CN107604273A - A kind of antirust composite and preparation method thereof - Google Patents
A kind of antirust composite and preparation method thereof Download PDFInfo
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- CN107604273A CN107604273A CN201710685822.1A CN201710685822A CN107604273A CN 107604273 A CN107604273 A CN 107604273A CN 201710685822 A CN201710685822 A CN 201710685822A CN 107604273 A CN107604273 A CN 107604273A
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Abstract
The invention discloses a kind of antirust composite and preparation method thereof, the raw material for preparing antirust composite is：40~60 parts of zinc-magnesium aluminium alloy, 100~140 parts of composite fibre, 2~6 parts of plasticizer, 4~10 parts of antioxidant；The composition and content of the zinc-magnesium aluminium alloy be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；The composite fibre is the combination of one or both of carbon fiber, alumina fibre.The present invention overcomes existing deficiency and provides a kind of antirust composite, it is simple that specific aim improves current composite function, complex manufacturing technology, consumptive material is time-consuming more, human cost is big, the problem of cost of manufacture is high, antirust composite of the present invention has the special-effect of antirust, can solve the problems, such as metal alloy compositions rust resistance and corrosion resistance and conventional composite intensity and impact resistance difference simultaneously, while improve antirust composite property, toughness is full, wear resistant corrosion resistant, anti-impact agent ability is strong, its preparation technology advantages of simple, can extensive use.
Description
Technical field
The present invention relates to field of compound material, and in particular to a kind of antirust composite and preparation method thereof.
Background technology
With the progress and the fast development of science and technology of the modern life, among a large amount of production activities, the corrosion problem of metal is deep
Paid close attention to by numerous researchers and operation user.According to incompletely statistics, the steel that the whole world is scrapped because getting rusty every year is high
Up to several ten million tons, therefore cause serious economic loss and energy waste.At present, the limitation and metallic article of technology are given birth to
Particularity, almost all of steel product seals antirust up for safekeeping and protects processing using antirust oil more for a long time, but due to follow-up
Process need to carry out oil removal treatment, and oil is not easily decomposed, and cause follow-up work complex process, operate extremely difficult, make
Into oil removing obstacle；It is most of to use organic solvent in addition, in oil removal process, in spite of certain devil liquor recovery and quality control,
Still the problem of environmental pollution that discharging of waste liquid is brought be present, have a strong impact on the life of people, and a certain degree of limit work
Industry metaplasia is produced.With the continuous enhancing of the growing tension and environmentally friendly protective awareness of petroleum resources, direction of scientific rersearch gradually changes, environmental protection
It is pollution-free, and the research of the composite of antirust can be continued by extensive concern both domestic and external.
Composite, it is by two or more material of different nature, tool is formed by method physically or chemically
There is the material of new capability.Its main difference by various materials in performance, makes up for each other's deficiencies and learn from each other, and produces cooperative effect, makes
The combination property of composite meets a variety of effects and functional requirement better than former composition material.Due to composite
Superiority, increasing research are directed to its further investigation and invention.By the use of metal dust as raw material, by shaping and burning
Knot, the technology of manufacture metal material, composite and all kinds product is not very rare, and PM technique has turned into
Solve the problems, such as the key of new material, very important effect is played in the development of new material.At present using iron powder as mainly into
The powdered metallurgical material divided is applied most, and application is also most wide, however, existing powder metallurgy prescription and technique still have
Have a limitation, the more various waste that result in the energy of processing step and production efficiency it is low, there is also stretching is strong for product
The problem of degree and hardness are relatively low, while with the continuous development of industry, for this types of material performance requirement also increasingly
Height, not only needs the powdered metallurgical material of excellent physical properties, while is also required to further improve the chemical property of material, wherein
Important one side is exactly the corrosion-resistant rustless property of material.
Patent CN201410571085.9 discloses a kind of iron-based antirust powdered metallurgical material and preparation method thereof, powder smelting
Golden material includes following components：Iron powder, copper powder, ethyl acrylate, makrolon, manganese dioxide, cement flour, zinc stearate, carbon
Dimethyl phthalate, nickel powder and carbon dust.Preparation method for each component is stirred in mixing and blending machine, be then dipped in water,
In the mixed liquor that glycerine, polyglyceryl fatty acid ester form, heating stirring is uniform, is dried up using hot nitrogen, is then pressed in mould
Pressed compact is made, pressed compact is sent into sintering furnace and will be sintered, the heating and thermal insulation stage by stage under the conditions of certain vacuum degree, is obtained just
Mould, blank mould is finally cooled to 100-150 DEG C, carries out stifling 40-60 minutes using ethanol solution steam, be then down to room temperature.
