CN107574671A - A kind of compound enzyme wool fiber cleaner - Google Patents
A kind of compound enzyme wool fiber cleaner Download PDFInfo
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- CN107574671A CN107574671A CN201710589459.3A CN201710589459A CN107574671A CN 107574671 A CN107574671 A CN 107574671A CN 201710589459 A CN201710589459 A CN 201710589459A CN 107574671 A CN107574671 A CN 107574671A
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Abstract
The invention discloses a kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:Component A:100 parts of complex enzyme, 10 15 parts of stabilizer, 27 parts of bleeding agent, 59 parts of chelating agent, 20 30 parts of coconut oleoyl monoethanolamine, 10 18 parts of fatty alcohol sulfate;Component B:40 60 parts of aspergillus pepsin, 30 50 parts of cutinase, 10 17 parts of phytic acid, 10 15 parts of stabilizer.Present invention also offers the application method of the compound enzyme wool fiber cleaner.The cleaner can effectively remove lanolin and smoits in raw wool, and dust removal rate is high, and effect is good.Also, the compound enzyme wool fiber cleaner has good stability, service life is longer.
Description
Technical field
The present invention relates to textile auxiliary field, more particularly to a kind of compound enzyme wool fiber cleaner.
Background technology
Sheep is during production, miscellaneous containing substantial amounts of mineral and vegetalitas in wool due to the relation of feeding environment
Matter, such as sandy soil, herbaceous stem etc.;In addition, can also have sweat, grease, scurf or excrement that sheep drains in growth course on wool
Deng.Therefore, raw wool needs to carry out scouring of wool processing before textile process is carried out, and removes impurity, the quality of scouring of wool quality is to rear
Continuous processing has a significant impact.Scoured wool surface residual pollutant load can influence scoured wool whiteness, dyeability and drawing-off and spin
Performance etc.;Scoured wool shatter value and injury tolerance can influence combing, spinning and weaving performance of scoured wool etc..
Crucial step is to remove lanolin and smoits during scouring of wool, and lanolin is adhered to above after removing
Sandy soil dirt can also depart from from wool, but lanolin is relatively difficult to be saponified.The method of conventional removal lanolin is main
It is the surface tension that water is reduced using surfactant detergent, makes wool easily wetted, surfactant molecule oozes afterwards
Weaken the adhesion of lanolin schmutzband and wool fibre into the gap of wool dirt thoroughly, and lanolin dirt damage layer is disperseed
Into the particulate of colloid size, greasy dirt impurity is set to be peeled off from wool fibre under heat and mechanism.But this method is easily damaged
Easy care, water consumption is larger to easily cause pollution, and cleaning effect is limited.
Smoits in wool are how tighter with wool entanglement, it is difficult to remove, do not done if smoits remove
Only it will be made troubles to many processes, such as yarn evenness is caused during spinning, broken end increase;Color is not inhaled during dyeing, is made
Finished appearance quality is influenceed into dye defect.Therefore smoits must remove totally as far as possible in preliminary working.Production at present
In go vegetable faults typically to use carbonizatin method, using inorganic acid by smoits formed fragility hydrocellulose, through pulverizing
Remove.Larger injury can be caused to wool fiber during carbonization treatment.
Enzyme is a kind of biocatalyst, and main component is protein, can effectively catalytic chemistry reaction process.Enzyme is seemingly
Other catalyst participate in the pilot process of reaction, but do not consume finally, and referred to as " enzymatic is anti-for the process of this usual catalytic reaction
Should " process.The catalytic property of enzyme is special, there is the advantages of other catalyst are incomparable.The main component of wool fiber is egg
White matter, the main component of vegetable fault is cellulose, and the main component of lanolin is fat, therefore can utilize enzymic catalytic reaction
The characteristics of high specificity, targetedly remove lanolin and smoits.Moreover the dosage of very little is used in enzymatic reaction
Catalysis efficiency with regard to protrusion can be played, while enzyme is as a kind of biological agent, safe and non-toxic evil, energy complete biodegradable, green
Environmental protection.
Chinese patent CN201611206589.6 discloses a kind of raw wool natural impurity remover, is related to wool processing
Technical field, it is made up of the raw material of following parts by weight:Pre-gelatinized starch 5-10 parts, modified polyethylene glycol oxide 2-4 parts, β-ring-type
Dextrin 2-4 parts, PDDA 1-2 parts, lanonol 1-2 parts, sodium gluconate 1-2 parts, coconut powder 0.5-1
Part, polyvinyl alcohol resin 0.5-1 parts, saleratus power 0.5-1 parts, sodium dihydrogen phosphate 0.3-0.5 parts, N hydroxymethyl acrylamide
0.1-0.3 parts, water 100-150 parts.The made remover of the invention can effectively remove natural impurity, and will not be to raw wool
Wool fiber causes to damage, and ensures the pliability and fluffy degree of raw wool.
