CN107603267A - A kind of nontoxic sponge of environment-friendly type and its manufacture craft - Google Patents
A kind of nontoxic sponge of environment-friendly type and its manufacture craft Download PDFInfo
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- CN107603267A CN107603267A CN201710972404.0A CN201710972404A CN107603267A CN 107603267 A CN107603267 A CN 107603267A CN 201710972404 A CN201710972404 A CN 201710972404A CN 107603267 A CN107603267 A CN 107603267A
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Abstract
The invention discloses a kind of nontoxic sponge of environment-friendly type and its manufacture craft, sponge component includes 20 40 parts of polymer polyatomic alcohol in parts by weight, 10 20 parts of string, 14 parts of polyvinylpyrrolidone, 14 parts of tin catalyst, 15 30 parts of sodium alginate, 8 18 parts of antistatic agent, 9 12 parts of fire retardant, 8 14 parts of silicone oil, 15 20 parts of secondary octyl phenol polyethenoxy ether, 18 parts of calcium carbonate, 26 parts of glutaraldehyde, 4 10 parts of magnesium carbonate, 5 12 parts of bamboo-carbon fibre, 4 12 parts of zirconium oxide, 3 12 parts of 13 parts of nano titanium oxide and deionized water, preparation method of the present invention is simple, preparation process is environment friendly and pollution-free, obtained sponge has antistatic, fire-retardant performance, good environmental protection, and service life is grown.
Description
Technical field
The present invention relates to sponge production technical field, the nontoxic sponge of specially a kind of environment-friendly type and its manufacture craft.
Background technology
Sponge, it is a kind of porous material, there is good water imbibition, can be used in clean article.The sponge that people commonly use
It is made up of wood cellulose fibers or foamed plastic polymer.In addition, also have the natural sponge made of spongia, most a couple of days
Right sponge is used for clean body or drawing.In addition, synthetic sponge, respectively low-density polyethers also made of three class other materials
（Not water-absorbing sponge）, polyvinyl alcohol（High-absorbent material, without obvious stomata）And polyester.Existing industrial sponge environmental-protecting performance, resistance
Combustion property, antistatic property are poor.
The content of the invention
It is an object of the invention to provide a kind of nontoxic sponge of environment-friendly type and its manufacture craft, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the nontoxic sponge of a kind of environment-friendly type, sponge component include polymer polyatomic alcohol in parts by weight
20-40 parts, string 10-20 parts, polyvinylpyrrolidone 1-4 parts, tin catalyst 1-4 parts, sodium alginate 15-30 parts, prevent
Electrostatic agent 8-18 parts, fire retardant 9-12 parts, silicone oil 8-14 parts, secondary octyl phenol polyethenoxy ether 15-20 parts, calcium carbonate 1-8 parts, penta
Dialdehyde 2-6 parts, magnesium carbonate 4-10 parts, bamboo-carbon fibre 5-12 parts, zirconium oxide 4-12 parts, nano titanium oxide 1-3 parts and go from
Sub- water 3-12 parts.
Preferably, preferable composition proportion is：30 parts of polymer polyatomic alcohol, 15 parts of string, polyvinylpyrrolidone 3
Part, 2 parts of tin catalyst, 22 parts of sodium alginate, 13 parts of antistatic agent, 11 parts of fire retardant, 11 parts of silicone oil, secondary octyl phenol polyethenoxy
18 parts of ether, 4 parts of calcium carbonate, 4 parts of glutaraldehyde, 7 parts of magnesium carbonate, 8 parts of bamboo-carbon fibre, 8 parts of zirconium oxide, 2 parts of nano titanium oxide with
And 8 parts of deionized water.
Preferably, its manufacture craft comprises the following steps：
A, by polymer polyatomic alcohol, string, polyvinylpyrrolidone is tin catalyst, sodium alginate, antistatic agent, fire-retardant
Stirring at low speed in agitator tank is added after agent, silicone oil mixing, stir speed (S.S.) is 200 revs/min, time 20min, obtains mixture A；
B, added in mixture A secondary octyl phenol polyethenoxy ether, calcium carbonate, glutaraldehyde, magnesium carbonate, bamboo-carbon fibre, zirconium oxide,
Heating response in water-bath is added after nano titanium oxide, deionized water mixing, heating-up temperature is 55 DEG C, and the heat time is
30min, constant temperature 10min, is slowly dropped to room temperature afterwards, obtains mixture B；
C, mixture B is added compressing in mould；
D, it is stripped afterwards, obtains semi-finished product；
E, finally cut using cutting machine, remove leftover pieces, obtain sponge finished product.
