CN105291507B - A kind of stealthy form laminating film - Google Patents
A kind of stealthy form laminating film Download PDFInfo
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- CN105291507B CN105291507B CN201410264238.5A CN201410264238A CN105291507B CN 105291507 B CN105291507 B CN 105291507B CN 201410264238 A CN201410264238 A CN 201410264238A CN 105291507 B CN105291507 B CN 105291507B
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Abstract
The invention discloses a kind of stealthy form laminating film, it includes one first superposed transparent thin film layer, a vacuum aluminium coated layer, a composite adhesive layer, one second transparent thin film layer, a colored ink printing layer, a pressure-sensitive adhesive layer, and one surface there is the film layer of separation property, wherein, the first described transparent thin film layer and described vacuum aluminium coated layer form a composite bed, and the light transmittance of described composite bed is 3.5%~4.5%；The light transmittance of described stealthy form laminating film is 2%~4%；It is 23mic that described surface, which has the thickness of the film layer of separation property,.The stealthy form laminating film of the present invention is easily removed from glass and the stealthy form laminating film is all suitable on the glass of plane and arc.Therefore, the product has good marketing and practical value.
Description
Technical field
The present invention relates to a kind of stealthy form laminating film.
Background technology
In recent years in white goods industry, intelligent household appliance is in the ascendant, is increasingly becoming the main flow in market, intelligent family
Intelligent operating system in electricity proposes to high-grade decoration plane material-i.e. glass panel and updates higher requirement.In the prior art
The preparation method of glass panel is mainly that printing color ink is realized on monolithic transparent glass panel by silk screen.But
Several drawbacks be present in above-mentioned preparation method：First, during End-Customer use, if the glass panel of intelligent household appliance by
To when impacting or toppling over, glass panel is easy to crush, and sharp keen fragment is easily formed in shattering process, or even occurs to fly
Splash, the people on periphery is caused serious injury, it is very dangerous, potential safety hazard be present；Second, glass panel is in print production process
In, during if there is silk-screen printing colored ink flaw, full wafer glass panel can only scrap processing, cause huge waste, into
This height；Third, the efficiency printed one by one on the glass panel of each monolithic continuously prints far below coiled plastic sheeting
Brush.These drawbacks, which are all needed badly, to be resolved.
Number of patent application 200820034482 provides a kind of VCM two-color clad steel plates, and the clad steel plate includes steel plate, in steel
Covering is bonded with composite film on plate, covering bonding is provided with the back of the body provided with protection film layer and at steel plate layer back on composite film
Enamelled coating, wherein, composite film is the composite film of PET/two color printing layer/polyvinyl chloride composition.Due to
The front of the clad steel plate is provided with PET/ two color printings layer/PVC composite films, user need not be made product or semi-finished product with
Row paints or decorated again afterwards；Meanwhile the back side of steel plate is provided with back of the body enamelled coating, and steel plate can be protected not invaded during transport and use
Erosion.The VCM two-color clad steel plates are applied to refrigerator door panel, have good wear resistance and resistance to soiling, can make refrigerator door panel
Integration, instead of using PVC profile and metallic plate splicing structure, simplifying technique in the past, reducing cost.But the double-colored clad steels of VCM
Plate all determines that it cannot be used for the fitting of intelligent Household electrical appliance decorating panel in terms of preparation technology and selection.
The content of the invention
The technical problems to be solved by the invention are in order to overcome traditional VCM composite membranes to cannot be used for high-grade intelligent household appliance
The defects of guidance panel is bonded, while also overcome in the prior art directly on glass panels with screen printing technique printing figure
Case, the wasting of resources, the defects such as production cost is high and efficiency is low are easily caused, and provide a kind of stealthy form laminating film.This
The stealthy form laminating film of invention easily from glass remove and the stealthy form laminating film on the glass of plane and arc all
It is applicable.Therefore, the product has good marketing and practical value.
The present inventor is had found by largely studying and testing repeatedly：The stealthy form laminating film of the present invention, when
Light transmittance exists at (preferably 2.5%~3.5%) between 2%~4% in the window of the guidance panel for intelligent touch-screen
Can be stealthy under sleep state, when operator removes touch operation window with hand, the effective activation manipulation window of and can, if printing opacity
Rate is higher than 4%, and action pane is visible so as to can not effectively realize hidden function under available light, if light transmittance on the contrary is less than
2%, then operator is with again can not effective activation manipulation window during hand touch operation window.
