CN107571589A - Titanium nitride glass fenestrated membrane and preparation method and application - Google Patents
Titanium nitride glass fenestrated membrane and preparation method and application Download PDFInfo
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- CN107571589A CN107571589A CN201710954690.8A CN201710954690A CN107571589A CN 107571589 A CN107571589 A CN 107571589A CN 201710954690 A CN201710954690 A CN 201710954690A CN 107571589 A CN107571589 A CN 107571589A
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- Prior art keywords
- titanium nitride
- fenestrated membrane
- layer
- primary colors
- glass fenestrated
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- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 title claims abstract description 115
- 239000012528 membrane Substances 0.000 title claims abstract description 74
- 239000011521 glass Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 210000004379 membrane Anatomy 0.000 claims abstract description 73
- 210000002469 basement membrane Anatomy 0.000 claims abstract description 45
- 239000003086 colorant Substances 0.000 claims abstract description 45
- 230000003678 scratch resistant effect Effects 0.000 claims abstract description 26
- 239000002131 composite material Substances 0.000 claims abstract description 25
- 229920006267 polyester film Polymers 0.000 claims abstract description 25
- 238000004544 sputter deposition Methods 0.000 claims abstract description 14
- 239000010410 layer Substances 0.000 claims description 115
- 239000011265 semifinished product Substances 0.000 claims description 21
- 238000007605 air drying Methods 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 14
- 239000003292 glue Substances 0.000 claims description 7
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 6
- 229920001875 Ebonite Polymers 0.000 claims description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 5
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 238000009738 saturating Methods 0.000 claims description 2
- 238000009413 insulation Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 14
- 238000010030 laminating Methods 0.000 description 10
- 238000003851 corona treatment Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000001755 magnetron sputter deposition Methods 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 4
- 241001074085 Scophthalmus aquosus Species 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000005204 hydroxybenzenes Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of titanium nitride glass fenestrated membrane and preparation method and application, the titanium nitride glass fenestrated membrane include be sequentially connected scratch resistant layer, titanium nitride magnetic control basement membrane, composite bed, primary colors film, mounting layer, mould release membrance, wherein the titanium nitride magnetic control basement membrane includes biaxially oriented polyester film and titanium nitride sputtering layer.For titanium nitride glass fenestrated membrane prepared by the present invention still without the dark line of black under strong light, presentation quality is good, and has good visible light transmissivity, high ultraviolet isolating rate and infrared ray rejection rate, good heat-insulation effect, keeps off fenestrated membrane after being used as automobile side, lifts automotive quality.
Description
Technical field
The present invention relates to automobile window films field, specifically, the present invention relates to a kind of titanium nitride glass fenestrated membrane and its preparation side
Method and application.
Background technology
Fenestrated membrane is kept off after automobile side, that is, is pasted on the fenestrated membrane kept off after automobile side.Vacuum magnetic-control sputtering technology was in 90 years 20th century
Formally enter market for latter stage, experienced multiple technologies innovation, magnetron sputtering technique is by nickel, silver, titanium, gold, ceramic material etc.
Advanced aerospace alloys material uses state-of-the-art multi-cavity high-speed rotating equipment, using electric field and the high strength of magnetic principles high speed
By metallic uniform sputter in the PET base material of high-tension.The product of magnetron sputtering technique except possess good metal-like,
Outside stable heat-proof quality, also with the definition that other techniques are unable to reach and low reflective and lasting color and luster.
Titanium nitride magnetic control basement membrane is the combination of magnetron sputtering technique and nitride metal technology and produced, and uses titanium nitride
Fenestrated membrane prepared by magnetic control basement membrane can reach simultaneously high-resolution, it is high it is heat-insulated, low it is reflective, without dyeing, be main flow skill in the market
Art product.Titanium nitride magnetic control basement membrane is the combination of magnetron sputtering technique and nitride metal technology and produced.Titanium nitride belongs to
Ceramic material, its titanium nitride layer of general titanium nitride magnetic control basement membrane have tens nanometers to arrive nanometer thickness up to a hundred, and titanium nitride layer is with respect to other
For sputter material it is crisp a lot, often just there is the dark line of black, the black because pad pasting work progress slightly folds to applied to fenestrated membrane
Dark line be due to titanium nitride layer it is cracked caused by (it is relatively thin to be applied to the titanium nitride magnetic control basement membrane of front its titanium nitride layer, no
Easily there is the problem), the dark line of the black is under strong sunlight it can be seen that (in-car light is weak, and to can't see the black dark outside vehicle window
Line), outward appearance is had a strong impact on, or even product quality problem can be treated as and returned goods.
