CN107629476A - A kind of antistatic glass fiber reinforced modeling grid of high-performance color - Google Patents
A kind of antistatic glass fiber reinforced modeling grid of high-performance color Download PDFInfo
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- CN107629476A CN107629476A CN201710757571.3A CN201710757571A CN107629476A CN 107629476 A CN107629476 A CN 107629476A CN 201710757571 A CN201710757571 A CN 201710757571A CN 107629476 A CN107629476 A CN 107629476A
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- China
- Prior art keywords
- antistatic
- addition
- glass fibre
- processing technology
- resin
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 46
- 238000005516 engineering process Methods 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000000945 filler Substances 0.000 claims abstract description 26
- 239000003085 diluting agent Substances 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 18
- 230000000996 additive effect Effects 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims description 21
- 239000002216 antistatic agent Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000007711 solidification Methods 0.000 claims description 9
- 230000008023 solidification Effects 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- -1 isophthalic Chemical group 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 238000004381 surface treatment Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 4
- 238000005452 bending Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antistatic glass fiber reinforced modeling grid of high-performance color, it is made up of resin, antistatic additive, filler, diluent, toner, other modifying agent and glass fibre, it is prepared by specific processing technology, the addition of the resin is 28 32%, the addition of the antistatic additive is 0.5 1%, the addition of the filler is 31 35%, the addition of the diluent is 2 5%, the addition of the toner is 3 4%, the addition of other modifying agent is 5 8%, and surplus is glass fibre.The present invention is allocated by using different raw material, and with the addition of new antistatic additive nanoscale carbon-point, and its sheet resistance is 106‑1011Ω, mechanical strength is not influenceed, and cause curved Qu Qiangdu≤260MPa of the present invention, bending mould amount≤12GPa, process operability is good, and color is varied.
Description
Technical field
The invention belongs to molding grating manufacture field, and in particular to a kind of high-performance color is antistatic glass fiber reinforced
Mould grid.
Background technology
The antistatic material used of molding grating has graphite, metal dust, tinsel etc., shortcoming:Using metal dust,
It is uneven that tinsel easily causes resistance, is easily settled in resin, and because surface is not handled, have a strong impact on mechanical property
Can, and graphite is seriously limited product color due to being black, is merely able to make black products.
The content of the invention
The defects of for prior art and deficiency, it is an object of the invention to provide a kind of process operability is good, color
The diversified antistatic glass fiber reinforced modeling grid of high-performance color.
To achieve the above object, the technical solution adopted by the present invention is:A kind of antistatic glass fibre of high-performance color increases
Strong molding grating, its innovative point are:By resin, antistatic additive, filler, diluent, toner, other modifying agent and glass fibers
Dimension composition, is prepared, the addition of the resin is 28-32%, and the antistatic additive adds by specific processing technology
Dosage is 0.5-1%, and the addition of the filler is 31-35%, and the addition of the diluent is 2-5%, the toner
Addition be 3-4%, the addition of other modifying agent is 5-8%, and surplus is glass fibre.
Further, the resin is from one kind in adjacent benzene, isophthalic, vinyl;The filler is from aluminium hydroxide, carbon
One kind in sour calcium;The toner is from one kind in color paste, mill base;The antistatic additive is nanoscale carbon-point.
Further, the specific processing technology includes overall antistatic processing technology and antistatic surface processing work
Skill.
Further, the antistatic processing technology of the entirety concretely comprises the following steps:Proportionally by resin, novel antistatic
Agent, diluent, filler, toner, other modifying agent are well mixed, and glass fibre laying is entered on side in a mold, and side will be mixed
The material got togather is put into, then allows glass fibre and compound complete wetting by pressure mode, and drives bubble away, heated mould
Have to 70-85 DEG C, after the curing be complete, mould unloading is simultaneously surface-treated.
Further, the antistatic surface processing technology concretely comprises the following steps:Proportionally by resin, diluent, filler,
Toner, other modifying agent are well mixed, in a mold side by glass fibre laying enter, while by the material mixed be put into
Go, then glass fibre and compound complete wetting are allowed by pressure mode, and drive bubble away, heating mould has been treated to 70-85 DEG C
After all solidstate, mould unloading is simultaneously surface-treated, and new anti-static agent material is uniformly applied into product surface with roller or brush,
Material solidification to be mixed.
The present invention has the beneficial effect that:The present invention is allocated by using different raw material, and with the addition of new
Antistatic additive-nanoscale carbon-point, its sheet resistance is 106-1011Ω, mechanical strength is not influenceed, and cause the bending of the present invention
Qiang Du≤260MPa, Mo Liang≤12GPa are bent, process operability is good, and color is varied.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, the present invention is carried out below further
Describe in detail.It should be appreciated that embodiment described herein is not used to limit this hair only to explain the present invention
It is bright.
