CN107586417A - A kind of cross-linking radiation sea work welding private cable sheath rubber - Google Patents
A kind of cross-linking radiation sea work welding private cable sheath rubber Download PDFInfo
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- CN107586417A CN107586417A CN201610534798.7A CN201610534798A CN107586417A CN 107586417 A CN107586417 A CN 107586417A CN 201610534798 A CN201610534798 A CN 201610534798A CN 107586417 A CN107586417 A CN 107586417A
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Abstract
The present invention relates to a kind of cross-linking radiation sea work to weld private cable sheath rubber, it is by haloflex, polyolefin elastomer, light magnesium oxide, carbon black, high-strength deposition white carbon black, superfine talcum powder, ultrafine aluminium hydroxide/magnesium, superfine antimony trioxide, chlorinated paraffin, liquid polyester, plasticizer, plasticizer, calcium stearate, age resistor, antioxidant, microcrystalline wax, silane coupler, it is crosslinked sensitising agent, the compositions such as sensitising agent are crosslinked to form, after being kneaded at room temperature, the rubber cable of extrusion molding is simultaneously crosslinked cable rubber by line irradiation, so as to produce the present invention.The beneficial effects of the invention are as follows：1st, there is the characteristic performance of heat-resisting, oil resistant, weatherability, fire-retardant, low cigarette, low in acidity, odorlessness, high flexibility and high intensity etc.；2nd, meet environmental requirement, simple production process, safety, be easy to produce, production efficiency is high.
Description
Technical field
The present invention relates to a kind of cross-linking radiation sea work to weld private cable sheath rubber.
Background technology
Common ship, offshore platform and marine New Equipment Engineering, when welding and/or cutting hardware or construction,
Because the useful space is small, environment closing, place is complicated, multilayer multiple tracks and continuous arc welding usually occurs, and welding equipment welds with soldering turret
Torch frequently need to be moved and pulled.The performance requirement for the welding cable thus built to extra large work New Equipment Engineering is extremely strict, its performance
Quality and its anti-flammability, reliable to Arc Welding Power supply and transmission, construction welding matter effect, production environment and personal safety are all
There is great influence.The extra large work welding cable that is commonly used is even to require high flexibility, in light weight, external diameter is small, work temperature
The performance that degree is high, combined closure system is big etc., it is disadvantageous in that：Broken in oil resistant, resistance to scraped finish, resistance to spreading, warping strength, resistance to mechanical external force
There are larger gap and deficiency in terms of the characteristic performance of bad and fire-retardant, low cigarette, odorlessness etc..
The content of the invention
It is an object of the invention to provide a kind of in addition to good electric, physical mechanical, oil resistant, heat-resisting, softness
Also have the cross-linking radiation sea work welding Special electric that odorlessness, low cigarette, low in acidity, low toxicity, fire-retardant and copper conductor can keep glossy concurrently
Cable sheath rubber.
Technical program of the present invention lies in：By mass percentage, it is made up of following composition：The percentage of formula is as follows：
Haloflex (CPE135B) 35% ~ 42%, polyolefin elastomer（POE8150）1% ~ 5%, light magnesium oxide（M-3）1% ~ 5%,
Carbon black（N330）2% ~ 6%, high-strength deposition white carbon black 4% ~ 10%, superfine talcum powder（2500#）6% ~ 10%, ultrafine aluminium hydroxide/magnesium
（2500#）13% ~ 18%, superfine antimony trioxide（1850#）2% ~ 6%, chlorinated paraffin 2% ~ 6%, liquid polyester（PPS）1% ~ 4%, increase
Mould agent（TOTM）1% ~ 4%, plasticizer（DOS）1% ~ 4%, calcium stearate 0.2% ~ 1%, age resistor（RD）0.1% ~ 0.5%, it is anti-oxidant
Agent（1010）0.2% ~ 0.6%, microcrystalline wax 0.2% ~ 0.6%, silane coupler（A-172）0.1% ~ 0.5%, crosslinking sensitising agent (PL-
400) 0.5% ~ 2%, it is crosslinked sensitising agent（TAIC）0.8%~2%.
Embodiment：
The production technology of the present invention：The present invention is to use chlorinated polyethylene rubber (CPE135B) and polyolefin elastomer（POE）For
Heat-resistant rubber main body is kneaded and formed, and cross-linking radiation sensitising agent uses（PL-400）With（TAIC）, stabilizer is steady from environment-friendly type heat
Determine agent calcium stearate, antioxidant（1010）, age resistor（RD）With ozone-resistant microcrystalline wax, heat-resisting oil resistant weatherability body protection choosing
With heat-resisting plasticizer（TOTM）, oil resistant liquid polyester（PPS）, cold resistant plasticizer（DOS）, the low sour fire retardant of low cigarette selects ultra-fine hydrogen
Aluminum oxide/magnesium（2500#）, acid-acceptor select light magnesium oxide（M-3）, environment friendly chlorinated paraffin（Chlorinity is 52%）With it is ultra-fine
Antimony oxide（1850#）, reinforcing agent selects high-strength deep white carbon and high wear-resistant carbon black（N330）, reinforced filling surface treatment
Silane coupler is selected in agent（A-172）.
