CN107629644A - A kind of new light curable conductive coating and preparation method thereof - Google Patents
A kind of new light curable conductive coating and preparation method thereof Download PDFInfo
- Publication number
- CN107629644A CN107629644A CN201710871526.0A CN201710871526A CN107629644A CN 107629644 A CN107629644 A CN 107629644A CN 201710871526 A CN201710871526 A CN 201710871526A CN 107629644 A CN107629644 A CN 107629644A
- Authority
- CN
- China
- Prior art keywords
- parts
- conductive coating
- light curable
- curable conductive
- new light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of new light curable conductive coating and preparation method thereof, constituent is：Constituent is：5~10 parts of light trigger, 25~35 parts of vinylated carbon nano-tube material, 70~80 parts of unsaturated-resin, 15~25 parts of activity diluting monomer, 1~5 part of dispersant, 0.5~2 part of defoamer, 0~10 part of function additive.The vinylated carbon nano-tube material of medium vinyl of the present invention participates in Light Curing, entirety is combined into chemical bond form with unsaturated-resin after solidification, improve the hardness and wearability of film, vinylated carbon nano-tube material forms tridimensional network after paint solidification with resin simultaneously, conductive channel is provided between different CNTs, thus the coating has good electric conductivity；The relatively conventional solvent-borne type electrically-conducting paint of described light curable conductive coating, more environmentally-friendly, energy-conservation.
Description
Technical field
The present invention relates to a kind of new light curable conductive coating and preparation method thereof, belong to electrically-conducting paint technical field.
Background technology
Electrically-conducting paint is applied on the high polymer material of high resistivity, with conduction electric current and excludes accumulation electrostatic charge
The sapecial coating of ability, the surface or inside of any shape base material can be coated on.Electrically-conducting paint can be divided by composition and electrical conduction mechanism
For two major classes：Structural type (also known as Intrinsical) electrically-conducting paint and compound (also known as addition type) electrically-conducting paint.It is wherein compound to lead
Electrocoating paint is in epoxy resin field using relatively broad.
Chinese patent CN201210556682.5 provides a kind of electrically-conducting paint, and it includes：1wt%~8wt% graphite
Alkene, 0.1w%~1wt% functionalization graphene, 15wt%~30wt% epoxy resin and curing agent, 0.2wt%~
1.5wt% wetting dispersing agent, 0.1wt%~0.5wt% defoamer, 0~30wt% conductive filler, surplus are solvent；
The functionalization graphene is the functionalization graphene containing amino or the functionalization graphene containing sulfydryl.Due to the invention
Amino or sulfydryl are carried in functionalization graphene, it preferably can be dispersed in system, while amino or sulfydryl energy and asphalt mixtures modified by epoxy resin
Epoxide group reaction in fat, improve the adhesion of coating；On the other hand, graphene not only have laminated structure and radius-thickness ratio compared with
Greatly, its plurality of layers arranged in parallel in film and under conditions of few additive, thus electrically-conducting paint have it is preferably conductive
Property and tack.But the invention organic solvent content is high, non-reactive conductive filler accounting is big, thus exist the feature of environmental protection it is poor,
The shortcomings that film easy efflorescence.
Photocureable coating is also known as ultraviolet-curing paint, is one kind of radiation curable coating, refers mainly under light illumination may be used
With a kind of new coating of rapid crosslinking curing film forming, because of its efficient application and the feature such as environment-friendly, obtained in coating industry
To extensive use.Compared with solvent based coating, photocureable coating has fast curing rate, thing volatile solvent, saves the energy, expense
With it is low, can automated production the features such as.But electrically-conducting paint is less in the application of curing field.
The content of the invention
The shortcomings that to overcome prior art and deficiency, primary and foremost purpose of the invention aim to provide a kind of new light curable conductive
Coating.
Another object of the present invention is to provide a kind of preparation method of described new light curable conductive coating.
A kind of new light curable conductive coating of the present invention, constituent are：5~10 parts of light trigger, vinyl
20~30 parts of carbon nano tube material, containing unsaturated group substitution 10~15 parts of polythiophene, 70~80 parts of unsaturated-resin,
15~25 parts of activity diluting monomer, 1~5 part of dispersant, 0.5~2 part of defoamer, 0~10 part of function additive.
