CN107619526A - Strong plastic floor of a kind of anti-impact force and preparation method thereof - Google Patents
Strong plastic floor of a kind of anti-impact force and preparation method thereof Download PDFInfo
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- CN107619526A CN107619526A CN201610549168.7A CN201610549168A CN107619526A CN 107619526 A CN107619526 A CN 107619526A CN 201610549168 A CN201610549168 A CN 201610549168A CN 107619526 A CN107619526 A CN 107619526A
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- plastic floor
- impact force
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Abstract
The invention discloses strong plastic floor of a kind of anti-impact force and preparation method thereof, it is made up of the raw material of following parts by weight：EVA resin 35 49, thermoplastic polyester elastomer 21 34, magnesium oleate 35, tricresyl phosphate (butoxyethyl group) ester 12 19, calcium titanate nanofiber 11 17, olefin-modified styrene-acrylonitrile copolymer resins 15 25, graphite whisker 10 15, distearyl acid hydroxyl aluminium 36, AES resins 14 22, cadmium carbonate 57, di-n-octyl sebacate 12 18, baddeleyite powder 18 24.The present invention is to be used as base material using four kinds of EVA resin, thermoplastic polyester elastomer, olefin-modified styrene-acrylonitrile copolymer resins, AES resins resins, and baddeleyite powder, calcium titanate nanofiber, graphite whisker are added as filler, make obtained plastic floor elasticity good, anti-impact force is strong, with good elastic recovery capability, it is not easy to crack, while there is good heat resistance, wearability and weatherability.
Description
Technical field
The present invention relates to a kind of plastic floor and preparation method thereof, and in particular to a kind of strong plastic floor of anti-impact force and
Its preparation method.
Background technology
Floor decorative material-plastic floor is because having the advantages that abundant color, good decorative effect, extensive use
In hospital, education and commercial center, school, figure embassy, social agency, airport, department store, elevator decoration etc..With biography
The characteristics of earth materials such as the terrazzo of system, floor tile, stone material are cold, hard, ring, dullness is compared, and the advantage of plastic floor is obvious.
But plastic floor itself there is also it is certain the defects of, there are still impact resistance difference to lack for plastic floor in the market
Point, the phenomenon easily to be ftractureed under external impacts.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of strong plastic floor of anti-impact force and its system
Preparation Method.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of strong plastic floor of anti-impact force, is made up of the raw material of following parts by weight：EVA resin 35-49, thermoplastic polyester bullet
Property body 21-34, magnesium oleate 3-5, tricresyl phosphate (butoxyethyl group) ester 12-19, calcium titanate nanofiber 11-17, olefin-modified benzene
Ethylene-propylene nitrile copolymer resins 15-25, graphite whisker 10-15, distearyl acid hydroxyl aluminium 3-6, AES resin 14-22, cadmium carbonate 5-
7th, di-n-octyl sebacate 12-18, baddeleyite powder 18-24.
A kind of preparation method of the strong plastic floor of anti-impact force, comprises the following steps：
（1）Baddeleyite powder, calcium titanate nanofiber, graphite whisker, tricresyl phosphate (butoxyethyl group) ester, di-n-octyl sebacate are added
Enter in high-speed mixer, the mixed at high speed 14-18min at 75-95 DEG C, be cooled to normal temperature, discharge；
（2）By EVA resin, thermoplastic polyester elastomer, olefin-modified styrene-acrylonitrile copolymer resins, AES resins, two hard
Resin acid hydroxyl aluminium is added in mill, and adjustment roll spacing be 2-3mm, and roller temperature is 120-140 DEG C, mixing 4-6min, add magnesium oleate,
Cadmium carbonate and step（1）Obtained compound, adjustment roll spacing are 1-2mm, and roller temperature is 105-115 DEG C, is kneaded 5-8min,
（3）By step（2）Obtained compound is added in plasticator, and it is thin logical 6-8 times to beat triangle bag, pulling-on piece, cooling and dicing；
（4）By step（3）Obtained pellet is added in double screw extruder and extruded, and through mould molding, normal temperature is cooled to after sizing,
Trimming again, it is finished product to examine qualified.
Beneficial effects of the present invention：
The present invention is with EVA resin, thermoplastic polyester elastomer, olefin-modified styrene-acrylonitrile copolymer resins, AES resins
Four kinds of resins add baddeleyite powder, calcium titanate nanofiber, graphite whisker as filler as base material, make obtained modeling
Adhesive floor elasticity is good, and anti-impact force is strong, has good elastic recovery capability, not easy to crack, at the same have good heat resistance,
Wearability and weatherability.
