CN107583611A - A kind of concave convex rod antirust drier - Google Patents
A kind of concave convex rod antirust drier Download PDFInfo
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- CN107583611A CN107583611A CN201711102681.2A CN201711102681A CN107583611A CN 107583611 A CN107583611 A CN 107583611A CN 201711102681 A CN201711102681 A CN 201711102681A CN 107583611 A CN107583611 A CN 107583611A
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- convex rod
- drier
- concave convex
- antirust
- magnesia
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Abstract
The invention discloses a kind of concave convex rod antirust drier, it is characterised in that:The concave convex rod antirust drier is made up of antirust agent and concave convex rod drier, the proportion of the antirust agent is 5 30%, the concave convex rod drier is made up of silica, calcium oxide, magnesia, aluminum oxide and iron oxide, and the formula of the concave convex rod drier is made up of following component by mass percentage:Silica 50 70%, calcium oxide 5 25%, magnesia 3 15%, aluminum oxide 5 11%, iron oxide 0.2 0.5%, the formula of the antirust agent is made up of following component by mass percentage:13~55% magnesia, 9~24% attapulgite, 12~35% iron powder and 0.3~12% carbon dust, the invention is refined and formed using concave convex rod drier and antirust agent mixing, the hygroscopicity of performance and drier with gasified rust-proofing, common dessicant is overcome there was only dry function.
Description
Technical field
The invention belongs to drier technical field, more particularly to a kind of concave convex rod antirust drier.
Background technology
Drier is the most frequently used material of industrial and civilian damp-prrof packing, and existing drier commodity have(1)Silica-gel desiccant:
Main component is silica, and granular or pearl is process by purification by natural minerals.(2)Ore deposit drier living:Outward appearance shape
Shape is grey bead, and adds calcium chloride in clay to improve moisture absorption, moisture absorption in environment of the optimum below 50 DEG C.When
Temperature is higher than 50 DEG C, and " discharging water " degree of clay is just more than " water suction " degree.(3)Molecular sieve desiccant:It is it is artificial synthesized and
There is the desiccant product of stronger adsorptivity to hydrone.The pore size of molecular sieve can be controlled by the difference of processing technology,
Except adsorbing aqueous vapor, it can also adsorb other gases.But hydroscopicity is low, environmental protection is poor(Non-degradable).(4)Montmorillonite is dried
Agent:Also known as bentonite, amargosite, heated drying, the clay crushed are mainly characterized by nontoxic, degradable, but moisture pick-up properties is low
In silica-gel desiccant.(5)Fiber desiccant:First fiber desiccant that weighs be it is exquisite through special process by pure natural plant fiber and
Into although Product Safety is high, processed complex cost is higher.As Chinese invention patent 03116717.9 discloses a kind of drying
Agent its using clay as primary raw material, it is 10-50%, attapulgite 90-50%, except main body that drier main body, which contains calcium-base bentonite,
In addition, also containing polyvinyl alcohol 0.2-0.6%, polyacrylamide 0.6-0.2%, calcium chloride 10-30%.Chinese invention patent Shen
92108509.5 a kind of efficient drying agent and preparation method thereof please be disclosed, belong to the solid absorbent of dry gas, it is with swollen
Swollen perlite is carrier, is combined with magnesium perchlorate and can add metallo-chelate as colored indicator, perlite, magnesium perchlorate
Weight ratio with metallo-chelate is 1: 1: 0.001 to 1: 5: 0.05, is made by thermal dehydration in mixing and normal pressure and vacuum
.
But the problem of generally existing hydroscopicity is relatively low in now widely used drier, such as silica gel, montmorillonite, calcium oxide
Hydroscopicity below 40%, added in montmorillonite, concave convex rod a certain amount of calcium chloride hydroscopicity also only 100% with
Under.Although it can reach 100% or so in fiber desiccant hydroscopicity, cost is higher.In recent years, with science and technology
Fast development, it is more and more high to the performance requirement of metal spare and accessory parts mineral agent, match somebody with somebody in the market for metal zero
There is the shortcomings that hygroscopicity is poor, and drying property is bad in the mineral agent of part, cause the easy burn into of metal spare and accessory parts to get rusty,
The market demand can not be met.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of concave convex rod antirust proposed is dried
Agent.
