CN107556946A - A kind of special paper tube adhesive of paper - Google Patents
A kind of special paper tube adhesive of paper Download PDFInfo
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- CN107556946A CN107556946A CN201710873680.1A CN201710873680A CN107556946A CN 107556946 A CN107556946 A CN 107556946A CN 201710873680 A CN201710873680 A CN 201710873680A CN 107556946 A CN107556946 A CN 107556946A
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Abstract
The invention discloses a kind of special paper tube adhesive of paper, belong to adhesive techniques field.Nano silicon, silane coupler and ethanol solution are stirred reaction by the present invention, then filtered, wash and dry, modified manometer silicon dioxide, then by gained modified manometer silicon dioxide and absolute ethyl alcohol ultrasonic disperse, obtain modified manometer silicon dioxide dispersion liquid；Glass fibre and modified manometer silicon dioxide dispersion liquid are mixed with dipping, then by the glass fibre drying after dipping to constant weight, impregnated glass fiber is mixed into immersion with dopamine solution, then the glass fibre drying after immersion is obtained into modified glass-fiber to constant weight；By polyvinyl alcohol, cyclodextrine derivatives and water are stirred, and add polyvinyl acetate emulsion, cellulase, and glass fibre and polystyrene emulsion are stirred, and produce the special paper tube adhesive of paper.The special paper tube adhesive of paper prepared by technical solution of the present invention has the characteristics of excellent adhesive property, promotes it to be applied and development in broader field.
Description
Technical field
The invention discloses a kind of special paper tube adhesive of paper, belong to adhesive techniques field.
Background technology
With the improvement of living standards, paper products industry is advanced by leaps and bounds, the dosage of paper tube adhesive also increasingly increases.It is for example, pressure-sensitive
The paper tube of adhesive tape, the spool of weaving, the composite packaging tank of food and drink, the pipe crimping and silk, cloth, paper of plastic sheeting
The mechanization production pipe crimping of product, leather etc. is packed for paper tube, is required for substantial amounts of paper tube and reel.And as the auxiliary of the said goods
Material is helped, its paper tube and reel there must be a kind of excellent performance, and the high paper tube adhesive of adhesion strength is to ensure its quality.Paper tube glue
Stick is commonly called as paper tube adhesive, paper web glue etc., is a kind of special-purpose adhesive for making various paper tubes, fiber drum, paper can and related paper products.
The deformable sheet materials such as paper, cloth, plastic foil, metal foil, commonly use paper web（Paper tube）Wind bundled, make paper tube core web-like finished product.These
Paper web is usually to be rolled, be bonded with brown paper or other raw material paper machineries, and binder used is referred to as paper web glue.
The conventional paper tube of tradition（Cylinder）Glue mainly has gelatin, gelatinized starch（Including oxidized starch and modified starch）, poly-vinegar
Sour vac emulsion（White glue with vinyl）, PVA solution etc..Wherein gelatin, starch adhesive are because adhesive strength is low, storage period short base
This without using；The initial bonding strength of polyvinyl acetate emulsion is preferable, and stability is also relatively strong, but vinyl acetate is rigid monomer, and poly-vinegar is sour
The glass transition temperature of vac emulsion is higher, the film embrittlement that it is formed.In winter, because temperature is relatively low, emulsion particle cannot gather
Collection melting forms complete film, and becomes ftracture shape or powdery, so that winter is in use, the paper tube made will produce " holding tube "
Phenomenon.Primary raw material additionally, due to manufacture polyvinyl acetate emulsion is vinyl acetate, price costly, so poly-vinegar acid second
The production cost of alkene emulsion is higher, and the compressive resistance after its bonding is poor, and therefore, the application of polyvinyl acetate emulsion is difficult all the time
To promote.It is the relatively low amylan of production cost that paper tube glue, which also has a kind of, but the initial bonding strength of amylan is relatively low, rate of drying
Slowly, be not as strong as polyvinyl acetate emulsion bonding force, and it is easily mouldy after use.
Therefore, adhesive property is more concerned by people, only constantly carried as one big standard of evaluation paper tube adhesive performance
The adhesion strength of high paper tube adhesive, its application value could be improved, expand its application.
