CN107619647A - A kind of environment-friendly type aqueous paste box adhesive and preparation method thereof - Google Patents
A kind of environment-friendly type aqueous paste box adhesive and preparation method thereof Download PDFInfo
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- CN107619647A CN107619647A CN201710800814.7A CN201710800814A CN107619647A CN 107619647 A CN107619647 A CN 107619647A CN 201710800814 A CN201710800814 A CN 201710800814A CN 107619647 A CN107619647 A CN 107619647A
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- type aqueous
- aqueous paste
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Abstract
The invention discloses a kind of environment-friendly type aqueous paste box adhesive, including following components：Modifying cinepazid emulsion 82 85%, rosin milk 14.8 17.8%, defoamer 0.01 0.05%, NMF 0.05 0.10%, wetting agent 0.05 0.10%；The preparation technology of the environment-friendly type aqueous paste box adhesive of the present invention is simple, easily operated, obtained environment-friendly type aqueous paste box adhesive good penetrability, adhesive strength are big, good mechanical stability, not skinning, not whirl coating, flanging bonding do not rebound, and easily wipe wild glue, it is not only suitable for the bonding of BOPP coated products, and can meets the bonding of UV glazing products, and below 20 DEG C of environment temperature and more than 70 DEG C do not influence adhesive property, has excellent low-temperature resistance resistance to elevated temperatures.
Description
Technical field
The present invention relates to field of adhesive technology, more specifically, more particularly to a kind of environment-friendly type aqueous paste box adhesive
And preparation method thereof.
Background technology
With requirement more and more higher of the market to product packaging, the various packaging products being beautifully printed, the glue being used for
Stick proposes higher requirement, also promotes the fast development of packaging adhesive.Especially for many color boxes that produce choice goods
Enterprise, it is necessary to glued by gluing machine, it is by hand that speciality paper, paperboard, laminating adhesive ticker tape etc. and industrial paperboard, MDF etc. is viscous
Close, make various high-grade wine boxes, gift box etc., custom is referred to as this kind of glue to paste box glue, color box glue, fine mounting glue, mounting box in industry
Glue, viscous box glue, water-based yellow glue etc..
The paste box adhesive resistance to low temperature of prior art is poor, easy degumming, and being suitable at low ambient temperatures
The adhesive of BOPP coated products bonding is not just suitable for UV glazing products, and is not suitable for the adhesive of UV glazing products just not
Suitable for BOPP coated products, both can not take into account, and limit the use of paste box adhesive.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art, there is provided a kind of tack is good, cohesive force is strong, resistance to low
The significant environment-friendly type aqueous paste box adhesive of temp effect, is not only suitable for the bonding of BOPP coated products, and can meets that UV glazings produce
The bonding of product.
To achieve the above object, present invention employs following technical scheme：
A kind of environment-friendly type aqueous paste box adhesive, including following components：
Modifying cinepazid emulsion 82-85%
Rosin milk 14.8-17.8%
Defoamer 0.01-0.05%
NMF 0.05-0.10%
Wetting agent 0.05-0.10%
Preferably, in said components, the defoamer is polymethyl siloxane emulsion or aliphatic Dormant oils.
Preferably, in said components, the NMF is ethylene glycol or urea.
Preferably, in said components, the wetting agent is APES.
Present invention also offers the preparation method of above-mentioned environment-friendly type aqueous paste box adhesive, comprise the following steps：
（1）By modifying cinepazid emulsion and rosin milk by proportioning input mixing plant, entered with 600-800 revs/min of speed of rotating speed
Row stirring；
（2）Defoamer, NMF and wetting agent are added under stirring, continues stirring to being well mixed, produces environment-friendly type aqueous
Paste box adhesive.
Compared with prior art, the present invention is environment-friendly type aqueous the advantages of pasting box adhesive：
1st, product is water base property adhesive, nontoxic, have no irritating odor, be corrosion-free, nonflammable, non-explosive.
2nd, glued membrane is flexible, and good penetrability, adhesive strength is big, good mechanical stability, not skinning, not whirl coating, and flanging bonds not
Bounce-back, easily wipes wild glue, is not only suitable for the bonding of BOPP coated products, and can meets the bonding of UV glazing products.
3rd, tack is good, holds viscous time length, and the open hour up to 30 minutes, can bond after glue is crossed in 2-30 minutes.
4th, below -20 DEG C of environment temperature and more than 70 DEG C do not influence adhesive property, has excellent low-temperature resistance heat-resisting quantity
Energy.
5th, cost is low, and raw material is easy to get, and preparation technology is simple, and production stability is good.
Embodiment
For a better understanding of the present invention, with reference to the specific embodiment content that the present invention is furture elucidated, but this hair
Bright content is not limited solely to the following examples.
