CN107586508A - A kind of high-decoration powdery paints applied on fork truck outer surface - Google Patents
A kind of high-decoration powdery paints applied on fork truck outer surface Download PDFInfo
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- CN107586508A CN107586508A CN201710713811.XA CN201710713811A CN107586508A CN 107586508 A CN107586508 A CN 107586508A CN 201710713811 A CN201710713811 A CN 201710713811A CN 107586508 A CN107586508 A CN 107586508A
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- fork truck
- decoration
- powdery paints
- truck outer
- wax
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Abstract
The invention discloses a kind of high-decoration powdery paints applied on fork truck outer surface, it is related to powder coating technology field, is made up of the raw material of following mass percent:Terminal carboxyl polyester resin 82.720%, curing agent 6.249%, levelling agent 1.011%, brightener 1.011%, styrax 0.459%, polytetrafluoroethylwax wax 0.184%, degassing wax 0.460%, titanium dioxide 0.735%, blanc fixe 1.379%, organic red pigment 1.654%, organic yellow pigment 2.482%, iron oxide yellow pigments 0.919%, charcoal blacks 0.001%, antioxidant 0.460%, defoamer 0.276%.The made powder of the present invention can quickly form fine and close and hard paint film after spraying in fork truck outer surface, and film curing condition is 200 DEG C, 15min, and the paint film has excellent wearability, corrosion resistance, weatherability and levelability etc..
Description
Technical field:
The present invention relates to powder coating technology field, and in particular to a kind of high-decoration powder applied on fork truck outer surface
Last coating.
Background technology:
Fork truck, it is industrial transportation vehicle, refers to load and unload member pallet cargo, stacking and short distance hauling operation
Various wheeled carrying vehicles.Because fork truck prolonged application is in handling goods and in outdoor environment, therefore to fork truck outer surface
Wearability and weatherability require it is very high.In the case where fork truck manufacture material is constant, it is necessary to be applied by being sprayed in its outer surface
The mode of material strengthens its wearability and weatherability.
Powdery paints, be it is a kind of it is new be free of the solid powdery coating of solvent 100%, have it is solvent-free, pollution-free, can
Recovery, environmental protection, save the energy and resource, reduce labor intensity with coating machinery intensity it is high the features such as.Without primary coat, disposably apply
Work is that can obtain the film of adequate thickness, and coating densification, adhesive force, impact strength and toughness are good, corner coverage
Height, there is excellent resistance to corrosive chemicals energy and electrical insulation properties.
In order to improve the wearability of fork truck outer surface and weatherability, our company develops a kind of be applied on fork truck outer surface
High decoration powder coating, paint film can quickly be formed by being sprayed at behind fork truck outer surface, and paint film have excellent wearability,
Weatherability and high-decoration, so as to ensure the use quality of fork truck outer surface and extend the service life of paint film.
The content of the invention:
The technical problems to be solved by the invention, which are to provide, a kind of has excellent wearability, weatherability to ensure fork truck
Outer surface use quality and the high-decoration powdery paints for extending paint film service life.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of high-decoration powdery paints applied on fork truck outer surface, it is made up of the raw material of following mass percent:
Terminal carboxyl polyester resin 82.720%, curing agent 6.249%, levelling agent 1.011%, brightener 1.011%, rest in peace
Perfume 0.459%, polytetrafluoroethylwax wax 0.184%, degassing wax 0.460%, titanium dioxide 0.735%, blanc fixe 1.379%,
Organic red pigment 1.654%, organic yellow pigment 2.482%, iron oxide yellow pigments 0.919%, charcoal blacks 0.001%, antioxidant
0.460%th, defoamer 0.276%;
Its preparation method is:Raw material is weighed according to the above ratio, is placed in being pre-mixed in high shear mixers, then through double spiral shells
Bar extruder melting extrusion, material after extrusion through tabletting, coarse crushing and it is finely divided after detect, it is qualified after testing can pack,
Storage.
The premixing time of the high shear mixers is in 15min.
The operating temperature of the double screw extruder is controlled in 30 DEG C of an area, 115 DEG C of 2nd area, 110 DEG C of 3rd area, screw speed
45r/s, charging rate 28r/s.
The speed of the tabletting is in 25r/s.