The invention provides a kind of stealthy form laminating film, it includes one first superposed transparent thin film layer, one true
Empty aluminium coated, a composite adhesive layer, one second transparent thin film layer, a colored ink printing layer, a pressure-sensitive adhesive layer, and a table
Face has the film layer of separation property, wherein, the first described transparent thin film layer and described vacuum aluminium coated layer form a composite bed,
The light transmittance of described composite bed is 3.5%~4.5%；The light transmittance of described stealthy form laminating film is 2%~4%；Institute
It is 23mic that the surface stated, which has the thickness of the film layer of separation property,.
The light transmittance of described stealthy form laminating film is preferably 2.5%~3.5% (3 ± 0.5%).
The measuring method of the light transmittance of described composite bed can be found in national standard：Transparent plastic light transmittance in GB/2410-2008
With the measure of mist degree.Transparent membrane in the first described transparent thin film layer can be transparent membrane commonly used in the art, compared with
It is pet film (abbreviation PET film) goodly.It is thin for described polyethylene terephthalate
For film, its thickness is preferably 8~30 microns, is more preferably 15~25 microns；Its light transmittance is preferably 80%~92%,
More preferably it is 89%~91%；The glossiness of its 45° angle is preferably 100~160 gloss units, is more preferably 130~160 light
Damp unit；Its mist degree is preferably 1.5%~3.0%, is more preferably 1.5%~2.0%；The wetting tension in its sided corona treatment face
Preferably >=48mN/m.
Described composite adhesive can be the conventional composite adhesive in this area.The preparation side of described composite adhesive
Method, it is preferably comprised the following steps：Adhesive and ethyl acetate are mixed, you can；More preferably be by adhesive, ethyl acetate and
Curing agent mixes, you can.Described adhesive can be adhesive conventional in the art, and preferably Beijing Gao Meng chemical industry is limited
The model YH2955 of company's production adhesive.Described curing agent can be curing agent commonly used in the art, preferably
For the model YH35 of Beijing Gaomeng Chemical Industry Co., Ltd's production curing agent.Described adhesive and the mass ratio of ethyl acetate
Preferably 1:1~1:2.The addition of described curing agent is preferably 1%~5%, and described percentage refers to curing agent
Quality account for adhesive and the percentage of ethyl acetate gross mass.The coating dry measure of described composite adhesive is preferably 3~5
Gram/m (g/m2)。
Transparent membrane in the second described transparent thin film layer can be transparent membrane commonly used in the art, preferably
Pet film.For described pet film, its thickness is preferably
It it is more preferably 50~75 microns for 50~100 microns；Its light transmittance is preferably 80%~92%, more preferably for 87%~
88%；The glossiness of its 45° angle is preferably 100~160 gloss units, is more preferably 120~140 gloss units；Its mist degree
Preferably 1.5%~3.0%, it is more preferably 2.0%~2.5%；The wetting tension in its sided corona treatment face preferably >=48mN/
m。
Colored ink in described pigmented ink layer can be colored ink commonly used in the art, the present invention preferably on
The serial Colored plastic film gravure printing ink of extra large Toyo Ink Manufacturing Co., Ltd production.The color of described colored ink
Preferably milky.The printing dry measure of described colored ink printing layer is preferably 1~3 gram/m of (g/m2)。
Pressure sensitive adhesive in described pressure-sensitive adhesive layer can be pressure sensitive adhesive commonly used in the art, preferred YCP- in the present invention
F09B types pressure sensitive adhesive (production of Shanghai Toyo Ink Manufacturing Co., Ltd).
Film of the surface with separation property in film layer of the described surface with separation property can be that this area routinely makes
Surface has the film of separation property, preferably mould release membrance or release liners.
In the present invention, the preparation method of described stealthy form laminating film, it is comprised the steps of：
(1) the non-corona surface of the first transparent membrane is subjected to vacuum aluminum-coated working process, obtains vacuum aluminium coated layer, described the
One transparent thin film layer and described vacuum aluminium coated layer form a composite bed, the light transmittance of described composite bed for 3.5%~
4.5%；
(2) corona surface of the second transparent membrane is printed into colored ink, obtains colored ink printing layer；
(3) it is the non-corona surface of the vacuum aluminium coated layer in step (1) and the second transparent membrane is compound using composite adhesive
Together, composite film-stuck main body is obtained；
(4) the colored ink printing layer in the composite film-stuck main body for obtaining step (3), has the thin of separation property with surface
Film is combined with each other by pressure sensitive adhesive, you can, it is 23mic that described surface, which has the thickness of the film of separation property,.
