CN107570326A - A kind of method of smithsonite type zinc oxide ore flotation desilication - Google Patents
A kind of method of smithsonite type zinc oxide ore flotation desilication Download PDFInfo
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- CN107570326A CN107570326A CN201710817737.6A CN201710817737A CN107570326A CN 107570326 A CN107570326 A CN 107570326A CN 201710817737 A CN201710817737 A CN 201710817737A CN 107570326 A CN107570326 A CN 107570326A
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- flotation
- smithsonite
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Abstract
The present invention relates to a kind of method of smithsonite type zinc oxide ore flotation desilication, and in particular to the flotation separation method of smithsonite and quartz, belongs to Mineral Processing Engineering field mineral floating separation technology field.A kind of method that smithsonite type zinc oxide ore flotation removes silicon, the mixing sample ore of pending smithsonite and quartz is mixed with deionized water, wherein deionized water and sample ore mass ratio are 3~5:1;First then collecting agent is added, collector dosage is 300~360g/t into the ore pulp to stir as pH adjuster using sodium carbonate;The flowsheet of slurry agitation for adding collecting agent is uniformly subjected to flotation afterwards.Wherein, the collecting agent is N, the double fatty acyl group ethylene diamine dipropionic acid sodium of N '.Flotation smithsonite silicon removing method regime of agent proposed by the present invention is simple, and technological process is simple, easy to operate, has preferable commercial viability prospect.
Description
Technical field
The present invention relates to a kind of method of smithsonite type zinc oxide ore flotation desilication, and in particular to smithsonite and quartz
Flotation separation method, belong to Mineral Processing Engineering field mineral floating separation technology field.
Background technology
The consumption figure of zinc resource is number three in non-ferrous metal, is number four in metal.Zinc is in dry external condition
Under relatively stable, and surface easily one layer of fine and close zinc carbonate film of generation under humid conditions, therefore can be to other materials table
Face is handled.Current most of zinc metal is applied in zinc-plated industry.In addition zinc rubber, battery, shielding material, pigment,
The industry such as printing, paint are also widely used.In recent years, with the rapid growth of China's economic, need of the China for zinc resource
The amount of asking also increases.In 2014, China's zinc concentrate import volume reached 219.82 ten thousand tons.Therefore, the ore dressing of zinc ore is improved
Sustainable development of the index to zinc resource has great importance.
Smithsonite is a kind of important mineral in zinc resource.At present floatation be the most important recovery method of smithsonite it
One.But because smithsonite is more crisp, therefore easily produces sludge in grinding process and be unfavorable for the sorting of valuable mineral and increase medicine
Agent usage amount.In addition smithsonite is a kind of carbonate mineral in itself, and easily dissolving produces zinc ion to silicate arteries and veins in ore pulp
Stone ore produce life-stylize effect, thus using fatty acid collecting agent also can collecting silicate gangue mineral, so as to cause concentrate
Grade is not high.Sulfidization-amine method is the most commonly used method for floating at present.But both need to add activator in floatation process to water chestnut
Zinc ore, which is activated, will also add inhibitor the gangue minerals such as quartz are suppressed, so as to cause flotation flowsheet i.e. complicated and difficult
With control.Therefore probing into new smithsonite ore floatation process, the rate of recovery for improving smithsonite provide with grade to China's zinc
Efficiently utilizing for source is significant.
The content of the invention
The present invention provides a kind of method of smithsonite type zinc oxide ore flotation drop silicon, and main purpose is according to new collecting
Agent realizes the effective of mineral to smithsonite and the different flotation behaviors of gangue mineral quartz by adding suitable regulator
Sorting.This method technological process and regime of agent are simple, and can realize the target of smithsonite ore floatation drop silicon.
A kind of method of smithsonite type zinc oxide ore flotation desilication, methods described include following processing steps:
(1) it is 1 in mass ratio by pending sample ore and water:3~5 mixing, size mixing 1~3min;Alternatively, into ore pulp
Add pH regulators to adjust slurry pH to 10~12, then size mixing 2~3min again;
(2) collecting agent N, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium, stirring are added into ore pulp obtained by step (1)
2min, wherein, the dosage of the collecting agent is 300~360g/t;Afterwards by add collecting agent flowsheet of slurry agitation it is uniform after floated
Choosing, 3~5min of flotation time.
In the method for smithsonite type zinc oxide ore flotation desilication of the present invention, in step (1), by pending sample ore
It is 1 in mass ratio with water:3~5 mixing, size mixing 1~3min;The then pH value of measurement gained ore pulp, as ore pulp pH value determination is
Required slurry pH, then directly carry out step (2);If ore pulp pH value determination is not the pH value of required ore pulp, then adjusted using pH
Agent adjusts slurry pH to required slurry pH, and then size mixing 2~3min again.