Compared with prior art, the beneficial effects of the invention are as follows：Preparation method of the present invention is simple, and preparation process environmental protection is without dirt
Dye, obtained sponge have antistatic, fire-retardant performance, good environmental protection；The antistatic agent added in the present invention has excellent
Antistatic property, and can keep longer；In addition, the fire retardant fire protection flame retarding effect added in the present invention is good, to ring
Border is friendly, and can improve the performance of sponge to a certain extent.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
The present invention provides following technical scheme：A kind of nontoxic sponge of environment-friendly type, sponge component include polymerization in parts by weight
Thing polyalcohol 20-40 parts, string 10-20 parts, polyvinylpyrrolidone 1-4 parts, tin catalyst 1-4 parts, sodium alginate 15-
30 parts, antistatic agent 8-18 parts, fire retardant 9-12 parts, silicone oil 8-14 parts, secondary octyl phenol polyethenoxy ether 15-20 parts, calcium carbonate
1-8 parts, glutaraldehyde 2-6 parts, magnesium carbonate 4-10 parts, bamboo-carbon fibre 5-12 parts, zirconium oxide 4-12 parts, nano titanium oxide 1-3 parts
And deionized water 3-12 parts.
Embodiment one：
Sponge component includes 20 parts of polymer polyatomic alcohol, 10 parts of string, 1 part of polyvinylpyrrolidone, tin in parts by weight
1 part of catalyst, 15 parts of sodium alginate, 8 parts of antistatic agent, 9 parts of fire retardant, 8 parts of silicone oil, 15 parts of secondary octyl phenol polyethenoxy ether,
1 part of calcium carbonate, 2 parts of glutaraldehyde, 4 parts of magnesium carbonate, 5 parts of bamboo-carbon fibre, 4 parts of zirconium oxide, 1 part of nano titanium oxide and deionization
3 parts of water.
The manufacture craft of the present embodiment comprises the following steps：
A, by polymer polyatomic alcohol, string, polyvinylpyrrolidone is tin catalyst, sodium alginate, antistatic agent, fire-retardant
Stirring at low speed in agitator tank is added after agent, silicone oil mixing, stir speed (S.S.) is 200 revs/min, time 20min, obtains mixture A；
B, added in mixture A secondary octyl phenol polyethenoxy ether, calcium carbonate, glutaraldehyde, magnesium carbonate, bamboo-carbon fibre, zirconium oxide,
Heating response in water-bath is added after nano titanium oxide, deionized water mixing, heating-up temperature is 55 DEG C, and the heat time is
30min, constant temperature 10min, is slowly dropped to room temperature afterwards, obtains mixture B；
C, mixture B is added compressing in mould；
D, it is stripped afterwards, obtains semi-finished product；
E, finally cut using cutting machine, remove leftover pieces, obtain sponge finished product.
Embodiment two：
Sponge component includes 40 parts of polymer polyatomic alcohol, 20 parts of string, 4 parts of polyvinylpyrrolidone, tin in parts by weight
4 parts of catalyst, 30 parts of sodium alginate, 18 parts of antistatic agent, 12 parts of fire retardant, 14 parts of silicone oil, secondary octyl phenol polyethenoxy ether 20
Part, 8 parts of calcium carbonate, 6 parts of glutaraldehyde, 10 parts of magnesium carbonate, 12 parts of bamboo-carbon fibre, 12 parts of zirconium oxide, 3 parts of nano titanium oxide and
12 parts of deionized water.