The content of the invention
It is an object of the invention to provide a kind of compound enzyme wool fiber cleaner, the cleaner can effectively remove sheep
Lanolin and smoits in hair raw wool, dust removal rate is high, and effect is good.Also, the compound enzyme wool fiber removal of impurities
Agent has good stability, and service life is longer.
It is a further object of the present invention to provide the application method of the compound enzyme wool fiber cleaner.
To achieve the above object, the present invention uses following technical scheme:
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, stabilizer 10-15 parts, bleeding agent 2-7 parts, chelating agent 5-9 parts, coconut oleoyl list second
Hydramine 20-30 parts, fatty alcohol sulfate 10-18 parts;
Component B:Aspergillus pepsin 40-60 parts, cutinase 30-50 parts, phytic acid 10-17 parts, stabilizer 10-15 parts;
The complex enzyme includes following components:
Cellulase, pectase, lignin-degrading enzymes, lipase, laccase;
The stabilizer includes following components:
Sodium chloride, magnesium chloride, glycerine, sorbierite, chitosan.
Preferably, the complex enzyme includes the cellulase that enzyme activity is 300U/mL-4000U/mL, and enzyme activity is
500U/mL-20000U/mL pectase, enzyme activity are 600U/mL-10000U/mL lignin-degrading enzymes, and enzyme activity is
2000U/mL-30000U/mL lipase, enzyme activity are 3000U/mL-20000U/mL laccase.
Preferably, the usage amount of the stabilizer each component is, in terms of parts by weight:
Sodium chloride 15-23 parts, magnesium chloride 18-27 parts, glycerine 15-30 parts, sorbierite 5-9 parts, chitosan 7-9 parts.
Preferably, aspergillic acid proteinase activity power is 20U/mL-300U/mL in the component B, and cutinase enzyme activity is
400U/mL-2000U/mL。
Preferably, the bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, regulation pH is 7-7.5, and regulation temperature is 35-
45 DEG C, it will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 1-2h, rinsed, dried with water afterwards;
(2) compound enzyme wool fiber cleaner B component is diluted with water, regulation pH is 7-7.5, and regulation temperature is 35-
45 DEG C, the wool fiber that step (1) treats is soaked in wherein, soaks 45-60min, taking-up afterwards is rinsed with water, is dried.
Preferably, the dilution ratio of component A is that the volume ratio of component A and water is 1 in the step (1):100.
Preferably, the dilution ratio of B component is that the volume ratio of B component and water is 1 in the step (2):100.
The invention has the advantages that the application utilizes cellulase, pectase and lignin-degrading enzymes decompose sheep
Smoits in hair, make smoits be decomposed, are easy to come off from raw wool, make smoits and wool
Tubercle is separated, and wool fiber can't be damaged.Using lipase, laccase decomposes the grease on wool, allow its with
Chelating agent in water combines, so as to be peeled off from wool.Aspergillus pepsin, cutinase can remove the protein of wool surfaces
Class impurity, the color brightness of wool fiber is improved, while the fluffy degree of wool fiber can be improved.Due to the master of wool fiber
It is protein to want composition, is easily damaged by protease, and the application utilizes phytic acid complexing aspergillus pepsin, cutinase so that enzyme
Vigor is restricted, so as to protect wool fiber not to be damaged.
Embodiment
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
The present invention is released, any restriction will not be formed to the present invention.
Embodiment 1
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, 10 parts of stabilizer, 2 parts of bleeding agent, 5 parts of chelating agent, coconut oleoyl monoethanolamine 20
Part, 10 parts of fatty alcohol sulfate;
Component B:40 parts of aspergillus pepsin, 30 parts of cutinase, 10 parts of phytic acid, 10 parts of stabilizer;Aspergillus acid egg in component B
White enzyme enzyme activity is 20U/mL, and cutinase enzyme activity is 400U/mL.
Complex enzyme include enzyme activity be 300U/mL cellulase, enzyme activity be 500U/mL pectase, enzyme activity
For 600U/mL lignin-degrading enzymes, enzyme activity is 2000U/mL lipase, and enzyme activity is 3000U/mL laccase.