In step (1), the method for described vacuum aluminum-coated working process can be that the vacuum aluminum-coated working process in this area is conventional
Method, the present invention preferably following method：
(a) vacuum storehouse is opened, the first transparent membrane film roll is installed on unreeling shaft, and be convergent on the refill of Scroll
On；
(b) evaporation boat that 10~26 webs are two boron monoxides is installed in vacuum storehouse；
(c) 10~26 disk aluminium wires are installed in vacuum storehouse, aluminium wire purity is more than 99.99%；Described percentage refers to
The quality of aluminium accounts for the percentage of aluminium wire gross weight in aluminium wire；
(d) vacuum storehouse is closed；
(e) it is evacuated, the vacuum values in vacuum storehouse is extracted into 3.0 × 10-4More than mbar；By the temperature of plated film hub
It is set as 5 DEG C~-20 DEG C scopes；It it is 1300 DEG C~1400 DEG C by the operating temperature setting value of evaporation boat；By the wire feed of aluminium wire
Speed is set as 240~700mm/min；The winding speed of plated film is set as 7~14m/s；
(f) when winding speed reaches more than 3m/s, baffle plate window is opened, starts that the first transparent membrane is deposited；Open etc. from
Sub-processing unit；
(g) thickness of vacuum aluminium coated layer is set as 4% ± 0.5%；
(h) uniformity of on-line checking vacuum aluminium coated layer thickness, the uniformity is ± 1%.
In step (2), the method for described colored ink printing is the conventional method in this area.Present invention preferably employs electricity
Brain is to version six-colour press, the corona surface progress full version printing to the second transparent thin film layer, full version background color in printing.It is described
Computer can be commonly used in the art to version six-colour press to version six-colour press, the present invention is preferably
1500C types computer is to version intaglio press.
In step (3), described compound method is the conventional method in this area, preferably following method of the invention：Using
Coating complex machine, with applicator roll, by the vacuum aluminium coated layer and the non-corona surface of the second transparent thin film layer in step (1), using multiple
Rubber alloy stick is combined with each other, and cures, cooling, you can.Wherein, described coating complex machine is preferably model ST1650-
21 coating complex machine.Described applicator roll is preferably the nick version applicator roll that roller number is H20.The method of described curing is
The conventional method in this area.The temperature of described curing is preferably 55 DEG C~60 DEG C.The time of described curing is preferably
More than 24 hours.
In step (4), described compound method can be the conventional method in this area, preferably following method of the invention：Adopt
With coating complex machine, with applicator roll, pressure sensitive adhesive is coated on the painting silicon face that surface has the film of separation property, after prebake,
It is compound with the colored ink printing layer in composite film-stuck main body, cure, cooling, you can.Wherein, described coating complex machine is preferable
Ground is model ST1650-21 coating complex machine.Described applicator roll is preferably the nick version applicator roll that roller number is H30.
The coating dry measure of described pressure sensitive adhesive can be that this area is routinely coated with dry measure, preferably 15~25 grams/m of (g/m2), more
It is 20 grams/m of (g/m goodly2).The method of described prebake can be the conventional method in this area, and the present invention is preferably following
Method：Being coated with the surface of pressure sensitive adhesive, there is the film of separation property to cross drying tunnel prebake.The method of described curing is ability
The conventional method in domain, the temperature of described curing is preferably 40~50 DEG C, is more preferably 45 DEG C, time of described curing compared with
It is 7 days goodly.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, and it is each preferably to produce the present invention
Example.
Agents useful for same and raw material of the present invention are commercially available.
The positive effect of the present invention is：
1st, preparation method of the invention is simple to operate, production cost is low, efficiency high and green；Obtained stealthy form
Laminating film easily removes from glass.Therefore, the preparation method and product have good marketing and practical value.
2nd, stealthy form laminating film of the invention has explosion-proof performance, i.e., using the intelligent electric appliance of stealthy form laminating film
In damaged fragmentation in the case of accident, fragment is tightly sticked together guidance panel by pressure sensitive adhesive and composite film-stuck main body, will not produce
Raw dangerous acute angle or the fragment of splashing.
3rd, patch stealth form laminating film of the invention overcomes that printed patterns on glass are only convenient to be carried out on glass panels,
It is not easy to carried out on globoidal glass the drawbacks of.
Brief description of the drawings
Fig. 1 is the stealthy form laminating film structural representation of embodiment 1.
Embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to described reality
Apply among a scope.The experimental method of unreceipted actual conditions in the following example, conventionally and condition, or according to business
Product specification selects.