It is described finely divided from ACM flour mills, main grinding machine speed 48r/s, secondary grinding machine speed 28r/s, feed rate 20r/
s。
The terminal carboxyl polyester resin is selected from the mixture of two kinds of model above terminal carboxyl polyesters.
The levelling agent is selected from the mixture or self-control poly-aspartic-acid/acrylic acid hydroxypropyl of two kinds of model above levelling agents
Ester.
The specific preparation method of the poly-aspartic-acid/hydroxypropyl acrylate is:Under grinding into poly-aspartic-acid
Deionized water is added dropwise until being completely dissolved, and is heated to reflux state insulated and stirred 5min, adds hydroxypropyl acrylate and two
Luxuriant iron, continue the insulated and stirred 30min that flows back, then add trihydroxymethylpropanyltri diglycidyl ether and epoxidized soybean oil, again
Flowed back insulated and stirred 30min, and gained mixture is sent into spray dryer after naturally cooling to room temperature, dries gained particle warp
Micro mist is made in micronizer, produces poly-aspartic-acid/hydroxypropyl acrylate.
The poly-aspartic-acid, hydroxypropyl acrylate, ferrocene, trihydroxymethylpropanyltri diglycidyl ether and epoxy are big
Mass percent shared by soya-bean oil is respectively 68.03%, 24.94%, 0.23%, 4.53%, 2.27%.
Above-mentioned poly-aspartic-acid/hydroxypropyl acrylate is through esterification by poly-aspartic-acid and hydroxypropyl acrylate
It is made with the physical modification after polymerisation again through trihydroxymethylpropanyltri diglycidyl ether and epoxidized soybean oil, its flow leveling
Better than commercially available L88 levelling agents and PL-200A levelling agents.
The beneficial effects of the invention are as follows:The present invention is aided with a variety of auxiliary agents and is made using terminal carboxyl polyester resin as primary raw material
Fork truck outer surface protection type powdery paints, the coating be easy to storage and it is safe to use, can be in fork truck appearance after spraying
Face quickly forms fine and close and hard paint film, and film curing condition is 200 DEG C, 15min, and the paint film have it is excellent wear-resisting
Property, corrosion resistance, weatherability and levelability etc., so as to improve the dicoration of fork truck outer surface and ensure the use quality of paint film
With extend paint film service life, to be adapted to long-term outdoor use environment.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
Terminal carboxyl polyester resin 769.3kg, curing agent 58.120kg, levelling agent 9.403kg, brightener 9.402kg, rest in peace
Fragrant 4.273kg, polytetrafluoroethylwax wax 1.710kg, degassing wax 4.275kg, titanium dioxide 6.838kg, blanc fixe 12.822kg,
Organic red pigment 15.386kg, organic yellow pigment 23.079kg, iron oxide yellow pigments 8.548kg, charcoal blacks 0.013kg, antioxidant
4.275kg, defoamer 2.564kg.
Its preparation method is:Raw material is weighed according to the above ratio, is placed in being pre-mixed in high shear mixers, then through double spiral shells
Bar extruder melting extrusion, material after extrusion through tabletting, coarse crushing and it is finely divided after detect, it is qualified after testing can pack,
Storage.
Wherein, the premixing time of high shear mixers is in 15min;The operating temperature of double screw extruder is controlled one
30 DEG C of area, 115 DEG C of 2nd area, 110 DEG C, screw speed 45r/s, charging rate 28r/s of 3rd area;The speed of tabletting is in 25r/s;Fine powder
It is broken to select ACM flour mills, main grinding machine speed 48r/s, secondary grinding machine speed 28r/s, feed rate 20r/s.
Wherein, terminal carboxyl polyester resin is selected from the SJ4588 terminal carboxyl polyester trees of Anhui Shenjian New Material Co., Ltd.