The content of the invention
The present invention solves the technical problem of：For traditional paper tube gluing knot low intensity, there is provided a kind of paper is special
Use paper tube adhesive.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of special paper tube adhesive of paper, is made up of the raw material of following parts by weight：50~60 parts of polyvinyl alcohol, 10~20 parts poly-
Vinyl acetate emulsion, 8~10 parts of cyclodextrine derivatives, 0.01~0.02 part of cellulase, 5~6 parts of modified glass-fibers,
180~200 water, 5~6 parts of polystyrene emulsions；
The preparation process of the modified glass-fiber is：
（1）Count in parts by weight, by 10~20 parts of nano silicons, 20~40 parts of silane couplers and 80~100 parts of ethanol
Solution is stirred reaction, then filtered, washing and dries, and obtains modified manometer silicon dioxide, then by gained modified nano-silica
SiClx is 1 in mass ratio with absolute ethyl alcohol：90~1：100 ultrasonic disperses, obtain modified manometer silicon dioxide dispersion liquid；
（2）It is 1 in mass ratio by glass fibre and modified manometer silicon dioxide dispersion liquid：15~1：20 are mixed with dipping, then will leaching
Glass fibre drying after stain obtains impregnated glass fiber to constant weight；
（3）It is 1 in mass ratio by impregnated glass fiber and dopamine solution：50~1：100 mixing immersions, then by the glass after immersion
Glass fiber drying obtains modified glass-fiber to constant weight；
The preparation process of the special paper tube adhesive of paper is：Each raw material is weighed by raw material composition, first polyvinyl alcohol, cyclodextrin spread out
Biology and water are stirred, and add polyvinyl acetate emulsion, cellulase, modified glass fibre peacekeeping polystyrene emulsion is stirred
Mixing is mixed, produces the special paper tube adhesive of paper.
The polyvinyl acetate emulsion solid content is 20~30%.
The cyclodextrine derivatives are alpha-cyclodextrin, any one in beta-schardinger dextrin or gamma-cyclodextrin.
Step（1）The silane coupler model silane resin acceptor kh-550, silane coupler KH-560 or silane are even
Join any one in agent KH-570.
Step（1）The ethanol solution mass fraction is 40~50%.
Step（2）The glass fibre is ultra-fine fibre glass；The ultra-fine fibre glass length is 10~14 μm, diameter
For 2~4 μm.
The polystyrene emulsion solid content is 20~30%.
The beneficial effects of the invention are as follows：
（1）Technical solution of the present invention is by adding cellulase, in use, due to cellulase have high efficiency and specially
One property, so the cellulose on decomposable asymmetric choice net paper surface, cellulose be by glucose group into macromolecular polysaccharide, in decomposable process,
C―O bond cleavage in cellulose, generate small molecule glucose, on the one hand, enrich the porosity on paper surface so that modified glass
Glass fiber is easier in embedded paper, strengthens the adhesion strength of system, and on the other hand, paper surface has more polyhydroxy, can be in poly-
Vinyl alcohol forms stable chemical bonding, strengthens the adhesion strength of system；
（2）Technical solution of the present invention is by adding nano-silicon dioxide modified glass fibre, and it is special it is scattered in paper
In paper tube adhesive system, after modified, adsorption nano silicon, roughness is improved glass fibre, between fiber
Mechanical snap power is improved, so as to improve the stability after binding agent solidification, in addition, during hot pressing use, on the one hand,
The nano silicon activity of adsorption is higher, and the glucose after being decomposed first with paper surface fiber element chemically reacts,
Chemical bonding is formed, during the course of the reaction, segment glass fiber also assists in wherein, further improves the adhesion strength of product, separately
On the one hand so that in segment glass fiber both ends insertion paper fiber, further improve the adhesion strength of product；
（3）Technical solution of the present invention after modified, is soaked with dopamine solution be modified again, add glass by glass fibre
The active group of fiber surface so that glass fibre forms stable chemical bonding with paper hydroxyl, further improves product
Adhesion strength.