Embodiment 1
Name that PET and PET is compound, finally with the embodiment of mould release membrance laminating production stealth form laminating film, and combine
Accompanying drawing 1 becomes apparent from intactly illustrating the present invention.
As shown in figure 1, the compound stealthy form laminating films of PET and PET that the present embodiment is produced include：One first thin transparent
Film layer 11, a vacuum aluminium coated layer 12, a composite adhesive layer 13, one second transparent thin film layer 21, a colored ink printing layer 22,
One pressure-sensitive adhesive layer 23 and a surface have the film layer 31 of separation property.A surface has the film layer of separation property in the present embodiment
31 be a release film layer 31.
Raw material used and source in the preparation method of the shading composite：
1. (abbreviation PET is thin for the first transparent membrane and the second transparent membrane selection pet film
Film), wherein, the thickness of the first transparent membrane is 16 microns；Its light transmittance is 90%~91%；The light of glossiness 156 of its 45° angle
Damp unit, its mist degree are 1.58%；Wetting tension >=the 48mN/m in its sided corona treatment face.The thickness of second transparent membrane is 75 micro-
Rice, its light transmittance 87%~88%, the glossiness of its 45° angle is 133 gloss units, and its mist degree is 2.20%, its sided corona treatment
Wetting tension >=the 48mN/m in face.
2. vacuum metallization processes are aluminized, equipment is purchased from German Lai Bao photoelectricity technology corporation, Ltd.s, the type packaging materials of PRO-M 2100
Coiled material coating system.
3. the serial Colored plastic film intaglio printing of the preferred Shanghai Toyo Ink Manufacturing Co., Ltd production of colored ink
Ink.
4. printing equipment is purchased from Wenzhou Xin Xu printing packagings Machinery Co., Ltd., 1500C types computer is to version intaglio press.
5. composite adhesive is made by following method：The model YH2955's of Beijing Gaomeng Chemical Industry Co., Ltd's production
Adhesive, mixed with ethyl acetate.The mass ratio of adhesive and ethyl acetate is 1:1；Usually required in composite adhesive
Add a small amount of curing agent, the model YH35 of the preferred Beijing Gaomeng Chemical Industry Co., Ltd's production of the present embodiment curing agent, Gu
The addition of agent is 1%.
6. coating complex machine is purchased from Zhongshan City Songde Coating Machine Co., Ltd, model：ST1650-21；Applicator roll is roller
Number for H20 nick version applicator roll or H30 nick version applicator roll.
7. pressure sensitive adhesive is the YCP-F09B type pressure sensitive adhesives of Shanghai Toyo Ink Manufacturing Co., Ltd production.
The preparation method of the stealthy form laminating film is as follows：
(1) the non-corona process face of the first transparent thin film layer 11 is subjected to vacuum aluminum-coated working process and obtains vacuum aluminium coated layer
13, the first described transparent thin film layer 11 and described vacuum aluminium coated layer 13 form a composite bed, the printing opacity of described composite bed
Rate is 3.5%~4.5%；The method of described vacuum aluminum-coated working process is as follows：
(a) vacuum storehouse is opened, the first transparent membrane film roll is installed on unreeling shaft, and film order is worn as defined in equipment
First transparent membrane is convergent on the refill of Scroll；
(b) evaporation boat (films of 1350 mm in width of production) that 16 webs are two boron monoxides is installed in vacuum storehouse；
(c) the 16 disk aluminium wires films of 1350 mm in width (production) are installed in vacuum storehouse, aluminium wire purity be 99.99% with
On；
(d) vacuum storehouse is closed；
(e) it is evacuated, the vacuum values in vacuum storehouse is extracted into 3.0 × 10-4More than mbar；By the temperature of plated film hub
It is set as 0 DEG C~-20 DEG C scopes；It it is 1300 DEG C~1400 DEG C by the operating temperature setting value of evaporation boat；By the wire feed of aluminium wire
Speed is set as 240~700mm/min；The winding speed of plated film is set as 7~14m/s；
(f) when speed reaches more than 3m/s, baffle plate window is opened, starts that the first transparent membrane is deposited；Open at plasma
Manage device；
(g) thickness of vacuum aluminium coated layer is set as 4% ± 0.5%；
(h) uniformity of on-line checking vacuum aluminium coated layer thickness, the requirement of the uniformity is ± 1%；Range of transmittance 4 ±
0.5% the first transparent membrane for being coated with vacuum aluminium coated layer.