Embodiment 1
By modifying cinepazid emulsion 82kg and rosin milk 17.8kg input mixing plants, entered with 600-800 revs/min of speed of rotating speed
Row stirring；Polymethyl siloxane emulsion 0.05kg, ethylene glycol 0.05kg and APES are added under stirring
0.1kg, continue stirring to being well mixed, get product.
Embodiment 2
Modifying cinepazid emulsion 83kg and rosin milk 16.85kg is put into mixing plant, with 600-800 revs/min of speed of rotating speed
It is stirred；Polymethyl siloxane emulsion 0.02kg, urea 0.08kg and APES are added under stirring
0.05kg, continue stirring to being well mixed, get product.
Embodiment 3
Modifying cinepazid emulsion 84kg and rosin milk 15.86kg is put into mixing plant, with 600-800 revs/min of speed of rotating speed
It is stirred；Aliphatic Dormant oils 0.01kg, ethylene glycol 0.04kg and APES 0.09kg are added under stirring,
Continue stirring to being well mixed, get product.
Embodiment 4
By modifying cinepazid emulsion 85kg and rosin milk 14.8kg input mixing plants, entered with 600-800 revs/min of speed of rotating speed
Row stirring；Aliphatic Dormant oils 0.04kg, urea 0.1kg and APES 0.06kg are added under stirring, is continued
Stirring is got product to being well mixed.
Environment-friendly type aqueous paste box adhesive, outward appearance made from above-described embodiment 1-4：Be creamy white uniform viscous liquid,
The quality index measured is as shown in the table：
| Sequence number | Index name | Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| 1 | Solid content | ≥45% | 51.4 | 50.8 | 51.6 | 50.3 |
| 2 | PH value | 6-7 | 6.8 | 7.0 | 7.0 | 6.9 |
| 3 | Viscosity（25℃） | ≥5000mpa.s | 7800 | 8000 | 8100 | 7900 |
| 4 | Peel strength | ≥2N/cm | 4 | 5 | 6 | 5 |
Claims (5)
- A kind of 1. environment-friendly type aqueous paste box adhesive, it is characterised in that：Including following components：Modifying cinepazid emulsion 82-85%Rosin milk 14.8-17.8%Defoamer 0.01-0.05%NMF 0.05-0.10%Wetting agent 0.05-0.10%.
- 2. environment-friendly type aqueous paste box adhesive according to claim 1, it is characterised in that：The defoamer is poly- methyl silicon Oxygen alkane emulsion or aliphatic Dormant oils.
- 3. environment-friendly type aqueous paste box adhesive according to claim 1, it is characterised in that：The NMF be ethylene glycol or Person's urea.
- 4. environment-friendly type aqueous paste box adhesive according to claim 1, it is characterised in that：The wetting agent gathers for alkyl phenol Oxygen vinethene.
- A kind of 5. preparation method of environment-friendly type aqueous paste box adhesive as claimed in claim 1, it is characterised in that：Including following Step：（1）By modifying cinepazid emulsion and rosin milk by proportioning input mixing plant, entered with 600-800 revs/min of speed of rotating speed Row stirring；（2）Defoamer, NMF and wetting agent are added under stirring, continues stirring to being well mixed, produces environment-friendly type aqueous Paste box adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710800814.7A CN107619647A (en) | 2017-09-07 | 2017-09-07 | A kind of environment-friendly type aqueous paste box adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710800814.7A CN107619647A (en) | 2017-09-07 | 2017-09-07 | A kind of environment-friendly type aqueous paste box adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107619647A true CN107619647A (en) | 2018-01-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710800814.7A Pending CN107619647A (en) | 2017-09-07 | 2017-09-07 | A kind of environment-friendly type aqueous paste box adhesive and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019201695A1 (en) * | 2018-04-20 | 2019-10-24 | Basf Se | Additive composition for aqueous dispersions of hydrophobic polymers |
| CN114015384A (en) * | 2021-12-01 | 2022-02-08 | 苏州健雄职业技术学院 | Nano SiO2Organic silicon elastomer modified single-component styrene-acrylic silicone sealant |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
-
2017
- 2017-09-07 CN CN201710800814.7A patent/CN107619647A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张俊乐: "水性胶在糊盒加工中的应用与发展", 《印刷技术》 * |
| 王坤: "医用包装材料的水性纸塑复膜胶的研制及性能研究", 《中国优秀硕士论文全文数据库 工程特辑 I辑》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019201695A1 (en) * | 2018-04-20 | 2019-10-24 | Basf Se | Additive composition for aqueous dispersions of hydrophobic polymers |
| CN111989377A (en) * | 2018-04-20 | 2020-11-24 | 巴斯夫欧洲公司 | Additive composition for aqueous dispersions of hydrophobic polymers |
| CN114015384A (en) * | 2021-12-01 | 2022-02-08 | 苏州健雄职业技术学院 | Nano SiO2Organic silicon elastomer modified single-component styrene-acrylic silicone sealant |
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Application publication date: 20180123 |