Raw material is put into kneading machine and is kneaded at room temperature 10~15 minutes by the present invention by formula, and page is rolled over after elastomeric compound is made
Slabbing and/or strip are for squeezing rubber, and by the temperature adjustment of extruder fuselage to 80~100 DEG C, head temperature adjusted to 100~
120 DEG C, so either elastomeric compound is processed or extruded, all without incipient scorch phenomenon is produced, there is good processing to pacify
Quan Xing, and the rubber cable of extrusion molding.Need to park a period of time after uncrosslinked rubber cable drum, being then wound around can be more
Line spoke is carried out by tumbler on the four-wheel synchronization modification dumbbell shape of secondary flexing upset cable or the winding displacement beam of the figure of eight
According to, the process of irradiation forms the crosslinking of cable rubber, and changes the original electrical and physical and mechanical properties of cable rubber material,
So as to produce the cross-linking radiation sea work welding private cable sheath rubber of the present invention.
It in energy is E that the molded rubber cable of the present invention, which is,：2.5Mev；Beam intensity is：30MA；Beam power is：75kW
Irradiation apparatus in carry out two-sided irradiation.As rubber thickness >=1mm, the outside diameter of cable >=10mm, irradiation dose is 7~9M；When
When rubber thickness >=2mm, the outside diameter of cable≤30mm, irradiation dose is 10~12M；As rubber thickness G T.GT.GT 3mm, outside diameter of cable ＞
During 30mm, irradiation dose is 12~14M；High energy electron line hands over the high-polymer molecular material photosensitizer of rubber in irradiation process
Join the rubber cable for tridimensional network.
The rubber strand of the present invention carries out line irradiation simultaneously in the state of normal temperature, no pressure, without pendency drawing tension
Physico crosslinking is realized, conductor of the invention allows to work long hours temperature for 90 DEG C after crosslinking, has temperature classification high, flexible
The characteristics of high, main performance indications reach：Rubber tensile strength：≥13MPa；Rubber elongation at break：≥400%；Tear
Intensity：≥45kN/m；Oxygen index (OI) OI >=30；HCL generating capacities≤50mg/g；Smoke density≤300（NBS methods）；Ageing properties：120
DEG C, 240h, K1≤0.7, K2≤0.6；Oil resistance：No. 20 machine oil, 100 DEG C, 24h, K1 and K2≤0.6；Pressure-resistant voltage test：
Soak 12h, 3000V, 5mim, passes through.The rubber of the present invention is due to without vulcanizing agent component, thus odorlessness, conductive surface can be protected
Hold glossy.The present invention is due to rubber moulding material and production link rationalization, the negative effect very little to environment, and meeting environmental protection will
Summation is easy to produce, and waste of material is few, and production efficiency is high, and energy saving efficiency is high.So that the present invention reach with heat-resisting, oil resistant,
Weatherability, fire-retardant, low cigarette, low in acidity, odorlessness, high flexibility, high-strength characteristic and the purpose for meeting environmental requirement.The present invention removes
It is applied to outside the various mechanically movings for bearing larger mechanical external force effect such as the extra large work source of welding current and equipment, could be applicable to ship
Oceangoing ship platform marine engineering cable, urban track traffic cable, motor cable jumper etc..
The beneficial effects of the invention are as follows：1st, there is heat-resisting, oil resistant, weatherability, fire-retardant, low cigarette, low in acidity, odorlessness, height
The characteristic performance of flexible and high intensity etc.；2nd, meet environmental requirement, simple production process, safety, be easy to produce, produce efficiency
It is high.
Highly preferred embodiment of the present invention：
The present invention by mass percentage, is made up of following composition：Haloflex（CPE135B）40%, polyolefin elastomer
（POE8150）3%, light magnesium oxide（M-3）3%, carbon black（N330）4.5%, high-strength deposition white carbon black 8%, superfine talcum powder
（2500#）8%, ultrafine aluminium hydroxide/magnesium（2500#）15%, superfine antimony trioxide（1850#）4%, chlorinated paraffin 4%, liquid gathers
Ester（PPS）2%, plasticizer（TOTM）2%, plasticizer（DOS）2%, calcium stearate 0.5%, age resistor（RD）0.2%, antioxidant
（1010）0.4%, microcrystalline wax 0.4%, silane coupler（A-172）0.3%, it is crosslinked sensitising agent（PL-400）1.5%, crosslinking is photosensitive
Agent（TAIC）1.2%.
