CN107573867A - A kind of preparation method of fire-retardant cold lamination film - Google Patents
A kind of preparation method of fire-retardant cold lamination film Download PDFInfo
- Publication number
- CN107573867A CN107573867A CN201710760741.3A CN201710760741A CN107573867A CN 107573867 A CN107573867 A CN 107573867A CN 201710760741 A CN201710760741 A CN 201710760741A CN 107573867 A CN107573867 A CN 107573867A
- Authority
- CN
- China
- Prior art keywords
- flame retardant
- preparation
- type transparent
- retardant type
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
The present invention relates to cold lamination film field, more particularly to a kind of preparation method of fire-retardant cold lamination film.The preparation method of the fire-retardant cold lamination film provided by the invention includes step:(1) flame retardant type transparent adhesive tape water layer is weighed into component by weight;There is the phosphorous acrylic monomers of 10 17wt% in the component;The phosphorous acrylic monomers is the one or more in 2 ethyls (methacrylic acid acyloxymethyl) phosphonate ester, 2 ethyls (acryloyloxymethyl) phosphonate ester and 2 ethyls (methacrylic acid acyloxymethyl) phosphate;(2) flame retardant type transparent adhesive tape water layer is prepared;(3) 30g/m of flame retardant type transparent adhesive tape water layer 15 is coated with flame retardant type transparent PVC film body layer2, coating speed is 20 40m/min, after drying, and after white silicon paper layer is bonded, winding.Fire-retardant cold lamination film fire resistance prepared by preparation method provided by the invention can reach VTM 2 fire-protection rating;Transparency is high.
Description
Technical field
The present invention relates to cold lamination film field, more particularly to a kind of preparation method of fire-retardant cold lamination film.
Background technology
In order to make the outdoor advertising life-span longer, photograph can have height anti-corrosive properties and anti-ultraviolet erosion, for a long time
Chang Xin, it is colour-fast, do not turn yellow, people start with transparent protective film and are covered on picture.The air brushing of air brushing membrane material makes
Afterwards because ink is in the surface of film, easily moist by moisture content in air, the natural cause influence such as sunlight, the easy oxygen of ink
Change or change colour, then, printing film surface needs PVC cold lamination films to be protected to arise at the historic moment, and solves printing ink oxidization image fault
Puzzlement.
It is although big there is can also be produced the defects of easy burning, and in burning but PVC material does not produce naked light
The toxic smoke of amount, outdoor advertising currently on the market often uses with outdoor lamp house collocation, therefore has been easier flammability issues, therefore opens
It is an important directions for developing new product to send out flame retardant type cold lamination film a kind of.But asked now below PVC cold lamination film generally existings
Topic:(1) glue is generally combustible material so that PVC cold lamination film fire resistances are not up to standard;(2) but if the inorganic resistance of glue
Combustion powder addition it is excessive not only caused by with PVC cold lamination films the problem of compatibility be present, can also influence the transparency of cold lamination film.
The content of the invention
In order to overcome existing technical deficiency, the invention provides a kind of preparation method of fire-retardant cold lamination film.
To achieve these goals, the technical scheme taken of the present invention is:
A kind of preparation method of fire-retardant cold lamination film, comprises the following steps:
(1) flame retardant type transparent adhesive tape water layer is weighed into component by following weight white powder ratio:
The phosphorous acrylic monomers is 2- ethyls (methacrylic acid acyloxymethyl) phosphonate ester, 2- ethyl (acryloyl-oxies
Methyl) one or more in phosphonate ester and 2- ethyls (methacrylic acid acyloxymethyl) phosphate;
(2) flame retardant type transparent adhesive tape water layer is prepared:All components in addition to initiator and curing agent are well mixed, Ran Houjia
Enter initiator, 70-90 DEG C of reaction 7-9h, then add curing agent and stir;
(3) flame retardant type transparent adhesive tape water layer 15-30g/m is coated with flame retardant type transparent PVC film body layer2, coating speed is
20-40m/min, after drying, and after white silicon paper layer is bonded, winding.
