A kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line
Technical field
The present invention relates to cleaning agent field, in particular it relates to a kind of cleaning for the maintenance of high and low voltage electric distribution equipment on-line
Agent.
Background technology
The power equipment of longtime running, particularly, high and low voltage electric distribution equipment of on-line operation etc., in atmospheric environment by
The influence of the environmental factor such as industrial emissions, moisture, oxidation, corrosive gas and natural airborne dust in air, its surface can not
Avoid adhering to solid, liquids and gases filth particulate, and generally have certain electric conductivity and hygroscopicity.
In the case of dry weather, perhaps this kind equipment of these surfaces with dunghill remains to remain higher exhausted
Edge is horizontal.However, when running into the wet weathers such as mist, dew, drizzle, frost and ice-melt, snow melt, can be due to dirt in insulator surface
Dissolved salt in layer, acid-base class is soluble in water and forms conductive moisture film, thus leakage current can be made to be flowed through along the surface of equipment.
Because the factors such as the shape of various equipment, physical dimension influence, the current density at each position in its surface is different, and meeting exists
The bigger position of electric current is initially formed dry zone, and dry zone carries higher voltage, and when electric-field intensity is sufficiently large, electric current will
In the creeping discharge across dry section, local arc is produced.When dirty and dampness is more serious, local arc reaches or surpassed
Transcritical regime, electric arc will run through the two poles of the earth, and flashover, i.e. pollution flashover occurs, causes power outage.
Charging equipment surface is contaminated, and pollute equipment surface is wetted and voltage is that pollution flashover occurs three
Necessary condition, therefore, taken some countermeasures for any one factor, the purpose for preventing pollution flashover can be reached.
With the fast development of national economy, net capacity and specified defeated voltage class increase substantially, simultaneous
The development of industrial or agricultural, the environmental pollution has become increasingly serious of some areas, harm and warp caused by the pollution flashover accident of charging equipment
Ji loses also getting worse.
The major measure that power department is taken for many years has:Antifouling flush paint is coated, such as:RTV coating, reinforced insulation, stop
Electricity cleaning etc., but these method efficiency are low, cleaning performance is poor, easily cause human accident etc..
Powered cleaning can effectively remove the filth of insulator surface deep layer, the generation of high-tension insulator accident be eliminated, however, mesh
The preceding insulation cleaning agent used on the market, on the one hand the cleaning performance due to cleaning agent in itself is bad, causes substantial amounts of solvent wave
Take, greatly improve cleaning cost.On the other hand, the cleaning agent developed at present is often to some plastics components, silicon rubber member
The materials such as device have certain corrosivity.Be additionally, since such cleaning agent often volatilize it is relatively slow, and cleaning agent be sprayed at it is cleaned
, certainly will be to being cleaned the component particularly plastics and silicon rubber member device of equipment if volatility is not strong in equipment or on component
Part has some corrosion, and the removing such as charged ion on the component of cleaned equipment, acid, alkali, salt is not thorough, influences clear
Wash quality.
The content of the invention
It is contemplated that overcome drawbacks described above, there is provided one kind can carry out cleaning decontamination to high and low voltage electric distribution equipment, prevent
The erosion of pollutant, and volatile performance is good, noresidue, colorless and odorless, do not burn, be non-conductive, be corrosion-free, nonhazardous, without ODS
Etc. the cleaning agent for being used for the maintenance of high and low voltage electric distribution equipment on-line of characteristic.
A kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, it is characterised in that:Include
Mass percent concentration is 1-50% polyaminoacid polyethylene glycol polyester.
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., it is prepared by the material of following mass fraction:
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., above-mentioned polyaminoacid polyethylene glycol polyester is mixed with by polyaminoacid, polyethylene glycol and polyacid forms;
Wherein, the mass ratio of above-mentioned polyaminoacid, polyethylene glycol and polyacid is:1:0.8-0.9:1.1-1.5.
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., the preparation method of above-mentioned polyaminoacid polyethylene glycol polyester is as follows:
Step 1: in the case where protecting gas shielded, molecular sieve (can be not added with, it is all raw materials such as to add its addition
Gross mass 2-10%), the polyethylene glycol of polyacid and half amount put into successively in autoclave, stirred at a temperature of 40-65 DEG C
20-30 minutes;
Step 2: add remaining polyethylene glycol and polyaminoacid, meanwhile, add the concentrated sulfuric acid of catalytic amount;
Step 3: after the addition of all raw materials, 80-105 DEG C is warming up to, reaction under high pressure 1-5 hours;
Step 4: after high temperature filters off insoluble matter, it is polyaminoacid polyethylene glycol polyester to be cooled to room temperature.
The polyaminoacid polyethylene glycol polyester actual any two or three kinds between polyaminoacid, polyethylene glycol and polyacid
The mixture reacted between compound.