Embodiment
Count in parts by weight, by 10~20 parts of nano silicons, 20~40 parts of silane couplers and 80~100 parts of ethanol
Solution is added in beaker, under the conditions of 400~500r/min of rotating speed, is stirred 40~50min of reaction, obtains mixed liquor, then will
Gained mixed liquor filters, and obtains filter cake, and washs filter cake 3~5 times with absolute ethyl alcohol, obtains wet stock, is then placed in wet stock very
30~40min is dried in vacuum freecing-dry case, obtains modified manometer silicon dioxide, then by gained modified manometer silicon dioxide and nothing
Water-ethanol is 1 in mass ratio：90~1：100 move to ultrasonic disperse instrument, under the conditions of supersonic frequency is 70~85kHz, ultrasound point
20~30min is dissipated, obtains modified manometer silicon dioxide dispersion liquid；Glass fibre and modified manometer silicon dioxide dispersion liquid are pressed into quality
Than for 1：15~1：20 are mixed with dipping 4~5h, obtain impregnated glass fiber, by impregnated glass fiber and dopamine solution in mass ratio
For 1：50~1：100 are transferred in single-necked flask, under the conditions of 400~500r/min of rotating speed, are stirred 40~50min of immersion,
Glass fibre must be soaked, immersion glass fibre is then moved into thermostatic drying chamber, freeze-day with constant temperature to constant weight, produces modified glass fibre
Dimension；Count in parts by weight, take 50~60 parts of polyvinyl alcohol, 10~20 parts of polyvinyl acetate emulsions, 8~10 parts of cyclodextrin successively
Derivative, 0.01~0.02 part of cellulase, 5~6 parts of modified glass-fibers, 180~200 parts of water, 5~6 parts of polystyrene breasts
Liquid, first polyvinyl alcohol, cyclodextrine derivatives and water are added in batch mixer, under the conditions of 1200~1300r/min of rotating speed at a high speed
40~50min is stirred, then polyvinyl acetate emulsion is added into batch mixer, cellulase, modified glass fibre peacekeeping gathers
Styrene emulsion, continue high-speed stirred 40~50min of mixing under the conditions of 1200~1300r/min of rotating speed, it is special to produce paper
Paper tube adhesive.The polyvinyl acetate emulsion solid content is 20~30%.The cyclodextrine derivatives are alpha-cyclodextrin, and β-ring is pasted
Essence or gamma-cyclodextrin in any one.The silane coupler model silane resin acceptor kh-550, silane coupler KH-
560 or Silane coupling reagent KH-570 in any one.The ethanol solution mass fraction is 40~50%.The glass fibre
For ultra-fine fibre glass；The ultra-fine fibre glass length is 10~14 μm, a diameter of 2~4 μm.The polystyrene emulsion is consolidated
Content is 20~30%.
Example 1
Count in parts by weight, by 20 parts of nano silicons, 40 parts of silane couplers and 100 parts of ethanol solutions are added in beaker,
Under the conditions of rotating speed 500r/min, reaction 50min is stirred, obtains mixed liquor, then gained mixed liquor is filtered, obtain filter cake, and
Filter cake is washed with absolute ethyl alcohol 5 times, obtains wet stock, wet stock then is placed in into vacuum freezing drying oven is dried 40min, obtains
Modified manometer silicon dioxide, then by gained modified manometer silicon dioxide and absolute ethyl alcohol be 1 in mass ratio：100 move to ultrasound point
Instrument is dissipated, under the conditions of supersonic frequency is 85kHz, ultrasonic disperse 30min, obtains modified manometer silicon dioxide dispersion liquid；By glass fibers
Dimension is 1 in mass ratio with modified manometer silicon dioxide dispersion liquid：20 are mixed with dipping 5h, obtain impregnated glass fiber, will impregnate glass
Fiber is 1 in mass ratio with dopamine solution：100 are transferred in single-necked flask, under the conditions of rotating speed 500r/min, are stirred leaching
50min is steeped, obtains immersion glass fibre, immersion glass fibre is then moved into thermostatic drying chamber, freeze-day with constant temperature to constant weight, produces and changes
Property glass fibre；Count in parts by weight, take 60 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate emulsions successively, 10 parts of cyclodextrin spread out
Biology, 0.02 part of cellulase, 6 parts of modified glass-fibers, 200 parts of water, 6 parts of polystyrene emulsions, first by polyvinyl alcohol, ring paste
Smart derivative and water are added in batch mixer, and high-speed stirred mixes 50min under the conditions of rotating speed 1300r/min, then into batch mixer
Add polyvinyl acetate emulsion, cellulase, modified glass fibre peacekeeping polystyrene emulsion, in rotating speed 1300r/min conditions
Lower continuation high-speed stirred mixing 50min, produces the special paper tube adhesive of paper.The polyvinyl acetate emulsion solid content is 30%.Institute
It is alpha-cyclodextrin to state cyclodextrine derivatives.The silane coupler model silane resin acceptor kh-550.The ethanol solution matter
It is 50% to measure fraction.The glass fibre is ultra-fine fibre glass；The ultra-fine fibre glass length is 14 μm, a diameter of 4 μm.