Butyl acrylate, methyl methacrylate, acrylic acid, propenyl and phosphorous acrylic monomers are triggered through initiator
Copolymerization, a kind of new flame-retardant polymer is made.It can pass through carboxyl and carboxyl, carboxyl and hydroxyl inside manufactured flame-retardant polymer
The hydrogen bond of base, carboxyl and amide groups, hydroxyl and amide groups, hydroxyl and hydroxyl, acid amides and acid amides forms meshed super molecular structure, makes
Polymeric inner forms network structure, and and melamine, form P-C-N Intumescent Retardant System.It is so viscous in increase
While spending, good flame retardant effect is reached.But melamine and the compatibility of this system are not so good, add a small amount of
Nitric acid adjusts pH value, can increase N content, increases anti-flammability, and can adjusts the compatibility of whole system, and increase significantly is transparent
The light transmittance of glue layer.But the amount of nitric acid crosses conference and causes the unstable of its internal network structure so that viscosity is greatly reduced,
Effect is not reached.
Preferably, phosphorous acrylic monomers, melamine and nitric acid form flame-retardant system in the step (1), when it
Weight ratio is 2-2.5:1:0.03-0.05, the P-C-N flame-retardant systems of formation, in the case where fire retardant addition is seldom, also can
Reach good flame retardant effect.
Preferably, the weight of melamine and nitric acid ratio is 1 in the step (1):0.04, under this system, nitric acid
Addition it is excessive, whole glue system can be influenceed, easily cause it is sticky not enough.But addition is too small, make melamine with
The compatibility of whole system is bad, influences transparency.
Preferably, phosphorous acrylic monomers is 2- ethyls (methacrylic acid acyloxymethyl) phosphate in the step (1).
Phosphate can be decomposed to form orthophosphoric acid, and it is good to be catalyzed into carbon effect, therefore 2- ethyls (methacrylic acid acyloxymethyl) phosphate
Addition it is less in the case of, same flame retardant effect can be reached.
Preferably, curing agent is the curing agent containing NCO group in the step (1).Such as can be toluene diisocynate
Ester (TDI);Methyl diphenylene diisocyanate (MDI).Hydroxyl (- OH) in propenyl after NCO group reaction with that can form friendship
Join network structure.So that P is distributed more evenly across inside flame retardant type transparent glue, therefore in the case where P content is less, also can
There is good flame retardant effect.
Preferably, step (1) initiator is ammonium persulfate.
Preferably, in the step (3), the drying course is, is 55 by the temperature gradient distribution of removable pressure sensitive adhesive
℃-60℃-65℃-70℃-65℃-60℃-55℃。
The present invention is advantageous in that:
1. fire-retardant cold lamination film fire resistance provided by the invention can reach VTM-2 fire-protection rating;
2. fire-retardant cold lamination film transparency provided by the invention is high.
Embodiment
With reference to embodiment, the invention will be further described:
Flame retardant type transparent PVC film body layer:The flame retardant type transparent PVC film of commercially available light transmittance more than 95%
White silicon paper layer:Commercially available white silicon paper layer
Embodiment 1
(1) flame retardant type transparent glue is prepared:2- ethyls (methacrylic acid acyloxymethyl) phosphate 10wt%;Melamine
6wt% is well mixed;Nitric acid 0.2wt%;Butyl acrylate 56wt%;Methyl methacrylate 14wt%;Acrylic acid 3wt%;
Propenyl 5.8wt% is well mixed;Then ammonium persulfate 2wt% is added, 80 DEG C of reaction 8h, then adds toluene diisocynate
Ester 3wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Embodiment 2
(1) flame retardant type transparent glue is prepared:2- ethyls (methacrylic acid acyloxymethyl) phosphate 17wt%;Melamine
8wt% is well mixed;Nitric acid 0.5wt%;Butyl acrylate 42wt%;Methyl methacrylate 8wt%;Acrylic acid 5wt%;Third
Enol 7.5wt% is well mixed;Then ammonium persulfate 4wt% is added, 80 DEG C of reaction 8h, then adds toluene di-isocyanate(TDI)
8wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Embodiment 3
(1) flame retardant type transparent glue is prepared:2- ethyls (methacrylic acid acyloxymethyl) phosphate 10.28wt%;Trimerization
Cyanamide 4.5wt% is well mixed;Nitric acid 0.22wt%;Butyl acrylate 57wt%;Methyl methacrylate 9wt%;Acrylic acid