In this invention although gained metallurgical material possesses good tensile strength and hardness, but due to raw material On The Choice, preparation
Metallurgical material its antirust ability does not obtain conspicuousness progress, and therefore, urgent need want one kind to possess superpower metallicity and together
When can be with the composite of fabulous antirust.
The content of the invention
A kind of antirust composite is provided it is an object of the invention to overcome existing deficiency, specific aim improves multiple at present
The problem of condensation material function is simple, complex manufacturing technology, and consumptive material is time-consuming more, and human cost is big, and cost of manufacture is high, antirust of the present invention
Composite has the special-effect of antirust, can solve metal alloy compositions rust resistance and corrosion resistance simultaneously and conventional composite is strong
The problem of degree and impact resistance difference, while antirust composite property is improved, toughness is full, wear resistant corrosion resistant, anti-impact agent energy
Power is strong, its preparation technology advantages of simple, can extensive use.
In order to solve the above-mentioned technical problem, the present invention takes following technical scheme：
A kind of antirust composite, is made up of the raw material of following parts by weight：40~60 parts of zinc-magnesium aluminium alloy, composite fibre
100~140 parts, 2~6 parts of plasticizer, 4~10 parts of antioxidant；The composition and content of the zinc-magnesium aluminium alloy be：Zinc 1.0%
~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；The composite fibre is one in carbon fiber, alumina fibre, boron fibre
Kind or two or more combinations.
Further, it is made up of the raw material of following parts by weight：45~55 parts of zinc-magnesium aluminium alloy, composite fibre 120~130
Part, 3~5 parts of plasticizer, 5~8 parts of antioxidant.
Further, it is made up of the raw material of following parts by weight：50 parts of zinc-magnesium aluminium alloy, 126 parts of composite fibre, plasticizer
4 parts, 7 parts of antioxidant.
Further the main function of above-mentioned adding ingredient is：
Zinc-magnesium aluminum alloy materials and composite fibre collective effect are used in the present invention, wherein alloy material has intensity resistance to greatly
Mill, the advantages of strong shock resistance, but toughness is not good enough, while antirust ability is poor, and composite fibre and increasing are added in the present invention
Agent and antioxidant are moulded, on the one hand strengthens the antirust ability and antioxidant capacity of alloy material, while promotes alloy material and multiple
Condensating fiber effectively combines, and strengthens adhesion between the two, and so as to which the composite property prepared is more preferable, feature is more prominent.
The preparation method step of the present invention is as follows：
Step S01, the preparation of zinc-magnesium aluminium alloy：Zinc, magnesium, aluminium simple substance is weighed by weight percentage to carry out vacuumizing melting,
Zinc-magnesium aluminium alloy is made in cooling, and crushes and obtain alloy material powder, standby；
Step S02, mixed after the composite fibre of the parts by weight is crushed respectively, it is standby；
Step S03, carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
Vacuum kneading, it is incubated after mixing to 180~200 DEG C and adds plasticizer and antioxidant, continued 1~2h of mixing, cooling granulation, obtain
To antirust composite.
Further, it is described to be warming up to 650~680 with 50~80 DEG C/min speed when vacuumizing melting in step S01
DEG C, it is incubated 20~30 minutes；During cooling 200~220 DEG C are cooled under inert gas shielding with 80~85 DEG C of speed.
Further, in step S01, the particle diameter of the alloy material powder is 6~8mm.
Further, in step S02, concrete operations are：
S001：Composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；
S002：Fiber pulverizer is crushed 20~25S, is obtained composite fibre with 800~1500r/min rotating speed, timing
Grain；
S003：Gained composite fibre sieving in step S003 is removed into the excessive fiber grain of particle diameter, obtains 10~20nm
Fiber grain, be then mixed uniformly, it is standby.
Further, in step S03, the vacuum kneading first adds alloy material powder with 80~95 DEG C/min speed
550~650 DEG C are warming up to, keeps 10~15min, 10~15s of composite fibre powder mixing is added and is incubated to 180~200 DEG C.