Fat and SJ4ET terminal carboxyl polyester resins (both quality are respectively 598.3kg and 171kg), curing agent are selected from Mount Huang Jin Feng industry
The TGIC curing agent of Co., Ltd, levelling agent are selected from PL-200A levelling agents and the force of Anhui An Zhibang Chemical Industry Science Co., Ltd
The L88 levelling agents (both quality are respectively 5.13kg and 4.273kg) of Han Yincai Science and Technology Ltd.s, brightener opens selected from Suzhou
The 701B brighteners of boat powder body material Co., Ltd, styrax are selected from Wuhan Yin Cai Science and Technology Ltd.s, polytetrafluoroethylwax wax choosing
From the SA5066 polytetrafluoroethylwax waxes of the prompt sensible new material Co., Ltd of six peaces, it is limited that degassing wax is selected from the prompt sensible new material of six peaces
The SA500 degassing waxes of company, titanium dioxide are selected from the BLR896 titanium dioxides of Henan Baililian Chemical Co., Ltd., sulfate precipitate
Barium is selected from Wuxi City Fuhua Chemical Co., Ltd., and the 2542H that organic red pigment is selected from Shanghai Lian Ping Chemical Co., Ltd.s is red, organic
Yellow pigment is selected from 1390 Huangs of Shanghai Lian Ping Chemical Co., Ltd.s, and iron oxide yellow pigments are selected from the 420 of Shanghai Lang Sheng Chemical Co., Ltd.s
Iron oxide yellow, charcoal blacks are selected from the C311 carbon blacks of Anhui An Zhibang Chemical Industry Science Co., Ltd, and it is prompt sensible new that antioxidant is selected from six peaces
The K7003 antioxidant of Materials Co., Ltd, defoamer are selected from the SA5060 defoamers of the prompt sensible new material Co., Ltd of six peaces.
Embodiment 2
Terminal carboxyl polyester resin 769.3kg, curing agent 58.120kg, levelling agent 9.403kg, brightener 9.402kg, rest in peace
Fragrant 4.273kg, polytetrafluoroethylwax wax 1.710kg, degassing wax 4.275kg, titanium dioxide 6.838kg, blanc fixe 12.822kg,
Organic red pigment 15.386kg, organic yellow pigment 23.079kg, iron oxide yellow pigments 8.548kg, charcoal blacks 0.013kg, antioxidant
4.275kg, defoamer 2.564kg.
Its preparation method is:Raw material is weighed according to the above ratio, is placed in being pre-mixed in high shear mixers, then through double spiral shells
Bar extruder melting extrusion, material after extrusion through tabletting, coarse crushing and it is finely divided after detect, it is qualified after testing can pack,
Storage.
Wherein, the premixing time of high shear mixers is in 15min;The operating temperature of double screw extruder is controlled one
30 DEG C of area, 115 DEG C of 2nd area, 110 DEG C, screw speed 45r/s, charging rate 28r/s of 3rd area;The speed of tabletting is in 25r/s;Fine powder
It is broken to select ACM flour mills, main grinding machine speed 48r/s, secondary grinding machine speed 28r/s, feed rate 20r/s.
Wherein, terminal carboxyl polyester resin is selected from the SJ4588 terminal carboxyl polyester trees of Anhui Shenjian New Material Co., Ltd.
Fat and SJ4ET terminal carboxyl polyester resins (both quality are respectively 598.3kg and 171kg), curing agent are selected from Mount Huang Jin Feng industry
The TGIC curing agent of Co., Ltd, levelling agent are selected from self-control poly-aspartic-acid/hydroxypropyl acrylate, and brightener opens selected from Suzhou
The 701B brighteners of boat powder body material Co., Ltd, styrax are selected from Wuhan Yin Cai Science and Technology Ltd.s, polytetrafluoroethylwax wax choosing
From the SA5066 polytetrafluoroethylwax waxes of the prompt sensible new material Co., Ltd of six peaces, it is limited that degassing wax is selected from the prompt sensible new material of six peaces
The SA500 degassing waxes of company, titanium dioxide are selected from the BLR896 titanium dioxides of Henan Baililian Chemical Co., Ltd., sulfate precipitate
Barium is selected from Wuxi City Fuhua Chemical Co., Ltd., and the 2542H that organic red pigment is selected from Shanghai Lian Ping Chemical Co., Ltd.s is red, organic
Yellow pigment is selected from 1390 Huangs of Shanghai Lian Ping Chemical Co., Ltd.s, and iron oxide yellow pigments are selected from the 420 of Shanghai Lang Sheng Chemical Co., Ltd.s
Iron oxide yellow, charcoal blacks are selected from the C311 carbon blacks of Anhui An Zhibang Chemical Industry Science Co., Ltd, and it is prompt sensible new that antioxidant is selected from six peaces
The K7003 antioxidant of Materials Co., Ltd, defoamer are selected from the SA5060 defoamers of the prompt sensible new material Co., Ltd of six peaces.