The content of the invention
Based on this, the defects of the invention reside in prior art is overcome, there is provided a kind of titanium nitride glass fenestrated membrane, the titanium nitride
For glass fenestrated membrane still without the dark line of black under strong light, presentation quality is good, and with good visible light transmissivity, high ultraviolet isolating
Rate and infrared ray rejection rate, good heat-insulation effect, fenestrated membrane is kept off after automobile side being used as.
Another object of the present invention is to provide the preparation method of the titanium nitride glass fenestrated membrane.The preparation method is simple
Easy, using current ripe coating technique and complex technique, and cost is cheap.
Another object of the present invention is to provide application of the titanium nitride glass fenestrated membrane being kept off after automobile side in fenestrated membrane.
Its technical scheme is as follows：
A kind of titanium nitride glass fenestrated membrane, including be sequentially connected scratch resistant layer, titanium nitride magnetic control basement membrane, composite bed, primary colors film
Layer, mounting layer, wherein the titanium nitride magnetic control basement membrane includes polyester film and titanium nitride sputtering layer.
Gear fenestrated membrane structure has four kinds behind common titanium nitride side on the market now：(1) scratch resistant layer, titanium nitride magnetic control are followed successively by
Basement membrane (polyester film and titanium nitride sputtering layer), mounting layer, referring to Fig. 1；(2) scratch resistant layer, titanium nitride magnetic control basement membrane (polyester film
With titanium nitride sputtering layer), composite bed, laminated polyester film, mounting layer, referring to Fig. 2；(3) scratch resistant layer, laminated polyester film, composite bed,
Titanium nitride magnetic control basement membrane (titanium nitride sputtering layer and polyester film), mounting layer, referring to Fig. 3；(4) scratch resistant layer, primary colors film layer, compound
Layer, titanium nitride magnetic control basement membrane (titanium nitride sputtering layer and polyester film), mounting layer, referring to Fig. 4.Above-mentioned four kinds of structures easily go out
The dark line of existing black, wherein, (4) kind is primary colors film layer and the warp of reflection-type basement membrane (including magnetic control basement membrane and aluminium plating basement membrane) collocation
Allusion quotation structure, the structure have using reduce internal reflection rate (GA/T744-2003 require Sunshade film visible light reflectance should be less than
In 20%), therefore the visible light transmissivity selection space of the reflection-type basement membrane of the structure is big, but still is difficult to solve the dark line of black
Problem.The present invention have adjusted primary colors film layer, composite bed, the position of titanium nitride magnetic control basement membrane, pass through the optimization of structure and material
After selection overcomes existing titanium nitride side there is the defects of dark line of black, quality is bad, resulting titanium nitride glass in gear fenestrated membrane
Glass fenestrated membrane is under strong light still without the dark line of black.
Its principle that titanium nitride glass fenestrated membrane of the present invention can play a part of weakening incident ray is as follows：Assuming that enter
It is L to penetrate light (light outside window) intensity, and primary colors film layer visible light transmissivity is V, and polyester film, composite bed, mounting layer are to light
Influence is ignored, and titanium nitride sputtering layer cracks visible reflectance is R, then the crack deflection light that eyes receive is strong
Spend and be：Fig. 1-4：L1-4 eyes=L × R=LR；The application (Fig. 5)：L5 eyes=L × V × R × V=LV2R.General primary colors film layer can
It is 10~75% to see light transmission rate V, under identical incident intensity and identical titanium nitride sputtering layer cracks, Fig. 5 structure eyes
The crack deflection light intensity received is only the V of Fig. 1~42, i.e., 1%~56%, greatly reduce cracks reflection light
Intensity, crackle is set not displayed under sunshine.
