Part；30 parts of polytrifluorochloroethylene；15 parts of PP resins；10 parts of PEN resins；Three 3 parts of (2,4- di-tert-butyl-phenyls) phosphite esters；The last of the ten Heavenly stems
The double 2 parts of -2,2,6,6- tetramethyl piperidines alcohol esters of diacid；2- (2'- hydroxyl -5'- aminomethyl phenyls) 3 parts of BTA；Peroxidating -2-
2 parts of ethylhexyl carbonate tert-pentyl ester；2 parts of three tert-butyl peroxide silane of vinyl；2 parts of black phosphorus alkene powder；Molybdenum sulfide nanometer
3 parts of grain；4 parts of titania nanoparticles；3 parts of single-walled carbon nanotube.
Wherein, the tack coat 4 of the first tack coat 2 and second is acrylic resin binder.The first weather-proof PVC
The thickness of composite bed 1 is 1000 microns, and the thickness of the PVC body layers 3 is 4 millimeters, the thickness of the PVC compound buffer layers 5
For 700 microns, the thickness of the second weather-proof PVC composite beds 6 is 1200 microns, the tack coat 4 of the first tack coat 2 and second
Thickness be 50 microns.The particle diameter of the aluminum oxide nanoparticle in the first weather-proof PVC composite beds 1 is 600 nanometers, institute
The particle diameter for stating magnesium fluoride nano particle is 700 nanometers, and the length of the alkali-free glass fibre is 4 microns, the silicon nanowires
Length is 2 microns.The length of glass fibre in the PVC body layers 3 is 4 microns.Carbon in the PVC compound buffer layers 5
The length of fiber is 3 microns, and the particle diameter of the nano SiO 2 particle is 700 nanometers, the particle diameter of the Cu9S5 nano particles
For 200 nanometers, the particle diameter of the boron nitride nanometer particle is 500 nanometers.Molybdenum sulfide in the second weather-proof PVC composite beds 6
The particle diameter of nano particle is 500 nanometers, 800 nanometers of the particle diameter of the titania nanoparticles.
Embodiment 2
Referring to Fig. 1, a kind of compound PVC board proposed by the present invention, the compound PVC board includes stacking gradually first weather-proof
PVC composite beds 1, the first tack coat 2, PVC body layers 3, the second tack coat 4,5 and second weather-proof PVC of PVC compound buffer layers are answered
Close layer 6；The first weather-proof PVC composite beds 1 are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；
40 parts of ethylene-tetrafluoroethylene copolymer；35 parts of polyethylene；3 parts of 2,4 dihydroxyl benzophenone；2 parts of triphenyl phosphite；Peroxide
3 parts of change -2- ethylhexyl carbonates tert-pentyl ester；3 parts of aluminum oxide nanoparticle；2 parts of magnesium fluoride nano particle；Alkali-free glass fibre 12
Part；5 parts of silicon nanowires；The PVC body layers 3 are by composed of the following components in percentage by weight：PVC100 parts；2-
(2'- hydroxyl -5'- aminomethyl phenyls) 1 part of BTA；3 parts of trisnonyl phenyl phosphite；1,1- (double tert-butyl peroxides) -3,
1 part of 3,5- trimethyl-cyclohexanes；1 part of γ-methacryloxypropyl trimethoxy silane；14 parts of glass fibre；The PVC
Compound buffer layer 5 is by composed of the following components in percentage by weight：PVC100 parts；35 parts of silicon rubber；EVA resin 25
Part；35 parts of Methacrylate-butadiene-styrene；3 parts of 2,4 dihydroxyl benzophenone；Four [β-(bis- tertiary fourths of 3,5-
Base -4- hydroxy phenyls) propionic acid] 4 parts of pentaerythritol ester；2 parts of 2,5- dimethyl -2,5- bis(t-butylperoxy)s hexane；Ethene
4 parts of base triacetoxysilane；12 parts of carbon fiber；5 parts of nano SiO 2 particle；4 parts of Cu9S5 nano particles；Boron nitride is received
3 parts of rice；The second weather-proof PVC composite beds 6 are by composed of the following components in percentage by weight：Polyvinyl chloride resin 100
Part；4 parts of polytrifluorochloroethylene；18 parts of PP resins；12 parts of PEN resins；Three 2 parts of (2,4- di-tert-butyl-phenyls) phosphite esters；The last of the ten Heavenly stems
The double 3 parts of -2,2,6,6- tetramethyl piperidines alcohol esters of diacid；2- (2'- hydroxyl -5'- aminomethyl phenyls) 4 parts of BTA；Peroxidating -2-
3 parts of ethylhexyl carbonate tert-pentyl ester；3 parts of three tert-butyl peroxide silane of vinyl；2 parts of black phosphorus alkene powder；Molybdenum sulfide nanometer
4 parts of grain；5 parts of titania nanoparticles；4 parts of single-walled carbon nanotube.