The preparation of poly-aspartic-acid/hydroxypropyl acrylate:Deionization is added dropwise into 15kg poly-aspartic-acids under grinding
Water is heated to reflux state insulated and stirred 5min up to being completely dissolved, and adds 5.5kg hydroxypropyl acrylates and 0.05kg bis-
Luxuriant iron, continue the insulated and stirred 30min that flows back, then add 1kg trihydroxymethylpropanyltri diglycidyl ethers and 0.5kg epoxy soybeans
Oil, flowed back insulated and stirred 30min again, and gained mixture is sent into spray dryer after naturally cooling to room temperature, dries institute
Obtain particle and micro mist is made through micronizer, produce poly-aspartic-acid/hydroxypropyl acrylate.
Reference examples 1
Terminal carboxyl polyester resin 769.3kg, curing agent 58.120kg, levelling agent 9.403kg, brightener 9.402kg, rest in peace
Fragrant 4.273kg, polytetrafluoroethylwax wax 1.710kg, degassing wax 4.275kg, titanium dioxide 6.838kg, blanc fixe 12.822kg,
Organic red pigment 15.386kg, organic yellow pigment 23.079kg, iron oxide yellow pigments 8.548kg, charcoal blacks 0.013kg, antioxidant
4.275kg, defoamer 2.564kg.
Its preparation method is:Raw material is weighed according to the above ratio, is placed in being pre-mixed in high shear mixers, then through double spiral shells
Bar extruder melting extrusion, material after extrusion through tabletting, coarse crushing and it is finely divided after detect, it is qualified after testing can pack,
Storage.
Wherein, the premixing time of high shear mixers is in 15min;The operating temperature of double screw extruder is controlled one
30 DEG C of area, 115 DEG C of 2nd area, 110 DEG C, screw speed 45r/s, charging rate 28r/s of 3rd area;The speed of tabletting is in 25r/s;Fine powder
It is broken to select ACM flour mills, main grinding machine speed 48r/s, secondary grinding machine speed 28r/s, feed rate 20r/s.
Wherein, terminal carboxyl polyester resin is selected from the SJ4588 terminal carboxyl polyester trees of Anhui Shenjian New Material Co., Ltd.
Fat and SJ4ET terminal carboxyl polyester resins (both quality are respectively 598.3kg and 171kg), curing agent are selected from Mount Huang Jin Feng industry
The TGIC curing agent of Co., Ltd, levelling agent are selected from self-control poly-aspartic-acid/hydroxypropyl acrylate, and brightener opens selected from Suzhou
The 701B brighteners of boat powder body material Co., Ltd, styrax are selected from Wuhan Yin Cai Science and Technology Ltd.s, polytetrafluoroethylwax wax choosing
From the SA5066 polytetrafluoroethylwax waxes of the prompt sensible new material Co., Ltd of six peaces, it is limited that degassing wax is selected from the prompt sensible new material of six peaces
The SA500 degassing waxes of company, titanium dioxide are selected from the BLR896 titanium dioxides of Henan Baililian Chemical Co., Ltd., sulfate precipitate
Barium is selected from Wuxi City Fuhua Chemical Co., Ltd., and the 2542H that organic red pigment is selected from Shanghai Lian Ping Chemical Co., Ltd.s is red, organic
Yellow pigment is selected from 1390 Huangs of Shanghai Lian Ping Chemical Co., Ltd.s, and iron oxide yellow pigments are selected from the 420 of Shanghai Lang Sheng Chemical Co., Ltd.s
Iron oxide yellow, charcoal blacks are selected from the C311 carbon blacks of Anhui An Zhibang Chemical Industry Science Co., Ltd, and it is prompt sensible new that antioxidant is selected from six peaces
The K7003 antioxidant of Materials Co., Ltd, defoamer are selected from the SA5060 defoamers of the prompt sensible new material Co., Ltd of six peaces.
The preparation of poly-aspartic-acid/hydroxypropyl acrylate:Deionization is added dropwise into 15kg poly-aspartic-acids under grinding
Water is heated to reflux state insulated and stirred 5min up to being completely dissolved, and adds 5.5kg hydroxypropyl acrylates and 0.05kg bis-
Luxuriant iron, continue the insulated and stirred 60min that flows back, gained mixture is sent into spray dryer after naturally cooling to room temperature, is dried
Micro mist is made through micronizer in gained particle, produces poly-aspartic-acid/hydroxypropyl acrylate.
