CN107598078A - Ultra-thin magnesium alloy electronic part die casting parting agent special - Google Patents
Ultra-thin magnesium alloy electronic part die casting parting agent special Download PDFInfo
- Publication number
- CN107598078A CN107598078A CN201711088070.7A CN201711088070A CN107598078A CN 107598078 A CN107598078 A CN 107598078A CN 201711088070 A CN201711088070 A CN 201711088070A CN 107598078 A CN107598078 A CN 107598078A
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- CN
- China
- Prior art keywords
- magnesium alloy
- ultra
- die casting
- electronic part
- emulsion
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 15
- 238000004512 die casting Methods 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 8
- 239000002480 mineral oil Substances 0.000 claims abstract description 8
- BXQNSPXDWSNUKE-UHFFFAOYSA-N 1,3-benzothiazole 1-oxide Chemical compound C1=CC=C2S(=O)C=NC2=C1 BXQNSPXDWSNUKE-UHFFFAOYSA-N 0.000 claims abstract description 7
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical class OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000019482 Palm oil Nutrition 0.000 claims abstract description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 7
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims abstract description 7
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002540 palm oil Substances 0.000 claims abstract description 7
- 239000012188 paraffin wax Substances 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 229920005990 polystyrene resin Polymers 0.000 claims abstract description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 7
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000005461 lubrication Methods 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000017 mucous membrane irritation Toxicity 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
The invention discloses a kind of ultra-thin magnesium alloy electronic part die casting parting agent special, including octamethylcy-clotetrasiloxane emulsion, silicone modified styrene-acrylate emulsion, paraffin base mineral oil, palm oil, neopelex, sodium sulfate of polyethenoxy ether of fatty alcohol, sodium phosphate, hydroxymethyl polystyrene resin, benzothiazolinone, pure water.Invention is with fine lubrication function, demolding performace, heat resistance.
Description
Technical field
The present invention relates to a kind of ultra-thin magnesium alloy electronic part die casting parting agent special.
Background technology
Ultralight, extra small, the ultrathin IT electronic products such as the mobile phone released in the market, laptop computer, its outward appearance housing
All cast using resin material.Resin material density is small, shaping is simple, but there is also drawback：First, waste and old housing can not divide again
Solution utilizes, and seriously pollutes environment；Second, with the further development of IT product ultrathin, casing rigidity and rigidity are difficult to meet to want
Ask.On the other hand, it is proposed the substitute of resin-case in the industry in recent years -- magnesium alloy shell.Because magnesium alloy shell has density
Small, outstanding advantages of intensity is high, thermal diffusivity and shielding are good, recyclable recycling, so getting most of the attention and favoring once listing.
But due to indispensable auxiliary agent in forming technique -- the research and development of releasing agent relatively lag behind, so domestic magnesium alloy at present
Shell cast factory is still generally stripped using common releasing agent, so as to seriously constrain the further of magnesium alloy shell ultrathin technology
Development.Also there is releasing agent of some producers in development ＆ production magnesium alloy electronic part die casting the country at present, but due to, it is backward in technique
It is poor in the prevalence of release property etc. reason（Adsorbance ＜ 0.5mg/100cm2）, poor lubricity（Coefficient of friction ＞ 0.25）, molten soup
Poor fluidity（100cm2Steel plate extension area ＜ 28.2cm2）The problems such as, cause magnesium alloy electronic part demoulding difficulty, be molded slow, table
Face blacks, is uneven.
The content of the invention
It is an object of the invention to provide a kind of ultra-thin magnesium conjunction with fine lubrication function, demolding performace, heat resistance
Golden soft copy die casting parting agent special.
The present invention technical solution be：
A kind of ultra-thin magnesium alloy electronic part die casting parting agent special, it is characterized in that：It is made up of the composition of following weight percents：
Octamethylcy-clotetrasiloxane emulsion 25-35%
Silicone modified styrene-acrylate emulsion 15-25%
Paraffin base mineral oil 1-5%
Palm oil 1-3%
Neopelex 3-6%
Sodium sulfate of polyethenoxy ether of fatty alcohol 1-3%
Sodium phosphate 2-5%
Hydroxymethyl polystyrene resin 2-5%
Benzothiazolinone 0.3-0.8%
Pure water surplus.