Embodiment
Embodiment 1
The strong plastic floor of a kind of anti-impact force, by following weight（kg）Raw material be made：EVA resin 35, thermoplastic polyester bullet
Property body 21, magnesium oleate 3, tricresyl phosphate (butoxyethyl group) ester 12, calcium titanate nanofiber 11, olefin-modified styrene-acrylonitrile
Copolymer resins 15, graphite whisker 10, distearyl acid hydroxyl aluminium 3, AES resins 14, cadmium carbonate 5, di-n-octyl sebacate 12, baddeleyite powder
18。
A kind of preparation method of the strong plastic floor of anti-impact force, comprises the following steps：
（1）Baddeleyite powder, calcium titanate nanofiber, graphite whisker, tricresyl phosphate (butoxyethyl group) ester, di-n-octyl sebacate are added
Enter in high-speed mixer, the mixed at high speed 14-18min at 75-95 DEG C, be cooled to normal temperature, discharge；
（2）By EVA resin, thermoplastic polyester elastomer, olefin-modified styrene-acrylonitrile copolymer resins, AES resins, two hard
Resin acid hydroxyl aluminium is added in mill, and adjustment roll spacing be 2-3mm, and roller temperature is 120-140 DEG C, mixing 4-6min, add magnesium oleate,
Cadmium carbonate and step（1）Obtained compound, adjustment roll spacing are 1-2mm, and roller temperature is 105-115 DEG C, is kneaded 5-8min,
（3）By step（2）Obtained compound is added in plasticator, and it is thin logical 6-8 times to beat triangle bag, pulling-on piece, cooling and dicing；
（4）By step（3）Obtained pellet is added in double screw extruder and extruded, and through mould molding, normal temperature is cooled to after sizing,
Trimming again, it is finished product to examine qualified.
Embodiment 2
The strong plastic floor of a kind of anti-impact force, by following weight（kg）Raw material be made：EVA resin 41, thermoplastic polyester bullet
Property body 27, magnesium oleate 4, tricresyl phosphate (butoxyethyl group) ester 15, calcium titanate nanofiber 14, olefin-modified styrene-acrylonitrile
Copolymer resins 20, graphite whisker 12, distearyl acid hydroxyl aluminium 4, AES resins 18, cadmium carbonate 6, di-n-octyl sebacate 15, baddeleyite powder
21。
Preparation method is the same as embodiment 1.
Embodiment 3
The strong plastic floor of a kind of anti-impact force, by following weight（kg）Raw material be made：EVA resin 49, thermoplastic polyester bullet
Property body 34, magnesium oleate 5, tricresyl phosphate (butoxyethyl group) ester 19, calcium titanate nanofiber 17, olefin-modified styrene-acrylonitrile
Copolymer resins 25, graphite whisker 15, distearyl acid hydroxyl aluminium 6, AES resins 22, cadmium carbonate 7, di-n-octyl sebacate 18, baddeleyite powder
24。
Preparation method is the same as embodiment 1.
The performance test results of plastic floor are as shown in the table made from above-described embodiment 1-3：
Claims (2)
1. the strong plastic floor of a kind of anti-impact force, it is characterised in that be made up of the raw material of following parts by weight：EVA resin 35-
49th, thermoplastic polyester elastomer 21-34, magnesium oleate 3-5, tricresyl phosphate (butoxyethyl group) ester 12-19, calcium titanate nanofiber
11-17, olefin-modified styrene-acrylonitrile copolymer resins 15-25, graphite whisker 10-15, distearyl acid hydroxyl aluminium 3-6, AES tree
Fat 14-22, cadmium carbonate 5-7, di-n-octyl sebacate 12-18, baddeleyite powder 18-24.
2. the preparation method of the strong plastic floor of anti-impact force according to claim 1, it is characterised in that including following step
Suddenly：
（1）Baddeleyite powder, calcium titanate nanofiber, graphite whisker, tricresyl phosphate (butoxyethyl group) ester, di-n-octyl sebacate are added
Enter in high-speed mixer, the mixed at high speed 14-18min at 75-95 DEG C, be cooled to normal temperature, discharge；
（2）By EVA resin, thermoplastic polyester elastomer, olefin-modified styrene-acrylonitrile copolymer resins, AES resins, two hard
Resin acid hydroxyl aluminium is added in mill, and adjustment roll spacing be 2-3mm, and roller temperature is 120-140 DEG C, mixing 4-6min, add magnesium oleate,
Cadmium carbonate and step（1）Obtained compound, adjustment roll spacing are 1-2mm, and roller temperature is 105-115 DEG C, is kneaded 5-8min,
（3）By step（2）Obtained compound is added in plasticator, and it is thin logical 6-8 times to beat triangle bag, pulling-on piece, cooling and dicing；
（4）By step（3）Obtained pellet is added in double screw extruder and extruded, and through mould molding, normal temperature is cooled to after sizing,
Trimming again, it is finished product to examine qualified.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549168.7A CN107619526A (en) | 2016-07-13 | 2016-07-13 | Strong plastic floor of a kind of anti-impact force and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549168.7A CN107619526A (en) | 2016-07-13 | 2016-07-13 | Strong plastic floor of a kind of anti-impact force and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107619526A true CN107619526A (en) | 2018-01-23 |
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ID=61086935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610549168.7A Pending CN107619526A (en) | 2016-07-13 | 2016-07-13 | Strong plastic floor of a kind of anti-impact force and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107619526A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114667315A (en) * | 2020-10-21 | 2022-06-24 | 株式会社Lg化学 | Thermoplastic resin composition and molded article produced using the same |
-
2016
- 2016-07-13 CN CN201610549168.7A patent/CN107619526A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114667315A (en) * | 2020-10-21 | 2022-06-24 | 株式会社Lg化学 | Thermoplastic resin composition and molded article produced using the same |
| CN114667315B (en) * | 2020-10-21 | 2024-05-24 | 株式会社Lg化学 | Thermoplastic resin composition and molded article produced using the same |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180123 |
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| WD01 | Invention patent application deemed withdrawn after publication |