To achieve the above object, the present invention provides following technical scheme:
A kind of concave convex rod antirust drier, the concave convex rod antirust drier is made up of antirust agent and concave convex rod drier, described
The proportion of antirust agent is 5-30%, and the concave convex rod drier is by silica, calcium oxide, magnesia, aluminum oxide and iron oxide group
Into the formula of the concave convex rod drier is made up of following component by mass percentage:Silica 50-70%, calcium oxide 5-25%,
Magnesia 3-15%, aluminum oxide 5-11%, iron oxide 0.2-0.5%, the formula of the antirust agent is by mass percentage by following component
Composition:13~55% magnesia, 9~24% attapulgite, 12~35% iron powder and 0.3~12% carbon dust.
Preferably, the preparation method of the concave convex rod drier is as follows:By the silica mixed, calcium oxide, magnesia,
Aluminum oxide and iron oxide, which are placed in comminutor, to be granulated, and the particle after granulation is placed in spheric granules input roaster and roasted
Burn, the temperature control baked and banked up with earth bakes and banks up with earth time control in 3-6 hours at 180-240 DEG C.
Preferably, the dried concave convex rod drier is sieved, by the size controlling of particle in 1.0-2.5 millis
Rice.
Preferably, the preparation method of the antirust agent is as follows:Magnesia, attapulgite, iron powder and carbon dust are proportionally mixed
Close and crush, calcine 3 hours in the environment of 600 DEG C, be granulated after taking-up, particle diameter is 1.0-2.5 millimeters.
Preferably, attapulgite weathering 2 months under natural environment.
Preferably, the concave convex rod drier and antirust agent are carried out hybrid packed.
The technique effect and advantage of the present invention:A kind of concave convex rod antirust drier provided by the invention, with conventional art phase
Than the present invention is refined and formed using concave convex rod drier and antirust agent mixing, performance and drier with gasified rust-proofing
Hygroscopicity, common dessicant is overcome there was only dry function, antirust agent can suppress the gas of metal erosion that can volatilize,
Metal surface forms layer protecting film, blocks metal surface contact with water and oxygen, suppresses the electrochemical reaction of metal erosion,
So as to reach antirust purpose.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.Based on the embodiment in the present invention, those of ordinary skill in the art are not before creative work is made
The every other embodiment obtained is put, belongs to the scope of protection of the invention.
Embodiment 1
A kind of concave convex rod antirust drier, the concave convex rod antirust drier is made up of antirust agent and concave convex rod drier, described
The proportion of antirust agent is 5%, and the concave convex rod drier is made up of silica, calcium oxide, magnesia, aluminum oxide and iron oxide,
The formula of the concave convex rod drier is made up of following component by mass percentage:Silica 65.63%, calcium oxide 18.83%, oxygen
Change magnesium 6.30%, aluminum oxide 8.75%, iron oxide 0.49%, the formula of the antirust agent is made up of following component by mass percentage:
40% magnesia, 25% attapulgite, 25% iron powder and 10% carbon dust.
Specifically, the preparation method of the concave convex rod drier is as follows:By the silica mixed, calcium oxide, magnesia,
Aluminum oxide and iron oxide, which are placed in comminutor, to be granulated, and the particle after granulation is placed in spheric granules input roaster and roasted
Burn, the temperature control baked and banked up with earth bakes and banks up with earth time control at 3 hours at 180 DEG C.
Specifically, the dried concave convex rod drier is sieved, by the size controlling of particle in 1.0-2.5 millis
Rice.