The polystyrene emulsion solid content is 30%.
Example 2
Count in parts by weight, by 20 parts of nano silicons, 40 parts of silane couplers and 100 parts of ethanol solutions are added in beaker,
Under the conditions of rotating speed 500r/min, reaction 50min is stirred, obtains mixed liquor, then gained mixed liquor is filtered, obtain filter cake, and
Filter cake is washed with absolute ethyl alcohol 5 times, obtains wet stock, wet stock then is placed in into vacuum freezing drying oven is dried 40min, obtains
Modified manometer silicon dioxide, then by gained modified manometer silicon dioxide and absolute ethyl alcohol be 1 in mass ratio：100 move to ultrasound point
Instrument is dissipated, under the conditions of supersonic frequency is 85kHz, ultrasonic disperse 30min, obtains modified manometer silicon dioxide dispersion liquid；By glass fibers
Dimension is 1 in mass ratio with modified manometer silicon dioxide dispersion liquid：20 are mixed with dipping 5h, obtain impregnated glass fiber, will impregnate glass
Fiber is 1 in mass ratio with dopamine solution：100 are transferred in single-necked flask, under the conditions of rotating speed 500r/min, are stirred leaching
50min is steeped, obtains immersion glass fibre, immersion glass fibre is then moved into thermostatic drying chamber, freeze-day with constant temperature to constant weight, produces and changes
Property glass fibre；Count in parts by weight, take 60 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate emulsions successively, 10 parts of cyclodextrin spread out
Biology, 6 parts of modified glass-fibers, 200 parts of water, 6 parts of polystyrene emulsions, first polyvinyl alcohol, cyclodextrine derivatives and water are added
Enter in batch mixer, high-speed stirred mixes 50min under the conditions of rotating speed 1300r/min, then polyvinyl acetate is added into batch mixer
Ester emulsion, modified glass fibre peacekeeping polystyrene emulsion, continue high-speed stirred mixing 50min under the conditions of rotating speed 1300r/min,
Produce the special paper tube adhesive of paper.The polyvinyl acetate emulsion solid content is 30%.The cyclodextrine derivatives are α-ring paste
Essence.The silane coupler model silane resin acceptor kh-550.The ethanol solution mass fraction is 50%.The glass fibers
Tie up as ultra-fine fibre glass；The ultra-fine fibre glass length is 14 μm, a diameter of 4 μm.The polystyrene emulsion solid content
For 30%.
Example 3
Count in parts by weight, take 60 parts of polyvinyl alcohol successively, 20 parts of polyvinyl acetate emulsions, 10 parts of cyclodextrine derivatives,
0.02 part of cellulase, 6 parts of glass fibres, 200 parts of water, 6 parts of polystyrene emulsions, first by polyvinyl alcohol, cyclodextrine derivatives
Added with water in batch mixer, high-speed stirred mixes 50min under the conditions of rotating speed 1300r/min, then poly-vinegar is added into batch mixer
Vinyl acetate emulsion, cellulase, glass fibre and polystyrene emulsion, continue high-speed stirring under the conditions of rotating speed 1300r/min
Mixing 50min is mixed, produces the special paper tube adhesive of paper.The polyvinyl acetate emulsion solid content is 30%.The cyclodextrin derives
Thing is alpha-cyclodextrin.The silane coupler model silane resin acceptor kh-550.The ethanol solution mass fraction is 50%.