Described light trigger is benzophenone, benzoin ethyl ether, benzoin dimethylether, 2- hydroxy-2-methyl -1- benzene
Base -1- acetone, 1- hydroxy-cyciohexyls phenyl ketone, 2,4,6- trimethylbenzoyls diphenyl phosphine oxide, double 2,4,6- trimethyls
At least one of benzoyloxy phenyl phosphine oxide.
The preparation method of described vinylated carbon nano-tube material is：By 15~20 parts of aminated carbon nano tubes, 40~
60 parts of organic solvents are added in reactor and are uniformly dispersed, and are heated to 50~80 DEG C, then dropwise be added dropwise 5~10 part 10%~
20% GMA, 20~30min are added dropwise, and 50~80 DEG C are continued 2~4h of reaction, are cooled to room temperature
By filtering, organic solvent washing, drying, vinylated carbon nanomaterial is obtained.
The described polythiophene containing unsaturated group substitution has lower graph structure (R is the substituent containing double bond), excellent
Elect as in poly- 3- acryloxies thiophene, poly- 3- methacroyloxyethoxies thiophene, poly- 3- phenyl vinyls thiophene
It is at least one.
Described unsaturated-resin is polyurethane acrylate resin, unsaturated polyester resin.
Described reactive diluent is hydroxy-ethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, metering system
Sour hydroxypropyl acrylate, BDO diacrylate, 1,6- hexanediyl ester, neopentylglycol diacrylate, 3 the third two
Alcohols diacrylate, Glycerin triacrylate, two contracting trimethylolpropane tetra-acrylates, the third oxidation neopentyl glycol
At least one of diacrylate, ethoxylated trimethylolpropane triacrylate.
Described dispersant is at least one of BYK-P104, BYK-P105, BYK-P5040 dispersant.
Described defoamer selects BYK-022, BYK-088, SN313, EFKA-2550 at least one.
Described function additive select in order to improve the hardening agent of hardness, in order to reduce the delustering agent of coating film gloss, in order to
Improve the scratch resistant scratching resistant of film, in order to prevent coating from laminating the antiblocking agent of adhesion, in order to increase the wear-resisting of coating
Property anti-wear agent, in order to prevent outdoor coating anti-aging and turn yellow ultra-violet absorber, in order to purify the negative ion powder of air
Additive, in order to change the mask agent of coating smell.
Described aminated carbon nano tube is the small size multi-walled carbon nanotube of ethylenediamine grafting, diethylenetriamine grafting
Small size multi-walled carbon nanotube, the small size multi-walled carbon nanotube of triethylene tetramine grafting, the small size of TEPA grafting
At least one of multi-walled carbon nanotube, N, the small size multi-walled carbon nanotube of N- dimethyl-p-toluidines grafting；Amination connects
Branch rate is 6~15%.
Described organic solvent is phenmethylol, benzyl carbinol, glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether
In acetic acid esters, propylene glycol monomethyl ether, propylene glycol monobutyl ether, ethyl acetate, butyl acetate, toluene, dimethylbenzene, acetone, butanone
It is at least one.
A kind of preparation method of new light curable conductive coating of the present invention comprises the steps：Into reactor according to
It is secondary to add light trigger, unsaturated-resin, vinylated carbon nano-tube material, the polythiophene containing unsaturated group substitution, work
Property diluting monomer, inorganic color stuffing, dispersant, defoamer；A kind of reaction raw materials are often added, after being stirred uniformly, then are added
Enter a kind of lower reaction raw materials, fully dispersed uniform photocureable coating that must be described；Finally by spraying, brush, the mode of dip-coating
Suitable for substrate surfaces such as timber, glass, ceramics, cement, in an oven after 60 ± 10 DEG C of dry 10~30min, with 80 ± 50W/
Cm mercury lamps, 5m/min linear velocity photocuring, film performance are tested after completion of cure.
A kind of the advantages of new light curable conductive coating of the present invention is：In described photocureable coating solidification process
In, vinylated carbon nano-tube material, the polythiophene containing unsaturated group substitution participate in Light Curing, with unsaturated tree
Fat, reactive diluent polymerize to form tridimensional network together, and conduction is provided between different CNTs, polythiophene unit
Passage, the coating have good electric conductivity；Described light curable conductive coating reactive diluent participates in Light Curing, nothing
Other organic solvents, more environmentally-friendly, energy-conservation.
Embodiment
A kind of new light curable conductive coating of the present invention and preparation method thereof is done with reference to embodiment further
Description.It is understood that specific embodiment described herein is used only for explaining related invention, rather than the limit to the invention
It is fixed.