In one of the embodiments, the polyester film is the biaxial tension handled by sided corona treatment or chemical primary coat
Polyester film.More preferably handled by chemical primary coat, chemical primary coat processing can be polyurethane processing or poly- third
The processing of olefin(e) acid ester, is so advantageous to improve its adhesive force with scratch resistant layer, does not allow scratch resistant layer easy to fall off.
In one of the embodiments, the light transmission rate of the titanium nitride magnetic control basement membrane is 40~60%.Being arranged such can
So that titanium nitride glass fenestrated membrane internal reflection is less high, the thermal insulation of titanium nitride glass fenestrated membrane can be ensured.
In one of the embodiments, the thickness of the titanium nitride magnetic control basement membrane is 12~100um.
In one of the embodiments, the mounting layer is pressure-sensitive adhesive layer, and thickness is 5~10um.Mounting layer can also add
Add ultraviolet absorber, be advantageous to protect primary colors film layer and titanium nitride magnetic control basement membrane, ultraviolet absorber can be that styrene acid is derivative
One or more collocation in thing, oxanilide, benzophenone, hydroxyl phenol and BTA, hydroxyl phenol and triazine make
With.
In one of the embodiments, the primary colors film layer is organic primary colors film or inorganic primary colors film.Primary colors film can be
It is heat-insulated can also be it is non-heat-insulated, can be every it is ultraviolet can also right and wrong every ultraviolet.
In one of the embodiments, the visible light transmissivity of the primary colors film layer be 10~75%, thickness be 12~
100um。
In one of the embodiments, the primary colors film layer is the primary colors film handled by sided corona treatment or chemical primary coat.
The corona surface of primary colors film layer or chemical primary coat face coating mounting layer, can improve and install the adhesion of glue, reduce film and tear off glass
The cull that glass occurs.
In one of the embodiments, the composite bed is ebonite or flexible glue.More specifically, ebonite is to cement type glue,
Thickness can be 1~5um.Flexible glue is pressure sensitive adhesive, and thickness can be 4~10um.
In one of the embodiments, the scratch resistant layer is uv-curing type urethane acrylate, and thickness is 1~3um.
In one of the embodiments, the titanium nitride glass fenestrated membrane also includes mould release membrance, and the mould release membrance is positioned at described
The side of mounting layer.Specifically, the mould release membrance is biaxially oriented polyester film, thickness is 12~50um.Release type can be with
From silicone oil or non-silicone oil.
The preparation method of the titanium nitride glass fenestrated membrane, comprises the following steps：
Titanium nitride magnetic control basement membrane, composite bed, primary colors film layer, the mounting layer that S1, preparation are sequentially connected, obtain semi-finished product nitridation
Titanium glass fenestrated membrane；
S2, scratch resistant layer is coated with the semi-finished product titanium nitride glass fenestrated membrane obtained by step S1, through baking oven heated-air drying, then passed through
UV irradiations solidify afterwards obtain titanium nitride glass fenestrated membrane.
In one of the embodiments, step S1 is：(1) it is coated with primary colors film by the way of nick or slot coated
Composite bed, the laminating titanium nitride magnetic control basement membrane again after baking oven heated-air drying, obtains semi-finished product；(2) nick or slot coated are used
The opposite side of mode primary colors film layer of semi-finished product obtained by the step (1) be coated with mounting layer, through baking oven heated-air drying.
In one of the embodiments, step S1 is：(1) applied in primary colors film layer by the way of nick or slot coated
Cloth composite bed, the laminating titanium nitride magnetic control basement membrane again after baking oven heated-air drying, obtains semi-finished product；(2) applied using nick or slit
The mode of cloth is coated with mounting layer in the opposite side of the primary colors film layer of semi-finished product obtained by step (1), laminating after baking oven heated-air drying
Mould release membrance.
In one of the embodiments, step S1 is：(1) applied in primary colors film layer by the way of nick or slot coated
Cloth mounting layer, through baking oven heated-air drying, obtain semi-finished product；(2) obtained by step (1) by the way of nick or slot coated
Composite bed is coated with semi-finished product, the laminating magnetic control basement membrane after baking oven heated-air drying.
In one of the embodiments, step S1 is：(1) applied in primary colors film layer by the way of nick or slot coated
Cloth mounting layer, laminating mould release membrance, obtains semi-finished product after baking oven heated-air drying；(2) by the way of nick or slot coated
Composite bed is coated with semi-finished product obtained by step (1), the laminating magnetic control basement membrane after baking oven heated-air drying.