The usage amount of stabilizer each component is, in terms of parts by weight:15 parts of sodium chloride, 18 parts of magnesium chloride, 15 parts of glycerine, mountain
5 parts of pears alcohol, 7 parts of chitosan.
Bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, the volume ratio of component A and water is 1:100, adjust
It is 7 to save pH, and regulation temperature is 35 DEG C, will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 1h, afterwards
Rinsed, dried with water;
(2) compound enzyme wool fiber cleaner B component is diluted with water, the volume ratio of B component and water is 1:100, adjust
It is 7 to save pH, and regulation temperature is 35 DEG C, and the wool fiber that step (1) treats is soaked in wherein, 45min is soaked, takes out afterwards
Rinsed, dried with water.
Wool fiber is less than 99%, and the fluffy softness of wool fiber through handling rear impurity content.
Embodiment 2
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, 15 parts of stabilizer, 7 parts of bleeding agent, 9 parts of chelating agent, coconut oleoyl monoethanolamine 30
Part, 18 parts of fatty alcohol sulfate;
Component B:60 parts of aspergillus pepsin, 50 parts of cutinase, 17 parts of phytic acid, 15 parts of stabilizer;Aspergillus acid egg in component B
White enzyme enzyme activity is 300U/mL, and cutinase enzyme activity is 2000U/mL.
Complex enzyme include enzyme activity be 4000U/mL cellulase, enzyme activity be 20000U/mL pectase, enzyme activity
Power is 10000U/mL lignin-degrading enzymes, and enzyme activity is 30000U/mL lipase, and enzyme activity is 20000U/mL paint
Enzyme.
The usage amount of stabilizer each component is, in terms of parts by weight:23 parts of sodium chloride, 27 parts of magnesium chloride, 30 parts of glycerine, mountain
9 parts of pears alcohol, 9 parts of chitosan.
Bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, the volume ratio of component A and water is 1:100, adjust
It is 7.5 to save pH, and regulation temperature is 45 DEG C, will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 2h, it
Rinsed, dried with water afterwards;
(2) compound enzyme wool fiber cleaner B component is diluted with water, the volume ratio of B component and water is 1:100, adjust
It is 7.5 to save pH, and regulation temperature is 45 DEG C, and the wool fiber that step (1) treats is soaked in wherein, soaks 60min, Zhi Houqu
Go out and rinsed with water, dried.
Wool fiber is less than 99%, and the fluffy softness of wool fiber through handling rear impurity content.
Embodiment 3
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, 10 parts of stabilizer, 7 parts of bleeding agent, 5 parts of chelating agent, coconut oleoyl monoethanolamine 30
Part, 10 parts of fatty alcohol sulfate;
Component B:60 parts of aspergillus pepsin, 30 parts of cutinase, 17 parts of phytic acid, 10 parts of stabilizer;Aspergillus acid egg in component B
White enzyme enzyme activity is 80U/mL, and cutinase enzyme activity is 600U/mL.
Complex enzyme include enzyme activity be 500U/mL cellulase, enzyme activity be 1000U/mL pectase, enzyme activity
For 2000U/mL lignin-degrading enzymes, enzyme activity is 5000U/mL lipase, and enzyme activity is 6000U/mL laccase.
The usage amount of stabilizer each component is, in terms of parts by weight:15 parts of sodium chloride, 27 parts of magnesium chloride, 15 parts of glycerine, mountain
9 parts of pears alcohol, 7 parts of chitosan.
Bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, the volume ratio of component A and water is 1:100, adjust
It is 7 to save pH, and regulation temperature is 45 DEG C, will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 2h, afterwards
Rinsed, dried with water;
(2) compound enzyme wool fiber cleaner B component is diluted with water, the volume ratio of B component and water is 1:100, adjust
It is 7 to save pH, and regulation temperature is 45 DEG C, and the wool fiber that step (1) treats is soaked in wherein, 60min is soaked, takes out afterwards
Rinsed, dried with water.
Wool fiber is less than 99%, and the fluffy softness of wool fiber through handling rear impurity content.
Embodiment 4
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, 15 parts of stabilizer, 2 parts of bleeding agent, 9 parts of chelating agent, coconut oleoyl monoethanolamine 20
Part, 18 parts of fatty alcohol sulfate;
Component B:40 parts of aspergillus pepsin, 50 parts of cutinase, 10 parts of phytic acid, 15 parts of stabilizer;Aspergillus acid egg in component B
White enzyme enzyme activity is 100U/mL, and cutinase enzyme activity is 1000U/mL.