(2) full version printing is carried out to the corona surface of the second transparent membrane using printing machine, milky full version bottom in printing
Color, the printing dry measure of colored ink is 1~3g/m2。
(3) coating complex machine is used, composite adhesive is first coated on to the non-corona surface of the second transparent membrane with applicator roll,
After crossing drying tunnel prebake, it is combined with each other with vacuum aluminium coated layer 13, cures, cools down, obtains compound laminating film main body.Wherein, cure
Temperature be 55 DEG C~60 DEG C, time of curing is more than 24 hours.
(4) coating complex machine is used, the painting silicon face that pressure sensitive adhesive is coated on to 23mic thickness mould release membrances with applicator roll (applies
Cloth dry measure is 20 grams/m), after crossing drying tunnel prebake, answered with the colored ink printing layer 22 of compound laminating film main body
Close, so as to obtain the adhesive sticker stealth form laminating film main body that integral light-transmitting rate is 3 ± 1%, (now tearing film can find to press
Quick glue has turned to be overlying on the surface of compound laminating film, also referred to as pressure sensitive membrane), after the completion of winding, compound good film roll is transferred to immediately
The maturation process of seven days is carried out in the curing chamber that 45 DEG C of constant temperature, maturation process, which finishes, should remove curing chamber natural cooling immediately, i.e.,
Obtain stealthy form laminating film.
Stealthy form laminating film is made by the above method to be bonded with glass panel through downstream client, refill assigned in refrigerator or
Tried out in the high-grade electric appliances such as air-conditioning, assessment result is：Outward appearance is magnificent, safe to use, the stealthy effect of form is excellent, touch control instruction
Fault rate average value 0.02%, telecommand fault rate average value 0.01%, the design requirement better than≤0.2%；Experiment 50
Pad pasting glass panel, from the parallel nature fell of 1.5 meters of eminences in cement flooring, result of the test：50 pad pasting glass panels are whole
Fragmentation, but fragment departs from pad pasting glass body after an only pad pasting glass panel ruptures, and depart from pad pasting glass body
Fragment number is 1；The fragment number for departing from pad pasting glass body reaches the safety post for being less than or equal to 5 of Customer design requirement
Accurate (in terms of 1 pad pasting glass panel)；Glass sheet quality qualification rate >=99.5% is developed, pastes curved glass panel quality qualification rate
>=99%, it is better than >=98% and >=95% design requirement respectively；It is fully able to meet requirement.
Embodiment 2
As shown in figure 1, the compound stealthy form laminating films of PET and PET that the present embodiment is produced include：One first thin transparent
Film layer 11, a vacuum aluminium coated layer 12, a composite adhesive layer 13, one second transparent thin film layer 21, a colored ink printing layer 22,
One pressure-sensitive adhesive layer 23 and a surface have the film layer 31 of separation property.A surface has the film layer of separation property in the present embodiment
31 be an off-style paper layer 31.
Raw material used and source in the preparation method of the shading composite：
1. (abbreviation PET is thin for the first transparent membrane and the second transparent membrane selection pet film
Film), wherein, the thickness of the first transparent membrane is 12 microns；Light transmittance is 87%~88%；The gloss list of glossiness 122 of 45° angle
Position, mist degree 2.88%；Wetting tension >=the 52mN/m in sided corona treatment face.The thickness of second transparent membrane is 100 microns, and its is saturating
Light rate 86%~87%, the glossiness of its 45° angle is 112 gloss units, and its mist degree is 2.94%, the wetting in its sided corona treatment face
Tension force >=52mN/m.
2. vacuum metallization processes are aluminized, equipment is purchased from German Lai Bao photoelectricity technology corporation, Ltd.s, the type packaging materials of PRO-M 2100
Coiled material coating system.
3. the serial Colored plastic film intaglio printing of the preferred Shanghai Toyo Ink Manufacturing Co., Ltd production of colored ink
Ink.
4. printing equipment is purchased from Wenzhou Xin Xu printing packagings Machinery Co., Ltd., 1500C types computer is to version intaglio press.
5. composite adhesive is made by following method：The model YH2955's of Beijing Gaomeng Chemical Industry Co., Ltd's production
Adhesive, mixed with ethyl acetate.The mass ratio of adhesive and ethyl acetate is 1:2；Usually required in composite adhesive
Add a small amount of curing agent, the model YH35 of the preferred Beijing Gaomeng Chemical Industry Co., Ltd's production of the present embodiment curing agent, Gu
The addition of agent is 5%.