The manufacture craft of the present embodiment comprises the following steps：
A, by polymer polyatomic alcohol, string, polyvinylpyrrolidone is tin catalyst, sodium alginate, antistatic agent, fire-retardant
Stirring at low speed in agitator tank is added after agent, silicone oil mixing, stir speed (S.S.) is 200 revs/min, time 20min, obtains mixture A；
B, added in mixture A secondary octyl phenol polyethenoxy ether, calcium carbonate, glutaraldehyde, magnesium carbonate, bamboo-carbon fibre, zirconium oxide,
Heating response in water-bath is added after nano titanium oxide, deionized water mixing, heating-up temperature is 55 DEG C, and the heat time is
30min, constant temperature 10min, is slowly dropped to room temperature afterwards, obtains mixture B；
C, mixture B is added compressing in mould；
D, it is stripped afterwards, obtains semi-finished product；
E, finally cut using cutting machine, remove leftover pieces, obtain sponge finished product.
Embodiment three：
Sponge component includes 25 parts of polymer polyatomic alcohol, 12 parts of string, 2 parts of polyvinylpyrrolidone, tin in parts by weight
2 parts of catalyst, 17 parts of sodium alginate, 10 parts of antistatic agent, 10 parts of fire retardant, 9 parts of silicone oil, secondary octyl phenol polyethenoxy ether 16
Part, 2 parts of calcium carbonate, 3 parts of glutaraldehyde, 5 parts of magnesium carbonate, 6 parts of bamboo-carbon fibre, 5 parts of zirconium oxide, 2 parts of nano titanium oxide and go
4 parts of ionized water.
The manufacture craft of the present embodiment comprises the following steps：
A, by polymer polyatomic alcohol, string, polyvinylpyrrolidone is tin catalyst, sodium alginate, antistatic agent, fire-retardant
Stirring at low speed in agitator tank is added after agent, silicone oil mixing, stir speed (S.S.) is 200 revs/min, time 20min, obtains mixture A；
B, added in mixture A secondary octyl phenol polyethenoxy ether, calcium carbonate, glutaraldehyde, magnesium carbonate, bamboo-carbon fibre, zirconium oxide,
Heating response in water-bath is added after nano titanium oxide, deionized water mixing, heating-up temperature is 55 DEG C, and the heat time is
30min, constant temperature 10min, is slowly dropped to room temperature afterwards, obtains mixture B；
C, mixture B is added compressing in mould；
D, it is stripped afterwards, obtains semi-finished product；
E, finally cut using cutting machine, remove leftover pieces, obtain sponge finished product.
Example IV：
Sponge component includes 30 parts of polymer polyatomic alcohol, 15 parts of string, 3 parts of polyvinylpyrrolidone, tin in parts by weight
2 parts of catalyst, 22 parts of sodium alginate, 13 parts of antistatic agent, 11 parts of fire retardant, 11 parts of silicone oil, secondary octyl phenol polyethenoxy ether 18
Part, 4 parts of calcium carbonate, 4 parts of glutaraldehyde, 7 parts of magnesium carbonate, 8 parts of bamboo-carbon fibre, 8 parts of zirconium oxide, 2 parts of nano titanium oxide and go
8 parts of ionized water.
The manufacture craft of the present embodiment comprises the following steps：
A, by polymer polyatomic alcohol, string, polyvinylpyrrolidone is tin catalyst, sodium alginate, antistatic agent, fire-retardant
Stirring at low speed in agitator tank is added after agent, silicone oil mixing, stir speed (S.S.) is 200 revs/min, time 20min, obtains mixture A；
B, added in mixture A secondary octyl phenol polyethenoxy ether, calcium carbonate, glutaraldehyde, magnesium carbonate, bamboo-carbon fibre, zirconium oxide,
Heating response in water-bath is added after nano titanium oxide, deionized water mixing, heating-up temperature is 55 DEG C, and the heat time is
30min, constant temperature 10min, is slowly dropped to room temperature afterwards, obtains mixture B；
C, mixture B is added compressing in mould；
D, it is stripped afterwards, obtains semi-finished product；
E, finally cut using cutting machine, remove leftover pieces, obtain sponge finished product.