Claims (1)
1. a kind of cross-linking radiation sea work welds private cable sheath rubber, it is characterised in that：By mass percentage, by below into
Part composition：The percentage of formula is as follows：Haloflex (CPE135B) 35% ~ 42%, polyolefin elastomer（POE8150）1%~
5%, light magnesium oxide（M-3）1% ~ 5%, carbon black（N330）2% ~ 6%, high-strength deposition white carbon black 4% ~ 10%, superfine talcum powder
（2500#）6% ~ 10%, ultrafine aluminium hydroxide/magnesium（2500#）13% ~ 18%, superfine antimony trioxide（1850#）2% ~ 6%, chlorination stone
Wax 2% ~ 6%, liquid polyester（PPS）1% ~ 4%, plasticizer（TOTM）1% ~ 4%, plasticizer（DOS）1% ~ 4%, calcium stearate 0.2% ~
1%, age resistor（RD）0.1% ~ 0.5%, antioxidant（1010）0.2% ~ 0.6%, microcrystalline wax 0.2% ~ 0.6%, silane coupler
（A-172）0.1% ~ 0.5%, crosslinking sensitising agent (PL-400) 0.5% ~ 2%, it is crosslinked sensitising agent（TAIC）0.8%~2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610534798.7A CN107586417A (en) | 2016-07-08 | 2016-07-08 | A kind of cross-linking radiation sea work welding private cable sheath rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610534798.7A CN107586417A (en) | 2016-07-08 | 2016-07-08 | A kind of cross-linking radiation sea work welding private cable sheath rubber |
Publications (1)
| Publication Number | Publication Date |
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| CN107586417A true CN107586417A (en) | 2018-01-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610534798.7A Pending CN107586417A (en) | 2016-07-08 | 2016-07-08 | A kind of cross-linking radiation sea work welding private cable sheath rubber |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206763A (en) * | 2018-08-15 | 2019-01-15 | 广州连达橡塑有限公司 | A kind of rubber hose chlorinated polyethylene rubber material and preparation method thereof |
| CN109880245A (en) * | 2019-01-31 | 2019-06-14 | 潍坊硕邑化学有限公司 | A kind of chlorinated polyethylene rubber composition of cross-linking radiation and preparation method thereof |
| CN112321956A (en) * | 2020-10-15 | 2021-02-05 | 威海市泓淋电力技术股份有限公司 | Rubber wire outer sheath for outdoor electrical appliance and preparation method thereof |
| CN114702762A (en) * | 2022-04-24 | 2022-07-05 | 镇江中佳电器有限公司 | Irradiation low-smoke flame-retardant rubber cable material and preparation process thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571072A (en) * | 2012-08-07 | 2014-02-12 | 广州番禺电缆集团有限公司 | Temperature-resistant weather-proof cable sheath rubber and production technology thereof |
-
2016
- 2016-07-08 CN CN201610534798.7A patent/CN107586417A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571072A (en) * | 2012-08-07 | 2014-02-12 | 广州番禺电缆集团有限公司 | Temperature-resistant weather-proof cable sheath rubber and production technology thereof |
Non-Patent Citations (2)
| Title |
|---|
| 巫松桢等编: "《电气绝缘材料科学与工程》", 31 August 1996, 西安交通大学出版社 * |
| 赵明启主编: "《电线电缆生产新工艺新技术及常用参数速查手册 第三卷》", 31 October 2004, 广州文化音像出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206763A (en) * | 2018-08-15 | 2019-01-15 | 广州连达橡塑有限公司 | A kind of rubber hose chlorinated polyethylene rubber material and preparation method thereof |
| CN109206763B (en) * | 2018-08-15 | 2021-02-19 | 广州连达橡塑有限公司 | Chlorinated polyethylene rubber material for rubber hose and preparation method thereof |
| CN109880245A (en) * | 2019-01-31 | 2019-06-14 | 潍坊硕邑化学有限公司 | A kind of chlorinated polyethylene rubber composition of cross-linking radiation and preparation method thereof |
| CN112321956A (en) * | 2020-10-15 | 2021-02-05 | 威海市泓淋电力技术股份有限公司 | Rubber wire outer sheath for outdoor electrical appliance and preparation method thereof |
| CN114702762A (en) * | 2022-04-24 | 2022-07-05 | 镇江中佳电器有限公司 | Irradiation low-smoke flame-retardant rubber cable material and preparation process thereof |
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| CB02 | Change of applicant information |
Address after: No.126 Baoyuan Road, Liwan District, Guangzhou City, Guangdong Province 510145 Applicant after: Guangzhou Jinxiang Industrial Group Co.,Ltd. Address before: 510150, No. 126, Po Yuen Road, Guangzhou, Guangdong, Liwan District Applicant before: GUANGZHOU JINXIANG INDUSTRIAL PRODUCTION Co.,Ltd. |
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Application publication date: 20180116 |
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| RJ01 | Rejection of invention patent application after publication |