Embodiment 1
A kind of new light curable conductive coating, concrete composition composition are such as following table：
6 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone, 20 parts of vinylated carbon nano-tube material, poly- 3- acryloyl-oxies
15 parts of base thiophene, 74 parts of polyurethane acrylate resin, 25 parts of 1,6- hexanediyl esters, 5 parts of BYK-P104, EFKA-
2550 2 parts, 2 parts of scratching resistant.
The preparation method of described vinylated carbon nano-tube material is：By the more wall carbon of small size of 15 parts of ethylenediamine grafting
Nanotube (amination grafting rate be 15%), 60 parts of phenmethylols are added in reactor and are uniformly dispersed, and are heated to 50 DEG C, then by
10 part 10% of part GMA is added dropwise in drop, and 30min is added dropwise, and 50 DEG C are continued to react 4h, are cooled to room
Wen Houjing filterings, phenmethylol washing, dry, obtain vinylated carbon nanomaterial.
Embodiment 2
A kind of new light curable conductive coating, concrete composition composition are such as following table：
5 parts of 2,4,6- trimethylbenzoyls diphenyl phosphine oxide, 25 parts of vinylated carbon nano-tube material, poly- 3- phenyl
12 parts of vinyl thiophene, 70 parts of unsaturated polyester resin, 15 parts of neopentylglycol diacrylate, 1 part of BYK-P105, SN313
0.5 part.
The preparation method of described vinylated carbon nano-tube material is：The small size of 20 parts of diethylenetriamine grafting is more
Wall carbon nano tube (amination grafting rate is 6%), 40 parts of propylene glycol monobutyl ethers are added in reactor and are uniformly dispersed, and are heated to 80
DEG C, then part GMA of 5 part 20% of dropwise addition, 20min are added dropwise dropwise, and 80 DEG C are continued to react 2h,
It is cooled to after room temperature and washs drying through filtering, propylene glycol monobutyl ether, obtains vinylated carbon nanomaterial.
Embodiment 3
A kind of new light curable conductive coating, concrete composition composition are such as following table：
10 parts of 1- hydroxy-cyciohexyls phenyl ketone, 30 parts of vinylated carbon nano-tube material, poly- 3- phenyl vinyls thiophene
10 parts of fen, 80 parts of polyurethane acrylate resin, 26 parts of tripropylene glycol class diacrylate, 5 parts of BYK-P5040 dispersants,
09 part of BYK-088,10 parts of anti-wear agent.
The preparation method of described vinylated carbon nano-tube material is：The small size of 17 parts of triethylene tetramine grafting is more
Wall carbon nano tube (amination grafting rate is 11%), 56 parts of ethyl acetate are added in reactor and are uniformly dispersed, and are heated to 70 DEG C,
Then 8 part 14% of part GMA is added dropwise dropwise, 27min is added dropwise, and 70 DEG C are continued to react 3h, cooling
Wash, dry through filtering, ethyl acetate after to room temperature, obtain vinylated carbon nanomaterial.
A kind of preparation method of new light curable conductive coating of the present invention in embodiment comprises the steps：To
Sequentially added in reactor light trigger, unsaturated-resin, vinylated carbon nano-tube material, containing unsaturated group substitution
Polythiophene, activity diluting monomer, inorganic color stuffing, dispersant, defoamer；A kind of reaction raw materials are often added, are stirred
After even, a kind of lower reaction raw materials, fully dispersed uniform photocureable coating that must be described are added；Finally by spraying, brush, leaching
The mode of painting is suitable to the substrate surfaces such as timber, glass, ceramics, cement, in an oven after 60 ± 10 DEG C of dry 10~30min, uses
80 ± 50W/cm mercury lamps, 5m/min linear velocity photocuring, film performance are tested after completion of cure.
The completely rear the performance test results such as following table of curing of coating in embodiment：
Claims (10)
1. a kind of new light curable conductive coating, it is characterised in that constituent is：5~10 parts of light trigger, vinylated carbon
20~30 parts of nano-tube material, 10~15 parts of the polythiophene containing unsaturated group substitution, 70~80 parts of unsaturated-resin, activity
15~25 parts of diluting monomer, 1~5 part of dispersant, 0.5~2 part of defoamer, 0~10 part of function additive.