Complex enzyme include enzyme activity be 2000U/mL cellulase, enzyme activity be 5000U/mL pectase, enzyme activity
Power is 3000U/mL lignin-degrading enzymes, and enzyme activity is 10000U/mL lipase, and enzyme activity is 10000U/mL laccase.
The usage amount of stabilizer each component is, in terms of parts by weight:23 parts of sodium chloride, 18 parts of magnesium chloride, 30 parts of glycerine, mountain
5 parts of pears alcohol, 9 parts of chitosan.
Bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, the volume ratio of component A and water is 1:100, adjust
It is 7.5 to save pH, and regulation temperature is 35 DEG C, will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 2h, it
Rinsed, dried with water afterwards;
(2) compound enzyme wool fiber cleaner B component is diluted with water, the volume ratio of B component and water is 1:100, adjust
It is 7.5 to save pH, and regulation temperature is 35 DEG C, and the wool fiber that step (1) treats is soaked in wherein, soaks 60min, Zhi Houqu
Go out and rinsed with water, dried.
Wool fiber is less than 99%, and the fluffy softness of wool fiber through handling rear impurity content.
Embodiment 5
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, 12 parts of stabilizer, 4 parts of bleeding agent, 6 parts of chelating agent, coconut oleoyl monoethanolamine 23
Part, 13 parts of fatty alcohol sulfate;
Component B:48 parts of aspergillus pepsin, 45 parts of cutinase, 12 parts of phytic acid, 12 parts of stabilizer;Aspergillus acid egg in component B
White enzyme enzyme activity is 100U/mL, and cutinase enzyme activity is 2000U/mL.
Complex enzyme include enzyme activity be 3000U/mL cellulase, enzyme activity be 6000U/mL pectase, enzyme activity
Power is 8000U/mL lignin-degrading enzymes, and enzyme activity is 10000U/mL lipase, and enzyme activity is 10000U/mL laccase.
The usage amount of stabilizer each component is, in terms of parts by weight:17 parts of sodium chloride, 22 parts of magnesium chloride, 23 parts of glycerine, mountain
6 parts of pears alcohol, 8 parts of chitosan.
Bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, the volume ratio of component A and water is 1:100, adjust
It is 7 to save pH, and regulation temperature is 35 DEG C, will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 1-2h, it
Rinsed, dried with water afterwards;
(2) compound enzyme wool fiber cleaner B component is diluted with water, the volume ratio of B component and water is 1:100, adjust
It is 7.5 to save pH, and regulation temperature is 45 DEG C, and the wool fiber that step (1) treats is soaked in wherein, soaks 45-60min, it
Taking-up is rinsed with water afterwards, drying.
Wool fiber is less than 99%, and the fluffy softness of wool fiber through handling rear impurity content.
Embodiment 6
A kind of compound enzyme wool fiber cleaner, in terms of volume parts, including following components:
Component A:100 parts of complex enzyme, 14 parts of stabilizer, 5 parts of bleeding agent, 7 parts of chelating agent, coconut oleoyl monoethanolamine 28
Part, 16 parts of fatty alcohol sulfate;
Component B:55 parts of aspergillus pepsin, 38 parts of cutinase, 15 parts of phytic acid, 14 parts of stabilizer;Aspergillus acid egg in component B
White enzyme enzyme activity is 300U/mL, and cutinase enzyme activity is 1500U/mL.
Complex enzyme include enzyme activity be 2000U/mL cellulase, enzyme activity be 10000U/mL pectase, enzyme activity
Power is 2000U/mL lignin-degrading enzymes, and enzyme activity is 20000U/mL lipase, and enzyme activity is 8000U/mL laccase.
The usage amount of stabilizer each component is, in terms of parts by weight:20 parts of sodium chloride, 25 parts of magnesium chloride, 25 parts of glycerine, mountain
7 parts of pears alcohol, 8 parts of chitosan.
Bleeding agent is the mixture of fast penetrant T and peregal.
A kind of application method of compound enzyme wool fiber cleaner, is comprised the steps of:
(1) compound enzyme wool fiber cleaner component A is diluted with water, the volume ratio of component A and water is 1:100, adjust
It is 7.5 to save pH, and regulation temperature is 40 DEG C, will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 2h, it
Rinsed, dried with water afterwards;
(2) compound enzyme wool fiber cleaner B component is diluted with water, the volume ratio of B component and water is 1:100, adjust
It is 7 to save pH, and regulation temperature is 40 DEG C, and the wool fiber that step (1) treats is soaked in wherein, 45min is soaked, takes out afterwards
Rinsed, dried with water.
Wool fiber is less than 99%, and the fluffy softness of wool fiber through handling rear impurity content.