6. coating complex machine is purchased from Zhongshan City Songde Coating Machine Co., Ltd, model：ST1650-21；Applicator roll is roller
Number for H20 nick version applicator roll or H30 nick version applicator roll.
7. pressure sensitive adhesive is the YCP-F09B type pressure sensitive adhesives of Shanghai Toyo Ink Manufacturing Co., Ltd production.
The preparation method of the stealthy form laminating film is as follows：
(1) the non-corona process face of the first transparent thin film layer 11 is subjected to vacuum aluminum-coated working process and obtains vacuum aluminium coated layer
13, the first described transparent thin film layer 11 and described vacuum aluminium coated layer 13 form a composite bed, the printing opacity of described composite bed
Rate is 3.5%~4.5%；The method of described vacuum aluminum-coated working process is as follows：
(a) vacuum storehouse is opened, the first transparent membrane film roll is installed on unreeling shaft, and film order is worn as defined in equipment
First transparent membrane is convergent on the refill of Scroll；
(b) evaporation boat (films of 1350 mm in width of production) that 16 webs are two boron monoxides is installed in vacuum storehouse；
(c) the 16 disk aluminium wires films of 1350 mm in width (production) are installed in vacuum storehouse, aluminium wire purity be 99.99% with
On；
(d) vacuum storehouse is closed；
(e) it is evacuated, the vacuum values in vacuum storehouse is extracted into 3.0 × 10-4More than mbar；By the temperature of plated film hub
It is set as 0 DEG C~-20 DEG C scopes；It it is 1300 DEG C~1400 DEG C by the operating temperature setting value of evaporation boat；By the wire feed of aluminium wire
Speed is set as 240~700mm/min；The winding speed of plated film is set as 7~14m/s；
(f) when speed reaches more than 3m/s, baffle plate window is opened, starts that the first transparent membrane is deposited；Open at plasma
Manage device；
(g) thickness of vacuum aluminium coated layer is set as 4% ± 0.5%；
(h) uniformity of on-line checking vacuum aluminium coated layer thickness, the requirement of the uniformity is ± 1%；Range of transmittance 4 ±
0.5% the first transparent membrane for being coated with vacuum aluminium coated layer.
(2) full version printing is carried out to the corona surface of the second transparent membrane using printing machine, milky full version bottom in printing
Color, the printing dry measure of colored ink is 1~3g/m2。
(3) coating complex machine is used, composite adhesive is first coated on to the non-corona surface of the second transparent membrane with applicator roll,
After crossing drying tunnel prebake, it is combined with each other with vacuum aluminium coated layer 13, cures, cools down, obtains compound laminating film main body.Wherein, cure
Temperature be 55 DEG C~60 DEG C, time of curing is more than 24 hours.
(4) coating complex machine is used, pressure sensitive adhesive is coated on to the painting silicon table for the release liners that thickness is 23mic with applicator roll
Face, (coating dry measure is 20 grams/m), after crossing drying tunnel prebake, the colored ink printing layer 22 with compound laminating film main body
Carry out it is compound, so as to obtain integral light-transmitting rate be 3 ± 1% adhesive sticker stealth form laminating film main body (now tear film meeting
It was found that pressure sensitive adhesive has turned to be overlying on the surface of compound laminating film, also referred to as pressure sensitive membrane), after the completion of winding, compound good film roll is stood
It is transferred to the maturation process carried out in the curing chamber of 45 DEG C of constant temperature seven days, maturation process finishes that should to remove curing chamber immediately naturally cold
But, stealthy form laminating film is produced.
Stealthy form laminating film is made by the above method to be bonded with glass panel through downstream client, refill assigned in refrigerator or
Tried out in the high-grade electric appliances such as air-conditioning, assessment result is：Outward appearance is magnificent, safe to use, the stealthy effect of form is qualified, and touch control refers to
Make fault rate average value 0.18%, telecommand fault rate average value 0.10%, reach≤0.2% design requirement；Experiment 50
Piece pad pasting glass panel, from the parallel nature fell of 1.5 meters of eminences in cement flooring, result of the test：50 pad pasting glass panels are complete
Portion's fragmentation, but fragment departs from pad pasting glass body after an only pad pasting glass panel ruptures, and depart from pad pasting glass body
Fragment number be 1；The fragment number for departing from pad pasting glass body reaches the safety for being less than or equal to 5 of Customer design requirement
Standard (in terms of 1 pad pasting glass panel)；Glass sheet quality qualification rate >=99.6% is developed, patch curved glass panel quality is qualified
Rate >=98%, it is better than >=98% and >=95% design requirement respectively；Reach requirement.