Described ultra-thin magnesium alloy electronic part die casting parting agent special, is made up of the composition of following weight percents：
Octamethylcy-clotetrasiloxane emulsion 30%
Silicone modified styrene-acrylate emulsion 20%
Paraffin base mineral oil 3%
Palm oil 2%
Neopelex 4%
Sodium sulfate of polyethenoxy ether of fatty alcohol 2%
Sodium phosphate 3%
Hydroxymethyl polystyrene resin 3%
Benzothiazolinone 0.5%
Pure water surplus.
Advantage of the present invention：
1. formula is from the polymerizable aqueous pitch dispersant of excellent thermal insulation performance（Substitute the synthetic ester that tradition uses）Compatibility, carry
The demolding performace of high product（Through experiment, under 400 DEG C of high temperature heating conditions, SPCC steel plates are sprayed on after being stripped 60 times of dilution agent
On, its adsorbance >=1.0mg/cm2；TGA thermogravimetric tests, active constituent content >=50%）.
2. formula is compounded from high viscosity mineral oil and vegetable oil（Substitute organic pulvis that tradition uses）, improve product
Greasy property（Through experiment, under 150 DEG C of hot conditions, product coefficient of friction≤0.158）.
3. formula, which is selected, has Long carbon chain（C8-C10）With the modification silicon emulsion with benzene ring structure（Substitute what tradition used
Dimethyl-silicon emulsion）, lift the ductility of product（Through experiment, 100cm2Steel plate extension area can lift 40.3cm2）.
Using without using poisonous and harmful substances such as heavy metal, aromatic hydrocarbon（It is high, right from function admirable, biodegradability
The friendly alternative material of human and environment）, product acute oral toxicity LD50 >=5000mg/kg, acute inhalation toxicity LC50 >=
5000mg/m3, No respiratory mucosal irritation, safety and sanitation quality height.
With reference to embodiment, the invention will be further described.
Embodiment
Embodiment 1：
A kind of ultra-thin magnesium alloy electronic part die casting parting agent special, is made up of the composition of following weight percents：
Octamethylcy-clotetrasiloxane emulsion 30%
Silicone modified styrene-acrylate emulsion 20%
Paraffin base mineral oil 3%
Palm oil 2%
Neopelex 4%
Sodium sulfate of polyethenoxy ether of fatty alcohol 2%
Sodium phosphate 3%
Hydroxymethyl polystyrene resin 3%
Benzothiazolinone 0.5%
Pure water surplus.
Embodiment 2：
A kind of ultra-thin magnesium alloy electronic part die casting parting agent special, is made up of the composition of following weight percents：
Octamethylcy-clotetrasiloxane emulsion 25-35%（Example 25%, 33%）
Silicone modified styrene-acrylate emulsion 15-25%（Example 15%, 24%）
Paraffin base mineral oil 1-5%（Example 1%, 4%）
Palm oil 1-3%（Example 1%, 3%）
Neopelex 3-6%（Example 3%, 5%）
Sodium sulfate of polyethenoxy ether of fatty alcohol 1-3%（Example 1%, 3%）
Sodium phosphate 2-5%（Example 2%, 5%）
Hydroxymethyl polystyrene resin 2-5%（Example 2%, 5%）
Benzothiazolinone 0.3-0.8%（Example 0.3%, 0.8%）
Pure water surplus.
Claims (2)
1. a kind of ultra-thin magnesium alloy electronic part die casting parting agent special, it is characterized in that：It is made up of the composition of following weight percents：
Octamethylcy-clotetrasiloxane emulsion 25-35%
Silicone modified styrene-acrylate emulsion 15-25%
Paraffin base mineral oil 1-5%
Palm oil 1-3%
Neopelex 3-6%
Sodium sulfate of polyethenoxy ether of fatty alcohol 1-3%
Sodium phosphate 2-5%
Hydroxymethyl polystyrene resin 2-5%
Benzothiazolinone 0.3-0.8%
Pure water surplus.