The glass fibre is ultra-fine fibre glass；The ultra-fine fibre glass length is 14 μm, a diameter of 4 μm.The polystyrene
Emulsion solid content is 30%.
Example 4
Count in parts by weight, by 20 parts of nano silicons, 40 parts of silane couplers and 100 parts of ethanol solutions are added in beaker,
Under the conditions of rotating speed 500r/min, reaction 50min is stirred, obtains mixed liquor, then gained mixed liquor is filtered, obtain filter cake, and
Filter cake is washed with absolute ethyl alcohol 5 times, obtains wet stock, wet stock then is placed in into vacuum freezing drying oven is dried 40min, obtains
Modified manometer silicon dioxide, then by gained modified manometer silicon dioxide and absolute ethyl alcohol be 1 in mass ratio：100 move to ultrasound point
Instrument is dissipated, under the conditions of supersonic frequency is 85kHz, ultrasonic disperse 30min, obtains modified manometer silicon dioxide dispersion liquid；By glass fibers
Dimension is 1 in mass ratio with modified manometer silicon dioxide dispersion liquid：20 are mixed with dipping 5h, obtain impregnated glass fiber, then will dipping
Glass fibre moves to thermostatic drying chamber, freeze-day with constant temperature to constant weight, produces modified glass-fiber；Count in parts by weight, take 60 successively
Part polyvinyl alcohol, 20 parts of polyvinyl acetate emulsions, 10 parts of cyclodextrine derivatives, 0.02 part of cellulase, 6 parts of modified glass fibres
Dimension, 200 parts of water, 6 parts of polystyrene emulsions, first polyvinyl alcohol, cyclodextrine derivatives and water are added in batch mixer, in rotating speed
High-speed stirred mixes 50min under the conditions of 1300r/min, then polyvinyl acetate emulsion is added into batch mixer, cellulase, changes
Property glass fibre and polystyrene emulsion, continue high-speed stirred mixing 50min under the conditions of rotating speed 1300r/min, produce paper
Special paper tube adhesive.The polyvinyl acetate emulsion solid content is 30%.The polyvinyl acetate emulsion solid content is 30%.Institute
It is alpha-cyclodextrin to state cyclodextrine derivatives.The silane coupler model silane resin acceptor kh-550.The ethanol solution matter
It is 50% to measure fraction.The glass fibre is ultra-fine fibre glass；The ultra-fine fibre glass length is 14 μm, a diameter of 4 μm.
The polystyrene emulsion solid content is 30%.
Example 5
Count in parts by weight, by 20 parts of nano silicons, 40 parts of silane couplers and 100 parts of ethanol solutions are added in beaker,
Under the conditions of rotating speed 500r/min, reaction 50min is stirred, obtains mixed liquor, then gained mixed liquor is filtered, obtain filter cake, and
Filter cake is washed with absolute ethyl alcohol 5 times, obtains wet stock, wet stock then is placed in into vacuum freezing drying oven is dried 40min, obtains
Modified manometer silicon dioxide, then by gained modified manometer silicon dioxide and absolute ethyl alcohol be 1 in mass ratio：100 move to ultrasound point
Instrument is dissipated, under the conditions of supersonic frequency is 85kHz, ultrasonic disperse 30min, obtains modified manometer silicon dioxide dispersion liquid；By glass fibers
Dimension is 1 in mass ratio with modified manometer silicon dioxide dispersion liquid：20 are mixed with dipping 5h, obtain impregnated glass fiber, will impregnate glass
Fiber is 1 in mass ratio with dopamine solution：100 are transferred in single-necked flask, under the conditions of rotating speed 500r/min, are stirred leaching
50min is steeped, obtains immersion glass fibre, immersion glass fibre is then moved into thermostatic drying chamber, freeze-day with constant temperature to constant weight, produces and changes
Property glass fibre；Count in parts by weight, take 60 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate emulsions successively, 10 parts of cyclodextrin spread out
Biology, 0.02 part of cellulase, 6 parts of modified glass-fibers, 200 parts of water, 6 parts of polystyrene emulsions, first by polyvinyl alcohol, ring paste
Smart derivative and water are added in batch mixer, and high-speed stirred mixes 50min under the conditions of rotating speed 1300r/min, then into batch mixer
Add polyvinyl acetate emulsion, cellulase, modified glass fibre peacekeeping polystyrene emulsion, in rotating speed 1300r/min conditions
Lower continuation high-speed stirred mixing 50min, produces the special paper tube adhesive of paper.The polyvinyl acetate emulsion solid content is 30%.Institute
It is alpha-cyclodextrin to state cyclodextrine derivatives.The silane coupler model silane resin acceptor kh-550.The ethanol solution matter
It is 50% to measure fraction.The glass fibre is simple glass fiber.The polystyrene emulsion solid content is 30%.