Embodiment 1
A kind of antistatic glass fiber reinforced modeling grid of high-performance color, by resin, antistatic additive, filler, diluent,
Toner, other modifying agent and glass fibre composition, are prepared, the addition of resin is by specific processing technology
28%, the addition of antistatic additive is 0.5%, and the addition of filler is 31%, and the addition of diluent is 2%, toner
Addition is 3%, and the addition of other modifying agent is 5%, and surplus is glass fibre.
Resin is from one kind in adjacent benzene, isophthalic, vinyl;Filler is from one kind in aluminium hydroxide, calcium carbonate;Toning
Agent is from one kind in color paste, mill base;Antistatic additive is nanoscale carbon-point.
Specific processing technology includes overall antistatic processing technology and antistatic surface processing technology.
Overall antistatic processing technology concretely comprises the following steps:Proportionally by resin, new anti-static agent, diluent, filler,
Toner, other modifying agent are well mixed, in a mold side by glass fibre laying enter, while by the material mixed be put into
Go, then glass fibre and compound complete wetting are allowed by pressure mode, and drive bubble away, heating mould is treated completely to 70 DEG C
After solidification, mould unloading is simultaneously surface-treated.
Antistatic surface processing technology concretely comprises the following steps:Proportionally by resin, diluent, filler, toner, other change
Property agent be well mixed, in a mold side by glass fibre laying enter, while the material mixed is put into, then pass through pressure
Mode allows glass fibre and compound complete wetting, and drives bubble away, and heating mould is to 70 DEG C, and after the curing be complete, mould unloading is simultaneously
It is surface-treated, new anti-static agent material is uniformly applied to product surface with roller or brush, material solidification to be mixed is
Can.
Embodiment 2
A kind of antistatic glass fiber reinforced modeling grid of high-performance color, by resin, antistatic additive, filler, diluent,
Toner, other modifying agent and glass fibre composition, are prepared, the addition of resin is by specific processing technology
32%, the addition of antistatic additive is 1%, and the addition of filler is 35%, and the addition of diluent is 5%, and toner adds
Dosage is 4%, and the addition of other modifying agent is 8%, and surplus is glass fibre.
Resin is from one kind in adjacent benzene, isophthalic, vinyl;Filler is from one kind in aluminium hydroxide, calcium carbonate;Toning
Agent is from one kind in color paste, mill base;Antistatic additive is nanoscale carbon-point.
Specific processing technology includes overall antistatic processing technology and antistatic surface processing technology.
Overall antistatic processing technology concretely comprises the following steps:Proportionally by resin, new anti-static agent, diluent, filler,
Toner, other modifying agent are well mixed, in a mold side by glass fibre laying enter, while by the material mixed be put into
Go, then glass fibre and compound complete wetting are allowed by pressure mode, and drive bubble away, heating mould is treated completely to 85 DEG C
After solidification, mould unloading is simultaneously surface-treated.
Antistatic surface processing technology concretely comprises the following steps:Proportionally by resin, diluent, filler, toner, other change
Property agent be well mixed, in a mold side by glass fibre laying enter, while the material mixed is put into, then pass through pressure
Mode allows glass fibre and compound complete wetting, and drives bubble away, and heating mould is to 85 DEG C, and after the curing be complete, mould unloading is simultaneously
It is surface-treated, new anti-static agent material is uniformly applied to product surface with roller or brush, material solidification to be mixed is
Can.
Embodiment 3
A kind of antistatic glass fiber reinforced modeling grid of high-performance color, by resin, antistatic additive, filler, diluent,
Toner, other modifying agent and glass fibre composition, are prepared, the addition of resin is by specific processing technology
302%, the addition of antistatic additive is 0.8%, and the addition of filler is 33%, and the addition of diluent is 4%, toner
Addition is 3.5%, and the addition of other modifying agent is 6.5%, and surplus is glass fibre.
Resin is from one kind in adjacent benzene, isophthalic, vinyl;Filler is from one kind in aluminium hydroxide, calcium carbonate;Toning
Agent is from one kind in color paste, mill base;Antistatic additive is nanoscale carbon-point.
Specific processing technology includes overall antistatic processing technology and antistatic surface processing technology.
Overall antistatic processing technology concretely comprises the following steps:Proportionally by resin, new anti-static agent, diluent, filler,
Toner, other modifying agent are well mixed, in a mold side by glass fibre laying enter, while by the material mixed be put into
Go, then glass fibre and compound complete wetting are allowed by pressure mode, and drive bubble away, heating mould is treated completely to 77 DEG C
After solidification, mould unloading is simultaneously surface-treated.
Antistatic surface processing technology concretely comprises the following steps:Proportionally by resin, diluent, filler, toner, other change
Property agent be well mixed, in a mold side by glass fibre laying enter, while the material mixed is put into, then pass through pressure
Mode allows glass fibre and compound complete wetting, and drives bubble away, and heating mould is to 77 DEG C, and after the curing be complete, mould unloading is simultaneously
It is surface-treated, new anti-static agent material is uniformly applied to product surface with roller or brush, material solidification to be mixed is
Can.