Claims (8)
- A kind of 1. compound enzyme wool fiber cleaner, it is characterised in that:In terms of volume parts, including following components:Component A:100 parts of complex enzyme, stabilizer 10-15 parts, bleeding agent 2-7 parts, chelating agent 5-9 parts, coconut oleoyl monoethanolamine 20-30 parts, fatty alcohol sulfate 10-18 parts;Component B:Aspergillus pepsin 40-60 parts, cutinase 30-50 parts, phytic acid 10-17 parts, stabilizer 10-15 parts;The complex enzyme includes following components:Cellulase, pectase, lignin-degrading enzymes, lipase, laccase;The stabilizer includes following components:Sodium chloride, magnesium chloride, glycerine, sorbierite, chitosan.
- 2. compound enzyme wool fiber cleaner according to claim 1, it is characterised in that:The complex enzyme includes enzyme Vigor is 300U/mL-4000U/mL cellulase, and enzyme activity is 500U/mL-20000U/mL pectase, and enzyme activity is 600U/mL-10000U/mL lignin-degrading enzymes, enzyme activity are 2000U/mL-30000U/mL lipase, and enzyme activity is 3000U/mL-20000U/mL laccase.
- 3. compound enzyme wool fiber cleaner according to claim 1, it is characterised in that:The stabilizer each component Usage amount is, in terms of parts by weight:Sodium chloride 15-23 parts, magnesium chloride 18-27 parts, glycerine 15-30 parts, sorbierite 5-9 parts, chitosan 7-9 parts.
- 4. compound enzyme wool fiber cleaner according to claim 1, it is characterised in that:Aspergillic acid in the component B Proteinase activity power is 20U/mL-300U/mL, and cutinase enzyme activity is 400U/mL-2000U/mL.
- 5. compound enzyme wool fiber cleaner according to claim 1, it is characterised in that:The bleeding agent is quickly to ooze Saturating agent T and peregal mixture.
- 6. the application method of the compound enzyme wool fiber cleaner according to claim any one of 1-5, it is characterised in that Comprise the steps of:(1) compound enzyme wool fiber cleaner component A being diluted with water, regulation pH is 7-7.5, and regulation temperature is 35-45 DEG C, It will be soaked in wherein with the flushed raw wool of clear water, and ultrasonication 1-2h, rinsed, dried with water afterwards;(2) compound enzyme wool fiber cleaner B component being diluted with water, regulation pH is 7-7.5, and regulation temperature is 35-45 DEG C, The wool fiber that step (1) treats is soaked in wherein, soaks 45-60min, taking-up afterwards is rinsed with water, is dried.
- 7. the application method of compound enzyme wool fiber cleaner according to claim 6, it is characterised in that:The step (1) dilution ratio of component A is that the volume ratio of component A and water is 1 in:100.
- 8. the application method of compound enzyme wool fiber cleaner according to claim 7, it is characterised in that:The step (2) dilution ratio of B component is that the volume ratio of B component and water is 1 in:100.
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CN201710589459.3A CN107574671A (en) | 2017-07-19 | 2017-07-19 | A kind of compound enzyme wool fiber cleaner |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112458548A (en) * | 2020-11-30 | 2021-03-09 | 江南大学 | Method for rapidly removing cashmere impurities by using complex enzyme |
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CN101805998A (en) * | 2010-03-22 | 2010-08-18 | 张茂明 | New complex biological enzyme wool detergent and preparation method thereof |
CN102965956A (en) * | 2012-10-19 | 2013-03-13 | 江南大学 | Wool worsted fabric compound enzyme padding-steaming stacking anti-felting finishing technology |
CN105567668A (en) * | 2016-02-15 | 2016-05-11 | 北京泛博科技有限责任公司 | Compound enzyme preparation for fur soaking and preparation method thereof |
CN106676883A (en) * | 2016-12-23 | 2017-05-17 | 五河县盛源畜牧养殖专业合作社 | Natural impurity remover for raw wool |
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2017
- 2017-07-19 CN CN201710589459.3A patent/CN107574671A/en active Pending
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CN101805998A (en) * | 2010-03-22 | 2010-08-18 | 张茂明 | New complex biological enzyme wool detergent and preparation method thereof |
CN102965956A (en) * | 2012-10-19 | 2013-03-13 | 江南大学 | Wool worsted fabric compound enzyme padding-steaming stacking anti-felting finishing technology |
CN105567668A (en) * | 2016-02-15 | 2016-05-11 | 北京泛博科技有限责任公司 | Compound enzyme preparation for fur soaking and preparation method thereof |
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