Comparison is further right in terms of stealthy form laminating film light transmittance is less than 2% and higher than 4% two again below
This patent method illustrates.The purpose emphasis of comparative example is to illustrate that stealthy form laminating film light transmittance must control
The importance and indispensability of scope 3 ± 1%.
Comparative example 1
The structure that the structural representation of obtained stealthy form laminating film can be found in embodiment 1 in comparative example 1 is shown
It is intended to, in preparation technology in addition to specified otherwise, other processes and embodiment 1 are completely the same.
The thickness of first transparent membrane is 16 microns；Its light transmittance is 90%~91%；The light of glossiness 156 of its 45° angle
Damp unit, its mist degree are 1.58%；Wetting tension >=the 52mN/m in its sided corona treatment face.
The method and condition and embodiment 1 of vacuum aluminum-coated working process are just the same, but are coated with the first of vacuum aluminium coated layer
The light transmittance of transparent membrane is 5 ± 0.5%, and final production goes out the adhesive sticker stealth form that finished product integral light-transmitting rate is 5 ± 0.5%
Laminating film.
Stealthy form laminating film is made by the above method to be bonded with glass panel through downstream client, refill assigned in refrigerator or
Tried out in the high-grade electric appliances such as air-conditioning, assessment result is：Outward appearance is magnificent, safe to use, the stealthy effect of form is poor, touch control instruction
Fault rate average value 0.01%, telecommand fault rate average value 0.01%, the design requirement better than≤0.2%；Experiment 50
Pad pasting glass panel, from the parallel nature fell of 1.5 meters of eminences in cement flooring, result of the test：50 pad pasting glass panels are whole
Fragmentation, but fragment departs from pad pasting glass body after an only pad pasting glass panel ruptures, and depart from pad pasting glass body
Fragment number is less than 2；The fragment number for departing from pad pasting glass body reaches the safety post for being less than or equal to 5 of design requirement
Accurate (in terms of 1 pad pasting glass panel)；Glass sheet quality qualification rate >=99.5% is developed, pastes curved glass panel quality qualification rate
>=99%, it is better than >=98% and >=95% design requirement respectively；But indoors under the conditions of available light or light-illuminating, naked eyes
I.e. it can be seen that control panel display screen below decoration panel, so as to have a strong impact on the uniformity of electrical equipment decorative appearance, due to
Its form stealth effect is bad, it is impossible to meets requirement, is determined as bad.
Comparative example 2
The structure that the structural representation of obtained stealthy form laminating film can be found in embodiment 1 in comparative example 2 is shown
It is intended to, in preparation technology in addition to specified otherwise, other processes and embodiment 2 are completely the same.
The thickness of first transparent membrane is 12 microns；Its light transmittance is 87%~88%；The glossiness of its 45° angle is 122
Gloss unit, its mist degree are 2.88%；Wetting tension >=the 52mN/m in its sided corona treatment face.
The method and condition and embodiment 1 of vacuum aluminum-coated working process are just the same, but are coated with the first of vacuum aluminium coated layer
The light transmittance of transparent membrane is 2 ± 1%, and final production goes out the adhesive sticker stealth form that finished product integral light-transmitting rate is 1.5 ± 0.5%
Laminating film.
Stealthy form laminating film is made by the above method to be bonded with glass panel through downstream client, refill assigned in refrigerator or
Tried out in the high-grade electric appliances such as air-conditioning, assessment result is：Outward appearance is magnificent, safe to use, the stealthy effect of form is excellent, touch control instruction
Fault rate average value 0.22%, the design requirement of telecommand fault rate average value 0.26%, not up to≤0.2%；Experiment 50
Piece pad pasting glass panel, from the parallel nature fell of 1.5 meters of eminences in cement flooring, result of the test：50 pad pasting glass panels are complete
Portion's fragmentation, but fragment departs from pad pasting glass body after an only pad pasting glass panel ruptures, and depart from pad pasting glass body
Fragment number be less than 2；The fragment number for departing from pad pasting glass body reaches the safety for being less than or equal to 5 of design requirement
Standard (in terms of 1 pad pasting glass panel)；Glass sheet quality qualification rate >=99.5% is developed, patch curved glass panel quality is qualified
Rate >=99%, it is better than >=98% and >=95% design requirement respectively；But because instruction success rate is below standard, it is impossible to meet to use and want
Ask.