Wherein, the tack coat 4 of the first tack coat 2 and second is acrylic resin binder.The first weather-proof PVC
The thickness of composite bed 1 is 1200 microns, and the thickness of the PVC body layers 3 is 5 millimeters, the thickness of the PVC compound buffer layers 5
For 900 microns, the thickness of the second weather-proof PVC composite beds 6 is 1500 microns, the tack coat 4 of the first tack coat 2 and second
Thickness be 80 microns.The particle diameter of the aluminum oxide nanoparticle in the first weather-proof PVC composite beds 1 is 650 nanometers, institute
The particle diameter for stating magnesium fluoride nano particle is 800 nanometers, and the length of the alkali-free glass fibre is 5 microns, the silicon nanowires
Length is 2 microns.The length of glass fibre in the PVC body layers 3 is 5 microns.Carbon in the PVC compound buffer layers 5
The length of fiber is 5 microns, and the particle diameter of the nano SiO 2 particle is 900 nanometers, the particle diameter of the Cu9S5 nano particles
For 150 nanometers, the particle diameter of the boron nitride nanometer particle is 600 nanometers.Molybdenum sulfide in the second weather-proof PVC composite beds 6
The particle diameter of nano particle is 500 nanometers, 900 nanometers of the particle diameter of the titania nanoparticles.
Finally it should be noted that：Obviously, above-described embodiment is only intended to clearly illustrate example of the present invention, and simultaneously
The non-restriction to embodiment.For those of ordinary skill in the field, can also do on the basis of the above description
Go out other various forms of changes or variation.There is no necessity and possibility to exhaust all the enbodiments.And thus drawn
Among the obvious changes or variations that Shen goes out is still in protection scope of the present invention.
Claims (7)
- A kind of 1. compound PVC board, it is characterised in that：The first weather-proof PVC that the compound PVC board includes stacking gradually is compound Layer, the first tack coat, PVC body layers, the second tack coat, PVC compound buffer layers and the second weather-proof PVC composite beds；The first weather-proof PVC composite beds are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；Second Alkene-TFE copolymer 20-50 parts；Polyethylene 20-40 parts；2,4 dihydroxyl benzophenone 1-4 parts；Triphenyl phosphite 1- 2 parts；Peroxidating -2- ethylhexyl carbonate tert-pentyl ester 1-3 parts；Aluminum oxide nanoparticle 2-4 parts；Magnesium fluoride nano particle 1-3 parts； Alkali-free glass fibre 5-15 parts；Silicon nanowires 3-6 parts；The PVC body layers are by composed of the following components in percentage by weight：PVC100 parts；2- (2'- hydroxyl -5'- first Base phenyl) BTA 1-3 parts；Trisnonyl phenyl phosphite 1-4 parts；1,1- (double tert-butyl peroxides) -3,3,5- trimethyls Hexamethylene 1-3 parts；γ-methacryloxypropyl trimethoxy silane 1-3 parts；Glass fibre 10-15 parts；The PVC compound buffer layers are by composed of the following components in percentage by weight：PVC100 parts；Silicon rubber 20-40 Part；EVA resin 10-30 parts；Methacrylate-butadiene-styrene 20-40 parts；2,4 dihydroxyl benzophenone 1-3 Part；Four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythritol ester 2-5 parts；Double (the tertiary fourths of 2,5- dimethyl -2,5- Base peroxy) hexane 1-3 parts；Vinyltriacetoxy silane 2-4 parts；Carbon fiber 5-15 parts；Nano SiO 2 particle 2-6 Part；Cu9S5 nano particle 2-5 parts；Boron nitride nanometer particle 1-3 parts；The second weather-proof PVC composite beds are by composed of the following components in percentage by weight：100 parts of polyvinyl chloride resin；Poly- three Fluorine vinyl chloride 20-50 parts；PP resin 10-20 parts；PEN resin 5-15 parts；Three (2,4- di-tert-butyl-phenyls) phosphite ester 1-5 Part；Double -2,2,6,6- tetramethyl piperidine alcohol ester 1-3 the parts of decanedioic acid；2- (2'- hydroxyl -5'- aminomethyl phenyls) BTA 2-4 parts； Peroxidating -2- ethylhexyl carbonate tert-pentyl ester 1-4 parts；The tert-butyl peroxide silane 1-4 parts of vinyl three；Black phosphorus alkene powder 1-3 Part；Molybdenum sulfide nanoparticles 2-5 parts；Titania nanoparticles 3-6 parts；Single-walled carbon nanotube 1-5 parts.