Application of the titanium nitride glass fenestrated membrane after automobile side in shelves fenestrated membrane.Titanium nitride windowpane prepared by the present invention
The dark line problem of black is not present in film, and fenestrated membrane is kept off after being suitable as automobile side.
The beneficial effects of the present invention are：The present invention overcomes existing nitridation by the optimization of structure and the selection of material
The defects of gear fenestrated membrane has the dark line of black behind titanium side, and quality is bad, resulting titanium nitride glass fenestrated membrane is under strong light still without black
The dark line of color, presentation quality is good, keeps off fenestrated membrane after being used as automobile side, lifts automotive quality；The polyester film passes through sided corona treatment
Or chemical primary coat processing, its adhesive force with scratch resistant layer is improved, does not allow scratch resistant layer easy to fall off；Titanium nitride magnetic control basement membrane light is saturating
It is 40~60% to cross rate, good heat-insulation effect；The primary colors film is handled by sided corona treatment or chemical primary coat, improves itself and installation
The adhesion of glue, the cull that film tears off glass appearance can be reduced；The preparation method of the titanium nitride glass fenestrated membrane is simple and easy,
It can be achieved using current ripe coating technique and complex technique, and cost is cheap.
Brief description of the drawings
Fig. 1 is the structural representation of gear fenestrated membrane structure common structure 1 behind titanium nitride side on the market.
Fig. 2 is the structural representation of gear fenestrated membrane structure common structure 2 behind titanium nitride side on the market.
Fig. 3 is the structural representation of gear fenestrated membrane structure common structure 3 behind titanium nitride side on the market.
Fig. 4 is the structural representation of gear fenestrated membrane structure common structure 4 behind titanium nitride side on the market.
Fig. 5 is the titanium nitride windowpane membrane structure schematic diagram of embodiment 1.
Fig. 6 is the titanium nitride windowpane membrane structure schematic diagram of embodiment 3.
1st, scratch resistant layer；2nd, titanium nitride magnetic control basement membrane；21st, polyester film；22nd, titanium nitride sputtering layer；3rd, composite bed；4th, primary colors
Film layer；5th, mounting layer；6th, mould release membrance；7th, laminated polyester film.
Embodiment
For the objects, technical solutions and advantages of the present invention are more clearly understood, below in conjunction with accompanying drawing and specific embodiment party
Formula, the present invention is described in further detail.It should be appreciated that embodiment described herein is only solving
The present invention is released, does not limit protection scope of the present invention.
Embodiment 1
As shown in figure 5, a kind of titanium nitride glass fenestrated membrane, scratch resistant layer 1 that the titanium nitride glass fenestrated membrane includes being sequentially connected,
Titanium nitride magnetic control basement membrane 2, composite bed 3, primary colors film layer 4, mounting layer 5, wherein the titanium nitride magnetic control basement membrane 2 includes biaxial tension
Polyester film 21 and titanium nitride sputtering layer 22.The light transmission rate of the titanium nitride magnetic control basement membrane 2 be 40~60%, thickness be 12~
100um.Mounting layer 5 is pressure-sensitive adhesive layer, and thickness is 5~10um.The visible light transmissivity of primary colors film layer 4 is 10~75%, thickness
For 12~100um.The composite bed 3 is ebonite, and thickness is 1~5um.The scratch resistant layer 1 is ultra-violet curing type polyurethane propylene
Acid esters, thickness are 1~3um.
The titanium nitride glass fenestrated membrane is prepared as follows：
(1) composite bed 4 is coated with by the way of nick or slot coated in primary colors film layer, after baking oven heated-air drying again
Laminating titanium nitride magnetic control basement membrane 2, obtains semi-finished product；
(2) in the opposite side coating of the primary colors film layer 4 of semi-finished product obtained by step (1) by the way of nick or slot coated
Mounting layer 5, through baking oven heated-air drying, obtain semi-finished product titanium nitride glass fenestrated membrane；
(3) scratch resistant layer 1 is coated with semi-finished product titanium nitride glass fenestrated membrane by the way of nick or slot coated, through baking oven
Heated-air drying, then obtain titanium nitride glass fenestrated membrane through UV irradiations solidify afterwards.