5wt%;Propenyl 6wt% is well mixed;Then ammonium persulfate 3wt% is added, 80 DEG C of reaction 8h, it is different then to add toluene two
Cyanate 5wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Embodiment 4
(1) flame retardant type transparent glue is prepared:2- ethyls (methacrylic acid acyloxymethyl) phosphate 10.32wt%;Trimerization
Cyanamide 4.5wt% is well mixed;Nitric acid 0.18wt%, butyl acrylate 50wt%;Methyl methacrylate 11wt%;Acrylic acid
6wt%;Propenyl 10wt% is well mixed;Then ammonium persulfate 3wt% is added, 80 DEG C of reaction 8h, then adds toluene two
Isocyanates 5wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Embodiment 5
(1) flame retardant type transparent glue is prepared:2- ethyls (methacrylic acid acyloxymethyl) phosphonate ester 10.32wt%;Trimerization
Cyanamide 4.5wt% is well mixed;Nitric acid 0.18wt%;Butyl acrylate 50wt%;Methyl methacrylate 11wt%;Acrylic acid
6wt%;Propenyl 10wt% is well mixed;Then ammonium persulfate 3wt% is added, 80 DEG C of reaction 8h, then adds toluene two
Isocyanates 5wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Embodiment 6
(1) flame retardant type transparent glue is prepared:2- ethyls (acryloyloxymethyl) phosphonate ester 10.32wt%;Melamine
4.5wt% is well mixed;Nitric acid 0.18wt%;Butyl acrylate 50wt%;Methyl methacrylate 11wt%;Acrylic acid
6wt%;Propenyl 10wt% is well mixed;Then ammonium persulfate 3wt% is added, 80 DEG C of reaction 8h, then adds toluene two
Isocyanates 5wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Comparative example 1
(1) flame retardant type transparent glue is prepared:Butyl acrylate 50wt%;Methyl methacrylate 11wt%;Acrylic acid
6wt%;Propenyl 10wt%;2- ethyls (methacrylic acid acyloxyethyl) phosphonate ester 15wt% is well mixed;Then added
Ammonium sulfate 3wt%, 80 DEG C of reaction 8h, then adds toluene di-isocyanate(TDI) 5wt% and stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Comparative example 2
(1) flame retardant type transparent glue is prepared:Butyl acrylate 50wt%;Methyl methacrylate 11wt%;Acrylic acid
6wt%;Propenyl 10wt%;The phosphonitrile halogen-free flameproof monomer of ring containing the double bond three-phosphorus of (2- allyl benzenes epoxide) five phenoxy group ring three
Nitrile (APPCP) 15wt% is well mixed;Then ammonium persulfate 3wt% is added, 80 DEG C of reaction 8h, then adds toluene diisocyanate
Acid esters 5wt% stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Comparative example 3
(1) flame retardant type transparent glue is prepared:Butyl acrylate 50wt%;Methyl methacrylate 11wt%;Acrylic acid
6wt%;Propenyl 10wt%;The phosphonitrile halogen-free flameproof monomer of ring containing the double bond three-phosphorus of (2- allyl benzenes epoxide) five phenoxy group ring three
Nitrile (APPCP) 10.32wt%;Melamine 4.5wt% is well mixed;Nitric acid 0.18wt% is well mixed;Then over cure is added
Sour ammonium 3wt%, 80 DEG C of reaction 8h, then adds toluene di-isocyanate(TDI) 5wt% and stirs.
(2) cold lamination film is prepared:The flame retardant type transparent adhesive tape water layer 15- made from coating on flame retardant type transparent PVC film body layer
30g/m2, coating speed 30-60m/min, after drying, drying course is, by the temperature gradient distribution of removable pressure sensitive adhesive
For 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C, and after the white silicon paper layer of traffic allowance is bonded, winding.
Method of testing:
1st, peeling force:180 ° of peeling forces are tested by GB/2792-1998;It is measured and (is peeled off using electron detachment machine
Speed is 250mm/min).
2nd, initial bonding strength:Tested by GB/4852-2002 (method A inclined-planes rolling ball method);
3rd, light transmittance:According to the sample preparation of GB2410-80 standards and test.
4th, fire resistance:According to UL 94-2006 standards, it is measured using horizontal vertical combustion testing machine.
5th, ghost is tested:Cold lamination film is pasted onto on the mirror face stainless steel plate of standard 304, aging 7d, by cold mounting from steel plate
Film slowly removes, and by naked eyes to being observed by steel bonding plate surface, and records.
Technical scheme and beneficial effect are described in detail embodiment described above, it should be understood that
The specific embodiment of the present invention is the foregoing is only, is not intended to limit the invention, it is all to be done in the spirit of the present invention
Any modification and improvement etc., should be included in the scope of the protection.