Preparation method of the present invention is simple, and preparation process is environment friendly and pollution-free, and obtained sponge has antistatic, fire-retardant property
Can, good environmental protection；The antistatic agent added in the present invention has excellent antistatic property, and can keep longer；Separately
Outside, the fire retardant fire protection flame retarding effect added in the present invention is good, environmentally friendly, and can improve sponge to a certain extent
Performance.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (3)
- A kind of 1. nontoxic sponge of environment-friendly type, it is characterised in that：Sponge component includes polymer polyatomic alcohol 20-40 in parts by weight Part, string 10-20 parts, polyvinylpyrrolidone 1-4 parts, tin catalyst 1-4 parts, sodium alginate 15-30 parts, antistatic agent 8-18 parts, fire retardant 9-12 parts, silicone oil 8-14 parts, secondary octyl phenol polyethenoxy ether 15-20 parts, calcium carbonate 1-8 parts, glutaraldehyde 2- 6 parts, magnesium carbonate 4-10 parts, bamboo-carbon fibre 5-12 parts, zirconium oxide 4-12 parts, nano titanium oxide 1-3 parts and deionized water 3- 12 parts.
- A kind of 2. nontoxic sponge of environment-friendly type according to claim 1, it is characterised in that：Preferably composition proportion is：Polymerization 30 parts of thing polyalcohol, 15 parts of string, 3 parts of polyvinylpyrrolidone, 2 parts of tin catalyst, 22 parts of sodium alginate, antistatic agent 13 parts, 11 parts of fire retardant, 11 parts of silicone oil, 18 parts of secondary octyl phenol polyethenoxy ether, 4 parts of calcium carbonate, 4 parts of glutaraldehyde, magnesium carbonate 7 Part, 8 parts of bamboo-carbon fibre, 8 parts of zirconium oxide, 2 parts of nano titanium oxide and 8 parts of deionized water.
- 3. realize a kind of manufacture craft of the nontoxic sponge of environment-friendly type described in claim 1, it is characterised in that：Its manufacture craft bag Include following steps：A, by polymer polyatomic alcohol, string, polyvinylpyrrolidone is tin catalyst, sodium alginate, antistatic agent, fire-retardant Stirring at low speed in agitator tank is added after agent, silicone oil mixing, stir speed (S.S.) is 200 revs/min, time 20min, obtains mixture A；B, added in mixture A secondary octyl phenol polyethenoxy ether, calcium carbonate, glutaraldehyde, magnesium carbonate, bamboo-carbon fibre, zirconium oxide, Heating response in water-bath is added after nano titanium oxide, deionized water mixing, heating-up temperature is 55 DEG C, and the heat time is 30min, constant temperature 10min, is slowly dropped to room temperature afterwards, obtains mixture B；C, mixture B is added compressing in mould；D, it is stripped afterwards, obtains semi-finished product；E, finally cut using cutting machine, remove leftover pieces, obtain sponge finished product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710972404.0A CN107603267A (en) | 2017-10-18 | 2017-10-18 | A kind of nontoxic sponge of environment-friendly type and its manufacture craft |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710972404.0A CN107603267A (en) | 2017-10-18 | 2017-10-18 | A kind of nontoxic sponge of environment-friendly type and its manufacture craft |
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| CN107603267A true CN107603267A (en) | 2018-01-19 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104725796A (en) * | 2015-03-02 | 2015-06-24 | 上海雨竺实业有限公司 | Pure natural environment-friendly sponge |
| CN107057023A (en) * | 2017-05-05 | 2017-08-18 | 温州市宏日海棉制造有限公司 | A kind of environment-friendly type sponge and its production technology |
| CN107118324A (en) * | 2017-05-05 | 2017-09-01 | 温州市宏日海棉制造有限公司 | A kind of novel sponge and its production technology |
| CN107254460A (en) * | 2017-06-23 | 2017-10-17 | 广东海洋大学 | A kind of carboxymethyl chitosan/sodium alginate composite sponge immobilized papain and its application |
-
2017
- 2017-10-18 CN CN201710972404.0A patent/CN107603267A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104725796A (en) * | 2015-03-02 | 2015-06-24 | 上海雨竺实业有限公司 | Pure natural environment-friendly sponge |
| CN107057023A (en) * | 2017-05-05 | 2017-08-18 | 温州市宏日海棉制造有限公司 | A kind of environment-friendly type sponge and its production technology |
| CN107118324A (en) * | 2017-05-05 | 2017-09-01 | 温州市宏日海棉制造有限公司 | A kind of novel sponge and its production technology |
| CN107254460A (en) * | 2017-06-23 | 2017-10-17 | 广东海洋大学 | A kind of carboxymethyl chitosan/sodium alginate composite sponge immobilized papain and its application |
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