Further, in step S03, after the addition plasticizer and antioxidant, 15~20min is stirred, and be incubated
20min。
Further, in step S03, the plasticizer be diethyl phthalate, di-sec-octyl phthalate,
One or both of ethyl benzoate；The antioxidant is ethyl-para-hydroxybenzoate, nano-titanium oxide
It is an advantage of the invention that：
1. the zinc-magnesium aluminium alloy that the present invention uses for matrix material, coordinates with complex fiber material and promoter material, prepare
Composite there is high antirust ability, it is high structural strength, good shock resistance, ductility, corrosion-resistant, radiation-resistant excellent
Point.
2. the composite fibre that the present invention uses and zinc-magnesium aluminum alloy materials fusion, with intensity is big, toughness is high, comfortable
Property strong, good hydrophilic property, easy to maintain, plasticity is strong, process operation is simple, biotic environment compatibility is excellent and environment friendly and pollution-free
Advantage.
3. the present invention combines modern advanced technologies, preparation method is simple, processing cost is low, significant effect, and prepared is anti-
Composite quality of becoming rusty is good, function is more, the lasting antirust of energy, convenient use
Embodiment
Embodiments of the invention are described in detail below, but what the present invention can be defined by the claims and cover
Multitude of different ways is implemented.
Experimental method in following embodiments, it is conventional method unless otherwise specified.Original used in following embodiments
Material, related dispensing etc., unless otherwise specified, are commercially available products.
Embodiment 1
(1) a kind of antirust composite
Raw material and composition：(unit：g)
Zinc-magnesium aluminium alloy 400g, composite fibre 1000g, plasticizer 20g, antioxidant 40g.
The composition and content of above-mentioned zinc-magnesium aluminium alloy be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；
The composite fibre is combination more than one or both of carbon fiber, alumina fibre, boron fibre.
It is prepared via a method which：
Step S01, the preparation of zinc-magnesium aluminium alloy：Weigh by weight percentage when zinc, magnesium, aluminium simple substance vacuumize melting with 50
DEG C/min speed is warming up to 650 DEG C, 20 minutes are incubated, 200 DEG C of systems are cooled to 80 DEG C of speed under inert gas shielding
Zinc-magnesium aluminium alloy is obtained, and crushes and obtains alloy material powder, it is standby；
In aforesaid operations, the particle diameter of alloy material powder is 6~8mm
Step S02, composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；It is fine
Pulverizer is tieed up to crush 20S with 800r/min rotating speed, timing, obtain composite fibre particle；By the compound fibre of gained in step S003
Dimension sieving removes the excessive fiber grain of particle diameter, obtains 10nm fiber grain, is then mixed uniformly, standby；
Step S03, carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
Vacuum kneading, first add alloy material powder and be warming up to 550 DEG C with 80 DEG C/min speed, keep 10min, add composite fibre
Powder is kneaded 10s, is incubated to 180 DEG C and adds plasticizer and antioxidant, stirs 15min, and is incubated 20min and continues to be kneaded 1h,
Cooling granulation, obtain antirust composite.
In aforesaid operations, the plasticizer is diethyl phthalate, di-sec-octyl phthalate, ethyl benzoate
One or both of；The antioxidant is ethyl-para-hydroxybenzoate, nano-titanium oxide.
Embodiment 2
(1) a kind of antirust composite
Raw material and composition：(unit：g)
Zinc-magnesium aluminium alloy 600g, composite fibre 1400g, plasticizer 60g, antioxidant 100g.
The composition and content of above-mentioned zinc-magnesium aluminium alloy be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；
The composite fibre is combination more than one or both of carbon fiber, alumina fibre, boron fibre.
It is prepared via a method which：
Step S01, the preparation of zinc-magnesium aluminium alloy：Weigh by weight percentage when zinc, magnesium, aluminium simple substance vacuumize melting with 80
DEG C/min speed is warming up to 680 DEG C, 30 minutes are incubated, 220 DEG C of systems are cooled to 85 DEG C of speed under inert gas shielding
Zinc-magnesium aluminium alloy is obtained, and crushes and obtains alloy material powder, it is standby；
In aforesaid operations, the particle diameter of alloy material powder is 6~8mm
Step S02, composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；It is fine
Pulverizer is tieed up to crush 25S with 1500r/min rotating speed, timing, obtain composite fibre particle；By the compound fibre of gained in step S003
Dimension sieving removes the excessive fiber grain of particle diameter, obtains 20nm fiber grain, is then mixed uniformly, standby；
Step S03, carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
Vacuum kneading, first add alloy material powder and be warming up to 650 DEG C with 95 DEG C/min speed, keep 15min, add composite fibre
Powder is kneaded 15s, is incubated to 200 DEG C and adds plasticizer and antioxidant, stirs 20min, and is incubated 20min and continues to be kneaded 2h,
Cooling granulation, obtain antirust composite.