2. ultra-thin magnesium alloy electronic part die casting parting agent special according to claim 1, it is characterized in that：By following weight
The composition composition of percentage：
Octamethylcy-clotetrasiloxane emulsion 30%
Silicone modified styrene-acrylate emulsion 20%
Paraffin base mineral oil 3%
Palm oil 2%
Neopelex 4%
Sodium sulfate of polyethenoxy ether of fatty alcohol 2%
Sodium phosphate 3%
Hydroxymethyl polystyrene resin 3%
Benzothiazolinone 0.5%
Pure water surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711088070.7A CN107598078A (en) | 2017-11-08 | 2017-11-08 | Ultra-thin magnesium alloy electronic part die casting parting agent special |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711088070.7A CN107598078A (en) | 2017-11-08 | 2017-11-08 | Ultra-thin magnesium alloy electronic part die casting parting agent special |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107598078A true CN107598078A (en) | 2018-01-19 |
Family
ID=61086041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711088070.7A Pending CN107598078A (en) | 2017-11-08 | 2017-11-08 | Ultra-thin magnesium alloy electronic part die casting parting agent special |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107598078A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108856643A (en) * | 2018-09-19 | 2018-11-23 | 广东赛米克新材料有限公司 | The ultra-thin magnesium alloy die casting release agent of plate in a kind of 3C electronic product casing frame |
| CN109022100A (en) * | 2018-07-19 | 2018-12-18 | 芜湖维软新材料有限公司 | The interior lubricated silicon oil containing octamethylcy-clotetrasiloxane |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101036933A (en) * | 2007-04-11 | 2007-09-19 | 华中科技大学 | Powderlike mold-releasing agent for die-casing |
| CN101152662A (en) * | 2006-10-01 | 2008-04-02 | 福建省测试技术研究所 | Heat resisting lubricating agent |
| CN101898227A (en) * | 2010-07-28 | 2010-12-01 | 启东尤希路化学工业有限公司 | Environmental-friendly magnesium alloy mold releasing agent |
| CN102407278A (en) * | 2011-11-29 | 2012-04-11 | 朱小英 | Method for preparing coating for metal molds for magnesium-alloy low-pressure casting |
| JP2013139495A (en) * | 2011-12-28 | 2013-07-18 | Nemoto & Co Ltd | Mold release agent |
-
2017
- 2017-11-08 CN CN201711088070.7A patent/CN107598078A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101152662A (en) * | 2006-10-01 | 2008-04-02 | 福建省测试技术研究所 | Heat resisting lubricating agent |
| CN101036933A (en) * | 2007-04-11 | 2007-09-19 | 华中科技大学 | Powderlike mold-releasing agent for die-casing |
| CN101898227A (en) * | 2010-07-28 | 2010-12-01 | 启东尤希路化学工业有限公司 | Environmental-friendly magnesium alloy mold releasing agent |
| CN102407278A (en) * | 2011-11-29 | 2012-04-11 | 朱小英 | Method for preparing coating for metal molds for magnesium-alloy low-pressure casting |
| JP2013139495A (en) * | 2011-12-28 | 2013-07-18 | Nemoto & Co Ltd | Mold release agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109022100A (en) * | 2018-07-19 | 2018-12-18 | 芜湖维软新材料有限公司 | The interior lubricated silicon oil containing octamethylcy-clotetrasiloxane |
| CN108856643A (en) * | 2018-09-19 | 2018-11-23 | 广东赛米克新材料有限公司 | The ultra-thin magnesium alloy die casting release agent of plate in a kind of 3C electronic product casing frame |
| CN108856643B (en) * | 2018-09-19 | 2020-05-12 | 广东赛米克新材料有限公司 | Mold release agent for ultrathin magnesium alloy die castings in middle plate of 3C electronic product shell frame |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180119 |