Reference examples 2
Terminal carboxyl polyester resin 769.3kg, curing agent 58.120kg, brightener 9.402kg, styrax 4.273kg, poly- four
PVF wax 1.710kg, degassing wax 4.275kg, titanium dioxide 6.838kg, blanc fixe 12.822kg, organic red pigment
15.386kg, organic yellow pigment 23.079kg, iron oxide yellow pigments 8.548kg, charcoal blacks 0.013kg, antioxidant 4.275kg, disappear
Infusion 2.564kg.
Its preparation method is:Raw material is weighed according to the above ratio, is placed in being pre-mixed in high shear mixers, then through double spiral shells
Bar extruder melting extrusion, material after extrusion through tabletting, coarse crushing and it is finely divided after detect, it is qualified after testing can pack,
Storage.
Wherein, the premixing time of high shear mixers is in 15min;The operating temperature of double screw extruder is controlled one
30 DEG C of area, 115 DEG C of 2nd area, 110 DEG C, screw speed 45r/s, charging rate 28r/s of 3rd area;The speed of tabletting is in 25r/s;Fine powder
It is broken to select ACM flour mills, main grinding machine speed 48r/s, secondary grinding machine speed 28r/s, feed rate 20r/s.
Wherein, terminal carboxyl polyester resin is selected from the SJ4588 terminal carboxyl polyester trees of Anhui Shenjian New Material Co., Ltd.
Fat and SJ4ET terminal carboxyl polyester resins (both quality are respectively 598.3kg and 171kg), curing agent are selected from Mount Huang Jin Feng industry
The TGIC curing agent of Co., Ltd, brightener are selected from the 701B brighteners of Suzhou departure powder body material Co., Ltd, styrax choosing
From Wuhan Yin Cai Science and Technology Ltd.s, polytetrafluoroethylwax wax is selected from the SA5066 polytetrafluoros of the prompt sensible new material Co., Ltd of six peaces
Ethylene waxes, degassing wax are selected from the SA500 degassing waxes of the prompt sensible new material Co., Ltd of six peaces, and titanium dioxide is selected from the sharp connectionization in Henan one hundred
The BLR896 titanium dioxides of limited company are learned, blanc fixe is selected from Wuxi City Fuhua Chemical Co., Ltd., organic red pigment
2542H selected from Shanghai Lian Ping Chemical Co., Ltd.s is red, and organic yellow pigment is selected from 1390 Huangs of Shanghai Lian Ping Chemical Co., Ltd.s,
Iron oxide yellow pigments are selected from 420 iron oxide yellows of Shanghai Lang Sheng Chemical Co., Ltd.s, and nation's chemical science and technology that charcoal blacks are selected from Anhui peace is limited
The C311 carbon blacks of company, antioxidant are selected from the K7003 antioxidant of the prompt sensible new material Co., Ltd of six peaces, and defoamer is selected from six peaces
The SA5060 defoamers of prompt sensible new material Co., Ltd.
Embodiment 3
Respectively by equivalent embodiment 1, embodiment 2, reference examples 1,2 made powder paint of reference examples in 0.5mm steel plates
On, and the film-forming under 200 DEG C of condition of cure, 15min, performance test is carried out to the film formed, as a result such as the institute of table 1
Show;And the flow leveling of made coating is determined, as a result as shown in table 2.