2. a kind of new light curable conductive coating according to claim 1, it is characterised in that described light trigger is two
Benzophenone, benzoin ethyl ether, benzoin dimethylether, 2- hydroxy-2-methyl -1- phenyl -1- acetone, 1- hydroxy-cyciohexyl phenyl
At least one in ketone, 2,4,6- trimethylbenzoyls diphenyl phosphine oxide, double 2,4,6- trimethylbenzoyls phenyl phosphine oxides
Kind.
A kind of 3. new light curable conductive coating according to claim 1, it is characterised in that：Described vinylated carbon is received
The preparation method of nanotube material is：
15~20 parts of aminated carbon nano tubes, 40~60 parts of organic solvents are added in reactor and are uniformly dispersed, are heated to 50
~80 DEG C, 5~10 part 10%~20% of GMA is then added dropwise dropwise, 20~30min is added dropwise,
50~80 DEG C are continued 2~4h of reaction, are cooled to after room temperature through filtering, organic solvent washing, drying, are obtained vinylated carbon nanometer material
Material.
A kind of 4. new light curable conductive coating according to claim 1, it is characterised in that：Described contains unsaturated group
The polythiophene of group's substitution has lower graph structure (R is the substituent containing double bond), be preferably poly- 3- acryloxies thiophene,
At least one of poly- 3- methacroyloxyethoxies thiophene, poly- 3- phenyl vinyls thiophene.
A kind of 5. new light curable conductive coating according to claim 1, it is characterised in that：Described unsaturated-resin is
Polyurethane acrylate resin, unsaturated polyester resin.
A kind of 6. new light curable conductive coating according to claim 1, it is characterised in that：Described reactive diluent is
Hydroxy-ethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxy propyl methacrylate, the propylene of BDO two
Acid esters, 1,6- hexanediyl ester, neopentylglycol diacrylate, tripropylene glycol class diacrylate, Glycerin
Triacrylate, two contracting trimethylolpropane tetra-acrylates, the third oxidation neopentylglycol diacrylate, the hydroxyl first of ethoxylation three
At least one of base propane triacrylate.
A kind of 7. new light curable conductive coating according to claim 1, it is characterised in that：Described dispersant is BYK-
At least one of P104, BYK-P105, BYK-P5040 dispersant；Described defoamer from BYK-022, BYK-088,
SN313, EFKA-2550 at least one.
A kind of 8. new light curable conductive coating according to claim 1, it is characterised in that：Described amination carbon nanometer
Manage the small size multi-walled carbon nanotube for ethylenediamine grafting, small size multi-walled carbon nanotube, the triethylene of diethylenetriamine grafting
Small size multi-walled carbon nanotube, small size multi-walled carbon nanotube, the N of TEPA grafting of tetramine grafting, N- dimethyl pair
At least one of small size multi-walled carbon nanotube of toluidines grafting；Amination grafting rate is 6~15%.
A kind of 9. new light curable conductive coating according to claim 1, it is characterised in that：Described organic solvent is benzene
Methanol, benzyl carbinol, glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol methyl ether acetate, propylene glycol monomethyl ether, propane diols
At least one of monobutyl ether, ethyl acetate, butyl acetate, toluene, dimethylbenzene, acetone, butanone.
10. a kind of preparation method of new light curable conductive coating as claimed in claim 1, it is characterised in that including following
Step：
Light trigger, unsaturated-resin are sequentially added into reactor, vinylated carbon nano-tube material, contains unsaturated group
Substituted polythiophene, activity diluting monomer, inorganic color stuffing, dispersant, defoamer；A kind of reaction raw materials are often added, are carried out
After stirring, a kind of lower reaction raw materials, fully dispersed uniform photocureable coating that must be described are added；Finally by spraying,
Brush, the mode of dip-coating is suitable to the substrate surfaces such as timber, glass, ceramics, cement, in an oven 60 ± 10 DEG C of dryings 10~