In aforesaid operations, the plasticizer is diethyl phthalate, di-sec-octyl phthalate, ethyl benzoate
One or both of；The antioxidant is ethyl-para-hydroxybenzoate, nano-titanium oxide.
Embodiment 3
(1) a kind of antirust composite
Raw material and composition：(unit：g)
Zinc-magnesium aluminium alloy 450g, composite fibre 1200g, plasticizer 30g, antioxidant 50g.
The composition and content of above-mentioned zinc-magnesium aluminium alloy be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；
The composite fibre is combination more than one or both of carbon fiber, alumina fibre, boron fibre.
It is prepared via a method which：
Step S01, the preparation of zinc-magnesium aluminium alloy：Weigh by weight percentage when zinc, magnesium, aluminium simple substance vacuumize melting with 58
DEG C/min speed is warming up to 650 DEG C, 25 minutes are incubated, 200 DEG C of systems are cooled to 80 DEG C of speed under inert gas shielding
Zinc-magnesium aluminium alloy is obtained, and crushes and obtains alloy material powder, it is standby；
In aforesaid operations, the particle diameter of alloy material powder is 6~8mm
Step S02, composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；It is fine
Pulverizer is tieed up to crush 20S with 1000r/min rotating speed, timing, obtain composite fibre particle；By the compound fibre of gained in step S003
Dimension sieving removes the excessive fiber grain of particle diameter, obtains 10nm fiber grain, is then mixed uniformly, standby；
Step S03, carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
Vacuum kneading, first add alloy material powder and be warming up to 600 DEG C with 80 DEG C/min speed, keep 10min, add composite fibre
Powder is kneaded 12s, is incubated to 190 DEG C and adds plasticizer and antioxidant, stirs 15min, and be incubated 20min and continue to be kneaded
1.5h, cooling granulation, obtain antirust composite.
In aforesaid operations, the plasticizer is diethyl phthalate, di-sec-octyl phthalate, ethyl benzoate
One or both of；The antioxidant is ethyl-para-hydroxybenzoate, nano-titanium oxide.
Embodiment 4
(1) a kind of antirust composite
Raw material and composition：(unit：g)
Zinc-magnesium aluminium alloy 550g, composite fibre 1300g, plasticizer 50g, antioxidant 80g.
The composition and content of above-mentioned zinc-magnesium aluminium alloy be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；
The composite fibre is combination more than one or both of carbon fiber, alumina fibre, boron fibre.
It is prepared via a method which：
Step S01, the preparation of zinc-magnesium aluminium alloy：Weigh by weight percentage when zinc, magnesium, aluminium simple substance vacuumize melting with 75
DEG C/min speed is warming up to 670 DEG C, 28 minutes are incubated, 210 DEG C of systems are cooled to 85 DEG C of speed under inert gas shielding
Zinc-magnesium aluminium alloy is obtained, and crushes and obtains alloy material powder, it is standby；
In aforesaid operations, the particle diameter of alloy material powder is 6~8mm
Step S02, composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；It is fine
Pulverizer is tieed up to crush 24S with 1200r/min rotating speed, timing, obtain composite fibre particle；By the compound fibre of gained in step S003
Dimension sieving removes the excessive fiber grain of particle diameter, obtains 20nm fiber grain, is then mixed uniformly, standby；
Step S03, carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
Vacuum kneading, first add alloy material powder and be warming up to 630 DEG C with 90 DEG C/min speed, keep 14min, add composite fibre
Powder is kneaded 13s, is incubated to 200 DEG C and adds plasticizer and antioxidant, stirs 18min, and be incubated 20min and continue to be kneaded
1.6h, cooling granulation, obtain antirust composite.
In aforesaid operations, the plasticizer is diethyl phthalate, di-sec-octyl phthalate, ethyl benzoate
One or both of；The antioxidant is ethyl-para-hydroxybenzoate, nano-titanium oxide.