Comparative example：The paper tube adhesive of Gaoyou City's paper tube adhesive process plants.
The special paper tube adhesive of paper of the gained of example 1 to 5 and comparative example product are subjected to performance detection, specific detection method is such as
Under：
1. viscosity：Determined with rotation viscometer at 30 DEG C by GB2794 assay methods.
2. adhesive strength：Take 25mm × 100mm pipe crimping paper two to open, one layer of paper tube is uniformly brushed by one therein
Glue, then bond with another a piece of paper, peeled off after being rolled one time, 30 seconds with rubber roll immediately, it was observed that paper fiber is all destroyed is
It is qualified.
Specific testing result is as shown in table 1：
Table 1
| Detection project | Viscosity（30℃）/mPa·s | Adhesion strength |
| Example 1 | 21304 | Paper fiber is torn after pipe crimping paper/pipe crimping paper bonding after 30S to destroy entirely |
| Example 2 | 20139 | Paper fiber is torn after pipe crimping paper/pipe crimping paper bonding after 30S to destroy entirely |
| Example 3 | 18465 | Paper fiber is torn after pipe crimping paper/pipe crimping paper bonding after 30S to destroy entirely |
| Example 4 | 17942 | 30S tears paper fiber and destroyed entirely after pipe crimping paper/pipe crimping paper bonding, but can not be used after less than 15 DEG C gels, loses viscosity |
| Example 5 | 18034 | 30S tears paper fiber and destroyed entirely after pipe crimping paper/pipe crimping paper bonding, but can not be used after less than 15 DEG C gels, loses viscosity |
| Comparative example | 15084 | 30S tears paper fiber partial destruction after pipe crimping paper/pipe crimping paper bonding, but can not be used after less than 15 DEG C gels, loses viscosity |
From the testing result of table 1, the special paper tube adhesive of paper prepared by technical solution of the present invention has excellent adhesive property
Feature, it is applied in broader field has facilitation with development.
Claims (7)
- A kind of 1. special paper tube adhesive of paper, it is characterised in that：It is made up of the raw material of following parts by weight：50~60 parts of polyethylene Alcohol, 10~20 parts of polyvinyl acetate emulsions, 8~10 parts of cyclodextrine derivatives, 0.01~0.02 part of cellulase, 5~6 parts change Property glass fibre, 180~200 water, 5~6 parts of polystyrene emulsions；The preparation process of the modified glass-fiber is：（1）Count in parts by weight, by 10~20 parts of nano silicons, 20~40 parts of silane couplers and 80~100 parts of ethanol Solution is stirred reaction, then filtered, washing and dries, and obtains modified manometer silicon dioxide, then by gained modified nano-silica SiClx is 1 in mass ratio with absolute ethyl alcohol：90~1：100 ultrasonic disperses, obtain modified manometer silicon dioxide dispersion liquid；（2）It is 1 in mass ratio by glass fibre and modified manometer silicon dioxide dispersion liquid：15~1：20 are mixed with dipping, then will leaching Glass fibre drying after stain obtains impregnated glass fiber to constant weight；（3）It is 1 in mass ratio by impregnated glass fiber and dopamine solution：50~1：100 mixing immersions, then by the glass after immersion Glass fiber drying obtains modified glass-fiber to constant weight；The preparation process of the special paper tube adhesive of paper is：Each raw material is weighed by raw material composition, first polyvinyl alcohol, cyclodextrin spread out Biology and water are stirred, and add polyvinyl acetate emulsion, cellulase, modified glass fibre peacekeeping polystyrene emulsion is stirred Mixing is mixed, produces the special paper tube adhesive of paper.