Claims (7)
1. a kind of preparation method of fire-retardant cold lamination film, it is characterised in that comprise the following steps:
(1) flame retardant type transparent adhesive tape water layer is weighed into component by following percentage by weight:
The phosphorous acrylic monomers is 2- ethyls (methacrylic acid acyloxymethyl) phosphonate ester, 2- ethyls (acryloyloxymethyl)
One or more in phosphonate ester and 2- ethyls (methacrylic acid acyloxymethyl) phosphate;
(2) flame retardant type transparent adhesive tape water layer is prepared:All components in addition to initiator and curing agent are well mixed, then adds and draws
Agent is sent out, 70-90 DEG C of reaction 7-9h, curing agent is then added and stirs;
(3) flame retardant type transparent adhesive tape water layer 15-30g/m is coated with flame retardant type transparent PVC film body layer2, coating speed 20-
40m/min, after drying, and after white silicon paper layer is bonded, winding.
2. preparation method according to claim 1, it is characterised in that:Phosphorous acrylic monomers, trimerization in the step (1)
The weight of cyanamide and nitric acid ratio is 2-2.5:1:0.03-0.05.
3. preparation method according to claim 1, it is characterised in that:Containing melamine and nitric acid in the step (1)
Weight ratio is 1:0.04.
4. preparation method according to claim 1, it is characterised in that:Phosphorous acrylic monomers is 2- in the step (1)
Ethyl (methacrylic acid acyloxymethyl) phosphate.
5. preparation method according to claim 1, it is characterised in that:Containing curing agent for containing NCO group in the step (1)
Curing agent.
6. preparation method according to claim 1, it is characterised in that:Containing initiator it is ammonium persulfate in the step (1).
7. preparation method according to claim 1, it is characterised in that:In the step (3), the drying course is to incite somebody to action
The temperature gradient distribution of removable pressure sensitive adhesive is 55 DEG C -60 DEG C -65 DEG C -70 DEG C -65 DEG C -60 DEG C -55 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710760741.3A CN107573867A (en) | 2017-08-30 | 2017-08-30 | A kind of preparation method of fire-retardant cold lamination film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710760741.3A CN107573867A (en) | 2017-08-30 | 2017-08-30 | A kind of preparation method of fire-retardant cold lamination film |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107573867A true CN107573867A (en) | 2018-01-12 |
Family
ID=61030090
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710760741.3A Pending CN107573867A (en) | 2017-08-30 | 2017-08-30 | A kind of preparation method of fire-retardant cold lamination film |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107573867A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108384067A (en) * | 2018-02-09 | 2018-08-10 | 长兴科创科技咨询有限公司 | A kind of degradable high environmental-friendfilm film and its preparation process thoroughly |
CN108728008A (en) * | 2018-04-28 | 2018-11-02 | 浙江福莱新材料股份有限公司 | A kind of antireflective cold lamination film and preparation method thereof |
CN108728009A (en) * | 2018-04-28 | 2018-11-02 | 浙江福莱新材料股份有限公司 | A kind of anti-reflection antireflective cold lamination film and preparation method thereof |
CN108754432A (en) * | 2018-04-28 | 2018-11-06 | 浙江福莱新材料股份有限公司 | A kind of cold lamination film antireflection layer and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102190971A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Preparation method of combined phosphorus type flame-retardant acrylic ester pressure-sensitive adhesive |
CN102206476A (en) * | 2011-05-11 | 2011-10-05 | 宝利时(深圳)胶粘制品有限公司 | PE (polyurethane) protective film glue and preparation method thereof |
CN203487076U (en) * | 2013-08-14 | 2014-03-19 | 惠州艺都影像科技有限公司 | Cold laminating film |
CN106833447A (en) * | 2017-01-17 | 2017-06-13 | 江苏源源山富数码喷绘科技有限公司 | A kind of PVC cold lamination films pressure-sensitive polyacrylate emulsion glue and preparation method thereof |
-
2017
- 2017-08-30 CN CN201710760741.3A patent/CN107573867A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102190971A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Preparation method of combined phosphorus type flame-retardant acrylic ester pressure-sensitive adhesive |