Claims (9)
1. a kind of stealthy form laminating film, it is characterised in that including one first superposed transparent thin film layer, one vacuum aluminum-coated
Layer, a composite adhesive layer, one second transparent thin film layer, a colored ink printing layer, a pressure-sensitive adhesive layer, and a surface have
The film layer of separation property, wherein, the first described transparent thin film layer and described vacuum aluminium coated layer form a composite bed, described
The light transmittance of composite bed is 3.5%~4.5%；The light transmittance of described stealthy form laminating film is 2%~4%；Described table
It is 23mic that face, which has the thickness of the film layer of separation property,.
2. stealthy form laminating film as claimed in claim 1, it is characterised in that the light transmittance of described stealthy form laminating film
For 2.5%~3.5%.
3. stealthy form laminating film as claimed in claim 1, it is characterised in that described the first transparent thin film layer or described
The second transparent thin film layer in transparent membrane be separately pet film.
4. stealthy form laminating film as claimed in claim 3, it is characterised in that described in the first described transparent thin film layer
Pet film thickness be 8~30 microns；Light transmittance is 80%~92%；The glossiness of 45° angle
For 100~160 gloss units；Mist degree is 1.5%~3.0%；Wetting tension >=the 48mN/m in sided corona treatment face；Described first
The non-corona process face of transparent thin film layer is the face being sticked with described vacuum aluminium coated layer, and described sided corona treatment face is described
The reverse side of non-corona process face；
And/or in the second described transparent thin film layer, the thickness of described pet film for 50~
100 microns；Light transmittance is 80%~92%；The glossiness of 45° angle is 100~160 gloss units；Mist degree be 1.5%~
3.0%；Wetting tension >=the 48mN/m in sided corona treatment face；The sided corona treatment face of the second described transparent thin film layer be with it is described
The face that colored ink printing layer is sticked.
5. stealthy form laminating film as claimed in claim 1, it is characterised in that described composite adhesive layer uses compound
The preparation method of adhesive comprises the following steps：Adhesive and ethyl acetate are mixed, you can.
6. stealthy form laminating film as claimed in claim 5, it is characterised in that the preparation method bag of described composite adhesive
Include the following steps：Adhesive, ethyl acetate and curing agent are mixed, you can.
7. stealthy form laminating film as claimed in claim 6, it is characterised in that the preparation method of described composite adhesive
In, the mass ratio of described adhesive and ethyl acetate is 1:1~1:2；And/or the addition of described curing agent be 1%~
5%, described percentage refers to that the quality of curing agent accounts for adhesive and the percentage of ethyl acetate gross mass；It is and/or described
The coating dry measure of composite adhesive is 3~5 grams/m.
8. stealthy form laminating film as claimed in claim 1, it is characterised in that the printing of described colored ink printing layer is done
Measure as 1~3 gram/m.
9. stealthy form laminating film as claimed in claim 1, it is characterised in that described surface has the film layer of separation property
It is mould release membrance or release liners that middle surface, which has the film of separation property,.
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| CN201410264238.5A CN105291507B (en) | 2014-06-13 | 2014-06-13 | A kind of stealthy form laminating film |
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| CN201410264238.5A CN105291507B (en) | 2014-06-13 | 2014-06-13 | A kind of stealthy form laminating film |
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| CN105291507A CN105291507A (en) | 2016-02-03 |
| CN105291507B true CN105291507B (en) | 2018-01-16 |
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| CN112143390B (en) * | 2020-09-12 | 2023-05-09 | 浙江辉柯纸塑制品有限公司 | Unreeling system and process of low-tensile PVC film |
| CN112297417B (en) * | 2020-11-12 | 2023-01-24 | 重庆建安仪器有限责任公司 | Film pasting process for aluminized MYLAR film |
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| JPH1181609A (en) * | 1997-09-09 | 1999-03-26 | Sankyo Kasei Kogyo Kk | Wall surface fancy sheet |
| CN1492267A (en) * | 2002-04-12 | 2004-04-28 | y一嘉 | Shading film and end device |
| CN101180179A (en) * | 2005-05-25 | 2008-05-14 | 三菱树脂株式会社 | Laminate for name plate preparation which can prevent fluctuation in reflected light |
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|---|---|
| CN105291507A (en) | 2016-02-03 |
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Address after: Song Ying Road Qingpu Industrial Park Qingpu District Shanghai City, No. 1288, 201706 Patentee after: Shanghai Yongchao New Material Technology Co.,Ltd. Address before: Song Ying Road Qingpu Industrial Park Qingpu District Shanghai City, No. 1288, 201706 Patentee before: SHANGHAI RADIX VACUUM METALLISING Co.,Ltd. |
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