- A kind of 2. special paper tube adhesive of paper according to claim 1, it is characterised in that：The polyvinyl acetate emulsion contains admittedly Measure as 20~30%.
- A kind of 3. special paper tube adhesive of paper according to claim 1, it is characterised in that：The cyclodextrine derivatives are α-ring paste Any one in essence, beta-schardinger dextrin or gamma-cyclodextrin.
- A kind of 4. special paper tube adhesive of paper according to claim 1, it is characterised in that：Step（1）The silane coupled formulation Number it is silane resin acceptor kh-550, any one in silane coupler KH-560 or Silane coupling reagent KH-570.
- A kind of 5. special paper tube adhesive of paper according to claim 1, it is characterised in that：Step（1）The ethanol solution quality Fraction is 40~50%.
- A kind of 6. special paper tube adhesive of paper according to claim 1, it is characterised in that：Step（2）The glass fibre is super Thin glass fiber；The ultra-fine fibre glass length is 10~14 μm, a diameter of 2~4 μm.
- A kind of 7. special paper tube adhesive of paper according to claim 1, it is characterised in that：The polystyrene emulsion solid content is 20~30%.
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| CN201710873680.1A CN107556946A (en) | 2017-09-25 | 2017-09-25 | A kind of special paper tube adhesive of paper |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710873680.1A CN107556946A (en) | 2017-09-25 | 2017-09-25 | A kind of special paper tube adhesive of paper |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110228731A (en) * | 2019-06-27 | 2019-09-13 | 福建省三丰纺织器材有限公司 | A kind of FDY paper tube and preparation with improvement unwinding effect and paper tube performance |
| CN112252629A (en) * | 2020-10-26 | 2021-01-22 | 李汉军 | Lime-batching-free indoor blank wall surface treatment construction method |
| CN113699794A (en) * | 2020-05-21 | 2021-11-26 | 南通碧辉石业有限公司 | Modification method for toughened marble back-adhered fiber mesh cloth |
| US20220106508A1 (en) * | 2018-10-05 | 2022-04-07 | Rockwool International A/S | Aqueous binder composition |
| CN115627656A (en) * | 2022-10-12 | 2023-01-20 | 江苏中凯纸业有限公司 | High-strength flame-retardant bobbin paper and preparation method thereof |
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| CN101402835A (en) * | 2008-01-25 | 2009-04-08 | 盐城华贸包装有限公司 | White latex adhesive agent for packaging paper product and method of producing the same |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20220106508A1 (en) * | 2018-10-05 | 2022-04-07 | Rockwool International A/S | Aqueous binder composition |
| CN110228731A (en) * | 2019-06-27 | 2019-09-13 | 福建省三丰纺织器材有限公司 | A kind of FDY paper tube and preparation with improvement unwinding effect and paper tube performance |
| CN113699794A (en) * | 2020-05-21 | 2021-11-26 | 南通碧辉石业有限公司 | Modification method for toughened marble back-adhered fiber mesh cloth |
| CN112252629A (en) * | 2020-10-26 | 2021-01-22 | 李汉军 | Lime-batching-free indoor blank wall surface treatment construction method |
| CN115627656A (en) * | 2022-10-12 | 2023-01-20 | 江苏中凯纸业有限公司 | High-strength flame-retardant bobbin paper and preparation method thereof |
| CN115627656B (en) * | 2022-10-12 | 2023-08-18 | 江苏中凯纸业有限公司 | High-strength flame-retardant bobbin paper and preparation method thereof |
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