Embodiment 5
(1) a kind of antirust composite
Raw material and composition：(unit：g)
Zinc-magnesium aluminium alloy 500g, composite fibre 1260g, plasticizer 40g, antioxidant 70g.
The composition and content of above-mentioned zinc-magnesium aluminium alloy be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；
The composite fibre is combination more than one or both of carbon fiber, alumina fibre, boron fibre.
It is prepared via a method which：
Step S01, the preparation of zinc-magnesium aluminium alloy：Weigh by weight percentage when zinc, magnesium, aluminium simple substance vacuumize melting with 70
DEG C/min speed is warming up to 665 DEG C, 26 minutes are incubated, 205 DEG C of systems are cooled to 85 DEG C of speed under inert gas shielding
Zinc-magnesium aluminium alloy is obtained, and crushes and obtains alloy material powder, it is standby；
In aforesaid operations, the particle diameter of alloy material powder is 6~8mm
Step S02, composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；It is fine
Pulverizer is tieed up to crush 22S with 1400r/min rotating speed, timing, obtain composite fibre particle；By the compound fibre of gained in step S003
Dimension sieving removes the excessive fiber grain of particle diameter, obtains 20nm fiber grain, is then mixed uniformly, standby；
Step S03, carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
Vacuum kneading, first add alloy material powder and be warming up to 620 DEG C with 85 DEG C/min speed, keep 12min, add composite fibre
Powder is kneaded 10s, is incubated to 200 DEG C and adds plasticizer and antioxidant, stirs 18min, and be incubated 20min and continue to be kneaded
1.2h, cooling granulation, obtain antirust composite.
In aforesaid operations, the plasticizer is diethyl phthalate, di-sec-octyl phthalate, ethyl benzoate
One or both of；The antioxidant is ethyl-para-hydroxybenzoate, nano-titanium oxide.
Experimental example
The antirust composite being prepared using the various embodiments described above, for the research of composite basic nature energy, enter
One step confirms the effect of the antirust composite：
Test 1：The antirust composite that above example and comparative example are prepared carries out performance test
Table 1：The performance parameter table of comparisons of waterproof footwear material and common footwear material in embodiment 1~5
From above test data can be seen that antirust composite tensile strength provided by the invention reached 654MPa with
On, elongation has reached 5.1-5.3%, and hardness (HRB) has reached more than 82, and antiseptic property is in relative humidity 70%, temperature 45
800h surfaces are unchanged under conditions of DEG C.Above it can be seen that to implement the 4 iron-based antirust powder properties that are prepared more prominent,
Therefore most preferred embodiment can be used as.
Without addition composite fibre and plasticizer and antioxidant in comparative example, the results showed that the stretching of final material is strong
Degree is just declined with elongation, while intensity is big, and antirust ability is not all right, and reason may be because single alloy material be hard
Embodiment is very strong in terms of degree, and toughness is relatively weak so that and tensile strength and elongation decline, and cause easily to wear, and produce rust staining,
Therefore with other components collective effect can occur for the addition of the component, improve the antiseptic property of material.
Claims (10)
1. a kind of antirust composite, it is characterised in that the raw material for preparing antirust composite and its parts by weight are：Zinc-magnesium
40~60 parts of aluminium alloy, 100~140 parts of composite fibre, 2~6 parts of plasticizer, 4~10 parts of antioxidant；The zinc-magnesium aluminium alloy
Composition and content be：Zinc 1.0%~2.5%, magnesium 2.0%~4.5%, remaining is aluminium；The composite fibre is carbon fiber, oxygen
Change the combination of one or both of aluminum fiber.
2. antirust composite according to claim 1, it is characterised in that it is described prepare antirust composite raw material and
Its parts by weight is：45~55 parts of zinc-magnesium aluminium alloy, 120~130 parts of composite fibre, 3~5 parts of plasticizer, 5~8 parts of antioxidant.
3. antirust composite according to claim 1, it is characterised in that it is described prepare antirust composite raw material and
Its parts by weight is：50 parts of zinc-magnesium aluminium alloy, 126 parts of composite fibre, 4 parts of plasticizer, 7 parts of antioxidant.