Above-mentioned " required slurry pH " can be 10~12 in arbitrary value, it can artificially be limited, in order to investigate and
Obtain the flotation results under condition of different pH.
In above-mentioned technical proposal, described " dosage of collecting agent refers to the pending sample ore institutes of every 1t for 300~360g/t "
It is 300~360g with the amount of collecting agent.
Product i.e. mine tailing in flotation froth product i.e. concentrate and groove is respectively dried after further, flotation terminates, weighed,
Calculate the rate of recovery and chemically examine grade.
In above-mentioned technical proposal, preferably pending sample ore be smithsonite with quartz artificial mixed ore, and smithsonite with
The mass ratio of quartz is 3:17.
In above-mentioned technical proposal, preferably it is described size mixing for:Ore pulp is stirred with 1600~1992r/min stir speed (S.S.)
Mix.
In above-mentioned technical proposal, preferably described pH adjuster is Na2CO3Solution.The method of the invention is to described
Na2CO3Solution has no particular/special requirement.
Compared with traditional method for floating, the beneficial effect of this method is:Smithsonite type zinc oxide ore proposed by the present invention
The method regime of agent of stone flotation desilication is simple, only need to add collecting agent N, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium and pH
It is worth regulator Na2CO3The target of smithsonite ore floatation drop silicon can be achieved, thus it is easy to operate, there is well industrial feasible
Property.
Brief description of the drawings
Fig. 1 is the process chart of zinc oxide ore flotation desilication described in embodiment 1.
Embodiment
Following non-limiting examples can make one of ordinary skill in the art be more fully understood the present invention, but not with
Any mode limits the present invention.
Test method described in following embodiments, it is conventional method unless otherwise specified;The reagent and material, such as
Without specified otherwise, commercially obtain.
Sample granularity prepared by smithsonite, quartz in following embodiments (refers to sample granularity to exist for -0.074mm
Below 0.074mm), smithsonite, quartzy purity are respectively 96.34%, 99.42%.
The XFGII-5 type hanging trough flotators used in following embodiments, purchased from Jilin Province Prospect Machinery Plant.
The collecting agent N, N ' used in following embodiments-bis- fatty acyl groups ethylene diamine dipropionic acid sodium is made as follows,
Concretely comprise the following steps:
Under conditions of 50 DEG C of reaction temperature, methyl acrylate is added dropwise into the there-necked flask equipped with ethylenediamine, works as ethylenediamine
It is 1 with methyl acrylate mol ratio:Stop being added dropwise when 2.Constant temperature flows back after being added dropwise completely, reacts 4h.After reaction terminates, to production
Thing is evaporated under reduced pressure, and steams unreacted product, obtains intermediate product.
Under conditions of 45 DEG C of reaction temperature, to equipped with lauric three-necked flask be added dropwise thionyl chloride to laurate with
Thionyl chloride mol ratio is 1:1.02.Reaction 5h, is then evaporated under reduced pressure to obtain fat acyl chloride to product after being added dropwise completely.
Fat acyl chloride is added dropwise to intermediate product, while controls the pH of reaction system for 10 (by the way that sodium hydroxide solution is added dropwise
The pH for controlling reaction system is 10), when intermediate product and fat acyl chloride mol ratio are 1:Terminate to be added dropwise after 2, obtain N, N '-bis- fat
Fat Ethylene Diamine dipropionic acid formicester.Yu Shuizhong, under the conditions of 90 DEG C, N, N '-bis- fatty acyl groups ethylene diamine dipropionic acid formicester and hydrogen
Sodium oxide molybdena carries out saponification and obtains final product N, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium, wherein, sodium hydroxide and N,
The mol ratio of N '-bis- fatty acyl groups ethylene diamine dipropionic acid formicester is 2:1.
Embodiment 1
(1) it is 3 by mass ratio:17 smithsonite and quartz configurations weigh 5g sample ores and are put into flotation cell into mixing sample ore
In, deionized water is then added, wherein, the mass ratio of sample ore and deionized water is 1:5;Using hanging trough flotator, in 1992r/
Under conditions of min, the 2min that sizes mixing is stirred;
(2) after sizing mixing, at 13 DEG C of room temperature, 1mol/L sodium carbonate liquor is added as pH adjuster, pH values of pulp is adjusted
It is whole to stir 2min to 10.82,300g/t N is then added, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium stirs as collecting agent
Flotation, flotation time 3min are carried out after mixing 2min.It is product i.e. mine tailing point in concentrate and groove to froth pulp after flotation terminates
Hong Gan, it not weigh, and sample examination grade, the rate of recovery is calculated, Zn grades are that the 40.40%, rate of recovery can wherein in flotation concentrate
Up to 82.01%.