The embodiment 1-2 of table 1, the made coating of reference examples 1-2 spray the film performance to be formed
The embodiment 1-2 of table 2, the flow leveling of the made coating of reference examples 1-2
Project | Embodiment 1 | Embodiment 2 | Reference examples 1 | Reference examples 2 |
Planarization (PCI) | 7-8 | 8 | 8 | 7 |
Bottom horizontal flow sheet (200 DEG C) | 29.5mm | 31mm | 30.5mm | 27mm |
Gloss (60 °) | 91% | 96% | 94% | 82% |
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
- A kind of 1. high-decoration powdery paints applied on fork truck outer surface, it is characterised in that:By following mass percent Raw material is made:Terminal carboxyl polyester resin 82.720%, curing agent 6.249%, levelling agent 1.011%, brightener 1.011%, styrax 0.459%th, polytetrafluoroethylwax wax 0.184%, degassing wax 0.460%, titanium dioxide 0.735%, blanc fixe 1.379%, have Machine red 1.654%, organic yellow pigment 2.482%, iron oxide yellow pigments 0.919%, charcoal blacks 0.001%, antioxidant 0.460%th, defoamer 0.276%;Its preparation method is:Raw material is weighed according to the above ratio, is placed in being pre-mixed in high shear mixers, then squeeze through twin-screw Go out machine melting extrusion, the material after extrusion through tabletting, coarse crushing and it is finely divided after detect, it is qualified after testing to pack, be put in storage.
- 2. the high-decoration powdery paints according to claim 1 applied on fork truck outer surface, it is characterised in that:It is described The premixing time of high shear mixers is in 15min.
- 3. the high-decoration powdery paints according to claim 1 applied on fork truck outer surface, it is characterised in that:It is described The operating temperature control of double screw extruder is in 30 DEG C of an area, 115 DEG C of 2nd area, 110 DEG C, screw speed 45r/s of 3rd area, charging speed Spend 28r/s.
- 4. the high-decoration powdery paints according to claim 1 applied on fork truck outer surface, it is characterised in that:It is described The speed of tabletting is in 25r/s.
- 5. the high-decoration powdery paints according to claim 1 applied on fork truck outer surface, it is characterised in that:It is described It is finely divided to select ACM flour mills, main grinding machine speed 48r/s, secondary grinding machine speed 28r/s, feed rate 20r/s.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108329805A (en) * | 2018-02-01 | 2018-07-27 | 海信科龙电器股份有限公司 | A kind of anticorrosive paint and preparation method thereof for air-conditioner outdoor unit babinet metal plate |
CN109401572A (en) * | 2018-11-13 | 2019-03-01 | 安徽桑瑞斯环保新材料有限公司 | A kind of concrete mixing tank car weather-resistant powder paint |
CN111100534A (en) * | 2019-12-28 | 2020-05-05 | 江阴市玲珑高分子材料有限公司 | Water spot-resistant powder coating |
CN111205750A (en) * | 2020-02-17 | 2020-05-29 | 安徽华辉塑业科技股份有限公司 | High-temperature-resistant powder coating and preparation method thereof |
CN111303680A (en) * | 2020-02-17 | 2020-06-19 | 安徽华辉塑业科技股份有限公司 | Hammer-type epoxy resin type powder coating and preparation method thereof |
Citations (1)
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CN103509439A (en) * | 2012-06-21 | 2014-01-15 | 佛山市顺德区百丽池涂料有限公司 | Low-temperature curing epoxy polyester powdery paint used on surface of bakelite and preparation method thereof |
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2017
- 2017-08-18 CN CN201710713811.XA patent/CN107586508A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103509439A (en) * | 2012-06-21 | 2014-01-15 | 佛山市顺德区百丽池涂料有限公司 | Low-temperature curing epoxy polyester powdery paint used on surface of bakelite and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108329805A (en) * | 2018-02-01 | 2018-07-27 | 海信科龙电器股份有限公司 | A kind of anticorrosive paint and preparation method thereof for air-conditioner outdoor unit babinet metal plate |
CN108329805B (en) * | 2018-02-01 | 2021-01-26 | 海信科龙电器股份有限公司 | Anticorrosive paint for sheet metal of outdoor unit box body of air conditioner and preparation method of anticorrosive paint |
CN109401572A (en) * | 2018-11-13 | 2019-03-01 | 安徽桑瑞斯环保新材料有限公司 | A kind of concrete mixing tank car weather-resistant powder paint |
CN111100534A (en) * | 2019-12-28 | 2020-05-05 | 江阴市玲珑高分子材料有限公司 | Water spot-resistant powder coating |
CN111205750A (en) * | 2020-02-17 | 2020-05-29 | 安徽华辉塑业科技股份有限公司 | High-temperature-resistant powder coating and preparation method thereof |
CN111303680A (en) * | 2020-02-17 | 2020-06-19 | 安徽华辉塑业科技股份有限公司 | Hammer-type epoxy resin type powder coating and preparation method thereof |
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Application publication date: 20180116 |