It is 4. a kind of such as the preparation method of antirust composite according to any one of claims 1 to 3, it is characterised in that including
Following steps：
Step S01, the preparation of zinc-magnesium aluminium alloy：Zinc, magnesium, aluminium simple substance are weighed by weight percentage to carry out vacuumizing melting, are cooled down
Zinc-magnesium aluminium alloy is made, and crushes and obtains alloy material powder, it is standby；
Step S02, mixed after the composite fibre of the parts by weight is crushed respectively, it is standby；
Step S03, vacuum is carried out after the composite fibre powder of gained alloy material powder in step S01 and step S02 is dried
It is kneaded, is incubated after mixing to 180~200 DEG C and adds plasticizer and antioxidant, continued 1~2h of mixing, cooling granulation, prevented
Become rusty composite.
5. preparation technology according to claim 4, it is characterised in that in step S01, it is described when vacuumizing melting with 50~
80 DEG C/min speed is warming up to 650~680 DEG C, is incubated 20~30 minutes；With 80~85 under inert gas shielding during cooling
DEG C speed be cooled to 200~220 DEG C.
6. preparation technology according to claim 4, it is characterised in that in step S01, the particle diameter of the alloy material powder
For 6~8mm.
7. preparation technology according to claim 4, it is characterised in that in step S02, concrete operations are：
S001：Composite fibre is separately dried removal of impurities, moisture is less than 0.1%, adds in fiber pulverizer；
S002：Fiber pulverizer is crushed 20~25S, is obtained composite fibre particle with 800~1500r/min rotating speed, timing；
S003：Gained composite fibre sieving in step S003 is removed into the excessive fiber grain of particle diameter, obtains 10~20nm fibre
Particle is tieed up, is then mixed uniformly, it is standby.
8. preparation technology according to claim 4, it is characterised in that in step S03, the vacuum kneading first adds alloy
Material powder is warming up to 550~650 DEG C with 80~95 DEG C/min speed, keeps 10~15min, adds composite fibre powder and mixes
10~15s is refined, is incubated to 180~200 DEG C.
9. preparation technology according to claim 4, it is characterised in that in step S03, the addition plasticizer and anti-oxidant
After agent, 15~20min is stirred, and be incubated 20min.
10. preparation technology according to claim 4, it is characterised in that in step S03, the plasticizer is O-phthalic
One or both of diethyl phthalate, di-sec-octyl phthalate, ethyl benzoate；The antioxidant is para hydroxybenzene first
Acetoacetic ester, nano-titanium oxide.
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| JPS61209149A (en) * | 1985-03-13 | 1986-09-17 | 古河アルミニウム工業株式会社 | Composite plate for can end |
| CN103233189A (en) * | 2013-04-18 | 2013-08-07 | 邱献腾 | Aluminum matrix composite material and processing technology thereof |
| CN103628005A (en) * | 2013-11-22 | 2014-03-12 | 江苏大学 | Carbon fiber reinforced aluminum base composite material for brake disc and preparation method of composite material |
| CN104213056A (en) * | 2014-09-15 | 2014-12-17 | 河南科技大学 | Carbon fiber-reinforced aluminum-magnesium alloy composite material and preparation method thereof |
| CN104711496A (en) * | 2015-04-01 | 2015-06-17 | 北京工业大学 | Carbon-nanotube-reinforced magnesium/aluminum-base composite material and preparation method thereof |
| CN105385968A (en) * | 2015-12-02 | 2016-03-09 | 重庆重通成飞新材料有限公司 | Magnesium-aluminum composite material |
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2017
- 2017-08-11 CN CN201710685822.1A patent/CN107604273A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61209149A (en) * | 1985-03-13 | 1986-09-17 | 古河アルミニウム工業株式会社 | Composite plate for can end |
| CN103233189A (en) * | 2013-04-18 | 2013-08-07 | 邱献腾 | Aluminum matrix composite material and processing technology thereof |
| CN103628005A (en) * | 2013-11-22 | 2014-03-12 | 江苏大学 | Carbon fiber reinforced aluminum base composite material for brake disc and preparation method of composite material |
| CN104213056A (en) * | 2014-09-15 | 2014-12-17 | 河南科技大学 | Carbon fiber-reinforced aluminum-magnesium alloy composite material and preparation method thereof |
| CN104711496A (en) * | 2015-04-01 | 2015-06-17 | 北京工业大学 | Carbon-nanotube-reinforced magnesium/aluminum-base composite material and preparation method thereof |
| CN105385968A (en) * | 2015-12-02 | 2016-03-09 | 重庆重通成飞新材料有限公司 | Magnesium-aluminum composite material |
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