CN102206476A (en) * | 2011-05-11 | 2011-10-05 | 宝利时(深圳)胶粘制品有限公司 | PE (polyurethane) protective film glue and preparation method thereof |
CN203487076U (en) * | 2013-08-14 | 2014-03-19 | 惠州艺都影像科技有限公司 | Cold laminating film |
CN106833447A (en) * | 2017-01-17 | 2017-06-13 | 江苏源源山富数码喷绘科技有限公司 | A kind of PVC cold lamination films pressure-sensitive polyacrylate emulsion glue and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
王钰 等: "《塑料改性实用技术与应用》", 30 June 2014, 印刷工业出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108384067A (en) * | 2018-02-09 | 2018-08-10 | 长兴科创科技咨询有限公司 | A kind of degradable high environmental-friendfilm film and its preparation process thoroughly |
CN108728008A (en) * | 2018-04-28 | 2018-11-02 | 浙江福莱新材料股份有限公司 | A kind of antireflective cold lamination film and preparation method thereof |
CN108728009A (en) * | 2018-04-28 | 2018-11-02 | 浙江福莱新材料股份有限公司 | A kind of anti-reflection antireflective cold lamination film and preparation method thereof |
CN108754432A (en) * | 2018-04-28 | 2018-11-06 | 浙江福莱新材料股份有限公司 | A kind of cold lamination film antireflection layer and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107573867A (en) | A kind of preparation method of fire-retardant cold lamination film | |
JP6172312B1 (en) | Re-peelable adhesive and surface protective film | |
TW201245378A (en) | Adhesive composition and surface protection film | |
CN110615882B (en) | Polyhydroxy nitrogen-phosphorus synergistic flame retardant, flame-retardant PU hot melt adhesive and preparation method thereof | |
CN107722908B (en) | A kind of preparation method of polyurethane fireproof glue for building | |
CN101835858A (en) | Acrylic pressure sensitive adhesive composition, protection film including the same, polarizer and liquid crystal display | |
CN102695766B (en) | Flame resistant adhesive composition, flame resistant adhesive tape and flame resistant adhesive sheet | |
CN110128967A (en) | A kind of Flame-retardant adhesive, the anti-flaming viscose band being prepared by it and preparation method | |
CN104629342A (en) | Resin composition and covering film prepared from resin composition | |
TW202000831A (en) | Flame-retardant pressure-sensitive adhesive, flame-retardant pressure-sensitive adhesive sheet and method for preparing same | |
CN105295783A (en) | Adhesive composition and display device | |
CN107488425A (en) | A kind of cold lamination film flame-proof acrylic ester pressure-sensitive and preparation method thereof | |
CN110407979A (en) | Pressure-sensitive gum resin and light transmission flame-retardant double sided tape comprising it | |
CN107722911B (en) | A kind of polyurethane fireproof glue for building | |
CN113861878A (en) | High temperature resistant protection film | |
CN108753182A (en) | A kind of OCA optical cements haveing excellent performance, optical adhesive tape and preparation method thereof | |
WO2014069461A1 (en) | Flame-retardant adhesive composition and flame-retardant adhesive sheet | |
CN113528041A (en) | Flame-retardant antistatic protective film and preparation method thereof | |
CN107603530A (en) | A kind of fire-retardant cold lamination film | |
CN108510874A (en) | Fire-retardant label of a kind of self-bleeding battery of environmental protection and preparation method thereof | |
TWI791843B (en) | Adhesive sheet | |
CN107603503A (en) | A kind of waterborne flame retardant bright gum PVC and preparation method thereof in vain | |
CN107573529A (en) | A kind of fire-retardant positive spray lamp of Weak solvent | |
CN110343479B (en) | Flame-retardant adhesive tape with high-temperature discoloration early warning function and preparation method thereof | |
CN112521868B (en) | UV-cured hot-melt rubber pressure-sensitive adhesive and electrical adhesive tape prepared from same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB02 | Change of applicant information | ||
CB02 | Change of applicant information |
Address after: 314100 No. 17, Yinhe Road, Yao Zhuang Town, Jiashan County, Jiaxing, Zhejiang. Applicant after: Zhejiang fry new material Limited by Share Ltd Address before: 314100 No. 17, Yinhe Road, Yao Zhuang Town, Jiashan County, Jiaxing, Zhejiang. Applicant before: Zhejiang Ouli Digital Printing Materials Co., Ltd. |
|
WD01 | Invention patent application deemed withdrawn after publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180112 |