Specifically, the preparation method of the antirust agent is as follows:Magnesia, attapulgite, iron powder and carbon dust are proportionally mixed
Close and crush, calcine 3 hours in the environment of 600 DEG C, be granulated after taking-up, particle diameter is 1.0-2.5 millimeters.
Specifically, attapulgite weathering 2 months under natural environment.
Specifically, the concave convex rod drier and antirust agent progress are hybrid packed.
Embodiment 2
A kind of concave convex rod antirust drier, the concave convex rod antirust drier is made up of antirust agent and concave convex rod drier, described
The proportion of antirust agent is 15%, and the concave convex rod drier is by silica, calcium oxide, magnesia, aluminum oxide and iron oxide group
Into the formula of the concave convex rod drier is made up of following component by mass percentage:Silica 50%, calcium oxide 25%, oxidation
Magnesium 15%, aluminum oxide 9.5%, iron oxide 0.5%, the formula of the antirust agent are made up of following component by mass percentage:55%
Magnesia, 20% attapulgite, 20% iron powder and 5% carbon dust.
Specifically, the preparation method of the concave convex rod drier is as follows:By the silica mixed, calcium oxide, magnesia,
Aluminum oxide and iron oxide, which are placed in comminutor, to be granulated, and the particle after granulation is placed in spheric granules input roaster and roasted
Burn, the temperature control baked and banked up with earth bakes and banks up with earth time control at 4 hours at 200 DEG C.
Specifically, the dried concave convex rod drier is sieved, by the size controlling of particle in 1.0-2.5 millis
Rice.
Specifically, the preparation method of the antirust agent is as follows:Magnesia, attapulgite, iron powder and carbon dust are proportionally mixed
Close and crush, calcine 3 hours in the environment of 600 DEG C, be granulated after taking-up, particle diameter is 1.0-2.5 millimeters.
Specifically, attapulgite weathering 2 months under natural environment.
Specifically, the concave convex rod drier and antirust agent progress are hybrid packed.
Embodiment 3
A kind of concave convex rod antirust drier, the concave convex rod antirust drier is made up of antirust agent and concave convex rod drier, described
The proportion of antirust agent is 30%, and the concave convex rod drier is by silica, calcium oxide, magnesia, aluminum oxide and iron oxide group
Into the formula of the concave convex rod drier is made up of following component by mass percentage:Silica 70%, calcium oxide 10%, oxidation
Magnesium 12%, aluminum oxide 7.8%, iron oxide 0.2%, the formula of the antirust agent are made up of following component by mass percentage:50%
Magnesia, 18% attapulgite, 22% iron powder and 10% carbon dust.
Specifically, the preparation method of the concave convex rod drier is as follows:By the silica mixed, calcium oxide, magnesia,
Aluminum oxide and iron oxide, which are placed in comminutor, to be granulated, and the particle after granulation is placed in spheric granules input roaster and roasted
Burn, the temperature control baked and banked up with earth bakes and banks up with earth time control at 6 hours at 240 DEG C.
Specifically, the dried concave convex rod drier is sieved, by the size controlling of particle in 1.0-2.5 millis
Rice.
Specifically, the preparation method of the antirust agent is as follows:Magnesia, attapulgite, iron powder and carbon dust are proportionally mixed
Close and crush, calcine 3 hours in the environment of 600 DEG C, be granulated after taking-up, particle diameter is 1.0-2.5 millimeters.
Specifically, attapulgite weathering 2 months under natural environment.
Specifically, the concave convex rod drier and antirust agent progress are hybrid packed.