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., one or more of the above-mentioned polyaminoacid in polylysine, poly-aspartate, poly-aspartic-acid;
Above-mentioned polyethylene glycol is selected from the polyethylene glycol that molecular weight is not less than 100;Preferably molecular weight is in 100-1000 scopes
Interior polyethylene glycol;
Above-mentioned polyacid is selected from binary or ternary acid of the carbon number no more than 16.Preferably ethanedioic acid, the third three acid, 12
Alkyl acid, tartaric acid, malic acid, citric acid etc..
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., the one kind of above-mentioned halogenated hydrocarbons in saturation of the carbon number no more than 10 or undersaturated halogenated aliphatic hydrocarbon
It is or several.
It is preferred that such as:Dichloro pentafluoropropane, trichloroethanes, dichloro one fluoroethane, trichloro ethylene, tetrachloro-ethylene, dichloromethane
Deng.
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., above-mentioned alcohols is selected from boiling point less than 120 DEG C, monohydric alcohol of the carbon number no more than 5, one kind in dihydric alcohol
It is or several.
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., the one kind or several of above-mentioned aliphatic hydrocarbon in saturation of the carbon number no more than 8 or undersaturated aliphatic hydrocarbon
Kind.
Further, a kind of cleaning agent for the maintenance of high and low voltage electric distribution equipment on-line provided by the invention, also with this
The characteristics of sample:I.e., one in dimethyl silicone polymer of viscosity of the above-mentioned dimethyl silicone polymer at 25 DEG C less than 5000
Kind is several.
In addition, present invention also offers it is above-mentioned for high and low voltage electric distribution equipment on-line maintenance cleaning agent preparation method,
It is characterized in that:
Reagent one is formed after halogenated hydrocarbons, alcohols and dimethyl silicone polymer are well mixed;
Reagent two is formed after aliphatic hydrocarbon, polyaminoacid polyethylene glycol polyester are well mixed;
At a temperature of 20-60 DEG C, reagent two is slowly mixed into reagent one and forms transparent mixed solution, is as cleaned
Agent.
The effect of the present invention and effect:
In the present invention, cleaning decontamination can be carried out to high and low voltage electric distribution equipment by having manufactured one kind, prevent invading for pollutant
Erosion, and volatile performance is good, noresidue, colorless and odorless, do not burn, be non-conductive, be corrosion-free, nonhazardous, the use without characteristics such as ODS
In the cleaning agent of high and low voltage electric distribution equipment on-line maintenance.
In the present invention, the polyaminoacid polyethylene glycol polyester of selection, the characteristics of due to its structure, there is polyaminoacid
Amide structure, polyethylene glycol polyether structure and its between each other or with the reacted ester chain structure of polyacid, make the chemical combination
Thing has polyfunctional group and function.And the component has biodegradable characteristic.
Due to, the presence of such functional group, after the compound is applied in system of the present invention, can improve between multicomponent
Intermiscibility.Based on a variety of groups on the polyaminoacid polyethylene glycol polyester Long carbon chain, can be risen in the formula group of the present invention
, by the weak bond effect such as hydrogen bond, covalent bond to the effect of connection, i.e., using polyaminoacid polyethylene glycol polyester as tie, improve each
Blending property between component.In addition, between the factor of surface-active is series at into each component, the cleaning effect of each component is improved
Rate, our experiments show that, cleaning agent of the invention can realize efficient cleaning capacity, on the premise of identical cleaning performance is obtained,
Its usage amount is the 10-20% of traditional on-line cleaning agent.
Further, since wire side effect caused by the linkage effect, after completing to clean, i.e., adsorbs or has wrapped up pollutant
Cleaning fluid complete dirt-removing functions after, can also charging equipment surface formed one layer of cuticula, come effectively protect pollutant setting
Hoarding and being formed again for standby surface, our experiments show that, using the charging equipment after the cleaning agent, it reaches 5% surface area quilt
The time of pollution is more than 5 times of commercially available cleaning agent.
Embodiment
Embodiment one, the cleaning agent 1# for the maintenance of high and low voltage electric distribution equipment on-line
It is prepared by the material of following mass fraction:
Trichloropropane |
63 parts; |
Ethanol |
21 parts; |
N-hexane |
17 parts; |
PMX-200 |
2 parts; |
Polyaminoacid polyethylene glycol polyester 1# |
5 parts. |
Polyaminoacid polyethylene glycol polyester 1# preparation method is as follows:
Step 1: in the case where protecting gas shielded, by 200g molecular sieves, 500g ethanedioic acids and 500g polyethylene glycol 400s
Put into successively in autoclave, stir at a temperature of 65 DEG C 20 minutes and be well mixed to all raw materials;
Step 2: adding 500g polyethylene glycol and 600g poly-aspartates, it is slowly added dropwise simultaneously, 45g 98% dense sulphur
Acid;
Step 3: after the addition of all raw materials, every 5 DEG C/min speed is warming up to 85 DEG C, reaction under high pressure 1.5 is small
When;
Step 4: after high temperature filters off insoluble matter, it is polyaminoacid polyethylene glycol polyester 1# to be cooled to room temperature.