The present invention is allocated by using different raw material, and with the addition of new antistatic additive-nano-scale carbon
Rod, its sheet resistance is 106-1011Ω, mechanical strength is not influenceed, and cause curved Qu Qiangdu≤260MPa of the present invention, bending
Mo Liang≤12GPa, process operability is good, and color is varied.
It is described above, it is merely illustrative of the technical solution of the present invention and unrestricted, those of ordinary skill in the art are to this hair
The other modifications or equivalent substitution that bright technical scheme is made, without departing from the spirit and scope of technical solution of the present invention,
It all should cover among scope of the presently claimed invention.
Claims (5)
- A kind of 1. antistatic glass fiber reinforced modeling grid of high-performance color, it is characterised in that:By resin, antistatic additive, fill out Material, diluent, toner, other modifying agent and glass fibre composition, are prepared, the resin by specific processing technology Addition be 28-32%, the addition of the antistatic additive is 0.5-1%, and the addition of the filler is 31-35%, institute The addition for stating diluent is 2-5%, and the addition of the toner is 3-4%, and the addition of other modifying agent is 5- 8%, surplus is glass fibre.
- A kind of 2. antistatic glass fiber reinforced modeling grid of high-performance color according to claim 1, it is characterised in that: The resin is from one kind in adjacent benzene, isophthalic, vinyl;The filler is from one kind in aluminium hydroxide, calcium carbonate;It is described Toner is from one kind in color paste, mill base;The antistatic additive is nanoscale carbon-point.
- A kind of 3. antistatic glass fiber reinforced modeling grid of high-performance color according to claim 1, it is characterised in that: The specific processing technology includes overall antistatic processing technology and antistatic surface processing technology.
- A kind of 4. antistatic glass fiber reinforced modeling grid of high-performance color according to claim 3, it is characterised in that: The antistatic processing technology of entirety concretely comprises the following steps:Proportionally by resin, new anti-static agent, diluent, filler, toning Agent, other modifying agent are well mixed, and glass fibre laying is entered on side in a mold, while the material mixed is put into, Glass fibre and compound complete wetting are allowed by pressure mode again, and drive bubble away, heating mould is treated complete to 70-85 DEG C After solidification, mould unloading is simultaneously surface-treated.
- A kind of 5. antistatic glass fiber reinforced modeling grid of high-performance color according to claim 3, it is characterised in that: The antistatic surface processing technology concretely comprises the following steps:Proportionally by resin, diluent, filler, toner, other modifying agent Well mixed, glass fibre laying is entered on side in a mold, while the material mixed is put into, then passes through the mode of pressing Allow glass fibre and compound complete wetting, and drive bubble away, heating mould is to 70-85 DEG C, and after the curing be complete, mould unloading is gone forward side by side Row surface treatment, new anti-static agent material is uniformly applied to product surface, material solidification to be mixed with roller or brush.
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CN201710757571.3A CN107629476A (en) | 2017-08-29 | 2017-08-29 | A kind of antistatic glass fiber reinforced modeling grid of high-performance color |
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CN201710757571.3A CN107629476A (en) | 2017-08-29 | 2017-08-29 | A kind of antistatic glass fiber reinforced modeling grid of high-performance color |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109648883A (en) * | 2018-11-19 | 2019-04-19 | 南通时瑞塑胶制品有限公司 | A kind of battery curing room support composite plate and its forming method |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101131039A (en) * | 2006-08-25 | 2008-02-27 | 江苏九鼎新材料股份有限公司 | Glass fiber reinforced plastics grille with conducting function and manufacturing method thereof |
CN102120836A (en) * | 2010-01-07 | 2011-07-13 | 北京普能世纪科技有限公司 | Elastomer plastic, conductive plastic, conductive plastic bipolar plate and preparation methods thereof |
CN102977574A (en) * | 2012-12-04 | 2013-03-20 | 中铁八局集团电务工程有限公司 | Glass fiber reinforced plastic curing agent composition and glass fiber reinforced plastic composite material prepared by same as well as cable trough |
-
2017
- 2017-08-29 CN CN201710757571.3A patent/CN107629476A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101131039A (en) * | 2006-08-25 | 2008-02-27 | 江苏九鼎新材料股份有限公司 | Glass fiber reinforced plastics grille with conducting function and manufacturing method thereof |
CN102120836A (en) * | 2010-01-07 | 2011-07-13 | 北京普能世纪科技有限公司 | Elastomer plastic, conductive plastic, conductive plastic bipolar plate and preparation methods thereof |
CN102977574A (en) * | 2012-12-04 | 2013-03-20 | 中铁八局集团电务工程有限公司 | Glass fiber reinforced plastic curing agent composition and glass fiber reinforced plastic composite material prepared by same as well as cable trough |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109648883A (en) * | 2018-11-19 | 2019-04-19 | 南通时瑞塑胶制品有限公司 | A kind of battery curing room support composite plate and its forming method |
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Application publication date: 20180126 |