Moisture absorption test test condition is carried out from concave convex rod antirust drier prepared by embodiment 1 and commercial silica gel drier
It is as follows for relative humidity 20%, relative humidity 50% and the test result of relative humidity 90%:
Drier species | Relative humidity 20% | Relative humidity 50% | Relative humidity 90% |
Silica-gel desiccant(Hydroscopicity %) | 9.0 | 25.0 | 35.3 |
Embodiment 1 prepares product(Hydroscopicity %) | 14.2 | 31.0 | 49.5 |
The present invention is refined and formed using concave convex rod drier and antirust agent mixing, performance and drier with gasified rust-proofing
Hygroscopicity, common dessicant is overcome there was only dry function, antirust agent can suppress the gas of metal erosion that can volatilize,
Metal surface forms layer protecting film, blocks metal surface contact with water and oxygen, suppresses the electrochemical reaction of metal erosion,
So as to reach antirust purpose.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention,
Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used
To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic,
Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's
Within protection domain.
Claims (6)
- A kind of 1. concave convex rod antirust drier, it is characterised in that:The concave convex rod antirust drier is done by antirust agent and concave convex rod Drying prescription forms, and the proportion of the antirust agent is 5-30%, and the concave convex rod drier is by silica, calcium oxide, magnesia, oxygen Change aluminium and iron oxide composition, the formula of the concave convex rod drier is made up of following component by mass percentage:Silica 50- 70%th, calcium oxide 5-25%, magnesia 3-15%, aluminum oxide 5-11%, iron oxide 0.2-0.5%, the formula of the antirust agent press quality Percentage is made up of following component:13~55% magnesia, 9~24% attapulgite, 12~35% iron powder and 0.3~12% Carbon dust.
- A kind of 2. concave convex rod antirust drier according to claim 1, it is characterised in that:The preparation of the concave convex rod drier Method is as follows:The silica mixed, calcium oxide, magnesia, aluminum oxide and iron oxide are placed in comminutor and are granulated, will be made Particle after grain is placed in spheric granules input roaster and is calcined, and the temperature control baked and banked up with earth is at 180-240 DEG C, when baking and banking up with earth Between control in 3-6 hours.
- A kind of 3. concave convex rod antirust drier according to claim 2, it is characterised in that:The dried concave convex rod is done Drying prescription is sieved, by the size controlling of particle in 1.0-2.5 millimeters.
- A kind of 4. concave convex rod antirust drier according to claim 4, it is characterised in that:The preparation method of the antirust agent is such as Under:By magnesia, attapulgite, iron powder and carbon dust proportionally co-grinding, calcine 3 hours, take out in the environment of 600 DEG C After be granulated, particle diameter is 1.0-2.5 millimeters.
- A kind of 5. concave convex rod antirust drier according to claim 1 or 4, it is characterised in that:The attapulgite is certainly Weathering 2 months under right environment.
- A kind of 6. concave convex rod antirust drier according to claim 1, it is characterised in that:The concave convex rod drier and anti- Agent of becoming rusty carries out hybrid packed.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110681374A (en) * | 2018-07-05 | 2020-01-14 | 金昌红泉膨润土有限责任公司 | Attapulgite clay solid acidifying agent |
CN112619204A (en) * | 2020-12-31 | 2021-04-09 | 浙江锦华新材料股份有限公司 | Deep dehydration drying agent and application thereof in synthesis of methyl tributyl ketoxime silane |
CN114632500A (en) * | 2022-03-31 | 2022-06-17 | 杭州干将实业有限公司 | Drying agent for precise optical instrument and preparation method thereof |
-
2017
- 2017-11-10 CN CN201711102681.2A patent/CN107583611A/en active Pending
Non-Patent Citations (1)
Title |
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化学工业部科学技术情报研究所编辑: "《世界精细化工手册》", 31 December 1982 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110681374A (en) * | 2018-07-05 | 2020-01-14 | 金昌红泉膨润土有限责任公司 | Attapulgite clay solid acidifying agent |
CN112619204A (en) * | 2020-12-31 | 2021-04-09 | 浙江锦华新材料股份有限公司 | Deep dehydration drying agent and application thereof in synthesis of methyl tributyl ketoxime silane |
CN114632500A (en) * | 2022-03-31 | 2022-06-17 | 杭州干将实业有限公司 | Drying agent for precise optical instrument and preparation method thereof |
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Application publication date: 20180116 |