After 30min, with 80 ± 50W/cm mercury lamps, 5m/min linear velocity photocuring, film performance is tested after completion of cure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710871526.0A CN107629644A (en) | 2017-09-24 | 2017-09-24 | A kind of new light curable conductive coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710871526.0A CN107629644A (en) | 2017-09-24 | 2017-09-24 | A kind of new light curable conductive coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107629644A true CN107629644A (en) | 2018-01-26 |
Family
ID=61102420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710871526.0A Pending CN107629644A (en) | 2017-09-24 | 2017-09-24 | A kind of new light curable conductive coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107629644A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108517183A (en) * | 2018-04-25 | 2018-09-11 | 湖南辰砾新材料有限公司 | A kind of novel light curable conductive coating and preparation method thereof based on black phosphorus alkene |
| CN109337534A (en) * | 2018-09-28 | 2019-02-15 | 合众（佛山）化工有限公司 | A kind of high rigidity unsaturated polyester resin conductive coating |
| CN110205014A (en) * | 2019-06-25 | 2019-09-06 | 江南大学 | A kind of photocuring flexibility wet sensitive coating and preparation method thereof based on carbon nano tube compound material |
| CN110205005A (en) * | 2019-06-25 | 2019-09-06 | 江南大学 | A kind of photocuring flexibility ethyl alcohol air-sensitive coating and preparation method thereof based on carbon nano tube compound material |
| RU2703230C1 (en) * | 2018-08-23 | 2019-10-15 | Сергей Юрьевич Уткин | Pasty photo-curable high-flowing composition |
| CN111073498A (en) * | 2020-01-02 | 2020-04-28 | 湖南宏泰新材料有限公司 | UV (ultraviolet) curing self-repairing antistatic coating |
| WO2023077079A1 (en) * | 2021-10-29 | 2023-05-04 | Board Of Regents, The University Of Texas System | Facile direct amination and alkylamination of carbon nanotubes |
| CN116251719A (en) * | 2023-03-24 | 2023-06-13 | 广西桂科院铝业有限公司 | Light-weight anticorrosion aluminum alloy material electric vehicle frame |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387828A (en) * | 2014-11-26 | 2015-03-04 | 东风商用车有限公司 | Carbon series conductive coating and preparation method thereof |
| CN104530932A (en) * | 2014-12-25 | 2015-04-22 | 湖州南浔双林振森实木加工厂 | Antibacterial and antistatic ultraviolet-curable coating and preparation method thereof |
| CN104710879A (en) * | 2015-04-08 | 2015-06-17 | 山东泰宝防伪技术产品有限公司 | UV (ultraviolet) conductive ink and preparation method thereof |
| CN105462478A (en) * | 2015-12-14 | 2016-04-06 | 天津凯华绝缘材料股份有限公司 | Ultraviolet light cured PPTC electrode slurry and preparation method thereof |
| CN105820746A (en) * | 2016-05-05 | 2016-08-03 | 宁波智锐新材料有限公司 | Preparation method and application of neutral polythiophene antistatic paint |
| CN106497343A (en) * | 2016-10-25 | 2017-03-15 | 黄远明 | A kind of modified carbon nano-tube anticorrosion and antistatic paint |
| CN107022319A (en) * | 2017-04-01 | 2017-08-08 | 东莞市睿泰涂布科技有限公司 | The preparation technology of antistatic UV visbreakings composition, diaphragm and the diaphragm |
-
2017
- 2017-09-24 CN CN201710871526.0A patent/CN107629644A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387828A (en) * | 2014-11-26 | 2015-03-04 | 东风商用车有限公司 | Carbon series conductive coating and preparation method thereof |
| CN104530932A (en) * | 2014-12-25 | 2015-04-22 | 湖州南浔双林振森实木加工厂 | Antibacterial and antistatic ultraviolet-curable coating and preparation method thereof |
| CN104710879A (en) * | 2015-04-08 | 2015-06-17 | 山东泰宝防伪技术产品有限公司 | UV (ultraviolet) conductive ink and preparation method thereof |
| CN105462478A (en) * | 2015-12-14 | 2016-04-06 | 天津凯华绝缘材料股份有限公司 | Ultraviolet light cured PPTC electrode slurry and preparation method thereof |
| CN105820746A (en) * | 2016-05-05 | 2016-08-03 | 宁波智锐新材料有限公司 | Preparation method and application of neutral polythiophene antistatic paint |
| CN106497343A (en) * | 2016-10-25 | 2017-03-15 | 黄远明 | A kind of modified carbon nano-tube anticorrosion and antistatic paint |
| CN107022319A (en) * | 2017-04-01 | 2017-08-08 | 东莞市睿泰涂布科技有限公司 | The preparation technology of antistatic UV visbreakings composition, diaphragm and the diaphragm |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108517183A (en) * | 2018-04-25 | 2018-09-11 | 湖南辰砾新材料有限公司 | A kind of novel light curable conductive coating and preparation method thereof based on black phosphorus alkene |
| RU2703230C1 (en) * | 2018-08-23 | 2019-10-15 | Сергей Юрьевич Уткин | Pasty photo-curable high-flowing composition |
| CN109337534A (en) * | 2018-09-28 | 2019-02-15 | 合众（佛山）化工有限公司 | A kind of high rigidity unsaturated polyester resin conductive coating |