- 2. compound PVC board according to claim 1, it is characterised in that：First tack coat and the second tack coat are equal For acrylic resin binder.
- 3. compound PVC board according to claim 1, it is characterised in that：The thickness of the first weather-proof PVC composite beds is 900-1500 microns, the thickness of the PVC body layers is 3-6 millimeters, and the thickness of the PVC compound buffer layers is micro- for 600-1000 Rice, the thickness of the second weather-proof PVC composite beds are 1000-1500 microns, the thickness of first tack coat and the second tack coat Spend for 20-100 microns.
- 4. compound PVC board according to claim 1, it is characterised in that：It is described in the first weather-proof PVC composite beds The particle diameter of aluminum oxide nanoparticle is 500-700 nanometers, and the particle diameter of the magnesium fluoride nano particle is 600-900 nanometers, described The length of alkali-free glass fibre is 3-6 microns, and the length of the silicon nanowires is 1-3 microns.
- 5. compound PVC board according to claim 1, it is characterised in that：The length of glass fibre in the PVC body layers Spend for 3-5 microns.
- 6. compound PVC board according to claim 1, it is characterised in that：Carbon fiber in the PVC compound buffer layers Length is 2-6 microns, and the particle diameter of the nano SiO 2 particle is 600-1000 nanometers, the grain of the Cu9S5 nano particles Footpath is 100-300 nanometers, and the particle diameter of the boron nitride nanometer particle is 300-700 nanometers.
- 7. compound PVC board according to claim 1, it is characterised in that：Vulcanization in the second weather-proof PVC composite beds The particle diameter of molybdenum nano particle is 200-900 nanometers, the particle diameter 600-1000 nanometers of the titania nanoparticles.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359172A (en) * | 2018-03-20 | 2018-08-03 | 湖南金龙电缆有限公司 | Insulating layer and sheath material of a kind of charging pile connecting cable and preparation method thereof |
| CN111270952A (en) * | 2020-03-27 | 2020-06-12 | 浙江宝盛塑业有限公司 | PVC folding door and preparation method thereof |
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| JP2004058583A (en) * | 2002-07-31 | 2004-02-26 | Du Pont Mitsui Polychem Co Ltd | Laminate |
| CN103524936A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Aging-resistant PVC cable sheath material and preparation method |
| CN104385735A (en) * | 2014-12-15 | 2015-03-04 | 山东博拓塑业股份有限公司 | Colored polyvinyl chloride foamed sheet and preparation method thereof |
| CN106700342A (en) * | 2016-12-23 | 2017-05-24 | 宁波泰甬汽车零部件有限公司 | Injection molding grade PVC composite material high in mobility and melt strength |
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2017
- 2017-09-28 CN CN201710894202.9A patent/CN107639912B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004058583A (en) * | 2002-07-31 | 2004-02-26 | Du Pont Mitsui Polychem Co Ltd | Laminate |
| CN103524936A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Aging-resistant PVC cable sheath material and preparation method |
| CN104385735A (en) * | 2014-12-15 | 2015-03-04 | 山东博拓塑业股份有限公司 | Colored polyvinyl chloride foamed sheet and preparation method thereof |
| CN106700342A (en) * | 2016-12-23 | 2017-05-24 | 宁波泰甬汽车零部件有限公司 | Injection molding grade PVC composite material high in mobility and melt strength |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359172A (en) * | 2018-03-20 | 2018-08-03 | 湖南金龙电缆有限公司 | Insulating layer and sheath material of a kind of charging pile connecting cable and preparation method thereof |
| CN111270952A (en) * | 2020-03-27 | 2020-06-12 | 浙江宝盛塑业有限公司 | PVC folding door and preparation method thereof |
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| CN107639912B (en) | 2019-07-19 |
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