Embodiment 2
(1) it is 3 by mass ratio:17 smithsonite and quartz configurations weigh 5g sample ores and are put into flotation cell into mixing sample ore
In, deionized water is then added, wherein, the mass ratio of sample ore and deionized water is 1:5;Using hanging trough flotator, in 1992r/
Under conditions of min, the 2min that sizes mixing is stirred;
(2) after sizing mixing, at 13 DEG C of normal temperature, 1mol/L sodium carbonate liquor is added as pH adjuster, pH values of pulp is adjusted
It is whole to stir 2min to 10.25,300g/t N is then added, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium stirs as collecting agent
Flotation, flotation time 3min are carried out after mixing 2min.It is product i.e. mine tailing point in concentrate and groove to froth pulp after flotation terminates
Hong Gan, it not weigh, and sample examination grade, the rate of recovery is calculated, Zn grades are that the 36.60%, rate of recovery can wherein in flotation concentrate
Up to 89.67%.
Embodiment 3
(1) it is 3 by mass ratio:17 smithsonite and quartz configurations weigh 5g sample ores and are put into flotation cell into mixing sample ore
In, deionized water is then added, wherein, the mass ratio of sample ore and deionized water is 1:5;Using hanging trough flotator, in 1992r/
Under conditions of min, the 2min that sizes mixing is stirred;
(2) after sizing mixing, at 25 DEG C of normal temperature, 1mol/L sodium carbonate liquor is added as pH adjuster, pH values of pulp is adjusted
It is whole to stir 2min to 11.20,360g/t N is then added, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium stirs as collecting agent
Flotation, flotation time 3min are carried out after mixing 2min.It is product i.e. mine tailing point in concentrate and groove to froth pulp after flotation terminates
Hong Gan, it not weigh, and sample examination grade, the rate of recovery is calculated, Zn grades are that the 41.7%, rate of recovery is reachable wherein in flotation concentrate
82.31%.
Embodiment 4
(1) it is 3 by mass ratio:17 smithsonite and quartz configurations weigh 5g sample ores and are put into flotation cell into mixing sample ore
In, deionized water is then added, wherein, the mass ratio of sample ore and deionized water is 1:5;Using hanging trough flotator, in 1992r/
Under conditions of min, the 2min that sizes mixing is stirred;
(2) after sizing mixing, after sizing mixing, at 25 DEG C of normal temperature, 1mol/L sodium carbonate liquor is added as pH adjuster, by ore deposit
Slurry pH is adjusted to 11.08, is stirred 2min, is then added 360g/t N, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium is used as and caught
Agent is received, flotation, flotation time 3min are carried out after stirring 2min.It is product in concentrate and groove to froth pulp after flotation terminates
I.e. mine tailing is respectively dried, weighed, and sample examination grade, calculates the rate of recovery, and Zn grades are 35.8%, returned wherein in flotation concentrate
Yield is up to 83.87%.
Claims (4)
- A kind of 1. method of smithsonite type zinc oxide ore flotation desilication, it is characterised in that:Methods described walks including following techniques Suddenly:(1) it is 1 in mass ratio by pending sample ore and water:3~5 mixing, size mixing 1~3min;Alternatively, added into ore pulp PH regulators adjust slurry pH to 10~12, and then size mixing 2~3min again;(2) collecting agent N, N '-bis- fatty acyl groups ethylene diamine dipropionic acid sodium are added into ore pulp obtained by step (1), stirs 2min, its In, the dosage of the collecting agent is 300~360g/t;The flowsheet of slurry agitation for adding collecting agent is uniformly subjected to flotation, flotation afterwards afterwards 3~5min of time.
- 2. according to the method for claim 1, it is characterised in that:Pending sample ore is that smithsonite mixes with the artificial of quartz Ore deposit, and the mass ratio of smithsonite and quartz is 3:17.
- 3. according to the method for claim 1, it is characterised in that:PH adjuster is Na2CO3Solution.
- 4. according to the method for claim 1, it is characterised in that:Flotation terminate after by flotation froth product i.e. in concentrate and groove Product is that mine tailing is respectively dried, weighed, calculating the rate of recovery and chemically examining grade.
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