| CN110205014A (en) * | 2019-06-25 | 2019-09-06 | 江南大学 | A kind of photocuring flexibility wet sensitive coating and preparation method thereof based on carbon nano tube compound material |
| CN110205005A (en) * | 2019-06-25 | 2019-09-06 | 江南大学 | A kind of photocuring flexibility ethyl alcohol air-sensitive coating and preparation method thereof based on carbon nano tube compound material |
| CN110205014B (en) * | 2019-06-25 | 2020-06-30 | 江南大学 | Photocuring flexible humidity-sensitive coating based on carbon nanotube composite material and preparation method thereof |
| CN110205005B (en) * | 2019-06-25 | 2020-08-25 | 江南大学 | Photocuring flexible ethanol gas-sensitive coating based on carbon nanotube composite material and preparation method thereof |
| CN111073498A (en) * | 2020-01-02 | 2020-04-28 | 湖南宏泰新材料有限公司 | UV (ultraviolet) curing self-repairing antistatic coating |
| CN111073498B (en) * | 2020-01-02 | 2021-07-23 | 湖南宏泰新材料有限公司 | UV (ultraviolet) curing self-repairing antistatic coating |
| WO2023077079A1 (en) * | 2021-10-29 | 2023-05-04 | Board Of Regents, The University Of Texas System | Facile direct amination and alkylamination of carbon nanotubes |
| CN116251719A (en) * | 2023-03-24 | 2023-06-13 | 广西桂科院铝业有限公司 | Light-weight anticorrosion aluminum alloy material electric vehicle frame |
| CN116251719B (en) * | 2023-03-24 | 2023-11-21 | 广西桂科院铝业有限公司 | Light-weight anticorrosion aluminum alloy material electric vehicle frame |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107629644A (en) | A kind of new light curable conductive coating and preparation method thereof | |
| CN103897579A (en) | Improved waterborne polyurethane UV light-cured woodware coating | |
| CN107502180A (en) | The photocureable coating of fluorine-containing boron modification methyl vinyl MQ silicon resin | |
| CN111253837B (en) | Water-based one-coating UV (ultraviolet) curing epoxy acrylate coating and preparation method thereof | |
| CN112745723A (en) | Water-based fluorocarbon resin heavy-duty anticorrosive paint and preparation method thereof | |
| CN103773151A (en) | High temperature resistance acid-proof alkali-proof coating | |
| CN102898878B (en) | Electron beam radiation cured coating of low cost, high adhesive force and preparation method thereof | |
| CN110117426A (en) | Graphene-based fluorine-containing photocuring anticorrosive paint of one kind and preparation method thereof | |
| CN102757724A (en) | Black rust-proof ultraviolet (UV) curing paint for oil steel pipe | |
| CN107805446A (en) | A kind of light curable conductive coating based on two-dimentional molybdenum disulfide and preparation method thereof | |
| CN112409868B (en) | Powder coating with ice flower texture effect | |
| CN108517183A (en) | A kind of novel light curable conductive coating and preparation method thereof based on black phosphorus alkene | |
| CN109337534A (en) | A kind of high rigidity unsaturated polyester resin conductive coating | |
| CN103131003B (en) | Functionalized soybean oil compounds, and coating compositions comprising the same | |
| CN114106671B (en) | Alkyd primer capable of being dried at low temperature and high humidity and preparation method thereof | |
| CN108084854A (en) | A kind of high rigidity unsaturated polyester resin electrically-conducting paint | |
| CN110628321B (en) | Photocuring conductive coating and preparation method thereof | |
| CN105001707B (en) | A kind of UV photocurings water-based ink and preparation method thereof | |
| CN115160906A (en) | Water-based high-temperature-resistant ceramic coating for microwave oven cavity and preparation method thereof | |
| CN105778727B (en) | coating composition and building template | |
| CN103602258B (en) | UV-curable finish coat adhesive agent | |
| CN114213962A (en) | Acrylate coating and preparation method and application thereof | |
| JP2020105235A (en) | Fluorine-based coating, production method of fluorine-based coating, coated article and its production method | |
| CN108690490A (en) | A kind of ultraviolet aluminium-silver size coating with light curing | |
| WO2022088135A1 (en) | Water-based ultraviolet-curable paint, preparation method therefor and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180126 |
|
| RJ01 | Rejection of invention patent application after publication |