Embodiment 2
As shown in figure 5, a kind of titanium nitride glass fenestrated membrane, scratch resistant layer 1 that the titanium nitride glass fenestrated membrane includes being sequentially connected,
Titanium nitride magnetic control basement membrane 2, composite bed 3, primary colors film layer 4, mounting layer 5, wherein the titanium nitride magnetic control basement membrane 2 includes biaxial tension
Polyester film 21 and titanium nitride sputtering layer 22.The light transmission rate of the titanium nitride magnetic control basement membrane 2 be 40~60%, thickness be 12~
100um.Mounting layer 5 is pressure-sensitive adhesive layer, and thickness is 5~10um.The visible light transmissivity of primary colors film layer 4 is 10~75%, thickness
For 12~100um.The composite bed 3 is flexible glue, and thickness is 4~10um.The scratch resistant layer 1 is ultra-violet curing type polyurethane propylene
Acid esters, thickness are 1~3um.
The titanium nitride glass fenestrated membrane is prepared as follows：
(1) mounting layer 5 is coated with by the way of nick or slot coated in primary colors film layer 4, through baking oven heated-air drying, is obtained
To semi-finished product；
(2) composite bed 3 is coated with the semi-finished product obtained by step (1) by the way of nick or slot coated, through baking oven
Laminating magnetic control basement membrane 2 after heated-air drying.
(3) scratch resistant layer 1 is coated with semi-finished product titanium nitride glass fenestrated membrane by the way of nick or slot coated, through baking oven
Heated-air drying, then obtain titanium nitride glass fenestrated membrane through UV irradiations solidify afterwards.
Embodiment 3
As shown in fig. 6, a kind of titanium nitride glass fenestrated membrane, scratch resistant layer 1 that the titanium nitride glass fenestrated membrane includes being sequentially connected,
Titanium nitride magnetic control basement membrane 2, composite bed 3, primary colors film layer 4, mounting layer 5, mould release membrance 6, wherein the titanium nitride magnetic control basement membrane 2 includes
Biaxially oriented polyester film 21 and titanium nitride sputtering layer 22.The polyester film 21 is handled by sided corona treatment or chemical primary coat,
Polyester film 21 described in the present embodiment is handled by chemical primary coat, specifically for scribble on polyester film polyurethane process layer or
Polyacrylate process layer 23, to improve the adhesive force with scratch resistant layer 1, do not allow scratch resistant layer 1 easy to fall off.The titanium nitride magnetic control
The light transmission rate of basement membrane 2 is 40~60%, and thickness is 12~100um.The mould release membrance 6 is biaxially oriented polyester film, thickness
For 12~50um, mould release membrance 6 is coated with silicone oil；Mounting layer 5 is pressure-sensitive adhesive layer, and thickness is 5~10um, mounting layer in the present embodiment
Ultraviolet absorber is also added in 5, ultraviolet absorber can be styrene acid derivative, oxanilide, benzophenone, hydroxy benzenes
One or more collocation in phenol and BTA, hydroxyl phenol and triazine, specifically, with the addition of hexichol first in the present embodiment
Ketone and hydroxyl phenol and BTA.The visible light transmissivity of primary colors film layer 4 is 10~75%, and thickness is 12~100um, former
Color film layer 4 is the primary colors film handled by sided corona treatment or chemical primary coat, and in the present embodiment, chemical bottom is carried out on primary colors film surface
Painting is handled, and adds primary coat process layer 41, to improve the adhesion of primary colors film layer 4 and mounting layer, is reduced film and is torn off glass appearance
Cull.The composite bed 3 is ebonite, and thickness is 1~5um.The scratch resistant layer 1 is uv-curing type urethane acrylate, thick
Spend for 1~3um.