Preparation method for the cleaning agent 1# of high and low voltage electric distribution equipment on-line maintenance:
Reagent A is formed after trichloropropane, ethanol and PMX-200 are well mixed in the ratio in form;By n-hexane, gather
Amino acid polyethylene glycol polyester 1# forms reagent B after being well mixed in the ratio in form;
At a temperature of room temperature, reagent B is slowly mixed into reagent A, using just can quickly make system be changed into transparent phase as
Good adding speed, form transparent mixed solution, as the cleaning agent 1# for the maintenance of high and low voltage electric distribution equipment on-line.
Usage amount:
Every square metre of dosage is the above-mentioned cleaning agent 1# for the maintenance of high and low voltage electric distribution equipment on-line of 0.09-0.11kg.
Volatile performance and cleaning efficiency:
The volatilization mass percent of every 60 seconds is 92%, to the cleaning rate of pollutant up to more than 98%.
Embodiment two, the cleaning agent 2# for the maintenance of high and low voltage electric distribution equipment on-line
It is prepared by the material of following mass fraction:
Tetrachloro-ethylene |
55 parts; |
Ethanol |
11 parts; |
Dodecane |
21 parts; |
PMX-1000 |
6 parts; |
Polyaminoacid polyethylene glycol polyester 2# |
2 parts. |
Polyaminoacid polyethylene glycol polyester 1# preparation method is as follows:
Step 1: in the case where protecting gas shielded, 100g tartaric acid and 40g polyethylene glycol 200s are put into high pressure successively
In kettle, stir at a temperature of 80 DEG C 20 minutes and be well mixed to all raw materials;
Step 2: adding 40g polyethylene glycol and 100g polylysines, it is slowly added dropwise simultaneously, 5g 98% concentrated sulfuric acid;
Step 3: after the addition of all raw materials, every 5 DEG C/min speed is warming up to 105 DEG C, reaction under high pressure 3 hours;
Step 4: after high temperature filters off insoluble matter, it is polyaminoacid polyethylene glycol polyester 2# to be cooled to room temperature.
Preparation method for the cleaning agent 2# of high and low voltage electric distribution equipment on-line maintenance:
Reagent A is formed after tetrachloro-ethylene, ethanol and PMX-1000 are well mixed in the ratio in form;By dodecane,
Polyaminoacid polyethylene glycol polyester 2# forms reagent B after being well mixed in the ratio in form;
At a temperature of 60 DEG C, reagent B is slowly mixed into reagent A, using just can quickly make system be changed into transparent phase as
Good adding speed, form transparent mixed solution, as the cleaning agent 2# for the maintenance of high and low voltage electric distribution equipment on-line.
Usage amount:
Every square metre of dosage is the above-mentioned cleaning agent 2# for the maintenance of high and low voltage electric distribution equipment on-line of 0.11-0.13kg.
Volatile performance and cleaning efficiency:
The volatilization mass percent of every 60 seconds is 93%, to the cleaning rate of pollutant up to more than 98%.
Embodiment three, the cleaning agent 3# for the maintenance of high and low voltage electric distribution equipment on-line
It is prepared by the material of following mass fraction:
Tetrachloro-ethylene |
35 parts; |
Dichloro pentafluoropropane |
35 parts |
Propane diols |
16 parts; |
Dodecane |
14 parts; |
PMX-200 |
2 parts; |
Polyaminoacid polyethylene glycol polyester 3# |
9 parts. |
Polyaminoacid polyethylene glycol polyester 3# preparation method is as follows:
Step 1: in the case where protecting gas shielded, 200g malic acid and 30g Macrogol 600s are put into high pressure successively
In kettle, stir at a temperature of 45 DEG C 30 minutes and be well mixed to all raw materials;
Step 2: adding 30g Macrogol 600s and 250g polylysines, it is slowly added dropwise simultaneously, 15g 98% dense sulphur
Acid;
Step 3: after the addition of all raw materials, every 5 DEG C/min speed is warming up to 95 DEG C, reaction under high pressure 2 hours;
Step 4: after high temperature filters off insoluble matter, it is polyaminoacid polyethylene glycol polyester 3# to be cooled to room temperature.
Preparation method for the cleaning agent 2# of high and low voltage electric distribution equipment on-line maintenance:
Formed and tried after tetrachloro-ethylene, dichloro pentafluoropropane, propane diols and PMX-200 are well mixed in the ratio in form
Agent A;Reagent B is formed after dodecane, polyaminoacid polyethylene glycol polyester 3# are well mixed in the ratio in form;
At a temperature of 30 DEG C, reagent B is slowly mixed into reagent A, using just can quickly make system be changed into transparent phase as
Good adding speed, form transparent mixed solution, as the cleaning agent 3# for the maintenance of high and low voltage electric distribution equipment on-line.
Usage amount:
Every square metre of dosage is the above-mentioned cleaning agent 2# for the maintenance of high and low voltage electric distribution equipment on-line of 0.15-0.17kg.
Volatile performance and cleaning efficiency:
The volatilization mass percent of every 60 seconds is 91%, to the cleaning rate of pollutant up to more than 98%.