The titanium nitride glass fenestrated membrane is prepared as follows：
(1) chemical primary coat processing is carried out on the surface of primary colors film layer 4, adds process layer 41, then using nick or slot coated
Mode be coated with mounting layer 5, laminating mould release membrance 6, obtains semi-finished product after baking oven heated-air drying；
(2) composite bed 3 is coated with the semi-finished product obtained by step (1) by the way of nick or slot coated, through baking oven
Laminating magnetic control basement membrane 2 after heated-air drying；
(3) scratch resistant layer 1 is coated with semi-finished product titanium nitride glass fenestrated membrane by the way of nick or slot coated, through baking oven
Heated-air drying, then obtain titanium nitride glass fenestrated membrane through UV irradiations solidify afterwards.
Comparative example 1
Fenestrated membrane is kept off after the automobile side produced from Mei Fute.
Titanium nitride glass fenestrated membrane prepared by embodiment 1-3 is tested, test result is shown in Table 1.
Table 1
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously
Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that come for one of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of titanium nitride glass fenestrated membrane, it is characterised in that including the scratch resistant layer being sequentially connected（1）, titanium nitride magnetic control basement membrane
（2）, composite bed（3）, primary colors film layer（4）, mounting layer（5）, wherein the titanium nitride magnetic control basement membrane（2）Including polyester film（21）
With titanium nitride sputtering layer（22）.
2. titanium nitride glass fenestrated membrane according to claim 1, it is characterised in that the polyester film（21）For by corona
Reason or the biaxially oriented polyester film of chemical primary coat processing.
3. titanium nitride glass fenestrated membrane according to claim 1, it is characterised in that the titanium nitride magnetic control basement membrane（2）Light it is saturating
Rate is crossed as 40~60%.
4. titanium nitride glass fenestrated membrane according to claim 1, it is characterised in that the titanium nitride magnetic control basement membrane（2）Thickness
For 12~100um.
5. titanium nitride glass fenestrated membrane according to claim 1, it is characterised in that the mounting layer（5）For pressure-sensitive adhesive layer, thickness
For 5~10um.
6. titanium nitride glass fenestrated membrane according to claim 1, it is characterised in that the primary colors film layer（4）For organic primary colors film
Or inorganic primary colors film.
7. titanium nitride glass fenestrated membrane according to claim 6, it is characterised in that the primary colors film layer（4）For by corona
Reason or the primary colors film of chemical primary coat processing.
8. titanium nitride glass fenestrated membrane according to claim 1, it is characterised in that the composite bed（3）For ebonite or flexible glue.
9. the preparation method of titanium nitride glass fenestrated membrane described in claim 1-8 any claims, it is characterised in that including as follows
Step：
The titanium nitride magnetic control basement membrane that S1, preparation are sequentially connected（2）, composite bed（3）, primary colors film layer（4）, mounting layer（5）, obtain half
Finished product nitrogenizes titanium glass fenestrated membrane；
S2, it is coated with scratch resistant layer on the semi-finished product titanium nitride glass fenestrated membrane obtained by step S1（1）, through baking oven heated-air drying, then pass through
UV irradiations solidify afterwards obtain titanium nitride glass fenestrated membrane.
10. the application that titanium nitride glass fenestrated membrane described in claim 1-8 any claims is kept off in fenestrated membrane after automobile side.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838289A (en) * | 2011-06-24 | 2012-12-26 | 核工业西南物理研究院 | Solar control film and double layer composite solar control film |
| CN105082705A (en) * | 2015-08-31 | 2015-11-25 | 广东鑫瑞新材料科技有限公司 | Method for lowering visible light reflectivity of vacuum heat evaporation film |
| CN207257041U (en) * | 2017-10-13 | 2018-04-20 | 广东鑫瑞新材料科技有限公司 | Glass pane is kept off after titanium nitride glass fenestrated membrane and automobile side comprising the glass fenestrated membrane |
-
2017
- 2017-10-13 CN CN201710954690.8A patent/CN107571589A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838289A (en) * | 2011-06-24 | 2012-12-26 | 核工业西南物理研究院 | Solar control film and double layer composite solar control film |
| CN105082705A (en) * | 2015-08-31 | 2015-11-25 | 广东鑫瑞新材料科技有限公司 | Method for lowering visible light reflectivity of vacuum heat evaporation film |
| CN207257041U (en) * | 2017-10-13 | 2018-04-20 | 广东鑫瑞新材料科技有限公司 | Glass pane is kept off after titanium nitride glass fenestrated membrane and automobile side comprising the glass fenestrated membrane |
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